JPH0410047Y2 - - Google Patents

Description

[Detailed description of the invention] The present invention is suitable for applications such as waterproofing, antisepticism, anticorrosion, vibration proofing, soundproofing, sound insulation, insect prevention, and fire prevention. This invention relates to a bitumen-containing vinyl chloride resin board that is free from stickiness, staining, and unpleasant odor.

Conventional bitumen-containing vinyl chloride resin products include vinyl chloride resin mixed with tar-based bitumen such as coal tar and coal tar pitch, and are used for corrosion-proofing tapes and sheets for steel pipes, as well as for buildings and structures. It is used in waterproof sheets and other sound insulation sheets. It is also known that coal powder is mixed in.

They are chemically stable, water resistant, acid resistant,
It has good alkali resistance, oil resistance, etc., as well as excellent waterproof, antiseptic, and corrosion resistance properties. Moreover, the electrical insulation property is also good. Furthermore, it has excellent features such as vibration-proofing and sound-insulating effects. However, tar-based bituminous materials have a characteristic tar odor and may contain carcinogenic substances, so the use of tar-based bituminous materials has been restricted. Further, there are drawbacks such as staining caused by seepage of tar oil.

The use of asphalt as bitumen is because asphalt has a weaker odor than tar-based bitumen.
The effect of carcinogenic substances is also advantageous, but
It has the characteristic odor of asphalt and has the disadvantage of poor compatibility with vinyl chloride resin.

However, by mixing bitumen with excellent compatibility or affinity with vinyl chloride resin, not only can the price of the product be lowered, but also the thermoplastic properties are increased and the vibration-proofing, sound-proofing, and sound-insulating effects are significantly improved. In addition, it has the advantage of improving the adhesion and construction of waterproof sheets, etc., and has good compatibility and affinity with vinyl chloride resin instead of tar-based bitumen, and is free of stains and odors. The appearance of blue is desired, and furthermore, there is a demand for the development of bitumen-containing vinyl chloride resin products (for example, sheets, boards, etc.) using such bitumen.

The purpose of this invention is to meet these demands, eliminate the drawbacks of conventional bitumen-containing vinyl chloride resin boards, and have stable physical properties with less staining and odor caused by oil seepage due to bitumen. , waterproof, corrosion resistant,
The present invention provides bitumen-containing vinyl chloride resin sheets and boards that can be used for a variety of purposes, including vibration isolation, sound insulation, and insect protection.

The present invention is characterized in that a coating layer is integrally provided on the surface of the board body made of vinyl chloride resin containing bitumen, which is made by mixing petroleum pitch or petroleum pitch and asphalt as bitumen in vinyl chloride resin. The gist is a reinforced vinyl chloride resin board.

First, the materials constituting the bitumen-containing vinyl chloride resin plate of the present invention will be explained.

Petroleum pitch or petroleum pitch and asphalt that are mixed into vinyl chloride resin as bitumen are as follows.

Petroleum pitch is a petroleum pitch produced through a process of high-temperature heat treatment of crude oil vacuum residue oil.
It has a high softening point (ring and ball method) of 130-250°C, and a high fixed carbon content of 40-80% by weight. It is also more aromatic than asphalt, and has an aromaticity similar to that of coal tar pitch. Shows good compatibility with coal tar, creosote, anthracene oil, etc.
In addition, it is compatible with asphalt and has good compatibility with process oils rich in aromatic and naphthenic hydrocarbons. It also has good affinity with plasticity. Furthermore, it is chemically stable, has excellent water resistance and chemical resistance, is stable against microorganisms, and is odorless. It is usually supplied in the form of lumps or powder, but it can also be pulverized into fine particles using a grinder, mill, etc. Petroleum pitch has good miscibility and affinity with vinyl chloride resin.

Asphalt includes natural asphalt such as gilsonite, lake asphalt (e.g. Trinidad asphalt), straight asphalt,
These are petroleum asphalts such as semi-blown asphalt, blown asphalt, and propane deasphalt.

Although it is difficult to mix asphalt with vinyl chloride resin alone, it becomes possible to mix it with vinyl chloride resin by using petroleum pitch together.

The ratio of petroleum pitch and asphalt when kneading into vinyl chloride resin is, when the sum of the amount of petroleum pitch and asphalt is 100% by weight.
Generally, the amount of petroleum pitch used is 100 to 20% by weight, and the amount of asphalt is used in the range of 0 to 80% by weight. Also,
The total amount of petroleum pitch and asphalt is in the range of 5 to 300 parts by weight based on 100 parts by weight of the vinyl chloride resin.

As the vinyl chloride resin, materials that are generally used for vinyl chloride resin sheets, plates, etc. are used. That is, they include commonly used homopolymers and copolymers, as well as those in which other polymers and rubbers are used in combination.

PVC resin products generally contain stabilizers, anti-aging agents, plasticizers, process oils, fillers, colorants, pigments, and other agents such as flame retardants, antistatic agents, fungicides, and foaming agents. It is also possible to use a product with appropriate additions such as agents). Also,
Vinyl chloride resin products that can be recycled can also be used, and the bitumen-containing vinyl chloride resin sheets and boards of the present invention can also be used in the same way.

Petroleum pitch for vinyl chloride resin, asphalt, other plasticizers, process oil, stabilizers,
Machines and equipment used for ordinary vinyl chloride resins are used for adding, mixing, kneading, and manufacturing products of antiaging agents, fillers, colorants, and other chemicals. In addition, the coating layer provided on the surface of the board body made of bitumen-containing vinyl chloride resin is for protecting and decorating the surface of the bitumen-containing vinyl chloride resin board of the present invention. It also improves the strength, dimensional stability, workability, etc. of vinyl resin boards.

The coating layer may include inorganic fibers (e.g. glass fibers), natural organic fibers, semi-synthetic fibers (e.g.
rayon, acetate, etc.), synthetic fibers (e.g.
polyester, polyamide, polyimide, aromatic, polyamide, polypropylene, polyethylene, vinylon, acrylic, polyvinyl chloride, polyvinylidene chloride, polyurethane, fluororesin, etc.), carbon fiber, metal fiber (e.g. steel,
Non-woven fabrics, woven fabrics, knitted fabrics made of stainless steel, etc., sheets of foamed plastics (e.g., urethane foam, etc.), paper sheets, plastics (e.g., polyethylene, polypropylene, vinylon, polyvinyl chloride, polyurethane, etc.) (vinyl acetate copolymer, etc.), natural rubber or synthetic rubber sheets, leather or synthetic leather sheets, metals (e.g. aluminum,
There are foils and sheets made of copper, tin, etc.).

These coating layers provide a smooth surface finish,
The surface may be roughened, bent into a corrugated shape, or the surface may be treated with chemicals or synthetic resin. Furthermore, it is also possible to flock a large number of single fibers or print designs and patterns.

Next, the bitumen-containing vinyl chloride resin material of the present invention will be explained according to illustrated examples.

In the figure, reference numeral 1 indicates the board body, which is made of bitumen-containing vinyl chloride resin, and ranges from thin sheet-like ones to those with appropriate thickness, depending on the purpose of use, place of use, etc. The thickness is selected. Reference numeral 2 denotes a coating layer, which is integrally bonded to one or both of the upper and lower surfaces of the plate body 1. The coating layer 2 can be bonded to the surface of the plate body 1 by supplying the coating layer 2 during the process of forming the plate body 1 from bitumen-containing vinyl chloride resin, or by integrally forming the coating layer 2. Alternatively, the plate main body 1 may be formed in advance from a bitumen-containing vinyl chloride resin, and then bonded to the surface thereof by an appropriate bonding means such as using an adhesive. Reference numeral 3 denotes a pressure-sensitive adhesive layer, which is provided as necessary on the surface of the plate main body 1 on which the coating layer 2 is not provided, and a known pressure-sensitive adhesive can be used as appropriate. This is for attaching the bituminous vinyl chloride resin board of the present invention to a location. Reference numeral 4 denotes a release paper, which covers and protects the pressure-sensitive adhesive layer 3 and prevents it from sticking during handling; the release paper 4 is peeled off before use. Reference numeral 5 indicates irregularities, which are provided as necessary on the coating layer 2 provided on the surface of the plate body 1, and can decorate the surface.

As mentioned above, the bitumen-containing vinyl chloride resin board of the present invention has a structure in which a coating layer is provided on the surface to protect the surface, strengthen the entire surface, and also allow the surface to be decorated. .

The bitumen-containing vinyl chloride resin that forms the board body uses petroleum pitch or petroleum pitch and asphalt for the bitumen, so it has good miscibility and affinity with the vinyl chloride resin, and has good physical and chemical properties. The target column shape is stable. Furthermore, due to the presence of oil pitch, there is no oozing of oil or the like, so there is no contamination or stickiness. Moreover, a product without unpleasant odor can be obtained. Furthermore, since it contains bitumen, it has good vibration-proofing, sound-proofing, and sound-insulating properties, as well as excellent waterproofing, moisture-proofing, antiseptic, and corrosion-proofing properties. Furthermore, since it is mainly made of vinyl chloride, it has self-extinguishing properties and can be used for fire prevention purposes, and also has the practical benefit of being expected to have an insect repellent effect.

Furthermore, according to the present invention, since a coating layer is provided on the surface of the bitumen-containing vinyl chloride resin board,
The surface of the bitumen-containing vinyl chloride resin board can be protected and the decorative effect can be enhanced. In addition, by providing a coating layer, it has excellent strength and dimensional stability, is stable against temperature changes, has good formability in press processing, and is easy to work with and handle, such as by making deep drawing possible. It has good practical benefits.

[Brief explanation of drawings]

The drawings show an embodiment of the present invention; FIG. 1 is a partially cutaway perspective view, and FIGS. 2 and 3 are longitudinal sectional side views showing other embodiments. The symbols in the figure are explained as follows. 1 is a board body made of vinyl chloride resin containing bitumen, 2 is a reinforcing material, 3 is a pressure-sensitive adhesive layer, 4 is a release paper, and 5 is an uneven surface.

Claims (1)

[Scope of utility model registration request] A bitumen-containing vinyl chloride resin board comprising a bitumen-containing vinyl chloride resin made by kneading petroleum pitch or petroleum pitch and asphalt as bitumen into a vinyl chloride resin, and having a coating layer integrally provided on the surface of the board body.