JPH04108876A - Coating composition - Google Patents
Coating compositionInfo
- Publication number
- JPH04108876A JPH04108876A JP22515590A JP22515590A JPH04108876A JP H04108876 A JPH04108876 A JP H04108876A JP 22515590 A JP22515590 A JP 22515590A JP 22515590 A JP22515590 A JP 22515590A JP H04108876 A JPH04108876 A JP H04108876A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- resin
- parts
- coating composition
- alkyd resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 20
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920000180 alkyd Polymers 0.000 claims abstract description 21
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 9
- 230000007797 corrosion Effects 0.000 abstract description 9
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract description 8
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- KPAPHODVWOVUJL-UHFFFAOYSA-N 1-benzofuran;1h-indene Chemical class C1=CC=C2CC=CC2=C1.C1=CC=C2OC=CC2=C1 KPAPHODVWOVUJL-UHFFFAOYSA-N 0.000 abstract description 3
- 239000000178 monomer Substances 0.000 abstract description 3
- 239000000470 constituent Substances 0.000 abstract description 2
- 150000002989 phenols Chemical class 0.000 abstract description 2
- 150000003440 styrenes Chemical class 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 12
- 238000005259 measurement Methods 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003921 oil Substances 0.000 description 5
- 235000019198 oils Nutrition 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004709 Chlorinated polyethylene Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 230000000051 modifying effect Effects 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、アルキド樹脂系塗料組成物に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to alkyd resin-based coating compositions.
アルキド樹脂系塗料は耐食性や耐候性の点でアクリル樹
脂系塗料に劣るものの、安価であるため常乾用塗料等の
各種の塗料に使用されている。また、アルキド樹脂系塗
料の耐候性を改良する検討も行われている（特開昭６２
−１８．４７７号及び特開昭６２−１９５．０５５号公
報）が、耐食性と耐候性の両者を十分満足させるものと
は言い難い。Alkyd resin paints are inferior to acrylic resin paints in terms of corrosion resistance and weather resistance, but because they are inexpensive, they are used in various paints such as air-drying paints. In addition, studies are being conducted to improve the weather resistance of alkyd resin paints (Japanese Unexamined Patent Publication No. 62
18.477 and JP-A-62-195.055) cannot be said to sufficiently satisfy both corrosion resistance and weather resistance.
クマロン−インデン樹脂は、塗料改質材として使用され
ているが（例えば、特開昭６３−１８３．９６６号公報
）、これを配合したものであってもやはりこれらを十分
満足させるものとは言い難い。Coumarone-indene resin is used as a paint modifier (for example, Japanese Patent Application Laid-open No. 183-966-1983), but even products containing this resin cannot be said to fully satisfy these requirements. hard.
本発明は、耐食性、耐候性が優れた新規なアルキド樹脂
系塗料を提供することを目的とする。An object of the present invention is to provide a novel alkyd resin paint with excellent corrosion resistance and weather resistance.
本発明者らは、アルキド樹脂系塗料に水素化クマロン−
インデン樹脂を配合すると耐候性が優れた新規なアルキ
ド樹脂系塗料が得られることを見出し本発明を完成した
。The present inventors have discovered that alkyd resin-based paints contain hydrogenated coumaron.
The present invention was completed by discovering that a new alkyd resin paint with excellent weather resistance can be obtained by blending an indene resin.
アルキド樹脂系塗料に用いられるアルキド樹脂には特に
制限はないが、好ましくは多塩基酸と多価アルコールと
からのポリエステルを、大豆油、アマニ油等の油脂又は
それより分離された脂肪酸で変成した油変成アルキド樹
脂である。この場合の油長は４０〜７５％が好ましく、
大きすぎると塗膜の硬度の低下、表面平滑性の低下等が
生じ、小さすぎると耐水性の低下等が生ずる。なお、油
長は樹脂中の脂肪酸がグリセリンと反応してトリグリセ
ライドを形成したと考えたときの、トリグリセライドが
樹脂中に占める重量百分率をいう。The alkyd resin used in the alkyd resin paint is not particularly limited, but it is preferably a polyester made from a polybasic acid and a polyhydric alcohol modified with an oil or fat such as soybean oil or linseed oil or a fatty acid separated from it. It is an oil-modified alkyd resin. In this case, the oil length is preferably 40 to 75%,
If it is too large, the hardness of the coating film will decrease, surface smoothness will decrease, and if it is too small, water resistance will decrease. Note that the oil length refers to the weight percentage of triglyceride in the resin, assuming that the fatty acid in the resin reacts with glycerin to form triglyceride.
本発明で使用する水素化クマロン−インデン樹脂は、ク
マロン−インデン樹脂を水素化して得られるものであり
、これは特開平１−２１３．３０５号公報等に記載され
た方法で製造することができる。例えば、石炭乾留で得
られるガス軽油又はコールタル軽油を脱硫精製し、これ
を酸触媒で重合してクマロン−インデン樹脂とし、つい
でこれを水素化して得られる。好ましくは、クマロンを
０．５〜１０重量％、インデンを３０〜９０重量％、フ
ェノール類を２〜２０重量％及びスチレン類を０〜３０
重量％を構成モノマー組成とするクマロンインデン樹脂
を、水素化率８０％以上、より好ましくは９５％以上と
なるまで水素化した水素化クマロン−インデン樹脂であ
る。水素化率が８０％未満では、塗料としての耐食性、
耐候性が十分に改良されない。水素化クマロン−インデ
ン樹脂の配合量は、アルキド樹脂１００重量部に対し２
０〜１００重量部の範囲か適当であり、少なすぎると改
質効果が不十分となり、多すぎると塗膜か硬くなりすぎ
る。The hydrogenated coumaron-indene resin used in the present invention is obtained by hydrogenating coumaron-indene resin, and can be produced by the method described in JP-A-1-213.305. . For example, it can be obtained by desulfurizing and refining gas light oil or coal tar light oil obtained by coal carbonization, polymerizing this with an acid catalyst to obtain coumaron-indene resin, and then hydrogenating this. Preferably, 0.5 to 10% by weight of coumarone, 30 to 90% by weight of indene, 2 to 20% by weight of phenols, and 0 to 30% of styrene.
This is a hydrogenated coumaron-indene resin obtained by hydrogenating a coumaron-indene resin having a monomer composition of % by weight to a hydrogenation rate of 80% or more, more preferably 95% or more. If the hydrogenation rate is less than 80%, the corrosion resistance as a paint
Weather resistance is not sufficiently improved. The amount of hydrogenated coumaron-indene resin is 2 parts by weight per 100 parts by weight of alkyd resin.
The amount is suitably in the range of 0 to 100 parts by weight; if it is too little, the modifying effect will be insufficient, and if it is too much, the coating will become too hard.
本発明の塗料組成物に塩素化ポリマーを配合すると、塗
料組成物の粘着性を上げて被着物への親和性を上けるほ
か、塗膜形成時における残留応力の緩和等の効果を生じ
させることができる。この目的で使用する塩素化ポリマ
ーとしては塩素含有量５０重量％以上、好ましくは６０
重量％以上の塩化ゴム、塩素化ポリプロピレン、塩素化
ポリエチレンが挙げられる。塩素化ポリマーの配合量は
、アルキド樹脂１００重量部に対し０〜１００重量部の
範囲が適当である。過剰に配合すると、相溶性が悪くな
る。When a chlorinated polymer is blended into the coating composition of the present invention, it not only increases the adhesiveness of the coating composition and improves its affinity for adherends, but also produces effects such as relieving residual stress during coating film formation. I can do it. The chlorinated polymer used for this purpose has a chlorine content of 50% by weight or more, preferably 60% by weight.
Examples include chlorinated rubber, chlorinated polypropylene, and chlorinated polyethylene in a weight percent or more. The appropriate amount of the chlorinated polymer is in the range of 0 to 100 parts by weight per 100 parts by weight of the alkyd resin. If blended in excess, compatibility will deteriorate.
本発明の塗料組成物には上記成分の他、通常の塗料に配
合される成分、例えば顔料、無機充填材、沈降防止剤、
硬化剤、安定剤、溶剤、可塑剤等を配合することができ
る。本発明の塗料組成物は、金属、その他の基材にロー
ル、はけ、スプレー等を用いる通常の塗装方法により塗
布することが可能である。In addition to the above-mentioned components, the coating composition of the present invention includes components that are included in ordinary coatings, such as pigments, inorganic fillers, antisettling agents,
A curing agent, stabilizer, solvent, plasticizer, etc. can be added. The coating composition of the present invention can be applied to metal or other substrates by a conventional coating method using a roll, brush, spray, or the like.
水素化クマロン−インデン樹脂をアルキド樹脂系塗料に
配合することにより、クマロン−インデン樹脂の有する
耐食性や耐水性改良作用に加えて、その脂環式構造によ
り耐候性も向上したものと推定される。It is presumed that by blending a hydrogenated coumaron-indene resin into an alkyd resin paint, in addition to the corrosion resistance and water resistance improving effects of the coumaron-indene resin, weather resistance is also improved due to its alicyclic structure.
使用した水素化クマロン−インデン樹脂の性状を下記に
示す。The properties of the hydrogenated coumaron-indene resin used are shown below.
水素化率：９９％
軟化点、１２３°Ｃ
数平均分子量 ８９０
構成モノマー組成
スチレン：１２重量％
ｐ−メチルスチレン：３重量％
クマロン＝２重量％
インデン：７６重量％
フェノールニア重量％
実施例１
アルキド樹脂（犬日本インキ化学工業■製、ベッコゾー
ルＪ−５１０、油長ニアＯＮ） ３０重量部、水素化ク
マロン−インデン樹脂１５重量部、酸化チタン系顔料（
石原産業■製：タイベークＣＲ−８０）２０重量部、ド
ライヤー（ナフテン酸コバルト）０．３重量部及び溶剤
（キシレン）３５重量部を配合して塗料組成物を得た。Hydrogenation rate: 99% Softening point, 123°C Number average molecular weight 890 Constituent monomer composition Styrene: 12% by weight p-methylstyrene: 3% by weight Coumaron = 2% by weight Indene: 76% by weight Phenolonia weight% Example 1 Alkyd Resin (manufactured by Inu Nippon Ink Kagaku Kogyo ■, Beccosol J-510, Yucho Nia ON) 30 parts by weight, hydrogenated coumaron-indene resin 15 parts by weight, titanium oxide pigment (
A coating composition was obtained by blending 20 parts by weight of Tybake CR-80 (manufactured by Ishihara Sangyo ■), 0.3 parts by weight of a dryer (cobalt naphthenate), and 35 parts by weight of a solvent (xylene).
この塗料組成物を、脱脂処理したＪＩＳ Ｇ−３１４１
の磨き軟鋼板（７０ｍｍ Ｘ １５０ ｍｍ Ｘ ０．
８ ｍｍ、＃２８０研磨）上に、膜厚３５趨となるよう
に塗布し、常温で７日間乾燥させた。得られた塗膜の耐
候性と耐食性を下記の条件で測定した。This coating composition was degreased to JIS G-3141.
Polished mild steel plate (70 mm x 150 mm x 0.
8 mm, #280 polished) to a film thickness of 35 mm, and dried at room temperature for 7 days. The weather resistance and corrosion resistance of the resulting coating film were measured under the following conditions.
スガ試験機■製のサンシャインウェザ−メータ内に試験
片を入れ、降雨サイクル１２分／６０分、ブラックパネ
ル温度６３℃で促進試験を行い、塗膜の光沢（ＪＩＳ
Ｋ−５４００，６０°−６０°）及び黄変度（△ＹＩ）
を測定した。A test piece was placed in a Sunshine Weather Meter manufactured by Suga Test Instruments, and an accelerated test was conducted at a rain cycle of 12 minutes/60 minutes and a black panel temperature of 63°C.
K-5400, 60°-60°) and yellowing index (△YI)
was measured.
ＪＩＳ Ｚ−２３７１に準拠した。スガ試験機■製の塩
水噴霧試験機を用い、試験室温度３５℃、空気飽和器温
度４７℃、噴霧圧１ ｋｇ ／ ＋ｆｆｌの条件で３０
日後のブリスター（ＡＳＴＭ Ｄ−７１４）とクロスカ
ット剥離幅を測定した。Compliant with JIS Z-2371. Using a salt water spray tester manufactured by Suga Test Instruments ■, the test room temperature was 35°C, the air saturator temperature was 47°C, and the spray pressure was 1 kg/+ffl.
Blister (ASTM D-714) and cross-cut peel width after 1 day were measured.
実施例２
実施例１と同様にしてアルキド樹脂３０重量部、水素化
クマロン−インデン樹脂１５重量部、塩化ゴム（旭電化
工業■製：ＣＲ−１０） １５重量部、酸化チタン系
顔料２０重量部、ドライヤー０．３重量部、安定剤（エ
ポキシ化大豆油、旭電化工業■製：アデカイザー０−１
３０Ｐ） ０． ４５重量部及び溶剤２０重量部を配合
して塗料組成物を得、これについて実施例１と同様に測
定を行った。Example 2 In the same manner as in Example 1, 30 parts by weight of alkyd resin, 15 parts by weight of hydrogenated coumaron-indene resin, 15 parts by weight of chlorinated rubber (manufactured by Asahi Denka Kogyo ■: CR-10), and 20 parts by weight of titanium oxide pigment. , dryer 0.3 parts by weight, stabilizer (epoxidized soybean oil, manufactured by Asahi Denka Kogyo ■: Adekaiser 0-1
30P) 0. A coating composition was obtained by blending 45 parts by weight and 20 parts by weight of a solvent, and measurements were carried out in the same manner as in Example 1.
実施例３
塩化ゴムの代わりに塩素化ポリエチレン（旭電化工業■
製ニアデカプレニ／ ＣＰ−１） １５重量部を配合
した他は、実施例２と同様にして塗料組成物を得、これ
について実施例１と同様に測定を行った。Example 3 Chlorinated polyethylene (Asahi Denka Kogyo ■) instead of chlorinated rubber
A coating composition was obtained in the same manner as in Example 2, except that 15 parts by weight of Niadecapleni/CP-1) was blended, and measurements were performed on this in the same manner as in Example 1.
実施例４
塩化ゴムの代わりに塩素化ポリプロピレン（旭電化工業
■製：アデカブｌ／：／ ＣＥ−４０５） １５重量
部を配合した他は、実施例２と同様にして塗料組成物を
得、これについて実施例１と同様に測定を行った。Example 4 A coating composition was obtained in the same manner as in Example 2, except that 15 parts by weight of chlorinated polypropylene (manufactured by Asahi Denka Kogyo ■: ADEKABU L/:/CE-405) was blended instead of chlorinated rubber. Measurements were made in the same manner as in Example 1.
比較例１
水素化クマロン−インデン樹脂の配合量を０とし、溶剤
の配合量を５０重量部とし他は、実施例１と同様にして
塗料組成物を得、これについて実施例１と同様に測定を
行った。Comparative Example 1 A coating composition was obtained in the same manner as in Example 1 except that the amount of hydrogenated coumaron-indene resin was 0 and the amount of solvent was 50 parts by weight, and it was measured in the same manner as in Example 1. I did it.
比較例２
水素化クマロン−インデン樹脂の配合量を０とし、溶剤
の配合量を３５重量部とした他は、実施例２と同様にし
て塗料組成物を得、これについて実施例１と同様に測定
を行った。Comparative Example 2 A coating composition was obtained in the same manner as in Example 2, except that the amount of hydrogenated coumaron-indene resin was 0 and the amount of solvent was 35 parts by weight. Measurements were taken.
比較例３
水素化クマロン−インデン樹脂の配合量を０とし、溶剤
の配合量を３５重量部とした他は、実施例３と同様にし
て塗料組成物を得、これについて実施例１と同様に測定
を行った。Comparative Example 3 A coating composition was obtained in the same manner as in Example 3, except that the amount of hydrogenated coumaron-indene resin was 0 and the amount of solvent was 35 parts by weight. Measurements were taken.
比較例４
水素化クマロン−インデン樹脂の配合量を０とし、溶剤
の配合量を３５重量部とした他は、実施例４と同様にし
て塗料組成物を得、これについて実施例１と同様に測定
を行った。Comparative Example 4 A coating composition was obtained in the same manner as in Example 4, except that the amount of hydrogenated coumaron-indene resin was 0 and the amount of solvent was 35 parts by weight. Measurements were taken.
比較例５
水素化クマロン−インデン樹脂の代わりに水素化０９石
油樹脂（荒用化学工業■製：アル、１：／ Ｐ−１２５
）を１５重量部配合した他は、実施例３と同様にして塗
料組成物を得、これについて実施例１と同様に測定を行
った。Comparative Example 5 Hydrogenated 09 petroleum resin (manufactured by Arayo Kagaku Kogyo ■: Al, 1:/P-125) instead of hydrogenated coumaron-indene resin
A coating composition was obtained in the same manner as in Example 3, except that 15 parts by weight of (15 parts by weight) was added.
上記各実施例及び比較例において得られた測定結果を第
１表に示す。Table 1 shows the measurement results obtained in each of the above Examples and Comparative Examples.
第 １ 表
〔発明の効果〕
本発明のアルキド樹脂系塗料組成物は、耐候性に優れ、
耐食性にも優れる。Table 1 [Effects of the Invention] The alkyd resin coating composition of the present invention has excellent weather resistance,
It also has excellent corrosion resistance.
Claims (2)
特徴とするアルキド樹脂系塗料組成物。(1) An alkyd resin coating composition characterized in that it contains a hydrogenated coumaron-indene resin.
ン−インデン樹脂２０〜１００重量部及び塩素化ポリマ
ー２０〜１００重量部を配合してなる請求項１記載のア
ルキド樹脂系塗料組成物。(2) The alkyd resin coating composition according to claim 1, wherein 20 to 100 parts by weight of a hydrogenated coumaron-indene resin and 20 to 100 parts by weight of a chlorinated polymer are blended with 100 parts by weight of the alkyd resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22515590A JPH04108876A (en) | 1990-08-29 | 1990-08-29 | Coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22515590A JPH04108876A (en) | 1990-08-29 | 1990-08-29 | Coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04108876A true JPH04108876A (en) | 1992-04-09 |
Family
ID=16824811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22515590A Pending JPH04108876A (en) | 1990-08-29 | 1990-08-29 | Coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04108876A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018135418A1 (en) * | 2017-01-20 | 2018-07-26 | 東洋紡株式会社 | Polyolefin coating composition |
| CN109320698A (en) * | 2018-08-27 | 2019-02-12 | 河北晨阳工贸集团有限公司 | A kind of aqueous coumarone indene resin modified alkyd resin and preparation method thereof |
| WO2019159953A1 (en) * | 2018-02-13 | 2019-08-22 | 株式会社Adeka | Coating composition, method for curing said composition, and method for manufacturing barrier film and cured product |
-
1990
- 1990-08-29 JP JP22515590A patent/JPH04108876A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018135418A1 (en) * | 2017-01-20 | 2018-07-26 | 東洋紡株式会社 | Polyolefin coating composition |
| JPWO2018135418A1 (en) * | 2017-01-20 | 2019-06-27 | 東洋紡株式会社 | Polyolefin-based paint composition |
| US10563082B2 (en) | 2017-01-20 | 2020-02-18 | Toyobo Co., Ltd. | Polyolefin coating composition |
| WO2019159953A1 (en) * | 2018-02-13 | 2019-08-22 | 株式会社Adeka | Coating composition, method for curing said composition, and method for manufacturing barrier film and cured product |
| CN111566173A (en) * | 2018-02-13 | 2020-08-21 | 株式会社艾迪科 | Coating composition, method for curing the composition, barrier film, and method for producing cured product |
| JPWO2019159953A1 (en) * | 2018-02-13 | 2021-02-04 | 株式会社Adeka | Coating composition, method of curing the composition, method of producing barrier film and cured product |
| CN109320698A (en) * | 2018-08-27 | 2019-02-12 | 河北晨阳工贸集团有限公司 | A kind of aqueous coumarone indene resin modified alkyd resin and preparation method thereof |
| CN109320698B (en) * | 2018-08-27 | 2022-10-25 | 河北晨阳工贸集团有限公司 | Waterborne coumarone resin modified alkyd resin and preparation method thereof |
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