JPH04126748A - Low-smoking resin composition and sheet containing the same - Google Patents
Low-smoking resin composition and sheet containing the sameInfo
- Publication number
- JPH04126748A JPH04126748A JP24786390A JP24786390A JPH04126748A JP H04126748 A JPH04126748 A JP H04126748A JP 24786390 A JP24786390 A JP 24786390A JP 24786390 A JP24786390 A JP 24786390A JP H04126748 A JPH04126748 A JP H04126748A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- chloride resin
- resin composition
- smoke
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims description 30
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000000463 material Substances 0.000 claims abstract description 32
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920005989 resin Polymers 0.000 claims abstract description 24
- 239000011347 resin Substances 0.000 claims abstract description 24
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 16
- 239000011787 zinc oxide Substances 0.000 claims abstract description 14
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 13
- 238000009408 flooring Methods 0.000 claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000010410 layer Substances 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 239000002344 surface layer Substances 0.000 claims 1
- 239000000779 smoke Substances 0.000 abstract description 37
- 239000000203 mixture Substances 0.000 abstract description 19
- 238000002485 combustion reaction Methods 0.000 abstract description 13
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002245 particle Substances 0.000 abstract description 5
- 239000001361 adipic acid Substances 0.000 abstract description 4
- 235000011037 adipic acid Nutrition 0.000 abstract description 4
- 150000002148 esters Chemical class 0.000 abstract description 4
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000003063 flame retardant Substances 0.000 description 6
- -1 phthalate ester Chemical class 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000002542 deteriorative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 239000000347 magnesium hydroxide Substances 0.000 description 2
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- DHZSIQDUYCWNSB-UHFFFAOYSA-N chloroethene;1,1-dichloroethene Chemical compound ClC=C.ClC(Cl)=C DHZSIQDUYCWNSB-UHFFFAOYSA-N 0.000 description 1
- KRGNPJFAKZHQPS-UHFFFAOYSA-N chloroethene;ethene Chemical group C=C.ClC=C KRGNPJFAKZHQPS-UHFFFAOYSA-N 0.000 description 1
- HGAZMNJKRQFZKS-UHFFFAOYSA-N chloroethene;ethenyl acetate Chemical compound ClC=C.CC(=O)OC=C HGAZMNJKRQFZKS-UHFFFAOYSA-N 0.000 description 1
- NBXMMTVKODTVSL-UHFFFAOYSA-N chloroethene;prop-1-ene Chemical group CC=C.ClC=C NBXMMTVKODTVSL-UHFFFAOYSA-N 0.000 description 1
- GRFFKYTUNTWAGG-UHFFFAOYSA-N chloroethene;prop-2-enenitrile Chemical compound ClC=C.C=CC#N GRFFKYTUNTWAGG-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000000644 propagated effect Effects 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、燃焼時に発生する発煙量を著しく低減化した
塩化ビニル系樹脂組成物、及び該組成物を使用した壁紙
類、床材類に関する。Detailed Description of the Invention <Industrial Application Field> The present invention relates to a vinyl chloride resin composition that significantly reduces the amount of smoke generated during combustion, and wallpapers and flooring materials using the composition. .
〈従来の技術及び問題点〉
塩化ビニル系樹脂は物性、加工性、コスト等が優れるた
め各種建材、電線被覆材料、日用品、玩具、室内装飾品
等あらゆる分野で汎用されている。<Prior Art and Problems> Vinyl chloride resins have excellent physical properties, processability, cost, etc., and are therefore widely used in various fields such as various building materials, wire coating materials, daily necessities, toys, and interior decoration products.
塩化ビニル系樹脂は他の樹脂に比較して燃焼時の発煙量
が多いため、火災時に於いて遊離誘導や消火活動に支障
をきたす難点があった。Vinyl chloride resins emit a large amount of smoke when burned compared to other resins, so they have the disadvantage of inducing release and hindering fire extinguishing efforts in the event of a fire.
一般に、塩化ビニル系樹脂の難燃化には適量の三酸化ア
ンチモンまたは、マグネシウム、アルミニウム等の水和
物を高充填配合する方法等が良く知られている。しかし
、前記の難燃化方法では、塩化ビニル系樹脂組成物の燃
焼時の発煙量を大幅に低減化することはできない。Generally, methods of blending a suitable amount of antimony trioxide or hydrates of magnesium, aluminum, etc. in high amounts are well known for making vinyl chloride resins flame retardant. However, the above-mentioned flame retardant method cannot significantly reduce the amount of smoke emitted when a vinyl chloride resin composition is burned.
特開平１−２９７４４８号には、酸化亜鉛、多価アルコ
ール系化合物、三酸化アンチモンを併用配合することを
特徴とした低発煙性塩化ビニル樹脂組成物が開示されて
いる。しかし、燃焼時の発煙量を更に低くする技術の開
発が望まれている。JP-A-1-297448 discloses a low-smoking vinyl chloride resin composition characterized by containing zinc oxide, a polyhydric alcohol compound, and antimony trioxide in combination. However, it is desired to develop a technology that further reduces the amount of smoke emitted during combustion.
特に電線、壁紙、床材用途に於いては要求が強い。Demand is especially strong for electrical wires, wallpaper, and flooring applications.
〈発明が解決しようとする課題〉
本発明の課題は、燃焼時の発煙量を著しく低減化させた
、難燃性低発煙性塩化ビニル系樹脂組成。<Problems to be Solved by the Invention> An object of the present invention is to provide a flame-retardant, low-smoke vinyl chloride resin composition that significantly reduces the amount of smoke emitted during combustion.
物を提供し、前記の技術的問題を解決することである。The goal is to provide products and solve the aforementioned technical problems.
く課題を解決するための手段〉
本発明者は前記の課題を達成するため鋭意研究を重ね、
塩化ビニル系樹脂組成物に減産効果のある化合物を配合
することにより、燃焼時の発煙量を著しく低減化させた
塩化ビニル系樹脂組成物を見い出した。さらに該組成物
を、基材と接着した樹脂層または裏打ち材として用い、
低１４性ビニル壁紙類や低発煙性床材類を開発し本発明
を完成させた。Means for Solving the Problems> In order to achieve the above problems, the present inventor has conducted extensive research,
By blending a compound with a production-reducing effect into a vinyl chloride resin composition, we have discovered a vinyl chloride resin composition that significantly reduces the amount of smoke emitted during combustion. Further, the composition is used as a resin layer or backing material adhered to a base material,
The present invention was completed by developing low-14-density vinyl wallpapers and low-smoke flooring materials.
即ち本発明の低発煙性塩化ビニル系樹脂組成物は、塩化
ビニル系樹脂１００ｆｉ量部に対し、酸化亜鉛を０．
５〜３０重量部と多価アルコール系化合物を０．０５〜
２０１ｉ量部、及び水酸化アルミニウムを２〜２００重
量部配重量部口とを特徴としている。That is, the low-smoking vinyl chloride resin composition of the present invention contains 0.00 parts of zinc oxide per 100 parts of vinyl chloride resin.
5-30 parts by weight and 0.05-30 parts of polyhydric alcohol compound
201i parts by weight, and 2 to 200 parts by weight of aluminum hydroxide.
本発明の低発煙性壁紙類は該低発煙性塩化ビニル系樹脂
組成物を紙、布等の基材に接着してなることを特徴とし
ている。The low smoke-emitting wallpaper of the present invention is characterized in that the low-smoke vinyl chloride resin composition is adhered to a base material such as paper or cloth.
本発明の低発煙性床材類は、該但発煙性塩化ビニル系樹
脂組成物を裏打ち材として用いることを特徴としている
。The low smoke emitting flooring material of the present invention is characterized in that the smoke emitting vinyl chloride resin composition is used as a backing material.
本発明に使用される塩化ビニル系樹脂は塩化ビニル単独
重合体または塩化ビニルを概ね５０％以上含む共重合体
である。例えば、塩化ビニル−塩化ビニリデン、塩化ビ
ニル−アクリルニトリル、塩化ビニル−酢酸ビニル、塩
化ビニル−エチレン−酢酸ビニル、塩化ビニル−エチレ
ン、塩化ビニル−プロピレン等である。共重合体として
は、ランダム共重合体、ブロック共重合体、グラフト共
重合体の何れでも良い。塩化ビニル系樹脂の重合度及び
粒径の大小は特に問わず、通常の市販品であれば良い。The vinyl chloride resin used in the present invention is a vinyl chloride homopolymer or a copolymer containing approximately 50% or more of vinyl chloride. Examples include vinyl chloride-vinylidene chloride, vinyl chloride-acrylonitrile, vinyl chloride-vinyl acetate, vinyl chloride-ethylene-vinyl acetate, vinyl chloride-ethylene, vinyl chloride-propylene, and the like. The copolymer may be a random copolymer, a block copolymer, or a graft copolymer. The polymerization degree and particle size of the vinyl chloride resin are not particularly limited, and any ordinary commercially available product may be used.
本発明に使用される酸化亜鉛は粒径が０． ２〜２０μ
ｍ程度で通常の市販品で良い。配合量は塩化ビニル系樹
脂１００］ｉ１部に対し０． ５〜３０重量部であり、
より好ましくは、１〜１５重量部である。酸化亜鉛の配
合量が０．５重１部以下では燃焼時の発煙量低減化効果
が小さく、１５重量・部以上では燃焼時の発煙量低減化
効果の伸びが小さい。The zinc oxide used in the present invention has a particle size of 0. 2~20μ
Normal commercially available products with a length of about m are sufficient. The blending amount is 0.00% for 1 part of vinyl chloride resin 100]i. 5 to 30 parts by weight,
More preferably, it is 1 to 15 parts by weight. If the amount of zinc oxide is less than 0.5 parts by weight, the effect of reducing the amount of smoke generated during combustion will be small, and if the amount is more than 15 parts by weight, the effect of reducing the amount of smoke generated during combustion will be small.
本発明に使用される多価アルコール系化合物はペンタエ
リスリトール、ジペンタエリスリトール、トリペンタエ
リスリトール等から少なくとも一種を含む多価アルコー
ル。または該多価アルコールと酢酸、プロピオン酸等の
一価のカルボン酸やアジピン酸、グルタミン酸等の二価
のカルボン酸との部分エステルであって、その分子中に
一個以上の水−基を持つ化合物であれば良い、この場合
の多価アルコール系化合物は、多価アルコールまたは多
価アルコールと有機酸との部分エステルを各々単独かま
たは、これらの混合物であっても良い。The polyhydric alcohol compound used in the present invention is a polyhydric alcohol containing at least one selected from pentaerythritol, dipentaerythritol, tripentaerythritol, and the like. Or a partial ester of the polyhydric alcohol with a monovalent carboxylic acid such as acetic acid or propionic acid or a divalent carboxylic acid such as adipic acid or glutamic acid, which has one or more water groups in its molecule. The polyhydric alcohol compound in this case may be a single polyhydric alcohol or a partial ester of a polyhydric alcohol and an organic acid, or a mixture thereof.
配合量は、塩化ビニル系樹脂１００重量部に対し０．０
５〜２０重量部であり、より好ましくは塩化ビニル系樹
脂との相溶性の良い、ジペンタエリスリトールとアジピ
ン酸の部分エステルと多価アルコールとの混合物であっ
て、該混合物中の多価アルコールの含有率が１８〜８０
ｉｊ１％である混合物、例えば味の素側製ブレンライザ
ー５Ｔ−２・１０を０．０７〜７重量部である。多価ア
ルコール系化合物の配合量が０．０７重１部以下では、
塩化ビニル系樹脂組成物の熱に対する安定性が極めて悪
く、７重量部以上では塩化ビニル系樹脂組成物の加工性
がやや悪くなる。The blending amount is 0.0 parts by weight for 100 parts by weight of vinyl chloride resin.
5 to 20 parts by weight, more preferably a mixture of a partial ester of dipentaerythritol and adipic acid and a polyhydric alcohol, which has good compatibility with a vinyl chloride resin, wherein the amount of polyhydric alcohol in the mixture is 5 to 20 parts by weight. Content rate is 18-80
ij 1%, for example, 0.07 to 7 parts by weight of Brenlyzer 5T-2.10 manufactured by Ajinomoto. If the amount of polyhydric alcohol compound is 0.07 parts by weight or less,
The heat stability of the vinyl chloride resin composition is extremely poor, and if it exceeds 7 parts by weight, the processability of the vinyl chloride resin composition will be somewhat poor.
本発明に使用する水酸化アルミニウムは粒径が０．５〜
３０μｍ程度で通常の市販品であれば良い。また、チタ
ネート系カップリング剤等による表面処理品でも良い。The aluminum hydroxide used in the present invention has a particle size of 0.5 to
Any ordinary commercially available product with a thickness of about 30 μm is sufficient. Moreover, a surface-treated product using a titanate coupling agent or the like may also be used.
配合量は塩化ビニル系樹脂１００重量部に対し２〜２０
０重量部である。The blending amount is 2 to 20 parts by weight per 100 parts by weight of vinyl chloride resin.
It is 0 parts by weight.
配合量が２重量部以下では塩化ビニル系樹脂組成物の燃
焼時の発煙量低減化効果が小さく、２００重量部以上で
は塩化ビニル系樹脂の物性低下が懸念され、好ましくは
２０〜１８０重量部である。If the amount is less than 2 parts by weight, the effect of reducing the amount of smoke generated during combustion of the vinyl chloride resin composition will be small, and if it is more than 200 parts by weight, there is a concern that the physical properties of the vinyl chloride resin will deteriorate, so preferably 20 to 180 parts by weight. be.
本発明の塩化ビニル系樹脂組成物は必要に応じて可塑剤
、例えばフタル酸ジオクチル、フタル酸ジイソデシル等
のフタル酸エステル系、アジビン酸ジオクチル、セバシ
ン酸ジオクチル等の脂肪酸エステル系、アジピン酸ポリ
エステル１．フタル酸ポリエステル等のポリエステル系
、トリクレジルホスフェート、オクチルジフェニルホス
フェート等のりん酸エステル、エポキシ化大豆油、塩素
化脂肪酸エステル、塩素化パラフィン等の単独または二
種以上とを併用しても構わない。The vinyl chloride resin composition of the present invention may optionally contain a plasticizer, such as a phthalate ester such as dioctyl phthalate or diisodecyl phthalate, a fatty acid ester such as dioctyl adibate or dioctyl sebacate, or a polyester adipic acid. Polyesters such as phthalic acid polyesters, phosphate esters such as tricresyl phosphate and octyl diphenyl phosphate, epoxidized soybean oil, chlorinated fatty acid esters, chlorinated paraffins, etc. may be used alone or in combination of two or more. .
更に安定剤、難燃剤、抗酸化剤、滑剤、無機充填剤、着
色剤、発泡剤、防かび剤等の各種添加剤を配合しても何
ら構わない。Furthermore, various additives such as stabilizers, flame retardants, antioxidants, lubricants, inorganic fillers, colorants, foaming agents, and fungicides may be added.
本発明のビニル壁紙類は、該低発煙性塩化ビニル系樹脂
組成物からなる樹脂層と難燃紙、布等の基材を裏打ち材
として貼り合わせた構造である。The vinyl wallpaper of the present invention has a structure in which a resin layer made of the low-smoking vinyl chloride resin composition and a base material such as flame-retardant paper or cloth are bonded together as a backing material.
その際、樹脂層の発泡状態や、その表面の模様、着色等
については何ら制限されない。At that time, there are no restrictions on the foaming state of the resin layer, the pattern on its surface, coloring, etc.
本発明の床材類は、例えば図−１及び図−２に示す１の
裏打ち材部分に該低発煙性塩化ビニル系樹脂組成物を利
用したものであって、裏打ち材に不織布等をラミネート
し、強度を付与させた構造でも良い。裏打ち材の厚さが
、１〜４ｍｍ程度であって、その上に０． １〜０．３
ｍｍの印刷層と０．２〜０．６ｍｍの透明樹脂層、更に
必要に応じて０．１〜０．３ｍｍのＵＶ硬化性樹脂等の
保護層等を積層しても良く、あるいは該裏打ち材をパイ
ル生地、例えば７５０〜８５０ｇ／ｃｍ２のナイロンパ
イルで表面を装飾した構造でも良い。The flooring materials of the present invention utilize the low smoke-emitting vinyl chloride resin composition for the backing material portion 1 shown in Figures 1 and 2, for example, and the backing material is laminated with a nonwoven fabric or the like. , a structure with added strength may be used. The thickness of the backing material is about 1 to 4 mm, and 0. 1-0.3
mm printing layer, 0.2 to 0.6 mm transparent resin layer, and if necessary, a 0.1 to 0.3 mm protective layer such as UV curable resin may be laminated, or the backing material It may also have a structure in which the surface is decorated with pile fabric, for example, nylon pile of 750 to 850 g/cm2.
〈作用〉
本発明の塩化ビニル系樹脂組成物は、熱安定性等の物性
低下を伴うことなく、燃焼時の発煙量が著しく低減する
。<Function> The vinyl chloride resin composition of the present invention significantly reduces the amount of smoke produced during combustion without deteriorating physical properties such as thermal stability.
本発明の壁紙類や床材類については、該低発煙性塩化ビ
ニル系樹脂組成物を用いるため、壁紙類や床材類の発煙
量が著しく低下する。Since the wallpapers and flooring materials of the present invention use the low smoke-emitting vinyl chloride resin composition, the amount of smoke emitted by the wallpapers and flooring materials is significantly reduced.
〈実施例〉
以下、実施例及び比較例により本発明を更に詳しく説明
する。これらの実施例は本発明を限定するものではない
。<Examples> Hereinafter, the present invention will be explained in more detail with reference to Examples and Comparative Examples. These examples are not intended to limit the invention.
〈実施例１〜５〉
表−１の配合Ｎｏ１〜５の配合物を６インチオーブンロ
ール（東洋精機■製）にて１６０ ’Ｃ１１０分間、前
ロール１１ ｒｐｍ後ロール１３．５ｒｐｍの回転数で
ロール混練し、厚さ約１ｍｍのシートを作製した。<Examples 1 to 5> The formulations No. 1 to 5 in Table 1 were rolled on a 6-inch oven roll (manufactured by Toyo Seiki) at 160'C for 110 minutes at a rotation speed of 11 rpm for the front roll and 13.5 rpm for the rear roll. The mixture was kneaded to produce a sheet with a thickness of about 1 mm.
次にこのシートを、プレス機で１６０℃５分間予熱後、
５分間１００ｋｇ／Ｃｍ２に加圧し、厚さ０．５ｍｍと
３ｍｍのシートにそれぞれ成型した。Next, after preheating this sheet in a press for 5 minutes at 160°C,
Pressure was applied to 100 kg/cm2 for 5 minutes and molded into sheets with thicknesses of 0.5 mm and 3 mm, respectively.
厚さ０．５ｍｍのシートは一辺が７６ｍｍの正方形に裁
断し、発煙量測定用試験片とした。該試験片は、発煙性
試験機の燃焼箱内に設置された燃焼炉により試験片表面
を一定輻射熱（２，５Ｗ／ｃｍ２）で加熱し、発生する
煙の量を光学的に測定するＮＢＳ発煙性試験機（東洋精
機■製）のノンフレーミング法により、発煙量Ｄｓを次
式に従い求めた。The sheet having a thickness of 0.5 mm was cut into a square having a side of 76 mm, and was used as a test piece for measuring smoke amount. The test piece was tested using NBS smoke generation, in which the surface of the test piece was heated with constant radiant heat (2.5 W/cm2) by a combustion furnace installed in the combustion box of a smoke generation tester, and the amount of smoke generated was optically measured. The amount of smoke Ds was determined using the non-flaming method using a sex tester (manufactured by Toyo Seiki ■) according to the following formula.
■
Ｄｓ＝ ｌｏｇｔｏ（Ｆｏ／Ｆ）Ｌ
式中の記号は以下の通り
ＤＳ： 比視覚密度
■ ＝燃焼箱の容積
Ａ ：試験片の表面積
Ｌ ：光路長
Ｆｏ：入射光量
Ｆ ：伝播光量
厚さ３ｍｍのシートは、ＪＩＳ Ｋ ７２０１に準
拠し酸素指数を測定した。■ Ds = logto(Fo/F)L The symbols in the formula are as follows: DS: Specific visual density ■ = Volume of combustion box A: Surface area of test piece L: Optical path length Fo: Incident light amount F: Propagated light amount Thickness: 3 mm The oxygen index of the sheet was measured in accordance with JIS K 7201.
またプレス成型する前のシートを約４Ｘ５ｃｍ程度に裁
断し、１８０ ”Ｃに調節したギヤーオーブン（東洋精
機■製）中で加熱した。この際黒褐色に変色するまでの
時間を測定し熱安定性の良否を判断した。In addition, the sheet before press molding was cut into approximately 4 x 5 cm and heated in a gear oven (manufactured by Toyo Seiki) adjusted to 180"C. At this time, the time until the color changed to blackish brown was measured and the thermal stability was determined. I decided whether it was good or bad.
得られた試験結果を表−１に示した。The test results obtained are shown in Table-1.
く比較例６〜１５〉
表−１の配合Ｎｏ６〜１５の配合物を実施例１〜５と同
様な操作を行い、得られた試験結果を表−１に示した。Comparative Examples 6 to 15> Comparisons Nos. 6 to 15 in Table 1 were subjected to the same operations as in Examples 1 to 5, and the test results obtained are shown in Table 1.
この結果、酸化亜鉛と水駿化アルミニウム及びブレンラ
イザー５Ｔ−２１０を併用配合した塩化ビニル樹脂組成
物は、何れも発煙量が低減し、がつ熱安定性が良好であ
った。しかし、ブレンライザー５Ｔ−２１０を配合しな
いで酸化亜鉛と水酸化アルミニウムを併用した塩化ビニ
ル樹脂組成物の発煙量は、ある程度低発煙化できるが、
熱安定性については極めて悪く実用性に欠ける。水酸化
アルミニウムを配合した塩化ビニル樹脂組成物は、重質
炭酸カルシウム、水酸化マグネシウムの場合に比較し、
難燃化と低発煙化傾向が見られた。As a result, all of the vinyl chloride resin compositions containing zinc oxide, aluminum hydroxide, and Blenlyzer 5T-210 had a reduced amount of smoke and good thermal stability. However, although the amount of smoke emitted by a vinyl chloride resin composition that uses zinc oxide and aluminum hydroxide in combination without blending Brenlyzer 5T-210 can be reduced to some extent,
Thermal stability is extremely poor and lacks practicality. Compared to heavy calcium carbonate and magnesium hydroxide, vinyl chloride resin compositions containing aluminum hydroxide have
A trend toward flame retardancy and low smoke emission was observed.
〈実施例１６〜１７＞
表−２の配合Ｎｏ、１６〜１７の配合物を石川式攪拌播
潰機（石川工場■製）にて３０分間混合攪拌し、難燃紙
（申越バルブ■製ＣＦ−７０ＹＮ）上に、壁紙重量が３
５０〜４００ｇ／ｍ２になるよう塗布した。次いで１５
０℃に調節したギヤーオーブンの中で１０分間加熱後、
更に２２０°Ｃに調節したギヤーオーブンの中で、３０
秒間加熱してビニル壁紙を試作した。この壁紙を１辺が
７６ｍｍの正方形に裁断後ＮＢＳ発煙性試験機のノンフ
レーミング法により、発煙量Ｄｓを測定した。<Examples 16 to 17> The formulations No. 16 to 17 in Table 2 were mixed and stirred for 30 minutes using an Ishikawa-type agitator and crusher (manufactured by Ishikawa Factory ■), and flame-retardant paper (manufactured by Shinetsu Bulb ■) was mixed and stirred for 30 minutes. CF-70YN), the wallpaper weight is 3
It was coated at a density of 50 to 400 g/m2. then 15
After heating for 10 minutes in a gear oven adjusted to 0℃,
Furthermore, in a gear oven adjusted to 220°C,
We made a prototype of vinyl wallpaper by heating it for a few seconds. This wallpaper was cut into squares with sides of 76 mm, and the amount of smoke Ds was measured using the non-framing method using an NBS smoke tester.
〈比較例１８〜２１＞
表−２の配合Ｎｏ、１８〜２１の配合物を実施例１６〜
１８と、同様な操作を行い、発煙ｆｉＤｓを測定した。<Comparative Examples 18 to 21> The formulations No. 18 to 21 in Table 2 were used in Examples 16 to 21.
The same operation as in No. 18 was performed to measure smoke fiDs.
得られた結果を表−２に示した。The results obtained are shown in Table-2.
この結果、酸化亜鉛とブレンライザー５Ｔ−２１０及び
水酸化アルミニウムを併用配合した塩化ビニル樹脂組成
物を塗布したビニル壁紙は、低発煙性であった。酸化亜
鉛と水酸化アルミニウムを配合した塩化ビニル樹脂組成
物を塗布した壁紙は、ある程度低発煙化できたが、加熱
工程の際黒色の斑点が発生し熱安定性が悪いことを示唆
していた。As a result, vinyl wallpaper coated with a vinyl chloride resin composition containing zinc oxide, Blenlyzer 5T-210, and aluminum hydroxide had low smoke generation. Wallpaper coated with a vinyl chloride resin composition containing zinc oxide and aluminum hydroxide was able to reduce smoke to some extent, but black spots appeared during the heating process, suggesting poor thermal stability.
〈実施例２２〜２３〉
表−３Ａ配合の配合Ｎｏ、２２．２３の配合物を前記の
６インチオーブンロールにて１７０°Ｃ１１０分間ロー
ル混練し、厚さ約１ｍｍのシートを作製した。次にこの
シートをプレス機で１７０°Ｃ５分間予熱後、５分間１
００Ｋｇ／ｃｍ２に加圧し、０．５ｍｍ厚のシートに成
型した。<Examples 22 to 23> The formulation No. 22.23 of the Table 3A formulation was roll-kneaded at 170°C for 110 minutes using the 6-inch oven roll to prepare a sheet with a thickness of about 1 mm. Next, this sheet was preheated for 5 minutes at 170°C in a press, and then
It was pressurized to 00 kg/cm2 and molded into a 0.5 mm thick sheet.
一方、表−３のＢ配合の配合Ｎｏ、２２．２３の配合物
を前記の６インチオーブンロールにて１６０℃、１０分
間ロール混練し、厚さ約１ｍｍ衣−２
ＰＶＣ： ＰＳＭ−３０（鐘淵化学工業側製〕ＤＯＰ
： ジオクチルフタレート（ボード−溶剤側＆り酸化
亜鉛：純正化学側製
７°レンライブ°〜５Ｔ２１０ ： 味の素側源Ｂ
ａ／Ｚ’ｎ系安定剤： ＩＲＧＡＳＴＡＢＥ Ｚ ５３
０ （チバガイギー側製）三酸化７ンチソン： 純正化
学＠製
水酸化アルミニウム： ハイシライト３２Ｍ（昭和アル
ミＨ製）水酸化マク゛ネシウム： キスマ５（協和化学
側製）重質炭酸カルシウム：住友化学側製
アソ゛シ゛カルネ゛ン７ミド： 和光純薬工業■製のシ
ートを作製した。次ぎにこのシート３枚を重ね、プレス
機により１６０°０５分間予熱後、５分間 １００Ｋｇ
／ｃｒｎ２に加圧し２．５ｍｍ厚の・シートに成型した
。こうして成型されたＡＢ両シートを接着剤（クキボン
ド２００タキロン■製）を用いて接着し、床材を試作し
た。On the other hand, the blend No. 22.23 of the B blend in Table 3 was roll-kneaded at 160°C for 10 minutes using the 6-inch oven roll, and the mixture was rolled to a thickness of about 1 mm. DOP manufactured by Fuchi Kagaku Kogyo
: Dioctyl phthalate (Board - Solvent side & Zinc oxide: Junsei Kagaku side 7° Renlive °~5T210 : Ajinomoto side source B
a/Z'n stabilizer: IRGASTABE Z 53
0 (manufactured by Ciba Geigy) Trioxide 7: Aluminum hydroxide manufactured by Junsei Kagaku@: Hisilite 32M (manufactured by Showa Aluminum H) Magnesium hydroxide: Kisuma 5 (manufactured by Kyowa Chemical) Heavy calcium carbonate: Associative carbonate manufactured by Sumitomo Chemical N7M: A sheet manufactured by Wako Pure Chemical Industries, Ltd. was prepared. Next, stack these 3 sheets together, preheat to 160° for 5 minutes using a press, and press 100Kg for 5 minutes.
/crn2 and molded into a 2.5 mm thick sheet. Both AB and A sheets thus molded were adhered using an adhesive (Kukibond 200 manufactured by Takiron ■) to fabricate a flooring material.
試作した床材を一辺が７６ｍｍの正方形に裁断し、ＮＢ
Ｓ発煙性試験機ノンフレーミング法により、発煙量Ｄｓ
を測定した。The prototype flooring material was cut into squares with a side of 76 mm, and the NB
Smoke generation amount Ds by non-flaming method of S smoke generation tester
was measured.
く比較例２４〜２７〉
表−３の配合Ｎｏ、２４〜２７の組成物を実施例２２．
２３と同様な操作を行い、発煙量Ｄｓを測定した。得ら
れた結果を表−３に示した。Comparative Examples 24 to 27> The compositions of Blend No. 24 to 27 in Table 3 were used in Example 22.
The same operation as in 23 was performed to measure the smoke amount Ds. The results obtained are shown in Table 3.
この結果、酸化亜鉛とブレンライザー５Ｔ−２１０及び
水酸化アルミニウムを併用配合した塩化ビニル樹脂組成
物を裏打ち材とした床材が低発煙であった。As a result, a floor material whose backing material was a vinyl chloride resin composition containing zinc oxide, Blenlyzer 5T-210, and aluminum hydroxide as a backing material produced low smoke.
〈発明の効果〉
以上水したように、塩化ビニル系樹脂に適量の酸化亜鉛
と多価アルコール系化合物及び水酸化アＰＶＣ： Ｇ
ｅｏｎ１０３ＥＰ
レオフィス６５． トソス（イソブロビルフエニ１シ）
ｔスフエート （味の素側製）シ゛メタチル錠メルカプ
タイド
ポリセーフＭＳ−１０： Ａｌ／Ｍｇ系減煙剤水酸化ア
ルミニウム： ハイシライト３２Ｍを１ｗｔ％のチタネ
ート系カップソング剤ＴＴＳ（味）素側Ｖ）による表面
処理品
ルミニウムを併用配合することにより、塩化ビニル系樹
脂組成物の熱安定性等の物性低下を伴うことなく燃焼時
の発煙量が著しく低減化する。<Effects of the Invention> As mentioned above, an appropriate amount of zinc oxide, polyhydric alcohol compound, and hydroxide PVC is added to vinyl chloride resin.
eon103EP Reoffice 65. Tosos (Isobrovir Feni 1)
tSphate (manufactured by Ajinomoto) Seametal Tablets Mercaptide Polysafe MS-10: Al/Mg smoke reducer Aluminum hydroxide: Surface with 1wt% of Hisilite 32M titanate cup song agent TTS (Ajinomoto V) By co-blending treated aluminum, the amount of smoke emitted during combustion is significantly reduced without deteriorating physical properties such as thermal stability of the vinyl chloride resin composition.
該低発煙性塩化ビニル樹脂組成物を応用することにより
、具体的にはビニル壁紙類や床材類の低発煙化ができる
。さらに他分野、例えば各種建材、電線被覆材料、日用
品、玩具、室内装飾品等あらゆる分野に該低発煙性塩化
ビニル系樹脂組成物を汎用できる．従って、火災時に於
いては、避難誘導、消火活動が従来に比較して容易とな
る。By applying the low smoke-emitting vinyl chloride resin composition, specifically, vinyl wallpapers and flooring materials can be made to have low smoke emissions. Furthermore, the low-smoke vinyl chloride resin composition can be used in various fields such as various building materials, wire coating materials, daily necessities, toys, and interior decoration products. Therefore, in the event of a fire, evacuation guidance and fire extinguishing activities are easier than in the past.
図−１は床材の断面図、１は裏打ち材 、２は不織布等
、３は印刷層、４は透明樹脂層、５は表面保護層である
。
図−２はタイルカーペットの断面図、１は裏打ち材、２
は不織布等、６はパイル生地である。Figure 1 is a cross-sectional view of the flooring material, 1 is a backing material, 2 is a nonwoven fabric, etc., 3 is a printed layer, 4 is a transparent resin layer, and 5 is a surface protection layer. Figure 2 is a cross-sectional view of the tile carpet, 1 is the backing material, 2
6 is a nonwoven fabric, etc., and 6 is a pile fabric.
Claims (3)
を０．５〜３０重量部と多価アルコール系化合物を０．
０５〜２０重量部、及び水酸化アルミニウムを２〜２０
０重量部を配合してなる低発煙性塩化ビニル系樹脂組成
物。(1) 0.5 to 30 parts by weight of zinc oxide and 0.5 to 30 parts by weight of a polyhydric alcohol compound to 100 parts by weight of vinyl chloride resin.
05 to 20 parts by weight, and 2 to 20 parts of aluminum hydroxide
A low-smoking vinyl chloride resin composition containing 0 parts by weight.
請求項１記載の低発煙性塩化ビニル系樹脂組成物である
ビニル壁紙類。(2) Vinyl wallpapers having a resin layer and a base material, wherein the resin layer is the low smoke-emitting vinyl chloride resin composition according to claim 1.
ち材が請求項１記載の低発煙性塩化ビニル系樹脂組成物
である床材類。(3) Flooring materials having a surface layer and a backing material, wherein the backing material is the low smoke-emitting vinyl chloride resin composition according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2247863A JP2990772B2 (en) | 1990-09-18 | 1990-09-18 | Low smoke resin composition and sheet comprising the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2247863A JP2990772B2 (en) | 1990-09-18 | 1990-09-18 | Low smoke resin composition and sheet comprising the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04126748A true JPH04126748A (en) | 1992-04-27 |
| JP2990772B2 JP2990772B2 (en) | 1999-12-13 |
Family
ID=17169761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2247863A Expired - Fee Related JP2990772B2 (en) | 1990-09-18 | 1990-09-18 | Low smoke resin composition and sheet comprising the same |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2990772B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103538306A (en) * | 2013-09-15 | 2014-01-29 | 杭州万事利丝绸科技有限公司 | Preparation method of antibacterial mildewproof silk wallpaper |
-
1990
- 1990-09-18 JP JP2247863A patent/JP2990772B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103538306A (en) * | 2013-09-15 | 2014-01-29 | 杭州万事利丝绸科技有限公司 | Preparation method of antibacterial mildewproof silk wallpaper |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2990772B2 (en) | 1999-12-13 |
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