JPH04116196A - Method and apparatus for manufacturing porous body metal - Google Patents
Method and apparatus for manufacturing porous body metalInfo
- Publication number
- JPH04116196A JPH04116196A JP23197890A JP23197890A JPH04116196A JP H04116196 A JPH04116196 A JP H04116196A JP 23197890 A JP23197890 A JP 23197890A JP 23197890 A JP23197890 A JP 23197890A JP H04116196 A JPH04116196 A JP H04116196A
- Authority
- JP
- Japan
- Prior art keywords
- oxidizing atmosphere
- porous metal
- metal
- producing
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002184 metal Substances 0.000 title claims abstract description 42
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 42
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 238000000034 method Methods 0.000 title claims description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 35
- 239000000463 material Substances 0.000 claims abstract description 25
- 239000012298 atmosphere Substances 0.000 claims abstract description 19
- 230000001590 oxidative effect Effects 0.000 claims abstract description 15
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910001873 dinitrogen Inorganic materials 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims abstract description 9
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims description 10
- 239000005416 organic matter Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 5
- 238000007747 plating Methods 0.000 abstract description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052799 carbon Inorganic materials 0.000 abstract description 9
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 239000004745 nonwoven fabric Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 description 6
- 238000005979 thermal decomposition reaction Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、連通空間を有する三次元綱状構造の多孔体
金属を製造する際に、基材の有機物体を加熱除去する方
法およびその装置に関するものである。Detailed Description of the Invention [Field of Industrial Application] This invention provides a method and apparatus for removing organic matter from a base material by heating when manufacturing a porous metal having a three-dimensional wire-like structure having communicating spaces. It is related to.
三次元綱状構造の多孔体金属は、電池の電極、各種フィ
ルター、触媒の担体等に使用されている。Porous metals with a three-dimensional wire-like structure are used for battery electrodes, various filters, catalyst carriers, etc.
このような多孔体金属は、連通気孔を有する発泡樹脂、
不織布の有機物体を基材にしてこの基材の骨格表面上に
、無電解メツキ、気相メツキ、塗布等の方法により金属
、あるいはカーボンを被覆して導電性を付与し、さらに
、必要な厚さまで金属を電気メツキした後に、基材の有
機物体を除去することによって製造されている。Such porous metals include foamed resins with continuous pores,
The skeletal surface of the nonwoven organic substance is coated with metal or carbon by electroless plating, vapor phase plating, coating, etc. to provide conductivity, and then the required thickness is coated with metal or carbon. It is manufactured by electroplating the metal and then removing the organic matter from the substrate.
ところで、従来、上記基材の有機物体の除去には、第５
図に示すような熱処理装置が使用されている。By the way, conventionally, in order to remove organic substances from the base material, a fifth
A heat treatment device as shown in the figure is used.
上記の熱処理装置は、焙焼炉１と、還元熱処理炉２と、
基材Ａと焙焼炉１、還元熱処理炉２内をそれぞれ通過さ
せるための搬送キャリヤとしてのメンシュベルト、金属
ベルト３とによって構成され、基材Ａを焙焼炉１内にお
いて大気中で焼却除去した後、焙焼によって酸化した金
属を、還元熱処理炉２において還元処理するようになっ
ている。The above heat treatment apparatus includes a roasting furnace 1, a reduction heat treatment furnace 2,
It is composed of a mensch belt and a metal belt 3 as transport carriers for passing the base material A through the roasting furnace 1 and the reduction heat treatment furnace 2, respectively, and the base material A is incinerated and removed in the atmosphere in the roasting furnace 1. After that, the metal oxidized by roasting is subjected to reduction treatment in a reduction heat treatment furnace 2.
第５図において、付量４はヒーター、５は水冷管、６は
マツフルをそれぞれ示している。In FIG. 5, the attached amount 4 indicates the heater, 5 indicates the water cooling pipe, and 6 indicates the matsufuru.
〔発明が解決しようとする課題］
ところが、上記のような熱処理装置を使用した方法では
、焙焼炉１内において金属骨格が酸化され、特に電析し
た金属は粒界が激しく酸化されるので、この後還元処理
を行っても、金属が密着、連結せず、機械的強度が小さ
く、剛性の弱い多孔体金属しか得られないという問題が
ある。[Problems to be Solved by the Invention] However, in the method using the heat treatment apparatus as described above, the metal skeleton is oxidized in the roasting furnace 1, and in particular, the grain boundaries of the electrodeposited metal are severely oxidized. Even if a reduction treatment is performed after this, there is a problem in that the metals do not adhere or connect, and only porous metals with low mechanical strength and rigidity are obtained.
また、焙焼炉１内において金属骨格が酸化してもろくな
ると、焙焼炉１および還元熱処理炉２を連続的に通過さ
せようとした場合に、そのまま弓張ることができないの
で、搬送用のキャリヤとして、上記のように、メソシュ
ヘルド、金属ベルト等を必要とする。このため、焙焼炉
１や還元熱処理炉２では、搬送用のキャリヤを加熱する
ために、余分なエネルギーを必要とする。In addition, if the metal skeleton becomes brittle due to oxidation in the roasting furnace 1, it will not be possible to straighten it as it is when passing through the roasting furnace 1 and the reduction heat treatment furnace 2 continuously. As mentioned above, it requires a metosheld, metal belt, etc. Therefore, the roasting furnace 1 and the reduction heat treatment furnace 2 require extra energy to heat the carrier for transportation.
さらに、還元熱処理炉２では、大量の還元性ガスを必要
とするという問題もある。Furthermore, the reduction heat treatment furnace 2 also has the problem of requiring a large amount of reducing gas.
そこで、この発明は、上記の問題を解決するために、多
孔体金属を製造する際に、金属を酸化させずに有機物体
を除去する方法と装置を捉供しようとするものである。SUMMARY OF THE INVENTION In order to solve the above-mentioned problems, the present invention provides a method and apparatus for removing organic matter without oxidizing metal when producing porous metal.
［課題を解決するだめの手段］
この発明は、上記の課題を解決するために、炉内を非酸
化性雰囲気に調整した熱処理装置により、基材の有機物
体を、非酸化性雰囲気下で加熱除去するようにしたので
ある。[Means for Solving the Problems] In order to solve the above problems, the present invention heats an organic substance as a base material in a non-oxidizing atmosphere using a heat treatment device whose inside of the furnace is adjusted to a non-oxidizing atmosphere. I decided to remove it.
基材の有機物体を非酸化性雰囲気下で加熱すると、有機
物体が加熱分解によって気化して除去され、この際、金
属は酸化されないので、機械的強度が大きく、剛性の強
い多孔体金属を得ることができる。When the base organic material is heated in a non-oxidizing atmosphere, the organic material is vaporized and removed by thermal decomposition. At this time, the metal is not oxidized, so a porous metal with high mechanical strength and high rigidity is obtained. be able to.
この発明における非酸化性雰囲気としてＣヨ、水素ガス
、窒素ガス、水素ガスと窒素ガスの混合ガスが使用され
るが、有機物体を加熱分解した気化ガスは、炉外に引出
されて燃焼させるので、その際には、可燃性ガスの存在
が有効であるため、上記混合ガス中の水素ガスの混合比
率は５％以上であることが望ましい。In this invention, hydrogen gas, nitrogen gas, or a mixed gas of hydrogen gas and nitrogen gas are used as the non-oxidizing atmosphere, but since the vaporized gas obtained by thermally decomposing the organic matter is drawn out of the furnace and burned. In that case, since the presence of flammable gas is effective, it is desirable that the mixing ratio of hydrogen gas in the mixed gas is 5% or more.
また、この発明においては、有機物体を蒸し焼き状態で
炭化させずにガス化することが重要であり、そのために
は、加熱温度を高くして有機物体の液化さらにガス化の
速度を早めることが望ましい。例えば、加熱温度が、４
５０°Ｃ〜６５０°Ｃの場合、有機物体の熱分解は行わ
れるが、その液化さらにガス化の速度が遅く、炉内汚染
が激しく実用生産に適さないし、得られる多孔体金属も
折り曲げ試験によって亀裂が生じる。また、６５０°Ｃ
〜８００°Ｃでも折り曲げ試験によって多孔体金属に亀
裂が生しる。In addition, in this invention, it is important to gasify the organic matter without carbonizing it in a steamed state, and for this purpose, it is desirable to increase the heating temperature to accelerate the rate of liquefaction and gasification of the organic matter. . For example, if the heating temperature is 4
In the case of 50°C to 650°C, thermal decomposition of organic substances takes place, but the rate of liquefaction and gasification is slow, the furnace is heavily contaminated, and it is not suitable for practical production. Cracks occur. Also, 650°C
Even at ~800°C, cracks occur in the porous metal during the bending test.
したがって、この発明における加熱温度は８００°Ｃ以
上であることが望ましい。Therefore, it is desirable that the heating temperature in this invention is 800°C or higher.
また、この発明においては非酸化性雰囲気中に酸素が混
入していてもよいが、酸素量が多くなれば有機物体の分
解は早くなっても金属の酸化が進むので、酸素量は金属
が酸化変色しない量でなければならない。In addition, in this invention, oxygen may be mixed in the non-oxidizing atmosphere, but if the amount of oxygen is large, the oxidation of the metal will proceed even though the decomposition of organic substances will be faster. It must be in an amount that does not cause discoloration.
以下に、この発明によって多孔体金属を製造する場合の
具体例を示す。A specific example of producing a porous metal according to the present invention will be shown below.
まず、有機物体の基材Ａとして、セル数（１インチに接
する孔数を表す）５０ケ／インチ、厚さ１．８閣、幅５
００ｍの連通気孔を有するウレタン発泡樹脂シートを使
用して、この基材Ａに、第２図に示すようなカーボン塗
布装置によってカーボン導電塗料１１を塗布して導電性
を付与する。First, as the base material A of the organic substance, the number of cells (representing the number of holes touching 1 inch) is 50 cells/inch, the thickness is 1.8 mm, and the width is 5 mm.
Using a urethane foam resin sheet having 00 m of continuous pores, a carbon conductive paint 11 is applied to this base material A using a carbon coating device as shown in FIG. 2 to impart conductivity.
第２図に示すカーボン塗布装置は、カーボン導！塗料液
１１の入った塗布槽１２内に、ロール体１３から繰り出
した基材Ａを引き入れて基材Ａにカーボン導１塗料液１
１を塗布した後、基材Ａを塗布槽１２から引き出し、ヒ
ーター１４によって乾燥させた後に巻取りロール１５に
巻き取るようになっている。The carbon coating device shown in Fig. 2 is a carbon coating device. The base material A fed out from the roll body 13 is drawn into the coating tank 12 containing the paint liquid 11, and the carbon conductor 1 paint liquid 1 is applied to the base material A.
1, the base material A is pulled out from the coating tank 12, dried by a heater 14, and then wound onto a winding roll 15.
上記のようにして導電性を付与した基材Ａを、第３図に
示すメツキ装置によって一次メツキを行い、その後、第
４図に示すメツキ装置によって二次メツキを行って、基
材Ａの骨格表面に３３０ ｇ ／イのニッケルを電析さ
せた。メツキの総電流量は１０００Ａ、メツキ時間は２
０分であった。The base material A, which has been imparted with conductivity as described above, is subjected to primary plating using the plating device shown in FIG. 3, and then second plating is performed using the plating device shown in FIG. 330 g/I of nickel was electrodeposited on the surface. The total current of plating is 1000A, the plating time is 2
It was 0 minutes.
第３図に示すメツキ装置は、メッキ槽１７内に給電ドラ
ム１８と、ニッケルの陽極１９を設け、導電性を付与し
た基材Ａを上記給電ドラム１８に巻き付けるように走行
させてメツキを行うようになっている。The plating device shown in FIG. 3 includes a power supply drum 18 and a nickel anode 19 in a plating tank 17, and performs plating by running a conductive base material A so as to wrap it around the power supply drum 18. It has become.
また、第４図に示すメツキ装置は、メツキ液２０の入っ
た第１メツキ槽２１、第２メツキ槽２２、第３メツキ槽
２３内を、導電性を付与した基材Ａを順次、対向するよ
うに設けた給電ロール２４と駆動ロール２５によって挟
んで通過させてメツキするようにしたものであり、第１
メツキ槽２１、第２メツキ槽２２、第３メツキ槽２３内
には、走行する基材Ａの上下に上部陽極２６と下部陽極
２７が設けられている。Further, the plating apparatus shown in FIG. 4 sequentially faces the conductive substrate A through the first plating tank 21, second plating tank 22, and third plating tank 23 containing the plating liquid 20. The first plate is plated by being sandwiched between a power supply roll 24 and a drive roll 25, which are provided as shown in FIG.
In the plating tank 21, the second plating tank 22, and the third plating tank 23, an upper anode 26 and a lower anode 27 are provided above and below the traveling base material A.
次に、上記のようにして骨格表面にメツキが施された基
材Ａを、第１図に示すこの発明に係る熱処理装置によっ
て熱処理を行って、基材Ａの有機物体を加熱除去するこ
とにより、多孔体金属が得られる。Next, the base material A whose skeleton surface has been plated as described above is heat-treated by the heat treatment apparatus according to the present invention shown in FIG. , a porous metal is obtained.
第１図に示す熱処理装置は、マンフル２８で覆った炉内
が非酸化雰囲気に調整されており、前段部分がヒーター
２９による加熱分解ゾーン３０になっており、後段部分
が水冷却管３１による冷却ゾーン３２になっている。基
材Ａは、対向一対の駆動ロール３３に挟まれて炉内を通
過するようになっており、基材Ａが加熱分解して発生す
る可燃性ガスは炉外に引出されて、燃焼させられる。ま
た、炉の出入口部分には、窒素ガスのシールゾーン３４
が設けられており、出入口部分における着火が防止され
ている。In the heat treatment apparatus shown in FIG. 1, the inside of the furnace covered with a manful 28 is adjusted to a non-oxidizing atmosphere, the front part is a thermal decomposition zone 30 by a heater 29, and the latter part is cooled by a water cooling pipe 31. It's in zone 32. The base material A is sandwiched between a pair of opposing drive rolls 33 and passes through the furnace, and the flammable gas generated by thermal decomposition of the base material A is drawn out of the furnace and burned. . In addition, a nitrogen gas seal zone 34 is provided at the entrance and exit portion of the furnace.
is provided to prevent ignition at the entrance/exit area.
上記熱処理装置の炉内の雰囲気を、水素ガスと窒素ガス
との容積混合比率を１：０．３：１．１：３．１：１９
．１：３０にして、加熱温度８００°Ｃ〜８５０″Ｃに
して熱処理を行って得られた多孔体金属の機械的特性を
表１のＮＣＬＩ〜ＮＣＬ５に示す。The atmosphere in the furnace of the above heat treatment equipment is set at a volumetric mixing ratio of hydrogen gas and nitrogen gas of 1:0.3:1.1:3.1:19.
．． The mechanical properties of the porous metals obtained by heat treatment at a heating temperature of 800° C. to 850″C are shown in NCLI to NCL5 in Table 1.
また、上記熱処理装置の炉内を、水素ガス３対窒素ガス
１の容積混合比率の雰囲気で加熱温度を４５０℃〜６５
０°Ｃと６５０°Ｃ〜８００°Ｃに設定して熱処理を行
って得られた多孔体金属の機械的特性を表１の隘６、Ｎ
［Ｌ７に示す。In addition, the inside of the furnace of the heat treatment apparatus was heated at a heating temperature of 450°C to 65°C in an atmosphere with a volumetric mixing ratio of 3 parts hydrogen gas to 1 part nitrogen gas.
The mechanical properties of porous metals obtained by heat treatment at 0°C and 650°C to 800°C are shown in Table 1, column 6, N
[Shown in L7.
さらに、比較例として第５回に示す従来の熱処理装置を
使用して、６００°Ｃ〜６５０°Ｃの焙焼炉１において
２０分間、大気雰囲気中で基材Ａの有機物体を焼却除去
した後、水素ガス３対窒素ガス１の容積混合比率の雰囲
気で温度８００°Ｃ〜８５０°Ｃにした還元熱処理炉２
で熱処理を行って得られた多孔体金属の機械的特性を表
１のＮα８に示す。Furthermore, as a comparative example, using the conventional heat treatment equipment shown in Part 5, the organic matter of the base material A was removed by incineration in the roasting furnace 1 at 600°C to 650°C for 20 minutes in the air atmosphere. , a reduction heat treatment furnace 2 at a temperature of 800°C to 850°C in an atmosphere with a volumetric mixing ratio of 3 hydrogen gas to 1 nitrogen gas.
The mechanical properties of the porous metal obtained by heat treatment are shown in Nα8 in Table 1.
表１
表１の結果から、水素ガス含有量が５％以上の場合は、
Ｎｏ、 ８に示す従来例よりも強度の向上がみられ、水
素ガス含有量が５％以下の場合は従来例に近い機械的特
性であることがわかった。Table 1 From the results in Table 1, when the hydrogen gas content is 5% or more,
It was found that the strength was improved compared to the conventional example shown in No. 8, and when the hydrogen gas content was 5% or less, the mechanical properties were close to those of the conventional example.
また、熱処理温度が４５０°Ｃ〜６５０°Ｃの場合は、
基材のウレタンの熱分解はできても、液化から気化への
速度が遅く、炉内汚染が激しかった。In addition, if the heat treatment temperature is 450°C to 650°C,
Although it was possible to thermally decompose the base material urethane, the rate from liquefaction to vaporization was slow, and the inside of the furnace was heavily contaminated.
また、熱処理温度が６５０°Ｃ〜８００°Ｃの場合は、
変色は少なかったが、折り曲げ試験で亀裂が生した。In addition, if the heat treatment temperature is 650°C to 800°C,
Although there was little discoloration, cracks appeared during the bending test.
〔発明の効果］
以上のように、この発明によれば、金属結晶粒が大きく
、骨格構造そのものに欠陥の少ない、機械的強度が大き
くて剛性の強い多孔体金属を得ることができるという効
果がある。[Effects of the Invention] As described above, according to the present invention, it is possible to obtain a porous metal having large metal crystal grains, few defects in the skeletal structure itself, high mechanical strength, and high rigidity. be.
第１図はこの発明に係る熱処理装置の概略図、第２回は
カーボン塗布装置の一例を示す概略図、第３図及び第４
圓はそれぞれメツキ装置の一例を示す概略図、第５図は
従来の熱処理装置の概略図である。
Ａ・・・・・・基材、 ３０・・・・・・加熱
分解ゾーン、３２・・・・・・冷却ゾーン。
特許出願人 住友電気工業株式会社
同 代理人 鎌 １） 文Fig. 1 is a schematic diagram of a heat treatment apparatus according to the present invention, Fig. 2 is a schematic diagram showing an example of a carbon coating apparatus, Figs.
Each circle is a schematic diagram showing an example of a plating device, and FIG. 5 is a schematic diagram of a conventional heat treatment device. A: Base material, 30: Thermal decomposition zone, 32: Cooling zone. Patent applicant Sumitomo Electric Industries, Ltd. Agent Kama 1) Text
Claims (8)
の骨格表面に金属を被覆した後、上記基材の有機物体を
除去する多孔体金属の製造方法において、上記基材の有
機物体を、非酸化性雰囲気下で加熱除去することを特徴
とする多孔体金属の製造方法。(1) A method for producing a porous metal in which the skeletal surface of an organic substance having a three-dimensional network structure having an internal communication space is coated with a metal, and then the organic substance of the base material is removed, wherein the organic substance of the base material is removed. A method for producing a porous metal, characterized by removing it by heating in a non-oxidizing atmosphere.
）記載の多孔体金属の製造方法。(2) Claim (1) wherein the non-oxidizing atmosphere is hydrogen gas.
) The method for producing the porous metal described in ).
）記載の多孔体金属の製造方法。(3) Claim (1) wherein the non-oxidizing atmosphere is nitrogen gas.
) The method for producing a porous metal according to the method.
ガスである請求項（１）記載の多孔体金属の製造方法。(4) The method for producing a porous metal according to claim (1), wherein the non-oxidizing atmosphere is a mixed gas of nitrogen gas and hydrogen gas.
ある請求項（４）記載の多孔体金属の製造方法。(5) The method for producing a porous metal according to claim (4), wherein the mixing ratio of hydrogen gas in the mixed gas is 5% or more.
記載の多孔体金属の製造方法。(6) Claim (1) wherein the heating temperature is 800°C or higher.
The method for producing the porous metal described above.
）記載の多孔体金属の製造方法。(7) Claim (1) wherein the organic substance is a urethane resin.
) The method for producing the porous metal described in ).
徴とする多孔体金属を製造する際における有機物体の加
熱除去用の熱処理装置。(8) A heat treatment apparatus for heating and removing organic matter during the production of porous metal, characterized in that the inside of the furnace is adjusted to a non-oxidizing atmosphere.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23197890A JPH04116196A (en) | 1990-08-31 | 1990-08-31 | Method and apparatus for manufacturing porous body metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP23197890A JPH04116196A (en) | 1990-08-31 | 1990-08-31 | Method and apparatus for manufacturing porous body metal |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04116196A true JPH04116196A (en) | 1992-04-16 |
Family
ID=16932029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP23197890A Pending JPH04116196A (en) | 1990-08-31 | 1990-08-31 | Method and apparatus for manufacturing porous body metal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04116196A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165590A (en) * | 1994-12-14 | 1996-06-25 | Shin Etsu Chem Co Ltd | Production of porous metal |
| US5725750A (en) * | 1996-04-19 | 1998-03-10 | Sumitomo Electric Industries, Ltd. | Process for producing porous iron metal body |
-
1990
- 1990-08-31 JP JP23197890A patent/JPH04116196A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08165590A (en) * | 1994-12-14 | 1996-06-25 | Shin Etsu Chem Co Ltd | Production of porous metal |
| US5725750A (en) * | 1996-04-19 | 1998-03-10 | Sumitomo Electric Industries, Ltd. | Process for producing porous iron metal body |
| AU713085B2 (en) * | 1996-04-19 | 1999-11-25 | Sumitomo Electric Industries, Ltd. | Process for producing porous iron metal body |
| CN1109132C (en) * | 1996-04-19 | 2003-05-21 | 住友电气工业株式会社 | Process for producing porous iron metal bady |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1970442B (en) | Mesoporous carbon, method of preparing the same, and fuel cell using the carbon | |
| CN1974381B (en) | Mesoporous carbon including heteroatom, manufacturing method thereof, and fuel cell using the mesoporous carbon | |
| US3160517A (en) | Method of depositing metals and metallic compounds throughout the pores of a porous body | |
| JPH0447430B2 (en) | ||
| JPH04116196A (en) | Method and apparatus for manufacturing porous body metal | |
| US2868702A (en) | Method of forming a dielectric oxide film on a metal strip | |
| Srikanth et al. | Effect of high-temperature heat treatment duration on the purity and microstructure of MWCNTs | |
| JPS6140459B2 (en) | ||
| CN110790267A (en) | Preparation method of nitrogen-doped graphene | |
| US2887984A (en) | Apparatus for gas plating continuous length of metal strip | |
| Takashima et al. | Catalytic decomposition of trichloroethylene over Pt-/Ni-catalyst under microwave heating | |
| JP2006273645A (en) | Apparatus and method for continuously firing organic substance, carbon material, catalyst structure using the same, electrode for polymer electrolyte fuel cell, and polymer electrolyte fuel cell | |
| US3567520A (en) | Process for manufacturing electrodes of fuel cells | |
| JPS58219945A (en) | Catalyst for reforming hydrocarbon | |
| Yamagiwa | Liquid-phase synthesis of vertically aligned carbon nanotubes and related nanomaterials on preheated alloy substrates | |
| US3055089A (en) | Gaseous metal product and processes | |
| JP2568175B2 (en) | Method for producing glass plate coated with thin metal oxide layer | |
| JPH0273988A (en) | Production of porous metal | |
| DE2453089A1 (en) | REACTION BED FOR A CATALYTIC CRACKING SYSTEM | |
| KR102276228B1 (en) | Method for treating surface of carbon material | |
| CN114597428B (en) | Flexible carbon paper, preparation method thereof, gas diffusion layer and fuel cell | |
| JPS62182264A (en) | Method for sealing pore in thermally sprayed film | |
| JPH0892669A (en) | Heat treatment of metallic porous body | |
| US3196003A (en) | Process of making metal strips and sheets from waste metal | |
| DE3047849C2 (en) | Heating element for a high temperature furnace |