JPH04119974A - Production of ceramic-metal composite material - Google Patents
Production of ceramic-metal composite materialInfo
- Publication number
- JPH04119974A JPH04119974A JP23457690A JP23457690A JPH04119974A JP H04119974 A JPH04119974 A JP H04119974A JP 23457690 A JP23457690 A JP 23457690A JP 23457690 A JP23457690 A JP 23457690A JP H04119974 A JPH04119974 A JP H04119974A
- Authority
- JP
- Japan
- Prior art keywords
- ceramic
- metal
- ceramic plate
- molten metal
- composite material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002905 metal composite material Substances 0.000 title claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000002184 metal Substances 0.000 claims abstract description 60
- 229910052751 metal Inorganic materials 0.000 claims abstract description 60
- 239000000919 ceramic Substances 0.000 claims abstract description 57
- 239000011800 void material Substances 0.000 claims description 8
- 238000010304 firing Methods 0.000 description 10
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000012255 powdered metal Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Powder Metallurgy (AREA)
- Ceramic Products (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、セラミックスの空隙内に溶融金属を流入含浸
させて、金属含有セラミック層と金属層とを有するセラ
ミックス・金属の複合材の製造方法に関するものである
。[Detailed Description of the Invention] <Industrial Application Field> The present invention provides a method for manufacturing a ceramic-metal composite material having a metal-containing ceramic layer and a metal layer by flowing and impregnating molten metal into the voids of the ceramic. It is related to.
〈従来の技術〉
金属は１弾性、加工性、伝熱性などの特性に優れている
が、耐久性、耐熱性はセラミックス程でもない、一方、
セラミックスは、弾性、加工性、伝熱性などは金属より
も劣るが、耐久性、耐熱性などは金属よりも遥かに優れ
ている。<Conventional technology> Metals have excellent properties such as elasticity, workability, and heat conductivity, but their durability and heat resistance are not as good as ceramics.
Ceramics are inferior to metals in terms of elasticity, workability, heat conductivity, etc., but they are far superior to metals in terms of durability, heat resistance, etc.
これらの特性を有する金属とセラミ−、クスとを接合す
ることは容易ではなく、遅蒔、拡ＦＢ！、接合によって
接合する技術も開発されている。It is not easy to join metals with these characteristics with ceramics and glass, and it is difficult to join them with slow sowing and expansion FB! , technology for joining by bonding has also been developed.
〈発明が解決しようとする課題〉
しかし、拡散接合するためには、接合面を鏡面にしなけ
ればならないので、前処理が極めて面倒である。<Problems to be Solved by the Invention> However, in order to carry out diffusion bonding, the bonding surface must be mirror-finished, so pretreatment is extremely troublesome.
また、拡散接合しても、冶金的接合部分が薄いので、接
合面の機械的強度が不十分あった。Furthermore, even with diffusion bonding, the metallurgically bonded portion was thin, so the mechanical strength of the bonded surface was insufficient.
〈課題を解決するための手段〉
本発明は上記に鑑み提案されたもので、内部に連続する
空隙を有するセラミックスを焼成し、該セラミックスの
表面に溶融した金属を接触させて上記空隙内に溶融金属
の一部を流入含浸させて。<Means for Solving the Problems> The present invention was proposed in view of the above, and involves firing a ceramic having continuous voids inside, and bringing molten metal into contact with the surface of the ceramic to melt the metal into the void. Part of the metal is impregnated with inflow.
金属含有セラミック層と金属層とを形成することを特徴
とするものである。This method is characterized by forming a metal-containing ceramic layer and a metal layer.
く作用）
内部に連続する空隙を有するセラミックスの表面に溶融
した金属を接触させると、溶融金属の一部が上記空隙内
に流入含浸する。そして、この状態で冷却して凝固させ
ると、金属とセラミックスとの接合部分では金属含有セ
ラミック層が形成され、空隙内に流入しなかった金属は
そのまま凝固して金属層となる。When molten metal is brought into contact with the surface of a ceramic having continuous voids inside, a portion of the molten metal flows into the voids and impregnates them. When the material is cooled and solidified in this state, a metal-containing ceramic layer is formed at the joint between the metal and the ceramic, and the metal that has not flowed into the gap is solidified to form a metal layer.
〈実施例〉 以下、本発明の実施例を図面にもとづいて説明する。<Example> Embodiments of the present invention will be described below based on the drawings.
図面に示す実施例は、建築物の壁面に張るタイルを製造
する場合の実施例である。The embodiment shown in the drawings is an embodiment for manufacturing tiles to be placed on the walls of buildings.
先ず、内部に連続する空隙１・・・を有するセラミック
ス板２を焼成し、このセラミックス板２を上面が開放し
た耐火材製枠３の底部に固定する。First, a ceramic plate 2 having a continuous void 1 therein is fired, and the ceramic plate 2 is fixed to the bottom of a refractory frame 3 having an open upper surface.
枠３は、第１図に示すように、多数のローラ４・・・を
設けた焼成炉５の一端から他端までをローラ４・・・の
回転によって搬送される。枠３が焼成炉５内の予熱ゾー
ン６に入ると、約２００度の温度まで予熱されるととも
に、ホッパ７内に貯留しであるアルミニウムなどの粉末
状金属８・・・が上方から所定量投入され、セラミック
ス板２を囲むよう１こして堆植する。そして、この枠３
が焼成炉５内を進行して溶融ゾーン９に達すると、第２
図に示すように、バーナｌＯ・・・などの加熱によって
粉末状金属８・・・が溶融点（約７００度）に達して溶
融する。粉末状金属８・・・が溶融しても、セラミック
ス板２が枠３の底部に固定しであるので、溶融金属８・
・・の浮力によって浮き上がることはなく、また、セラ
ミックス板２と底部との間に溶融金属８・・・が流入す
ることもない、そして、セラミックス板２には表面に連
通ずる空隙ｌ・・・があるので溶融金属８・・・の一部
は自重によりこの空隙１・・・内に流入浸透し、残りの
溶融金属８・・・はセラミックス板２上に残る。枠３が
焼成炉５の冷却ゾーンに達すると、約５００度まで冷却
されるので、空隙１・・・内の溶融金属８・・・及びセ
ラミックス板２上の溶融金Ｊ＋！８・・・が凝固する。As shown in FIG. 1, the frame 3 is conveyed by the rotation of the rollers 4 from one end to the other end of a firing furnace 5 provided with a large number of rollers 4. When the frame 3 enters the preheating zone 6 in the firing furnace 5, it is preheated to a temperature of approximately 200 degrees, and a predetermined amount of powdered metal 8 such as aluminum stored in the hopper 7 is charged from above. and then strain it and compost it so as to surround the ceramic plate 2. And this frame 3
When the melt progresses through the firing furnace 5 and reaches the melting zone 9, the second
As shown in the figure, the powdered metal 8 reaches its melting point (approximately 700 degrees) and melts by heating with a burner lO, etc. Even if the powdered metal 8... melts, the ceramic plate 2 is fixed to the bottom of the frame 3, so the molten metal 8...
... will not float up due to the buoyancy of the ceramic plate 2, and the molten metal 8 will not flow between the ceramic plate 2 and the bottom, and the ceramic plate 2 has a void l... that communicates with the surface. Therefore, a part of the molten metal 8 flows into and permeates into the gap 1 due to its own weight, and the remaining molten metal 8 remains on the ceramic plate 2. When the frame 3 reaches the cooling zone of the firing furnace 5, it is cooled to about 500 degrees, so that the molten metal 8 in the voids 1 and the molten gold J+ on the ceramic plate 2! 8... solidifies.
冷却ゾーン１１で十分に冷却した後に脱型すると、第３
図に示すように、上面の金属層１２と下面のセラミック
ス層１３との間において空隙１・・・内に金属８・・・
が流入含浸した金属含有セラミック層１４が形成された
セラミックス・金属の複合材ができる。When the mold is removed after being sufficiently cooled in the cooling zone 11, the third
As shown in the figure, metal 8... is placed in the gap 1 between the metal layer 12 on the top surface and the ceramic layer 13 on the bottom surface.
A ceramic-metal composite material having a metal-containing ceramic layer 14 impregnated with inflow is produced.
なお、セラミックスの焼成までを含めた一連の工程、例
えば連続加熱炉で製造する場合、セラミックス板２の焼
成熱が残っている状態（例えば、約１２００度で焼成し
たセラミックス板２が約５００度まで温度降下した状態
）で枠３内にセラミックス板２をセットすると、少ない
予熱で所定温度まで昇温することができ、効率が良く経
済的である。In addition, when producing a series of processes including firing ceramics, for example in a continuous heating furnace, the firing heat of the ceramic plate 2 remains (for example, the ceramic plate 2 fired at about 1200 degrees heats up to about 500 degrees). If the ceramic plate 2 is set in the frame 3 in a state where the temperature has dropped, the temperature can be raised to a predetermined temperature with a small amount of preheating, which is efficient and economical.
上記した実施例では、溶融金属８・・・の一部を溶融金
属８・・・の自正により空隙１・・・内に流入含浸させ
たが１本発明はこれに限らず、グイキャスト鋳造のよう
に金型１５内にセラミックス板２を固定し、この状態で
溶融金属８・・・を加圧装置１６によって加圧しながら
空隙ｌ・・・内に圧入させたり、或はセラミックス板２
側を負圧Ｖとして溶融金属８・・・を空隙１・・・内に
吸引するようにしてもよい。In the above-mentioned embodiment, a part of the molten metal 8 was flowed into the gap 1 and impregnated by the self-correction of the molten metal 8, but the present invention is not limited to this, and the present invention is not limited to this. The ceramic plate 2 is fixed in the mold 15 as shown in FIG.
The molten metal 8 may be sucked into the void 1 by applying a negative pressure V on the side.
この様に加圧含浸、或は吸引含浸させると、溶融金属８
・・・を連続空隙１・・・の深部まで効率良く含浸させ
ることができる。By pressure impregnation or suction impregnation in this way, the molten metal 8
... can be efficiently impregnated deep into the continuous voids 1.
また、」−記した実施例は、セラミックス板２上に粉末
状金属８・・・を投入した後に加熱して粉末状金属８・
・・を溶融したが、本発明は、第５図に示すように、直
接溶融金属８・・・をセラミックス上に流し込んでもよ
いし、また、溶融金属８・・・を予め注入した枠３内に
セラミックス板２を押し入れてもよい。In addition, in the embodiment described with "-", the powdered metal 8... is placed on the ceramic plate 2 and then heated.
However, in the present invention, as shown in FIG. 5, the molten metal 8... may be directly poured onto the ceramic, or the molten metal 8... may be poured into the frame 3 in advance. The ceramic plate 2 may be pushed into the hole.
また、上記した実施例においては、セラミックス板２に
不規則で細かな連続空隙ｌ・・・を形成し、この空隙１
・・・内に溶融金属８・・・を流入含浸させたが、本発
明においては、これよりも大きな空隙ｌ・・・を所定の
形状に形成してもよい０例えば、第６図に示すセラミ−
２クス・金属８・・・の複合材は、セラミックス板２の
上面に開口幅が底部幅よりも狭い凸字状の溝を空隙１・
・・とじて形成し、セラミックス板２の上面の溶融金属
８・・・が溝内に流入して凝固するようにしたものであ
る。Further, in the above-described embodiment, irregular and fine continuous voids l... are formed in the ceramic plate 2, and this void 1
Although the molten metal 8 was injected into the space and impregnated into it, in the present invention, a larger gap l may be formed in a predetermined shape.For example, as shown in FIG. Ceramic
In the composite material of 2x and metal 8..., a convex groove with an opening width narrower than the bottom width is formed on the top surface of the ceramic plate 2 with a void 1.
... is formed so that the molten metal 8 on the upper surface of the ceramic plate 2 flows into the groove and solidifies.
要するに、空隙１・・・は、溶融金Ｍ、８・・・が流入
含浸するものであれば、大きさや形状は限定されるもの
ではない、同様に、セラミックスは板状の物に限らず、
どのような形状でもよい。In short, the size and shape of the voids 1 are not limited as long as the molten gold M, 8, etc. can flow in and impregnate them.Similarly, ceramics are not limited to plate-shaped ones.
It can be of any shape.
上記の様にして製造したセラミックスφ金属の複合材は
、金属８・・・の一部がセラミックス板２の空隙１・・
・内に入り込んで凝固しているので、金属８・・・とセ
ラミックス板２との接合強度が極めて高く、剥離するお
それがない、また、金属８・・・とセラミックスとの複
合材なので、画素材の相乗効果により、弾性、加工性、
伝熱性などの特性に優れ、しかも耐久性、耐熱性に優れ
た特性を発揮する。In the ceramic φ metal composite material manufactured as described above, a part of the metal 8... is the void 1 of the ceramic plate 2.
・Since the metal 8... and the ceramic plate 2 are solidified after entering the interior, the bonding strength between the metal 8... and the ceramic plate 2 is extremely high, and there is no risk of peeling. Due to the synergistic effect of materials, elasticity, workability,
It has excellent properties such as heat conductivity, as well as excellent durability and heat resistance.
したがって、この様な複合材は様々な用途に利用するこ
とができる０例えば、耐久性、耐火性に優れたタイル張
りカーテンウオールも簡単に作ることができる。即ち、
第３図及び第６図に示すように１本発明により製造した
タイル１７の金属層１２に雌ねじ部１８・・・を形成す
る。このタイル１７を張るには、第７図に示すように、
鉄骨１９に固定する支持材２０に室内側からボルト２１
・・・を通し、各ボルト２１の先端雄ねじ部をタイル１
７の裏面の上記酸ねじ部１８に螺合する。Therefore, such composite materials can be used for various purposes. For example, tiled curtain walls with excellent durability and fire resistance can be easily produced. That is,
As shown in FIGS. 3 and 6, female threads 18 are formed in the metal layer 12 of the tile 17 manufactured according to the present invention. To lay out this tile 17, as shown in FIG.
Bolts 21 are attached to the support member 20 fixed to the steel frame 19 from the indoor side.
..., and connect the male threaded end of each bolt 21 to the tile 1.
It is screwed into the acid threaded portion 18 on the back side of 7.
この様にして、タイル１７・・・をねじ止めすると、モ
ルタルによりタイルを止着する従来の張り方に比較する
と、止着強度が経年変化により低下することを防止する
ことができ、タイル１７・・・が剥れて落下する事故を
未然に防止することができる。By screwing the tiles 17 in this way, compared to the conventional method of fixing the tiles with mortar, it is possible to prevent the fixing strength from decreasing due to aging, and it is possible to prevent the fixing strength from decreasing due to aging. It is possible to prevent accidents in which the material peels off and falls.
なお、タイル１７の表面となるセラミックス板２の表面
側の空隙を少なくして金属８・・・と接する裏側を空隙
ｌ・・・の多い多孔質とすると、体裁が良く、しかもセ
ラミックス板２と金属８・・・との接合強度を高く維持
することができ、商品価値が高まる。Note that if the surface side of the ceramic plate 2, which is the surface of the tile 17, has fewer voids and the back side that contacts the metal 8... is made porous with many voids l..., the appearance will be good, and the ceramic plate 2 will be similar to the ceramic plate 2. The bonding strength with the metal 8 can be maintained high, increasing the commercial value.
また、本発明における金属は、上記したアルミニウムに
限らず、セラミックスよりも融点の低いものであればど
のような金属でもよく、例えば亜鉛、鉛、錫、銅などが
ある。Further, the metal in the present invention is not limited to the above-mentioned aluminum, but may be any metal having a melting point lower than that of ceramics, such as zinc, lead, tin, copper, etc.
〈発明の効果〉
以上説明したように本発明によれば、従来接合が困難で
あったセラミックスと金属とを簡単な操作で接合するこ
とができ、しかも溶融金属がセラミックスの空隙内に流
入して凝固して機械的に接合するので、高い接合強度を
得ることができる。<Effects of the Invention> As explained above, according to the present invention, it is possible to join ceramics and metals, which have been difficult to join in the past, with a simple operation. Since it is solidified and mechanically bonded, high bonding strength can be obtained.
そして、本発明により製造したセラミックス・金属の複
合材は、セラミックス自体が有している優れた耐久性、
耐熱性と、金属自体が有している優れた弾性、加工性、
伝熱性との相乗効果により優れた機械特性を発揮する。The ceramic-metal composite material produced according to the present invention has the excellent durability that ceramics itself has,
Heat resistance, the excellent elasticity and workability of the metal itself,
Demonstrates excellent mechanical properties due to the synergistic effect with heat conductivity.
図面は本発明の実施例を示すもので、第１図は焼成炉の
概略断面図、第２図は焼成炉の溶融ゾーンの断面図、第
３図はセラミックス・金属の複合材をタイルとした拡大
断面図、第４図は溶融金属を空隙内に加圧流入させる装
置の概略断面図、第５図は溶融金属を枠内に流入する状
態を示す概略図、第６図は空隙を凸字状に形成したタイ
ルの拡大断面図、第７図はタイルをねじ止めした状態の
側面図である。
図中、ｌはセラミックス板の空隙、２はセラミックス板
、３は枠、４はローラ、５は焼成炉。
６は予熱ゾーン、７はホッパ、８は金属、９は溶融ゾー
ン、１０はバーナ、１１は冷却ゾーン、１２は金属層、
１３はセラミックス層、１４は金属含有セラミックス層
、１５は金型、１６は加圧装置、１７はタイル、１８は
雌ねじ部、１９は鉄骨、２０は支持材、２１はボルトで
ある。
特許出願人 小沢コンクリート工業株式会社第１図
第２図
第３図
第６図
第４図
第７図The drawings show embodiments of the present invention; Fig. 1 is a schematic cross-sectional view of a firing furnace, Fig. 2 is a cross-sectional view of the melting zone of the firing furnace, and Fig. 3 is a tile made of a ceramic-metal composite material. An enlarged sectional view, Figure 4 is a schematic cross-sectional view of a device for pressurizing molten metal to flow into the cavity, Figure 5 is a schematic diagram showing the state in which molten metal flows into the frame, and Figure 6 shows the cavity with a convex shape. FIG. 7 is an enlarged cross-sectional view of the tile formed in a shape, and FIG. 7 is a side view of the tile screwed together. In the figure, l is a gap in the ceramic plate, 2 is a ceramic plate, 3 is a frame, 4 is a roller, and 5 is a firing furnace. 6 is a preheating zone, 7 is a hopper, 8 is a metal, 9 is a melting zone, 10 is a burner, 11 is a cooling zone, 12 is a metal layer,
13 is a ceramic layer, 14 is a metal-containing ceramic layer, 15 is a mold, 16 is a pressurizing device, 17 is a tile, 18 is a female screw portion, 19 is a steel frame, 20 is a support material, and 21 is a bolt. Patent applicant: Ozawa Concrete Industries Co., Ltd. Figure 1 Figure 2 Figure 3 Figure 6 Figure 4 Figure 7
Claims (1)
セラミックスの表面に溶融した金属を接触させて上記空
隙内に溶融金属の一部を流入含浸させてから冷却して、
金属含有セラミック層と金属層とを形成することを特徴
とするセラミックス・金属の複合材の製造方法。A ceramic having continuous voids inside is fired, a molten metal is brought into contact with the surface of the ceramic, a part of the molten metal flows into the void, and is impregnated, and then cooled.
A method for producing a ceramic-metal composite material, comprising forming a metal-containing ceramic layer and a metal layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23457690A JPH04119974A (en) | 1990-09-06 | 1990-09-06 | Production of ceramic-metal composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23457690A JPH04119974A (en) | 1990-09-06 | 1990-09-06 | Production of ceramic-metal composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04119974A true JPH04119974A (en) | 1992-04-21 |
Family
ID=16973181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23457690A Pending JPH04119974A (en) | 1990-09-06 | 1990-09-06 | Production of ceramic-metal composite material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04119974A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104001904A (en) * | 2013-02-25 | 2014-08-27 | 阿尔斯通技术有限公司 | Method for manufacturing a metal-ceramic composite structure and metal-ceramic composite structure |
| KR101707608B1 (en) * | 2016-05-04 | 2017-02-17 | 주식회사 에이치앤티 | Coating foamed vermiculite and its manufacturing method and vermiculite pannel using this |
| CN110819843A (en) * | 2019-11-15 | 2020-02-21 | 南京理工大学 | Negative poisson ratio cellular lattice shaped ceramic skeleton reinforced composite material and manufacturing method thereof |
| CN111842853A (en) * | 2020-07-30 | 2020-10-30 | 南昌工程学院 | Porous metal ceramic matrix composite material for preparing self-lubricating bearing and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01212283A (en) * | 1988-02-19 | 1989-08-25 | Daihatsu Motor Co Ltd | Production of joined body of ceramics and metal |
-
1990
- 1990-09-06 JP JP23457690A patent/JPH04119974A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01212283A (en) * | 1988-02-19 | 1989-08-25 | Daihatsu Motor Co Ltd | Production of joined body of ceramics and metal |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104001904A (en) * | 2013-02-25 | 2014-08-27 | 阿尔斯通技术有限公司 | Method for manufacturing a metal-ceramic composite structure and metal-ceramic composite structure |
| EP2769969A1 (en) * | 2013-02-25 | 2014-08-27 | Alstom Technology Ltd | Method for manufacturing a metal-ceramic composite structure and metal-ceramic composite structure |
| US9174275B2 (en) | 2013-02-25 | 2015-11-03 | Alstom Technology Ltd | Method for manufacturing a metal-ceramic composite structure and metal-ceramic composite structure |
| CN104001904B (en) * | 2013-02-25 | 2017-01-11 | 通用电器技术有限公司 | Method for manufacturing a metal-ceramic composite structure and metal-ceramic composite structure |
| KR101707608B1 (en) * | 2016-05-04 | 2017-02-17 | 주식회사 에이치앤티 | Coating foamed vermiculite and its manufacturing method and vermiculite pannel using this |
| CN110819843A (en) * | 2019-11-15 | 2020-02-21 | 南京理工大学 | Negative poisson ratio cellular lattice shaped ceramic skeleton reinforced composite material and manufacturing method thereof |
| CN111842853A (en) * | 2020-07-30 | 2020-10-30 | 南昌工程学院 | Porous metal ceramic matrix composite material for preparing self-lubricating bearing and preparation method thereof |
| CN111842853B (en) * | 2020-07-30 | 2022-02-01 | 南昌工程学院 | Porous metal ceramic matrix composite material for preparing self-lubricating bearing and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8097336B2 (en) | Methods and systems for manufacturing a structure having organized areas | |
| US5720835A (en) | Decorative construction material and methods of its production | |
| US3800014A (en) | Method of constructing a refractory wall in a float glass furnace | |
| CN105478994B (en) | The welding manufacturing process of foam aluminium sandwich sandwich component | |
| ES2000419T3 (en) | MANUFACTURE METHOD OF PROFILE CERAMIC COMPOUNDS WITH THE USE OF A BARRIER. | |
| FR2612508A1 (en) | MULTILAYER CELLULAR GLASS BLOCK WITH DENSE GLASS SURFACE LAYER AND METHOD OF PRODUCING THE SAME | |
| JPH04119974A (en) | Production of ceramic-metal composite material | |
| US3309123A (en) | Attachment of inserts and fixing devices to pieces of vitreous silica, glass and such material | |
| CN105777070A (en) | Making method of thermal insulation decorative ceramic tiles | |
| CN105819826A (en) | Manufacturing method of thermal insulation decorative ceramic brick | |
| JPH09164469A (en) | Mold for casting strap for connecting lug group of pole plate group for lead battery and method for casting strap | |
| EP0271222A3 (en) | Production of metal matrix composites | |
| CN101349094A (en) | Decorative heat preservation composite board with lugs and construction method thereof | |
| CN212822653U (en) | Masonry structure of hot-metal bottle | |
| CN1968772B (en) | Slide plate and its production method | |
| JPS6110035A (en) | Melted tin bath for making flat glass | |
| CN101498552B (en) | Molten pool working layer of aluminum melting furnace built by flame-proof precast blocks | |
| JPH022835B2 (en) | ||
| US3224853A (en) | Process for increasing the thermal insulating properties of vitreous materials and their adhesion to coherent substances | |
| FR2584485A1 (en) | Profiled refractory brick, for vaults (roofs), cast in material to be melted and vaults (roofs) comprising such bricks | |
| JPH0239647Y2 (en) | ||
| CN1048442C (en) | Method for manufacturing concrete secondary product on the surface of which facing materials are fitted in advance | |
| KR100767048B1 (en) | Plate glass fusion adhered with white silica stone particle and the forming process of the same | |
| CN112443053A (en) | Heat-insulation type steel structure building external wall panel | |
| JP2644982B2 (en) | Method for producing composite plate of inorganic material and metal |