JPH04108482A - Household/business incision press-fit implement - Google Patents

Household/business incision press-fit implement

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Publication number
JPH04108482A
JPH04108482A JP22722790A JP22722790A JPH04108482A JP H04108482 A JPH04108482 A JP H04108482A JP 22722790 A JP22722790 A JP 22722790A JP 22722790 A JP22722790 A JP 22722790A JP H04108482 A JPH04108482 A JP H04108482A
Authority
JP
Japan
Prior art keywords
reactor
diamond
base material
press
pascals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP22722790A
Other languages
Japanese (ja)
Inventor
Takeo Takino
瀧野 武雄
Tamaki Iida
飯田 玉樹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shin Etsu Chemical Co Ltd
Original Assignee
Shin Etsu Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shin Etsu Chemical Co Ltd filed Critical Shin Etsu Chemical Co Ltd
Priority to JP22722790A priority Critical patent/JPH04108482A/en
Publication of JPH04108482A publication Critical patent/JPH04108482A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To improve the cuttability, corrosion resistance and durability by forming a diamond-like carbon film on the outermost surface of the base material surface. CONSTITUTION:A stainless steel blade is washed and dried, and thereafter, installed so that the blade tip becomes right opposite against the flow direction of molybdenum vapor, on a base material supporting base of a reactor of a spatter vapor deposition device having an evaporation source of molybdenum in the inside. Subsequently, pressure in the reactor is exhausted to about 5 pascals, the evaporation source is heated to about 2100 deg.C and after molybdenum vapor is generated, a shielding plate between the evaporation source and the base body is opened and closed for 1-5 seconds. Next, a base material is installed in the reactor in which a coil-like tungsten wire is installed in the inside, and after the reactor is exhausted to about 5 pascals, methane is led in so as to become about 3% in capacity concentration, pressure in the reactor is adjusted to about 30 pascals, and under this atmosphere, an electric furnace is adjusted to about 800-850 deg.C, and the tungsten wire is conducted electrically and held at about 2000 deg.C.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は家庭用又は事務用のカミソリ、カッタ、包丁、
注入針等の切開、圧入器具類の改良に関するものである
Detailed Description of the Invention (Industrial Application Field) The present invention relates to razors, cutters, kitchen knives for home or office use,
This relates to improvements in incision and press-fit instruments such as injection needles.

(従来の技術) 家庭用又は事務用のカミソリ、カッター、包丁ハサミ、
注入針等の切開、圧入器具類は、生体、野菜、食肉等か
ら紙、プラスチックフィルム等の比較約款かいものを切
る機会が多く、また調理台やまな板の様な硬質材の上で
切ったり、対象物が多少の酸、アルカリ性のものであっ
たりするため、切削、切開力に優れたものであること、
耐久性があること及び耐腐触性に富むこと等が要求され
ている。従来このような分野で使用される器具としては
主として金属、金属合金、セラミックスあるいは金属、
金属合金にセラミックスを被覆したものが使用されてき
た。
(Prior art) Razors, cutters, knife scissors for household or office use,
Cutting and press-fitting instruments such as injection needles are often used to cut living things, vegetables, meat, etc. into paper, plastic film, and other materials, and they are also used when cutting on hard materials such as countertops and cutting boards. Since the target object may be somewhat acidic or alkaline, it must have excellent cutting and cutting power.
It is required to be durable and have high corrosion resistance. Conventionally, the instruments used in this field are mainly metals, metal alloys, ceramics, metals,
Metal alloys coated with ceramics have been used.

(発明が解決しようとする課題) 然しなから、従来の製品は腐蝕性の強いものを切削、切
開、圧入すると切味即ち切削力、切開力が急速に低下し
、耐久性に乏しく、刃面が腐蝕するために摩擦抵抗が大
きくなる等の欠点を有していた。
(Problem to be solved by the invention) However, when conventional products cut, incise, or press-fit highly corrosive materials, the cutting quality, that is, the cutting force and cutting force, decrease rapidly, and the durability is poor and the blade surface deteriorates. This has disadvantages such as increased frictional resistance due to corrosion.

本発明はこのような欠点を解消した家庭用又は事務用の
切開、圧入器具を提供しようとするものである。
The present invention aims to provide an incision and press-fitting instrument for home or office use that eliminates these drawbacks.

(課題を解決するための手段) 本発明者等は、このような問題点を解決すべく種々検討
した結果、切削性、耐腐蝕性はもとより異質のものを多
頻度に切削するときの耐久性に優れた総合的に高性能の
切開、圧入器具を得ることに成功し、本発明に至ったの
である。
(Means for Solving the Problems) As a result of various studies to solve these problems, the inventors of the present invention have found that not only machinability and corrosion resistance, but also durability when cutting different materials frequently are obtained. They succeeded in obtaining a comprehensively high-performance incision and press-fitting instrument with excellent performance, leading to the present invention.

即ち、本発明は改良された家庭用又は事務用切開、圧入
器具に係るもので、これは基材表面の最外表面がダイヤ
モンド状炭素膜で被覆されてなることを特徴とする家庭
用又は事ム用切開、圧入器具を要旨とするものである。
That is, the present invention relates to an improved cutting and press-fitting tool for household or office use, which is characterized in that the outermost surface of the base material is coated with a diamond-like carbon film. The main focus is on incisions and press-fit instruments.

以下本発明の詳細な説明する。The present invention will be explained in detail below.

本発明者等は、先に従来公知のミクロトーム用セラミッ
クス刃をダイヤモンド膜で被覆することにより高性能化
する方法を発明し、特許出願(特願昭60−49545
号、特願昭60−141815号)したが、本発明はこ
れを基礎にして改良を加えたものである。
The present inventors previously invented a method for improving the performance of a conventionally known ceramic blade for a microtome by coating it with a diamond film, and filed a patent application (Japanese Patent Application No. 60-49545).
(Japanese Patent Application No. 60-141815), but the present invention is based on this and has been improved.

本発明の家庭用又は事務用切開、圧入器具の基材として
は鉄、青銅、ステンレススチール(以下SUSとする)
、超硬金属等の金属、ジルコニア、アルミナ等のセラミ
ックス、HIP処理をしたジルコニア、アルミナ等の特
殊セラミックス等が例示される。
The base material of the household or office cutting and press-fitting instruments of the present invention is iron, bronze, and stainless steel (hereinafter referred to as SUS).
Examples include metals such as cemented carbide metals, ceramics such as zirconia and alumina, and special ceramics such as HIP-treated zirconia and alumina.

本発明の最大の特徴は、これら基材の最外表面をダイヤ
モンド状炭素膜で被覆することを特徴とするが、ダイヤ
モンド状炭素膜で被覆することにより切削性、耐腐触性
はもとより、多頻度に切削使用した場合における耐久性
が著しく向上した家庭用、事務用、切削、圧入器具の提
供が可能となった。さらにこのダイヤモンド状炭素膜に
おいてダイヤモンド含有率が80容量%以上であること
が好ましく、これ未満では満足すべき切削、切開力は得
られない。本発明では基材を先ず機械加工または成形加
工により鋭利な刃先を付けて次いで表面加工に移るが、
このダイヤモンド状炭素膜の厚さが100人より薄いと
耐久性に乏しいものとなり5000人を超えると被切削
物、被切開物、又は被圧入物との摩擦抵抗が大きくなる
で100〜5000人の範囲、好ましくは300〜30
00人とすることが良い。なお、カミソリの様な基材の
厚さが薄いものは300〜500人が良く、包丁、カッ
ターの様な基材の厚さが比較的厚いものにあっては10
00〜3000人が好ましい。また、ダイヤモンド状炭
素膜を被覆するにあたっては、基材の材質により被覆で
きなかったり、付着強度の比較的弱いものがあるため、
予め、基材表面に下地としてダイヤモンド状炭素膜の付
着強度が比較的強いMo、 W、Ta、Stおよびこれ
らの酸化物、窒化物ならびにA1□03等をスパッター
蒸着装置または真空蒸着装置にて50〜200人、好ま
しくは50〜100人蒸着してからダイヤモンド状炭素
膜を被覆しても良い。
The greatest feature of the present invention is that the outermost surface of these base materials is coated with a diamond-like carbon film. It is now possible to provide household, office, cutting, and press-fitting tools that have significantly improved durability when frequently used for cutting. Further, it is preferable that the diamond content in this diamond-like carbon film is 80% by volume or more, and if it is less than this, satisfactory cutting and cutting force cannot be obtained. In the present invention, the base material is first machined or molded to give it a sharp cutting edge, and then the surface is processed.
If the thickness of this diamond-like carbon film is less than 100 mm, it will have poor durability, and if it exceeds 5,000 mm, the frictional resistance with the object to be cut, incised, or press-fitted will increase, and the thickness of 100 to 5,000 range, preferably 300-30
It is better to set it to 00 people. In addition, for items with thin base materials such as razors, 300 to 500 people are recommended, and for items with relatively thick base materials such as kitchen knives and cutters, 10
00 to 3000 people is preferable. In addition, when coating a diamond-like carbon film, it may not be possible to coat it depending on the material of the base material, or the adhesion strength may be relatively weak.
In advance, Mo, W, Ta, St, oxides and nitrides thereof, A1□03, etc., which have relatively strong adhesion strength for a diamond-like carbon film, are deposited on the surface of the substrate as a base using a sputter deposition device or a vacuum deposition device for 50 min. The diamond-like carbon film may be coated after ~200 depositions, preferably 50-100 depositions.

次に基材表面にダイヤモンド状膜を被覆する方法を述べ
る。炭素源としては炭化水素ガス(A)を用い、必要に
応じてキャリアーガスとしてアルゴン等の不活性ガス(
C)を加えた混合ガスを用い、公知の熱フイラメント法
又はプラズマCVD法により基材上に炭化水素からダイ
ヤモンド状炭素膜を析出させる方法で実施される。炭化
水素ガスと水素ガス(B)との容量割合はA/B=0.
10〜0.001の広範囲で使用できる。また使用する
水素ガスと不活性ガスおよび炭化水素ガスの容量割合は
A/ (B−C) =0.10〜0.001でCのBに
対する置換率は50%以下であることが好ましい。又、
ここで使用される炭化水素ガスとしてはメタン、エタン
、プロパン、エチレン等が例示される。この方法の実施
について熱フイラメント法を用いた場合で示すと、まず
反応器内に基材を設置し、次いで反応器内の圧力を0.
001〜0.01Torrの範囲内になるまで排気した
後、この反応器内に炭化水素ガスと水素または必要に応
じて不活性ガスとの混合ガスを導入し圧力を10〜30
Torrの範囲内に調整する。基材表面上部数mm〜1
0mmのところにコイル状のタングステン線を設置して
通電しコイルの表面温度を1,950〜2.100℃に
保持する。基材の表面温度は800〜1.000℃に保
持するのが良く、800℃以下では本発明のダイヤモン
ド状炭素膜が生成せず、又1.000℃以上でもダイヤ
モンド状炭素膜を成膜することができない。一方、プラ
ズマCVD法を用いた場合は、先ず反応器内に基材を設
置し次いで反応器内の圧力を0.001〜0.01To
rrの範囲になるまで排気した後、この反応器内に炭化
水素ガスと水素または必要に応じて不活性ガスとの混合
ガスを導入する。反応器内の圧力はプラズマを安定に維
持するために10〜30Torrの範囲内になるように
調整し、次いでこれにマイクロ波高周波電力を印加して
系内にプラズマを発生させるとともに、基材の表面温度
が800〜1000℃になるように調整する。基材温度
が800℃以下では、ダイヤモンド状炭素膜中に水素が
混入する恐れがあり、1000℃を超えると析出したダ
イヤモンドが黒鉛に逆転移する欠点を生ずる。上記した
、熱フイラメント法、プラズマCVD法を用いることに
より炭化水素がプラズマ火炎との接触で熱分解されてダ
イヤモンドあるいは黒鉛を含むダイヤモンド膜または、
ダイヤモンド状炭素膜が均一な板状となって基材表面上
に所望の厚さに被着される。
Next, a method for coating the surface of a substrate with a diamond-like film will be described. A hydrocarbon gas (A) is used as the carbon source, and an inert gas such as argon (
A diamond-like carbon film is deposited from hydrocarbons on a substrate by a known hot filament method or plasma CVD method using a mixed gas containing C). The volume ratio of hydrocarbon gas and hydrogen gas (B) is A/B=0.
It can be used in a wide range of 10 to 0.001. Further, it is preferable that the volume ratio of the hydrogen gas, inert gas, and hydrocarbon gas used is A/(B-C) = 0.10 to 0.001, and the substitution ratio of C to B is 50% or less. or,
Examples of the hydrocarbon gas used here include methane, ethane, propane, and ethylene. To carry out this method using the hot filament method, first, a substrate is placed in a reactor, and then the pressure in the reactor is reduced to 0.
After evacuation until the pressure is within the range of 0.001 to 0.01 Torr, a mixed gas of hydrocarbon gas and hydrogen or an inert gas as necessary is introduced into the reactor to reduce the pressure to 10 to 30 Torr.
Adjust to within the Torr range. Several mm to 1 on the top of the base material surface
A coiled tungsten wire is installed at a distance of 0 mm, and electricity is applied to maintain the surface temperature of the coil at 1,950 to 2,100°C. The surface temperature of the base material is preferably maintained at 800 to 1,000°C; the diamond-like carbon film of the present invention will not form below 800°C, and the diamond-like carbon film will form even above 1,000°C. I can't. On the other hand, when using the plasma CVD method, the base material is first placed in the reactor, and then the pressure in the reactor is adjusted to 0.001 to 0.01 To.
After evacuation to a range of rr, a mixed gas of hydrocarbon gas and hydrogen or an inert gas as required is introduced into the reactor. The pressure inside the reactor is adjusted to be within the range of 10 to 30 Torr in order to maintain stable plasma, and then microwave high frequency power is applied to it to generate plasma in the system and to release the base material. Adjust the surface temperature to 800-1000°C. If the substrate temperature is below 800°C, hydrogen may be mixed into the diamond-like carbon film, and if it exceeds 1000°C, there will be a drawback that the precipitated diamond will reversely transform into graphite. By using the above-described thermal filament method or plasma CVD method, hydrocarbons are thermally decomposed by contact with plasma flame, and a diamond film containing diamond or graphite is formed.
A diamond-like carbon film is deposited in the form of a uniform plate to a desired thickness on the surface of the substrate.

第1図に家庭用、事務用切開、圧入器具の一例としてナ
イフの側面図を、第2図にこのナイフのa−a断面図に
よりダイヤモンド状炭素膜の被覆状態を示した。
FIG. 1 is a side view of a knife as an example of a cutting and press-fitting tool for household and office use, and FIG. 2 is a cross-sectional view taken along the line a-a of this knife to show the state in which the diamond-like carbon film is coated.

以下本発明の実施態様を実施例を挙げて具体的に説明す
るが、本発明はこれらに限定されるものではない。
The embodiments of the present invention will be specifically described below with reference to Examples, but the present invention is not limited thereto.

なお、成膜したダイヤモンド状炭素膜のダイヤモンド含
有率は以下に示す方法により測定し、評価した。
The diamond content of the formed diamond-like carbon film was measured and evaluated by the method shown below.

[ダイヤモンド含有率測定方法] (1)被着した膜の組成をX線回折よりダイヤモンド成
分の確認を行う。
[Method for Measuring Diamond Content] (1) Confirm the composition of the deposited film using X-ray diffraction to confirm the diamond component.

(2)基材および下地蒸着膜を溶解除去後の成膜された
ダイヤモンド状炭素膜の比重(B/A)を測定したのち
、下記式によりダイヤモンド含有率を測定評価する。ダ
イヤモンドの真比重3.515 、黒鉛の真比重2.2
5、試料の容積A (cc)、試料の重量B (gr)
、試料は黒鉛とダイヤモンドのみから成ると仮定し、黒
鉛の容積をW(cc)とすれば、B = 3.515 
(A−W) + 2.25 W(実施例) 巾6cm長さ15cm厚さ0.4mm刃角14@のステ
ンレス刃を純水及びIPAで洗浄し、乾燥してから内部
にモリブデンの蒸発源をもつスパッター蒸着装置の反応
器の基材支持台上にモリブデン蒸気の流れ方向に対して
刃先が真向いになるよう設置した。
(2) After measuring the specific gravity (B/A) of the diamond-like carbon film formed after dissolving and removing the base material and the underlying deposited film, the diamond content is measured and evaluated using the following formula. True specific gravity of diamond is 3.515, true specific gravity of graphite is 2.2
5. Sample volume A (cc), sample weight B (gr)
, assuming that the sample consists only of graphite and diamond, and assuming that the volume of graphite is W (cc), B = 3.515
(A-W) + 2.25 W (Example) A stainless steel blade with a width of 6 cm, a length of 15 cm, a thickness of 0.4 mm, and a blade angle of 14 @ was washed with pure water and IPA, dried, and then a molybdenum evaporation source was placed inside. The blade was placed on the substrate support of the reactor of a sputter vapor deposition apparatus with the cutting edge directly facing the direction of flow of molybdenum vapor.

ついでこの反応器内の圧力を5パス力ル程度に排気した
。ついで蒸発源を2100℃に加熱しモリブデン蒸気が
発生した後に蒸発源と基体との間の遮へい板を1〜3秒
開閉することによって基体の表面に膜厚80〜150人
となるモリブデンの薄膜を蒸着させた。
Then, the pressure inside the reactor was evacuated to about 5 pass pressure. Next, after heating the evaporation source to 2100°C and generating molybdenum vapor, a thin molybdenum film with a thickness of 80 to 150 mm is formed on the surface of the substrate by opening and closing the shield plate between the evaporation source and the substrate for 1 to 3 seconds. It was vapor deposited.

次にこの基材を内部にコイル状のタングステン線の設置
した反応器内に設置し反応器を5パスカルに排気したの
ちメタンが容量濃度で3%となるように導入し反応器内
の圧力は30パスカルに調整し、この雰囲気下で電気炉
を調整して800〜850℃に調整し、タングステン線
に通電し2.000℃に保ったところ基材には1,00
0〜2,000人の膜が析出した。つぎにこのステンレ
ス刃を器内から取り出して被覆膜の構造をX線回折装置
を用いて検査したところダイヤモンド成分が認められた
Next, this base material was placed in a reactor equipped with a coiled tungsten wire inside, and after the reactor was evacuated to 5 Pascals, methane was introduced to a volume concentration of 3%, and the pressure inside the reactor was The temperature was adjusted to 30 Pascals, and in this atmosphere, the electric furnace was adjusted to 800 to 850°C, and when the tungsten wire was energized and maintained at 2,000°C, the base material had a temperature of 1,000 Pascals.
0 to 2,000 membranes were deposited. Next, this stainless steel blade was taken out of the container and the structure of the coating film was examined using an X-ray diffraction device, and diamond components were found.

つづいて比重の測定結果からダイヤモンド成分の含有率
ははf90%であることが確認された。
Subsequently, it was confirmed from the measurement results of specific gravity that the content of diamond components was f90%.

次にこのステンレ刃の切味試験(JISTO201)を
行なった場合、 4.7ccであった。これに対し従来
研磨処理したま\のメスを用いて同じ試験を行うと12
ccであった。又耐久試験として一般に市販されている
塩ビフィルム(厚さ100μ)をこの刃で引き切り、5
0回繰返した後上述の切味試験を行ったところ5.3c
cであったのに対し、従来の研磨処理した刃は21cc
であった。
Next, when this stainless steel blade was subjected to a sharpness test (JISTO201), it was found to be 4.7cc. On the other hand, when the same test was performed using a conventionally polished scalpel, the result was 12
It was cc. In addition, as a durability test, a commercially available PVC film (thickness 100μ) was cut with this blade.
After repeating 0 times, the sharpness test described above was performed and the result was 5.3c.
c, whereas the conventional polished blade is 21cc.
Met.

(発明の効果) 本発明は基材表面の最外表面にダイヤモンド状炭素膜を
成膜した家庭用または事務用切開、圧入器具で、特には
ダイヤモンド含有率が80%以上の膜で被覆されている
ことが良く、切削性、耐腐触性及び耐久性に優れ、家庭
用および事務用として極めて有益である。
(Effects of the Invention) The present invention provides a cutting and press-fitting instrument for household or office use in which a diamond-like carbon film is formed on the outermost surface of a base material surface, and in particular, a device coated with a film having a diamond content of 80% or more. It has excellent machinability, corrosion resistance, and durability, making it extremely useful for household and office uses.

4、4,

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の切開、 正大器具の一例を示す ナイフの側面図、 第2図は刃先のa−a断面図で ある。 基材 ・被覆ダイヤモンド状炭素膜 柄 特許出願人  信越化学工業株式会り一代理人・弁理士
  山 本 亮 −−ヨーク第1 図 第2 図
FIG. 1 is a side view of a knife showing an example of the incision and enlargement instrument of the present invention, and FIG. 2 is a sectional view taken along line a-a of the cutting edge. Substrate/Coating Diamond-like Carbon Film Pattern Patent Applicant Shin-Etsu Chemical Co., Ltd. Agent/Patent Attorney Ryo Yamamoto --York 1 Figure 2

Claims (1)

【特許請求の範囲】 1、基材表面の最外表面がダイヤモンド状炭素膜で被覆
されてなることを特徴とする家庭用事務用切開、圧入器
具。 2、ダイヤモンド状炭素膜のダイヤモンド含有率が80
容量%以上である請求項1に記載の家庭用事務用切開、
圧入器具。
[Scope of Claims] 1. A cutting and press-fitting instrument for domestic and office use, characterized in that the outermost surface of the base material is coated with a diamond-like carbon film. 2. The diamond content of the diamond-like carbon film is 80
The household office incision according to claim 1, which has a capacity of % or more.
Press-fitting equipment.
JP22722790A 1990-08-29 1990-08-29 Household/business incision press-fit implement Pending JPH04108482A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP22722790A JPH04108482A (en) 1990-08-29 1990-08-29 Household/business incision press-fit implement

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22722790A JPH04108482A (en) 1990-08-29 1990-08-29 Household/business incision press-fit implement

Publications (1)

Publication Number Publication Date
JPH04108482A true JPH04108482A (en) 1992-04-09

Family

ID=16857498

Family Applications (1)

Application Number Title Priority Date Filing Date
JP22722790A Pending JPH04108482A (en) 1990-08-29 1990-08-29 Household/business incision press-fit implement

Country Status (1)

Country Link
JP (1) JPH04108482A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012074017A1 (en) * 2010-11-30 2012-06-07 京セラ株式会社 Ceramic knife and method for manufacturing same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012074017A1 (en) * 2010-11-30 2012-06-07 京セラ株式会社 Ceramic knife and method for manufacturing same
JP5595519B2 (en) * 2010-11-30 2014-09-24 京セラ株式会社 Ceramic blade

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