JPH0391750A - Processing method for photosensitive planographic plate - Google Patents
Processing method for photosensitive planographic plateInfo
- Publication number
- JPH0391750A JPH0391750A JP22875789A JP22875789A JPH0391750A JP H0391750 A JPH0391750 A JP H0391750A JP 22875789 A JP22875789 A JP 22875789A JP 22875789 A JP22875789 A JP 22875789A JP H0391750 A JPH0391750 A JP H0391750A
- Authority
- JP
- Japan
- Prior art keywords
- plate
- positive
- negative
- developer
- replenisher
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000003672 processing method Methods 0.000 title claims description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 30
- 238000012545 processing Methods 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000011161 development Methods 0.000 claims abstract description 15
- 230000000694 effects Effects 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 230000007423 decrease Effects 0.000 claims description 4
- 239000007788 liquid Substances 0.000 abstract description 15
- 239000003513 alkali Substances 0.000 abstract description 2
- -1 ethyl acetate Chemical class 0.000 description 46
- 239000000243 solution Substances 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 15
- 239000002736 nonionic surfactant Substances 0.000 description 13
- 230000018109 developmental process Effects 0.000 description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000004115 Sodium Silicate Substances 0.000 description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 8
- 229910052911 sodium silicate Inorganic materials 0.000 description 8
- 239000003638 chemical reducing agent Substances 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 125000000217 alkyl group Chemical group 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000003093 cationic surfactant Substances 0.000 description 6
- 159000000000 sodium salts Chemical class 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000005711 Benzoic acid Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 235000010233 benzoic acid Nutrition 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 230000002950 deficient Effects 0.000 description 3
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 235000021317 phosphate Nutrition 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- 238000010186 staining Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 229940082044 2,3-dihydroxybenzoic acid Drugs 0.000 description 2
- UIAFKZKHHVMJGS-UHFFFAOYSA-N 2,4-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1O UIAFKZKHHVMJGS-UHFFFAOYSA-N 0.000 description 2
- WXTMDXOMEHJXQO-UHFFFAOYSA-N 2,5-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC(O)=CC=C1O WXTMDXOMEHJXQO-UHFFFAOYSA-N 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229960004050 aminobenzoic acid Drugs 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- XBMOWLAOINHDLR-UHFFFAOYSA-N dipotassium;hydrogen phosphite Chemical compound [K+].[K+].OP([O-])[O-] XBMOWLAOINHDLR-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000010413 mother solution Substances 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N nonanoic acid Chemical compound CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 125000006353 oxyethylene group Chemical group 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229960005323 phenoxyethanol Drugs 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 229910052913 potassium silicate Inorganic materials 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 235000019795 sodium metasilicate Nutrition 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 150000008054 sulfonate salts Chemical class 0.000 description 2
- ROVRRJSRRSGUOL-UHFFFAOYSA-N victoria blue bo Chemical compound [Cl-].C12=CC=CC=C2C(NCC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 ROVRRJSRRSGUOL-UHFFFAOYSA-N 0.000 description 2
- FFJCNSLCJOQHKM-CLFAGFIQSA-N (z)-1-[(z)-octadec-9-enoxy]octadec-9-ene Chemical compound CCCCCCCC\C=C/CCCCCCCCOCCCCCCCC\C=C/CCCCCCCC FFJCNSLCJOQHKM-CLFAGFIQSA-N 0.000 description 1
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical compound NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 1
- YUCTUWYCFFUCOR-UHFFFAOYSA-N 1,4-dihexoxy-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCC YUCTUWYCFFUCOR-UHFFFAOYSA-N 0.000 description 1
- CUOSYYRDANYHTL-UHFFFAOYSA-N 1,4-dioctoxy-1,4-dioxobutane-2-sulfonic acid;sodium Chemical compound [Na].CCCCCCCCOC(=O)CC(S(O)(=O)=O)C(=O)OCCCCCCCC CUOSYYRDANYHTL-UHFFFAOYSA-N 0.000 description 1
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- BFXKJHOJSIMHSJ-UHFFFAOYSA-N 1-(hexadecoxymethyl)pyridin-1-ium Chemical class CCCCCCCCCCCCCCCCOC[N+]1=CC=CC=C1 BFXKJHOJSIMHSJ-UHFFFAOYSA-N 0.000 description 1
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- LNETULKMXZVUST-UHFFFAOYSA-N 1-naphthoic acid Chemical compound C1=CC=C2C(C(=O)O)=CC=CC2=C1 LNETULKMXZVUST-UHFFFAOYSA-N 0.000 description 1
- XDESGXRLUIHEJT-UHFFFAOYSA-N 2,3,4-tribenzylphenol Chemical compound C=1C=CC=CC=1CC1=C(CC=2C=CC=CC=2)C(O)=CC=C1CC1=CC=CC=C1 XDESGXRLUIHEJT-UHFFFAOYSA-N 0.000 description 1
- VZQBDGHUOBRFAA-UHFFFAOYSA-N 2-(2,6-dihydroxyphenyl)benzaldehyde Chemical compound C1(O)=C(C(O)=CC=C1)C1=CC=CC=C1C=O VZQBDGHUOBRFAA-UHFFFAOYSA-N 0.000 description 1
- IWSZDQRGNFLMJS-UHFFFAOYSA-N 2-(dibutylamino)ethanol Chemical compound CCCCN(CCO)CCCC IWSZDQRGNFLMJS-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- JUVBNUWZRZREEE-UHFFFAOYSA-N 2-hydroxyethyl hexanoate Chemical compound CCCCCC(=O)OCCO JUVBNUWZRZREEE-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- UPHOPMSGKZNELG-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=C(O)C=CC2=C1 UPHOPMSGKZNELG-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- CUZKCNWZBXLAJX-UHFFFAOYSA-N 2-phenylmethoxyethanol Chemical compound OCCOCC1=CC=CC=C1 CUZKCNWZBXLAJX-UHFFFAOYSA-N 0.000 description 1
- ZDFKSZDMHJHQHS-UHFFFAOYSA-N 2-tert-butylbenzoic acid Chemical compound CC(C)(C)C1=CC=CC=C1C(O)=O ZDFKSZDMHJHQHS-UHFFFAOYSA-N 0.000 description 1
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 1
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- XZIIFPSPUDAGJM-UHFFFAOYSA-N 6-chloro-2-n,2-n-diethylpyrimidine-2,4-diamine Chemical compound CCN(CC)C1=NC(N)=CC(Cl)=N1 XZIIFPSPUDAGJM-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 description 1
- ISBWNEKJSSLXOD-UHFFFAOYSA-N Butyl levulinate Chemical compound CCCCOC(=O)CCC(C)=O ISBWNEKJSSLXOD-UHFFFAOYSA-N 0.000 description 1
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000005643 Pelargonic acid Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- 239000005819 Potassium phosphonate Substances 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 229940022663 acetate Drugs 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229940010556 ammonium phosphate Drugs 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- XFOZBWSTIQRFQW-UHFFFAOYSA-M benzyl-dimethyl-prop-2-enylazanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC1=CC=CC=C1 XFOZBWSTIQRFQW-UHFFFAOYSA-M 0.000 description 1
- 229940114055 beta-resorcylic acid Drugs 0.000 description 1
- 239000001191 butyl (2R)-2-hydroxypropanoate Substances 0.000 description 1
- 229940043232 butyl acetate Drugs 0.000 description 1
- 229940005460 butyl levulinate Drugs 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 229940116349 dibasic ammonium phosphate Drugs 0.000 description 1
- 229940111685 dibasic potassium phosphate Drugs 0.000 description 1
- 229940061607 dibasic sodium phosphate Drugs 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- YXXXKCDYKKSZHL-UHFFFAOYSA-M dipotassium;dioxido(oxo)phosphanium Chemical compound [K+].[K+].[O-][P+]([O-])=O YXXXKCDYKKSZHL-UHFFFAOYSA-M 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- ZRRLFMPOAYZELW-UHFFFAOYSA-N disodium;hydrogen phosphite Chemical compound [Na+].[Na+].OP([O-])[O-] ZRRLFMPOAYZELW-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940074391 gallic acid Drugs 0.000 description 1
- 235000004515 gallic acid Nutrition 0.000 description 1
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 1
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229940079826 hydrogen sulfite Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940031993 lithium benzoate Drugs 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229940006116 lithium hydroxide Drugs 0.000 description 1
- LDJNSLOKTFFLSL-UHFFFAOYSA-M lithium;benzoate Chemical compound [Li+].[O-]C(=O)C1=CC=CC=C1 LDJNSLOKTFFLSL-UHFFFAOYSA-M 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N n-hexadecyl alcohol Natural products CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002900 organolithium compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- HKOOXMFOFWEVGF-UHFFFAOYSA-N phenylhydrazine Chemical compound NNC1=CC=CC=C1 HKOOXMFOFWEVGF-UHFFFAOYSA-N 0.000 description 1
- 229940067157 phenylhydrazine Drugs 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- DJEHXEMURTVAOE-UHFFFAOYSA-M potassium bisulfite Chemical compound [K+].OS([O-])=O DJEHXEMURTVAOE-UHFFFAOYSA-M 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000010259 potassium hydrogen sulphite Nutrition 0.000 description 1
- 229940093932 potassium hydroxide Drugs 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 1
- 235000019252 potassium sulphite Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 229940047670 sodium acrylate Drugs 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940083608 sodium hydroxide Drugs 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- FGXAXWOAJVOILP-UHFFFAOYSA-M sodium;2-[methyl(pentadecyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCCCCN(C)CC([O-])=O FGXAXWOAJVOILP-UHFFFAOYSA-M 0.000 description 1
- KIMPPGSMONZDMN-UHFFFAOYSA-N sodium;dihydrogen phosphite Chemical compound [Na+].OP(O)[O-] KIMPPGSMONZDMN-UHFFFAOYSA-N 0.000 description 1
- 229940035044 sorbitan monolaurate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229940062627 tribasic potassium phosphate Drugs 0.000 description 1
- 229940001496 tribasic sodium phosphate Drugs 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Photosensitive Polymer And Photoresist Processing (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は感光性平版印刷版(耽下、「PS版」という)
の処理方法に関し、更に詳しくは、ネガ型PS版とボジ
型PS版とを自動現像機を用い補充液を補充してネガ・
ポジ共通現像液で現像する処理方法に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a photosensitive lithographic printing plate (referred to as a "PS plate").
Regarding the processing method, in more detail, the negative-tone PS plate and the positive-tone PS plate are refilled with replenisher using an automatic developing machine and the negative and positive PS plates are processed.
The present invention relates to a processing method of developing with a positive common developer.
従来、ネガ型PS版とポジ型PS版をI台の自動現像機
を用いネガ型PS版とポジ型PS版の共通現像液で補充
液を補充して現像処理を行う方法においては、ネガ型P
S版を現像するtこめに現像液に有機溶剤を含有させる
ことが必要であったが、同時にポジ型PS版の画像部が
侵されるという問題があった。Conventionally, in the method of developing a negative PS plate and a positive PS plate by replenishing a replenisher with a common developer for the negative PS plate and positive PS plate using I automatic developing machines, P
It was necessary to include an organic solvent in the developer before developing the S plate, but at the same time there was a problem in that the image area of the positive PS plate was attacked.
この問題を解決する手段として現像液に界面活性剤を添
加することが知られていたが、補充液を添加しながら現
像処理を行う際にはネガ型PS版を処理する際とポジ型
PS版を処理する際の界面活性剤の消費量が異なるため
に、ネガ型PS版とポジ型Ps版の処理比率によっては
現像液中の界面活性剤の濃度が低下してボジ型PS版の
画像部が侵されたり、逆に界面活性剤の濃度が過大にな
って、ボジ型PS版の現像性が抑制されるという問題が
あった。It has been known to add a surfactant to the developing solution as a means to solve this problem, but when developing while adding a replenisher, there is a difference between processing a negative PS plate and a positive PS plate. Since the amount of surfactant consumed during processing differs, depending on the processing ratio of the negative PS plate and the positive PS plate, the concentration of surfactant in the developer may decrease, causing the image area of the positive PS plate to decrease. There was a problem that the surfactant was attacked or the concentration of the surfactant became excessive, which inhibited the developability of the positive type PS plate.
本発明の目的は、ネガ型PS版とボジ型PS版とをネガ
・ポジ共通現像液で補充液を補充して現像処理するPS
版の処理方法において、ボジ型PS版の現像品質を安定
に維持できる処理方法を提供することである。The purpose of the present invention is to develop a negative PS plate and a positive PS plate by replenishing a replenisher with a common negative/positive developer.
An object of the present invention is to provide a processing method that can stably maintain the development quality of a positive type PS plate.
本発明の上記目的は、自動現像機を用い、ネガ型感光性
平版印刷版及びボジ型感光性平版印刷版を同一の繰り返
し使用される水を主たる溶媒とするアルカリ性のネガ・
ボジ共通現像液で現像処理し、該現像処理によって低下
する現像液の活性度を補充液を添加して補償する感光性
平版印刷版の処理方法において、ネガ型感光性平版印刷
版とボジ型感光性平版印刷版との処理比率によって補充
液中の界面活性剤の含有量を調節することを特徴とする
感光性平版印刷版の処理方法によって達戊される。また
、本発明は、上記処理方法における補充液中の界面活性
剤の含有量の調節方法として、補充液と界面活性剤溶液
とを別々に用意しておき、その混合比を変えることによ
って調節することを特徴とするものである。The above-mentioned object of the present invention is to produce an alkaline negative film containing water as the main solvent by using an automatic developing machine to process a negative-working photosensitive lithographic printing plate and a positive-working photosensitive lithographic printing plate in the same repeated manner.
In a method for processing a photosensitive lithographic printing plate in which a photosensitive lithographic printing plate is developed with a common developer and a replenisher is added to compensate for the decreased activity of the developer due to the development process, a negative photosensitive lithographic printing plate and a positive photosensitive lithographic printing plate are used. This is achieved by a method for processing a photosensitive lithographic printing plate, which is characterized in that the content of the surfactant in the replenisher is adjusted depending on the processing ratio with the photosensitive lithographic printing plate. In addition, the present invention provides a method for adjusting the surfactant content in the replenisher solution in the above treatment method, in which the replenisher solution and the surfactant solution are prepared separately, and the content is adjusted by changing the mixing ratio of the replenisher solution and the surfactant solution. It is characterized by this.
以下、本発明について詳述する。The present invention will be explained in detail below.
本発明に用いられる現像液は、水を主たる溶媒とする(
具体的には溶媒の50重量%以上が水である)アルカリ
性のネガ・ポジ共通現像液である。The developer used in the present invention has water as its main solvent (
Specifically, it is an alkaline negative/positive common developer (in which 50% by weight or more of the solvent is water).
その組戒は、アルカリ剤のほかに有機溶剤及び界面活性
剤を含有する。The composition contains organic solvents and surfactants in addition to alkaline agents.
本発明の現像液はアルカリ剤としてケイ酸アルカリを含
有する。ケイ酸アルカリとしては例えばケイ酸カリウム
、ケイ酸ナトリウム、メタケイ酸ナトリウム、メタケイ
酸カリウム、ケイ酸アンモニウム等が挙げられる。ケイ
酸アルカリの現像液中の含有量は0.3〜IO重量%の
範囲が好ましい。The developer of the present invention contains an alkali silicate as an alkaline agent. Examples of the alkali silicate include potassium silicate, sodium silicate, sodium metasilicate, potassium metasilicate, and ammonium silicate. The content of alkali silicate in the developing solution is preferably in the range of 0.3 to IO% by weight.
また、ケイ酸アルカリはS10.濃度でO.l〜7,0
重量%の範囲が好ましい。In addition, alkali silicate is S10. The concentration is O. l~7,0
A weight percent range is preferred.
現像液及び現像補充液にはケイ酸アルカリ以外のアルカ
リ剤を併用することができ、例えば、水酸化カリウム、
水酸化ナトリウム、水酸化リチウム、第三リン酸ナトリ
ウム、第二リン酸ナトリウム、第三リン酸カリウム、第
二リン酸カリウム、第三リン酸アンモニウム、第二リン
酸アンモニウム、メタケイ酸ナトリウム、重炭酸ナトリ
ウム、炭酸ナトリウム、炭酸カリウム、炭酸アンモニウ
ムなどのような無機アルカリ剤、モノ、ジ又はトリエタ
ノールアミン及び水酸化テトラアルキルのような有機ア
ルカリ剤を併用することができる。Alkali agents other than alkali silicates can be used in combination with the developer and developer replenisher, such as potassium hydroxide,
Sodium hydroxide, lithium hydroxide, tribasic sodium phosphate, dibasic sodium phosphate, tribasic potassium phosphate, dibasic potassium phosphate, tribasic ammonium phosphate, dibasic ammonium phosphate, sodium metasilicate, bicarbonate Inorganic alkaline agents such as sodium, sodium carbonate, potassium carbonate, ammonium carbonate, etc., organic alkaline agents such as mono-, di- or triethanolamine and tetraalkyl hydroxide can be used in combination.
現像液のpHは12以上が好ましく、より好ましくは1
2.5〜13.5の範囲である。The pH of the developer is preferably 12 or higher, more preferably 1.
It is in the range of 2.5 to 13.5.
本発明に係る現像液が含有する有機溶媒としては2 0
’0おける水に対する溶解度がIO重量%以下のもの
が好ましく、例えば酢酸エチル、酢酸プロビル、酢酸ブ
チル、酢酸べ冫ジル、エチレングリコールモノブチルア
セート、乳酸ブチル、レブリン酸ブチルのようなカルポ
ン酸エステル;エチルブチルケトン、メチルイソブチル
ケトン、シクロヘキサノンのようなケトン類:エチレン
グリコーノレモノブチルエーテル、エチレングリコール
ベンジルエーテル、エチレングリコールモノフェニルエ
一テル、べ冫シノレアルコーノレ、ノチノレ7エニルカ
ルビノール、n−アミルアルコール、メチルアミンアル
コールのようなアルコール類;キシレンのようなアルキ
ル置換芳香族炭化水素;メチレンジクロライド、エチレ
ンジクロライド、モノクロベンゼンのようなハロゲン化
炭化水素などがある。これらの有機溶媒は一種以上を用
いてもよい。The organic solvent contained in the developer according to the present invention is 20
The solubility in water at '0 is preferably IO% by weight or less, such as carboxylic acid esters such as ethyl acetate, probyl acetate, butyl acetate, benzyl acetate, ethylene glycol monobutylacetate, butyl lactate, and butyl levulinate. Ketones such as ethyl butyl ketone, methyl isobutyl ketone, cyclohexanone: ethylene glycol monobutyl ether, ethylene glycol benzyl ether, ethylene glycol monophenyl ether, vecinoreal alcohol, notinol 7-enyl carbinol, n- Alcohols such as amyl alcohol and methylamine alcohol; alkyl-substituted aromatic hydrocarbons such as xylene; halogenated hydrocarbons such as methylene dichloride, ethylene dichloride, and monochlorobenzene. One or more types of these organic solvents may be used.
有機溶剤の現像液中の含有量は0,05〜IO重量%の
範囲が好ましい。The content of the organic solvent in the developer is preferably in the range of 0.05 to IO% by weight.
本発明における現像液が含有する界面活性剤は、ノニオ
ン、カチオン、アニオン、両性のいずれでもよいが、好
ましくはノニオン界面活性剤又は力チオン界面活性剤で
あり、より好ましくはノニオン界面活性剤である。The surfactant contained in the developer in the present invention may be nonionic, cationic, anionic, or amphoteric, but is preferably a nonionic surfactant or a cationic surfactant, and more preferably a nonionic surfactant. .
ノニオン界面活性剤にはポリエチレングリコール型と多
価アルコール型であるが、どちらも使用できる。現像性
能の点からはポリエチレングリコール型のノニオン界面
活性剤が好ましく、その中でもエチレンオキシ基( −
CH2CH,O− )を3以上有し、かつHLB値(
HLBはHydrophile−Lipopbile
Balanceの略)が5以上(より好ましくは8〜2
0.更に好ましくは15〜20)のノニオン界面活性剤
がより好ましい。Nonionic surfactants include polyethylene glycol type and polyhydric alcohol type, and both can be used. From the viewpoint of development performance, polyethylene glycol type nonionic surfactants are preferred, and among them, ethyleneoxy group (-
CH2CH,O-) is 3 or more, and HLB value (
HLB is Hydrophile-Lipopbile
Balance) is 5 or more (more preferably 8 to 2)
0. More preferably, the nonionic surfactants 15 to 20) are more preferred.
また、ノニオン界面活性剤のうち、エチレン才キン基と
プロピレンオキシ基の両者を有するものが特に好ましく
、そのなかでHLB値が8以上のものがより好ましい。Furthermore, among nonionic surfactants, those having both an ethylene group and a propylene oxy group are particularly preferable, and among these, those having an HLB value of 8 or more are more preferable.
ノニオン界面活性剤の好ましい例として下記一般式〔l
〕〜〔8〕で表される化合物が挙げられる。As a preferable example of the nonionic surfactant, the following general formula [l
] to [8] are mentioned.
( 1 ) R−0− (CHx01.O)nH〔3
〕
R−0
(CHzCHO)m (C}IzCHzO)nH〔6
〕
Ho(C,H40)a − (C,H.O)b − (
Czl{ao)cHC8) I{O−(α{zcH2
0)nu(1)〜〔8〕式において、Rは水素原子又は
l価の有機基を表す。該有機基としては、例えば直鎖も
しくは分岐の炭素数1〜30の、置換基{例えばアリー
ル基(フェニル等)}を有していてもよいアルキル基、
アルキル部分が上記アルキル基であるアルキルカルボニ
ル基、置換基(例えばヒドロキシル基、上記のようなア
ルキル基等)を有していてもよいフェニル基等が挙げら
れる。a1b,c,m,n,x及びyは各々l〜40の
整数を表す。(1) R-0- (CHx01.O)nH[3
] R-0 (CHzCHO)m (C}IzCHzO)nH[6
] Ho(C,H40)a − (C,H.O)b − (
Czl{ao)cHC8) I{O-(α{zcH2
0) nu In the formulas (1) to [8], R represents a hydrogen atom or a l-valent organic group. Examples of the organic group include a linear or branched alkyl group having 1 to 30 carbon atoms that may have a substituent {for example, an aryl group (phenyl, etc.)};
Examples thereof include an alkylcarbonyl group in which the alkyl moiety is the above alkyl group, a phenyl group which may have a substituent (for example, a hydroxyl group, an alkyl group as described above, etc.). a1b, c, m, n, x and y each represent an integer of 1 to 40.
次に、ノニオン界面活性剤の具体例を示す。Next, specific examples of nonionic surfactants will be shown.
ポリエチレングリコール、ポリオキシエチレンラウリル
エーテル、ポリオキシエチレンノニルエーテル、ポリオ
キシエチレンセチノレエーテル、ポリオキシエチレンス
テアリルエーテル、ポリオキシエチレンオレイルエーテ
ル、ポリオキシエチレンベヘニルエーテル、ポリオキシ
エチレンポリオキシプロピレンセチルエーテル、ボリオ
キシエチレンポリオキシプロピレンベヘニルエーテル、
ポリオキシエチレンノニル7エニルエーテル、ポリオキ
シエチレンオクチルフェニルエーテル、ホリオキシエチ
レンステアリルアミン、ボリオキシエチレンオレイルア
ミン、ポリオキシエチレンステアリン酸アミド、ポリオ
キシエチレンオレイン酸アミド、ポリオキシエチレンヒ
マシ油、ポリオキシエチレンアビエチルエーテル、ポリ
オキンエチレンラノリンエーテノレ、ホリオキシエチレ
ンモノラウレート、ポリオキシエチレンモノステアレー
ポリオキシエチレングリセノレモノステアレート、ポリ
オキシエチレンプロピレングリコールモノステアレート
、オキシエチレンオキシブロビレンブロックボリマー
ジスチレン化フェノールポリエチレンオキシト付加物、
トリベンジルフェノールポリエチレンオキシド付加物、
オクチルフェノールポリオキシエチレンポリオキシプロ
ピレン付加物、グリセロールモノステアレート、ソルビ
タンモノラウレート、ポリオキシエチレンソルビタンモ
ノラウレート等。Polyethylene glycol, polyoxyethylene lauryl ether, polyoxyethylene nonyl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene behenyl ether, polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene oxyethylene polyoxypropylene behenyl ether,
Polyoxyethylene nonyl 7-enyl ether, polyoxyethylene octylphenyl ether, polyoxyethylene stearylamine, polyoxyethylene oleylamine, polyoxyethylene stearic acid amide, polyoxyethylene oleic acid amide, polyoxyethylene castor oil, polyoxyethylene abi Ethyl ether, polyoxyethylene lanolin ether, polyoxyethylene monolaurate, polyoxyethylene monostearate, polyoxyethylene glycol monostearate, polyoxyethylene propylene glycol monostearate, oxyethylene oxybrobylene block polymer
distyrenated phenol polyethylene oxyto adduct,
Tribenzylphenol polyethylene oxide adduct,
Octylphenol polyoxyethylene polyoxypropylene adduct, glycerol monostearate, sorbitan monolaurate, polyoxyethylene sorbitan monolaurate, etc.
ノニオン界面活性剤の重量平均分子量は300〜100
00の範囲が好まし<、500〜5000の範囲が特に
好ましい。ノニオン型界面活性剤は1種を単独で含有さ
せても、又2種以上を併用してもよい。The weight average molecular weight of the nonionic surfactant is 300 to 100
The range of 00 is preferred, and the range of 500 to 5000 is particularly preferred. One type of nonionic surfactant may be contained alone, or two or more types may be used in combination.
カチオン界面活性剤はアミン型と第四アンモニウム塩型
に大別されるが、これらの何れをも用いることができる
。Cationic surfactants are broadly classified into amine type and quaternary ammonium salt type, and any of these can be used.
アミン型の例としては、ポリオキシエチレンアノレキル
アミン、N−アルキルプロピレンアミン、Nリエチレン
ボリアミンジメチル硫酸塩、アルキルビグアニド、長鎖
アミンオキシド、アルキルイミダゾリン、l−ヒドロキ
シエチル−2−アルキルイミダゾリン、■−アセチルア
ミノエチル−2−アルキルイミダゾリン、2−アルキル
ー4−メチル−4−ヒドロキシメチルオキサゾリン等が
ある。Examples of amine types include polyoxyethylene anolekylamine, N-alkylpropylene amine, N-lyethylenebolyamine dimethyl sulfate, alkyl biguanide, long-chain amine oxide, alkylimidazoline, l-hydroxyethyl-2-alkylimidazoline, -acetylaminoethyl-2-alkylimidazoline, 2-alkyl-4-methyl-4-hydroxymethyloxazoline, and the like.
また、第四アンモニウム塩型の例としては、長鎖第1ア
ミン塩、アルキルトリメチルアンモニウム塩、ジアルキ
ルジメチルエチルアンモニウム塩、アルキルジメチルア
ンモニウム塩、アルキルジメチルベンジルアンモニウム
塩、アルキルピリジニウム塩、アルキルキノリニウム塩
、アルキルイソキノリニウム塩、アルキルビリジニウム
硫酸塩、ステアラミドメチルビリジニウム塩、アシルア
ミノエチルジエチルアミン塩、アシルアミノエチルメチ
ルジエチルアンモニウム塩、アルキルアミドプロビルジ
メチルベンジルアンモニウム塩、脂肪酸ポリエチレンポ
リアミド、アシルアミノエチルビリジニウム塩、アシル
コラミノホルミルメチルビリジニウム塩、ステアロオキ
シメチルピリジニウム塩、脂肪酸トリエタノールアミン
、脂肪酸トリエタノールアミンギ酸塩、1・リオキシエ
チレン脂肪酸トリエタノールアミン、脂肪酸ジブチルア
ミノエタノール、セチルオキシメチルピリジニウム塩、
p−インオクチルフエノキシエトキシエチルジメチルベ
ンジルアンモニウム塩等がある。(上記化合物の例の中
の 「アルキル」とは炭素数6〜20の、直鎖または一
部置換されたアルキルを示し、具体的には、ヘキシル、
オクチル、セチル、ステアリル等の直鎖アルキルが好ま
しく用いられる。)これらの中では、特に水溶性の第四
アンモニウム塩型のカチオン界面活性剤が有効で、その
中でも、アノレキノレトリメチルアンモニウム塩、アル
キルジメチルベンジルアンモニウム塩、エチレンオキシ
ド付加アンモニウム塩等が好適である。また、カチ才冫
戊分をくり返し単泣として有する重合体も広い意味では
カチオン界面活性剤であり、本発明のカチオン界面活性
剤に含包される。特に、親油性モノマーと共重合して得
られた第四アンモニウム塩を含む重合体は好適に用いる
ことができる。Examples of quaternary ammonium salts include long-chain primary amine salts, alkyltrimethylammonium salts, dialkyldimethylethylammonium salts, alkyldimethylammonium salts, alkyldimethylbenzylammonium salts, alkylpyridinium salts, and alkylquinolinium salts. , alkylisoquinolinium salt, alkylpyridinium sulfate, stearamidemethylpyridinium salt, acylaminoethyldiethylamine salt, acylaminoethylmethyldiethylammonium salt, alkylamidoprobyldimethylbenzylammonium salt, fatty acid polyethylene polyamide, Acylaminoethylpyridinium salt, acylcolaminoformylmethylpyridinium salt, stearoxymethylpyridinium salt, fatty acid triethanolamine, fatty acid triethanolamine formate, 1-lyoxyethylene fatty acid triethanolamine, fatty acid dibutylamino Ethanol, cetyloxymethylpyridinium salt,
Examples include p-yneoctylphenoxyethoxyethyldimethylbenzyl ammonium salt. ("Alkyl" in the above compound examples refers to straight chain or partially substituted alkyl having 6 to 20 carbon atoms, specifically hexyl,
Straight chain alkyls such as octyl, cetyl and stearyl are preferably used. ) Among these, water-soluble quaternary ammonium salt type cationic surfactants are particularly effective, and among these, anolequinoletrimethylammonium salts, alkyldimethylbenzyl ammonium salts, ethylene oxide addition ammonium salts, etc. are preferred. In addition, polymers having repeating monotonous monomers are also cationic surfactants in a broad sense, and are included in the cationic surfactants of the present invention. In particular, a polymer containing a quaternary ammonium salt obtained by copolymerizing with a lipophilic monomer can be suitably used.
該重合体の重量平均分子量は300〜50000の範囲
であり、特に好ましくは500〜5000の範囲である
。The weight average molecular weight of the polymer is in the range of 300 to 50,000, particularly preferably in the range of 500 to 5,000.
これらのカチオン界面活性剤は単独で使用するほか、2
種以上を併用してもよい。These cationic surfactants can be used alone or in combination with
You may use more than one species in combination.
ア二オン型界面活性剤としては、高級アルコール(CS
〜C22)硫酸エステル塩類〔例えば、ラウリルアルコ
ールサルフエートのナトリウム塩、オクテルアルコール
サルフェートのナトリウム塩、ラウリルアルコールサル
フエートのアンモニウム塩、r Teepol−81J
(商品名・シェル化学製)、第二ナトリウムアルキ
ルサルフェートなど〕、脂肪族アルコールリン酸エステ
ル塩類(例えば、セチルアルコールリン酸エステルのナ
トリウム塩など)、アルキルアリールスルホン酸塩類(
例えば、ドデシルベンゼンスノレホン酸のナトリウム塩
、イングロビルナフタレンスルホン酸のナトリウム塩、
ジナフタリンジスルホン酸のナリトウム塩、メタニトロ
ベンゼンスルホン酸のナトリウム塩など)、アルキルア
ミドのスルホン酸塩類(例えば、C+yH3!CON
( CHs) Cf{zsOJaなど)、二塩基性脂肪
酸エステルのスルホン酸塩類(例えば、ナトリウムスル
ホコハク酸ジオクチルエステル、ナトリウムスルホコハ
ク酸ジヘキシルエステルなど)がある。これらの中で特
にスルホン酸塩類が好適に用いられる。As anionic surfactants, higher alcohols (CS
~C22) Sulfuric ester salts [e.g., sodium salt of lauryl alcohol sulfate, sodium salt of octyl alcohol sulfate, ammonium salt of lauryl alcohol sulfate, r Teepol-81J
(trade name, manufactured by Shell Chemical Co., Ltd.), sodium chloride alkyl sulfate, etc.], aliphatic alcohol phosphate ester salts (e.g., sodium salt of cetyl alcohol phosphate ester, etc.), alkylaryl sulfonates (
For example, the sodium salt of dodecylbenzenesnolephonic acid, the sodium salt of inglovirnaphthalenesulfonic acid,
sodium salt of dinaphthalene disulfonic acid, sodium salt of metanitrobenzenesulfonic acid, etc.), sulfonate salts of alkylamides (for example, C+yH3!CON)
(CHs)Cf{zsOJa, etc.), sulfonic acid salts of dibasic fatty acid esters (for example, sodium sulfosuccinate dioctyl ester, sodium sulfosuccinate dihexyl ester, etc.). Among these, sulfonate salts are particularly preferably used.
両性界面活性剤としては、例えばN−メチルーN−ペン
タデシルアミノ酢酸ナトリウムのような化合物を用いる
ことができる。As the amphoteric surfactant, for example, a compound such as sodium N-methyl-N-pentadecylaminoacetate can be used.
界面活性剤は、現像液に0.Ol〜10重量%の範囲の
濃度で含有させるのが好ましい。The surfactant is added to the developer at a concentration of 0. It is preferable to contain it at a concentration in the range of OI to 10% by weight.
本発明に係る現像液には還元剤を含有させることができ
る。還元剤としては水溶性又はアルカリ可溶性の有機又
は無機の還元剤を用いることができる。The developer according to the present invention can contain a reducing agent. As the reducing agent, a water-soluble or alkali-soluble organic or inorganic reducing agent can be used.
有機の還元剤としては、例えばハイドロキノン、メトー
ル、メトキシキノン等のフェノール化合物、フェニレン
ジアミン、フェニルヒドラジン等のアミン化合物があり
、無機の還元剤としては、例えば亜硫酸ナトリウム、亜
硫酸カリウム、亜硫酸アンモニウム、亜硫酸水素ナトリ
ウム、亜硫酸水素カリウム等の亜硫酸塩、亜リン酸ナト
リウム、亜リン酸カリウム、亜リン酸水素ナトリウム、
亜リン酸水素カリウム、亜リン酸二水素ナトリウム、亜
リン酸水素二カリウム等のリン酸塩、ヒドラジン、チオ
硫酸ナトリウム、亜ジチオン酸ナトリウム等を挙げるこ
とができるが、本発明において特に効果が優れている還
元剤は亜硫酸塩である。Examples of organic reducing agents include phenolic compounds such as hydroquinone, methol, and methoxyquinone, and amine compounds such as phenylenediamine and phenylhydrazine. Examples of inorganic reducing agents include sodium sulfite, potassium sulfite, ammonium sulfite, and hydrogen sulfite. Sulfites such as sodium and potassium hydrogen sulfite, sodium phosphite, potassium phosphite, sodium hydrogen phosphite,
Examples include phosphates such as potassium hydrogen phosphite, sodium dihydrogen phosphite, and dipotassium hydrogen phosphite, hydrazine, sodium thiosulfate, and sodium dithionite, which are particularly effective in the present invention. The reducing agent used is sulfite.
還元剤は現像液中に0.1〜20重量%の範囲で含有さ
せることができる。The reducing agent can be contained in the developer in an amount of 0.1 to 20% by weight.
本発明に係る現像液には、有機カルポン酸を含有させる
ことができる。The developer according to the present invention can contain an organic carboxylic acid.
有機カルポン酸には、炭素原子数6〜20の脂肪族カル
ボン酸、およびベンゼン環またはナフタレン環にカルポ
キシル基が置換した芳香族カルポン酸が包含される。Organic carboxylic acids include aliphatic carboxylic acids having 6 to 20 carbon atoms, and aromatic carboxylic acids in which a benzene ring or a naphthalene ring is substituted with a carpoxyl group.
脂肪族カルポン酸としては炭素数6〜20のアルカン酸
が好ましく、具体的な例としては、カプロン酸、エナン
チル酸、カブリル酸、ペラルゴン酸、カブリン酸、ラウ
リン酸、ミスチリン酸、パルミチン酸、ステアリン酸等
があり、特に好ましいのは炭素数6〜l2のアルカン酸
である。また炭素鎖中に二重結合を有する脂肪酸でも、
枝分れした炭素鎖のものでもよい。上記脂肪族カルポン
酸はナトリウムやカリウムの塩またはアンモニウム塩と
して用いてもよい。The aliphatic carboxylic acid is preferably an alkanoic acid having 6 to 20 carbon atoms, and specific examples include caproic acid, enantylic acid, cabrylic acid, pelargonic acid, cabric acid, lauric acid, mystylic acid, palmitic acid, and stearic acid. etc., and particularly preferred are alkanoic acids having 6 to 12 carbon atoms. Also, fatty acids with double bonds in their carbon chains,
It may also have a branched carbon chain. The above aliphatic carboxylic acid may be used as a sodium or potassium salt or an ammonium salt.
芳香族カルポン酸の具体的な化合物としては、安息香酸
、0−クロロ安息香酸、p−クロロ安息香酸、0−ヒド
ロキシ安息香a、p−ヒドロキシ安息香酸、p−ter
t−ブチル安息香酸、0−アミノ安息香酸、pアミノ安
息香酸、2,4−ジヒドロキシ安息香酸、2,5−ジヒ
ドロキシ安息香酸、2,3−ジヒドロキシ安息香酸、2
,3−ジヒドロキシ安息香酸、3.5−ジヒドロキシ安
息香酸、没食子酸、l−ヒドロキン−2−ナフトエ酸、
3−ヒドロキシ−2−ナフトエ酸、2−ヒドロキシ−1
−ナフトエ酸、l−ナフトエ酸、2−ナフトエ酸等があ
る。Specific compounds of aromatic carboxylic acids include benzoic acid, 0-chlorobenzoic acid, p-chlorobenzoic acid, 0-hydroxybenzoic acid, p-hydroxybenzoic acid, p-ter
t-Butylbenzoic acid, 0-aminobenzoic acid, p-aminobenzoic acid, 2,4-dihydroxybenzoic acid, 2,5-dihydroxybenzoic acid, 2,3-dihydroxybenzoic acid, 2
, 3-dihydroxybenzoic acid, 3.5-dihydroxybenzoic acid, gallic acid, l-hydroquine-2-naphthoic acid,
3-hydroxy-2-naphthoic acid, 2-hydroxy-1
-naphthoic acid, l-naphthoic acid, 2-naphthoic acid, etc.
上記芳香族カルポン酸はナトリウムやカリウムの塩また
はアンモニウム塩として用いてもよい。The above-mentioned aromatic carboxylic acid may be used as a sodium or potassium salt or an ammonium salt.
脂肪族カルボン酸、芳香族カルポン酸の含有量は格別な
制限はないが、0.I重量%より低いと効果が十分でな
く、また30重量%以上ではそれ以上の効果の改善が計
れないばかりか、別の添加剤を併用する時に溶解をさま
たげることがある。従って好ましくは(Ll−10重量
%の添加量であり、より好ましくは0.5〜4重量%で
ある。There are no particular restrictions on the content of aliphatic carboxylic acid and aromatic carboxylic acid, but the content is 0. If it is less than 1% by weight, the effect will not be sufficient, and if it is more than 30% by weight, not only will the effect not be improved any further, but it may also hinder dissolution when other additives are used together. Therefore, the amount added is preferably (Ll-10% by weight), more preferably 0.5 to 4% by weight.
本発明に用いる現像液には現像性能を高めるために前記
の他に以下のような添加剤を加えることができる。例え
ば特開昭58−75152号公報記載のNaC(2,
KCQ, KBr等の中性塩、特開昭59−19095
2号公報記載のEDTA, NTA等のキレート剤、特
開昭59−121336号公報記載の(Co(NHx)
)ecl2s等の錯体、特開昭56−142528号公
報記載のビニルベンジルトリメチルアンモニウムクロラ
イドとアクリル酸ナトリウムの共重合体等の両性高分子
電解質、特開昭58−59444号公報記載の塩化リチ
ウム等の無機リチウム化合物、特公昭50−34442
号公報記載の安息香酸リチウム等の有機リチウム化合物
、特開昭59−75255号公報記載のSi. Ti等
を含む有機金属界面活性剤、特開昭59−84241号
公報記載の有機硼素化合物、特開昭63−188142
号公報記載の有機カルボン酸等が挙げられる。In addition to the above, the following additives can be added to the developer used in the present invention in order to improve the development performance. For example, NaC (2,
Neutral salts such as KCQ, KBr, etc., JP-A-59-19095
Chelating agents such as EDTA and NTA described in Publication No. 2, (Co(NHx) described in JP-A-59-121336)
) complexes such as ecl2s, amphoteric polymer electrolytes such as the copolymer of vinylbenzyltrimethylammonium chloride and sodium acrylate described in JP-A-56-142528, lithium chloride as described in JP-A-58-59444, etc. Inorganic lithium compound, Special Publication No. 50-34442
Organolithium compounds such as lithium benzoate described in JP-A-59-75255, Si. Organometallic surfactants containing Ti etc., organoboron compounds described in JP-A-59-84241, JP-A-63-188142
Examples include organic carboxylic acids described in the above publication.
本発明の補充液は、前記のような現像液に対して、現像
処理によって低下する現像液の活性度(現像性能)を補
充対象の現像液(現像母液)へ添加して補償する組戊を
有するものであればよい。好ましい実施態様として、補
充液のアルカリ活性度(pH)が現像母液と同等あるい
はそれ以上である態様が挙げられる。具体的には現像液
補充液のpHが現像液のpHより0.0〜1.0高いこ
とが好ましい。また、本発明における現像液への補充方
法は、現像処理による疲労及び経時による疲労の両方を
補償するものであることが好ましい。The replenisher of the present invention has a structure that compensates for the activity (development performance) of the developer that decreases due to development processing by adding it to the developer (development mother solution) to be refilled. It is fine as long as you have it. A preferred embodiment is one in which the alkaline activity (pH) of the replenisher is equal to or higher than that of the developing mother solution. Specifically, it is preferable that the pH of the developer replenisher is 0.0 to 1.0 higher than the pH of the developer. Further, it is preferable that the method for replenishing the developer in the present invention compensates for both fatigue due to development processing and fatigue due to aging.
本発明において、補充液中の界面活性剤の濃度を調節す
る手段は、任意であり、例えば補充液を界面活性剤の濃
度を異にする2液(例えば一方の液はネガ型PS版に適
した濃度、他方の液はボジ型PS版に適した濃度とする
等)に分けその混合比率でyA節する方法を用いること
ができる。好ましい方法として、補充液とは別に界面活
性剤溶液を用意しておき、この界面活性剤溶液と補充液
との混合比を変えることによって補充液中の界面活性剤
の濃度を11節する方法が挙げられる。この場合、界面
活性剤溶液は水溶液とすることが好ましい。In the present invention, the means for adjusting the concentration of surfactant in the replenisher is optional. For example, the replenisher can be divided into two solutions having different surfactant concentrations (for example, one solution is suitable for negative-tone PS plates). A method can be used in which the concentration of the liquid is divided into two liquids (one liquid has a concentration suitable for a positive type PS plate, the other liquid has a concentration suitable for a positive type PS plate, etc.), and the mixing ratio is used. A preferred method is to prepare a surfactant solution separately from the replenisher and adjust the concentration of surfactant in the replenisher by changing the mixing ratio of this surfactant solution and the replenisher. Can be mentioned. In this case, the surfactant solution is preferably an aqueous solution.
本発明における補充液は濃厚液に調製しておき、水で希
釈して用いることが補充液の調製効率及び運搬効率の点
から好ましい。The replenisher in the present invention is preferably prepared as a concentrated solution and diluted with water before use from the viewpoint of preparation efficiency and transport efficiency of the replenisher.
本発明においては、前記のようにネガ型PS版とポジ型
ps版の処理比率で補充液中の界面活性剤の濃度を変え
るのであるが、ここで処理比率とは処理!(具体的には
面積)の比率である。処理比率と補充液中の界面活性剤
の濃度との関係は、予め実験により容易に求めることが
できる。In the present invention, as mentioned above, the concentration of surfactant in the replenisher is changed depending on the processing ratio of the negative PS plate and the positive PS plate. (specifically, the area). The relationship between the treatment ratio and the concentration of surfactant in the replenisher can be easily determined in advance through experiments.
補充液の界面活性剤の濃度を調節するタイミングはポジ
型PS版とネガ型PS版との1日を通じての処理比率を
予め予定し、この予定処理比率に対応する界面活性剤の
平均濃度の補充液でそのI日を通じて補充すればよい。The timing for adjusting the concentration of surfactant in the replenisher is determined by planning in advance the processing ratio of positive PS plate and negative PS plate throughout the day, and replenishing the average concentration of surfactant corresponding to this planned processing ratio. You can replenish it with liquid throughout the day.
本発明において、補充液の補充量は処理するPS版の処
理面積,枚数、長手(搬送方向)の長さ等によってIM
節してもよい。In the present invention, the amount of replenisher to be refilled depends on the processing area, number of PS plates to be processed, length (transfer direction), etc.
It may be divided into sections.
本発明方法で処理するのに適するPS版には、ネガ型P
S版は感光性戒分としてジアゾ化合物を用いた感光層を
有するもの、ポジ型PS版は感光性或分として0−キノ
ンジアジド化合物を用いた感光層を有するもの、例えば
特開昭62−175757号公報第5頁左下欄第18行
〜第7頁右上欄第11行に記載されているようなPS版
が包含される。PS plates suitable for processing in the method of the invention include negative-tone P
The S plate has a photosensitive layer using a diazo compound as a photosensitive component, and the positive PS plate has a photosensitive layer using an 0-quinonediazide compound as a photosensitive component, for example, JP-A-62-175757. Includes PS versions as described in page 5, lower left column, line 18 to page 7, upper right column, line 11.
以下、実施例により本発明を説明する。 The present invention will be explained below with reference to Examples.
ナ7トキノン−1.2−ジアジド−5−スルホニルクロ
ライドとレゾルシンーベンズアルデヒド樹脂とのエステ
ル化物(特開昭56−1044号の実施例−1に記載の
もの)3重量部、クレゾールノポラック樹脂91t量部
及びビクトリア・ピュア・ブルー・BOH(保土谷化学
工業(株)製、染料) 0.12重量部をメチルセロソ
ルプ100重量部に溶解し感光液を調製しt;。厚さ0
.3r++iの砂目立てしたアルミニウム板を硫酸中で
陽極酸化し、2.7g/m”の酸化皮膜をつくり、よく
洗浄した後乾燥し、その上に上記感光液を塗布乾燥し、
約2.4g/m”の感光層を有するPS版を得た。この
ようにして得られたボジ型PS版を1003mmX 8
00mmの大きさに裁断したものを多数枚用意し、これ
らに透明陽画を通して80cmの距離から2kWのメチ
ルハライドランプを用いて60秒間露光した。3 parts by weight of esterified product of na7toquinone-1,2-diazido-5-sulfonyl chloride and resorcinol-benzaldehyde resin (described in Example 1 of JP-A-56-1044), 91 tons of cresol nopolac resin A photosensitive solution was prepared by dissolving 0.12 parts by weight of Victoria Pure Blue BOH (manufactured by Hodogaya Chemical Industry Co., Ltd., dye) in 100 parts by weight of methyl cellosol. Thickness 0
.. A grained aluminum plate of 3r++i was anodized in sulfuric acid to form an oxide film of 2.7 g/m'', washed thoroughly and dried, and the above photosensitive solution was applied on it and dried.
A PS plate having a photosensitive layer of approximately 2.4 g/m" was obtained. The positive type PS plate thus obtained was 1003 mm x 8
A large number of sheets cut to a size of 0.00 mm were prepared and exposed through a transparent positive for 60 seconds from a distance of 80 cm using a 2 kW methyl halide lamp.
一方、ネガ型PS版を次のようにして作製した。On the other hand, a negative PS plate was produced as follows.
厚さO − 24mmの砂目立てしたアルミニウム板を
硫酸中で陽極酸化し、約1.5g/m”の酸化皮膜をつ
くり、よく洗浄した後、珪酸ナトリウム水溶液に浸漬し
、充分水洗後、乾燥し、下記組成の感光液を堕布した。A grained aluminum plate with a thickness of O - 24 mm was anodized in sulfuric acid to form an oxide film of approximately 1.5 g/m'', and after being thoroughly washed, it was immersed in a sodium silicate aqueous solution, thoroughly rinsed with water, and then dried. A photosensitive solution having the following composition was applied.
感光液
p−ヒドロキシ7エニルメタクリルアミド、アクリロニ
トリル、エチルアクリレート、及びメタアクリル酸の共
重合体
(モル比は上記の順に8.5: 24: 60.5:
7 )5.0重量部
p−ジアゾジフェニルアミンと
バラホルムアルデヒドとの縮金物の
ヘキサフルオ口リン酸塩 0.5重量部ビクト
リア・ピュア・ブルー・BOH
(保土谷化学工業(株)製、染料)O、1重量部エチレ
ングリコールモノメチルエーテル100重量部
乾燥後の塗布量は、1.8g/m”であった。Photosensitive liquid A copolymer of p-hydroxy 7enylmethacrylamide, acrylonitrile, ethyl acrylate, and methacrylic acid (molar ratio in the above order: 8.5: 24: 60.5:
7) 5.0 parts by weight Hexafluorophosphate, a condensate of p-diazodiphenylamine and paraformaldehyde 0.5 parts by weight Victoria Pure Blue BOH (manufactured by Hodogaya Chemical Co., Ltd., dye) O, The coating amount after drying was 1.8 g/m'' after drying 100 parts by weight of ethylene glycol monomethyl ether.
このようにして得られたネガ型PS版を300mm x
1003mmの大きさに裁断したものを多数枚用意し、
これらに透明陰画を通して80cmの距離から2kWの
メタルハライドランプを用いて50秒間露光した。The negative PS plate obtained in this way was
Prepare a large number of pieces cut to a size of 1003mm,
These were exposed through a transparent negative for 50 seconds from a distance of 80 cm using a 2 kW metal halide lamp.
次に以下のような組戊の現像濃縮液を調製した。Next, the following composition developer concentrate was prepared.
現像濃縮液
エチレングリコールモノ7エニルエーテル3重量部
安息香酸 65重量部50%
水酸化ナトリウム水溶液 150重量部エマルゲン
l30K2重量部
(花王(株)製、ノニオン界面活性剤)ケイ酸ナトリウ
ム水溶液 140重量部(JIS規格ケイ酸ソ
ーダ3号)
40%亜硫酸ナトリウム水溶液 260重量部水
550重量部第1
図に示す自動現像機の現像液タンク5に上記現像濃縮液
と水を1:5の比率で混合した現像液24Qを仕込み、
現像液温を27°CにR整した。また、以下に示す組戊
の濃縮現像補充液を′F4製した。Development concentrate Ethylene glycol mono-7enyl ether 3 parts by weight Benzoic acid 65 parts by weight 50%
Sodium hydroxide aqueous solution 150 parts by weight Emulgen 130K 2 parts by weight (manufactured by Kao Corporation, nonionic surfactant) Sodium silicate aqueous solution 140 parts by weight (JIS standard sodium silicate No. 3) 40% sodium sulfite aqueous solution 260 parts by weight Water
550 parts by weight 1st
A developer solution 24Q, which is a mixture of the developer concentrate and water at a ratio of 1:5, is charged into the developer tank 5 of the automatic developing machine shown in the figure.
The developer temperature was adjusted to 27°C. In addition, a concentrated developer replenisher of the following composition was prepared as F4.
濃縮現像補充液A
エチレングリコールモノフエニルエーテルlO重量部
安息香酸 90重量部50%水
酸化ナトリウム水溶液 300重量部エマルゲン1
30K 1.3重量部(花王(株)
製、ノニオン界面活性剤)ケイ酸ナトリウム水溶液
240重量部(JIS規格ケイ酸ソーダ3号)
40%亜硫酸ナトリウム水溶液 150重量部水
320重量部濃縮
現像補充液B
エマルゲン130K 13.7重量部
(花王(株)製、ノニオン界面活性剤)水
100重量部自動現像機の搬
送スピードを現像時間が20秒間になるように設定し、
現像補充液の補充量をネガ型ps版l1処理毎に50m
Q,ポジ型PS版1一処理毎に70ra(1、シャワー
作動時間に対しては1分間当りlQ+Q,シャワー停止
時の経時補充としてl時間当りlロQ@l2となるよう
Cこ設定した。なお、現像補充液としては濃縮現像補充
液を水と1=3の比率で混合したものを現像液タンク5
に補充するようにした。続いて、水洗水タンク6に水1
5(2を仕込み、ガム液夕冫ク7にSGW−2 (コニ
カ(株)製 ガム液)を水と1:1の比率で混合したも
のを1012仕込んだ。Concentrated developer replenisher A Ethylene glycol monophenyl ether lO parts by weight Benzoic acid 90 parts by weight 50% aqueous sodium hydroxide solution 300 parts by weight Emulgen 1
30K 1.3 parts by weight (Kao Corporation)
(nonionic surfactant) sodium silicate aqueous solution
240 parts by weight (JIS standard sodium silicate No. 3) 40% aqueous sodium sulfite solution 150 parts by weight Water
320 parts by weight Concentrated developer replenisher B Emulgen 130K 13.7 parts by weight (manufactured by Kao Corporation, nonionic surfactant) Water
The conveyance speed of the 100 parts by weight automatic developing machine was set so that the developing time was 20 seconds,
The amount of developer replenisher to be refilled is 50 m per negative PS plate 1 process.
Q, 70 ra for each positive PS plate 1 treatment (1, 1 Q + Q per minute for the shower operating time, 1 Q @ 12 per hour for replenishment over time when the shower is stopped). The developer replenisher is a mixture of concentrated developer replenisher and water at a ratio of 1=3 in the developer tank 5.
I decided to replenish it. Next, add water 1 to the flush water tank 6.
A mixture of SGW-2 (gum liquid manufactured by Konica Corp.) and water at a ratio of 1:1 was added to Gum Liquid Sampler 7.
実施例l
濃縮現像補充液タンク8に前記濃縮現像補充液Aを仕込
み、前記の処理条件で前記ネガ型PS版を100版連続
して処理した後、前記ボジ型PS版を処理した。こうし
て得られた平版印刷版(ポジ型PS版を現像処理して得
られたもの)にSPO−1 (コニカ(株)製現像イン
キ)を用いてインキ盛りを行ったが、非画像部に地汚れ
は生じず、また、画像部での着肉不良も起こらなかった
。Example 1 The concentrated developer replenisher A was charged into the concentrated developer replenisher tank 8, and after 100 plates of the negative PS plate were continuously processed under the above processing conditions, the positive PS plate was processed. The lithographic printing plate thus obtained (obtained by developing a positive PS plate) was inked using SPO-1 (development ink manufactured by Konica Corporation), but the non-image areas were filled with ink. No staining occurred, and no defective inking occurred in the image area.
実施例2
濃縮現像補充液タンク8に前記濃縮現像補充液AとBを
10:lの比率で混合したものを仕込み、前記の処理条
件で前記ポジ型PS版を100版連続して処理した後、
前記ポジ型PS版を処理した。こうして得られた平版印
刷版( 101版目のもの)にSP〇一1を用いてイン
キ盛りを行ったが、非画像部に地汚れは生じず、また、
画像部での着肉不良も起こらなかった。Example 2 A mixture of the concentrated developer replenishers A and B at a ratio of 10:1 was charged into the concentrated developer replenisher tank 8, and after 100 positive PS plates were continuously processed under the above processing conditions. ,
The positive PS plate was processed. The lithographic printing plate thus obtained (the 101st plate) was inked using SP011, but no background staining occurred in the non-image area.
There were no defects in inkling in the image area.
実施例3
濃縮現像補充液タンク8に前記濃縮現像補充液AとBを
10 : 0.5の比率で混合したものを仕込み、前記
の処理条件で前記ポジ型PS版と前記ネガ型PS版をl
:lの比率で計100版交互に処理した後、前記ポジ型
PS版を処理した。こうして得られた平版印刷版( 1
01版目のもの)にSPO− 1を用いてインキ盛りを
行ったが、非画像部に地汚れは生じず、また、画像部で
の着肉不良も起こらなかった。Example 3 A concentrated developer replenisher tank 8 was charged with a mixture of the concentrated developer replenishers A and B at a ratio of 10:0.5, and the positive PS plate and the negative PS plate were processed under the above processing conditions. l
After a total of 100 plates were processed alternately at a ratio of :1, the positive PS plate was processed. The lithographic printing plate thus obtained (1
When inking was applied to the 01st edition) using SPO-1, no scumming occurred in the non-image areas, and no defective inking occurred in the image areas.
実施例4
前記ネガ型PS版を50版連続処理した後、前記ポジ型
PS版を50版連続処理した以外は実施例3と同様の処
理を行った。こうして得られた平版印刷版のうち、前記
ボジ型PS版から得られたもの全てにSPO− 1を用
いてインキ盛りを行ったが、非画像部に地汚れは生じず
、また、画像部での着肉不良も起こらなかった。Example 4 The same process as in Example 3 was performed except that after 50 plates of the negative PS plate were continuously processed, 50 plates of the positive PS plate were processed continuously. Of the lithographic printing plates thus obtained, all of the plates obtained from the above-mentioned positive type PS plate were inked using SPO-1, but no scumming occurred in the non-image areas, and no staining occurred in the image areas. No defective fleshing occurred.
比較例l
前記ボジ型PS版と前記ネガ型PS版を1:lの比率で
計100版交互に処理した後、前記ポジ型PS版を処理
した以外は実施例1と同様の処理を行った。Comparative Example 1 The same process as in Example 1 was performed except that the positive PS plate and the negative PS plate were alternately treated at a ratio of 1:1 for a total of 100 plates, and then the positive PS plate was treated. .
こうして得られた平版印刷版(101版目のもの)にS
PO− 1を用いてインキ盛りを行ったところ、画像部
に着肉不良を生じた。The lithographic printing plate thus obtained (101st edition) has S
When inking was performed using PO-1, poor inking occurred in the image area.
比較例2
前記ポジ型PS版と前記ネガ型PS版をl:1の比率で
計100版交互に処理した後、前記ポジ型PS版を処理
した以外は実施例2と同様の処理を行った。Comparative Example 2 The positive PS plate and the negative PS plate were alternately treated at a ratio of 1:1 for a total of 100 plates, and then the same process as in Example 2 was performed except that the positive PS plate was treated. .
こうして得られた平版印刷版(lot版目のもの)にS
PO− 1を用いてインキ盛りを行ったところ、非画像
部に地汚れを生じた。The lithographic printing plate (lot number) obtained in this way has S
When ink was applied using PO-1, scumming occurred in non-image areas.
本発明によれば、ネガ型PS版とポジ型PS版とを補充
液を補充して繰り返し使用する共通現像液で現像する処
理方法において、ネガ型PS版とボジ型PS版の両方に
ついて現像品質を安定に維持することができる。According to the present invention, in a processing method in which a negative PS plate and a positive PS plate are developed with a common developer that is repeatedly used by replenishing a replenisher, the development quality of both the negative PS plate and the positive PS plate is improved. can be maintained stably.
vgl図は実施例に用いた自動現像機の断面図である。 ■ ・・・現像部 2 ・・・水洗部 3 ・・・ ガム引き部 8 ・・・現像補充液タンク 9 ・・・希釈水タンク The vgl diagram is a sectional view of the automatic developing machine used in the example. ■...Developing section 2...Water washing section 3... Gum pulling part 8...Developer replenisher tank 9... Dilution water tank
Claims (2)
ポジ型感光性平版印刷版を同一の繰り返し使用される水
を主たる溶媒とするアルカリ性のネガ・ポジ共通現像液
で現像処理し、該現像処理によって低下する現像液の活
性度を補充液を添加して補償する感光性平版印刷版の処
理方法において、ネガ型感光性平版印刷版とポジ型感光
性平版印刷版との処理比率によつて補充液中の界面活性
剤の含有量を調節することを特徴とする感光性平版印刷
版の処理方法。(1) Using an automatic developing machine, develop the negative-working photosensitive lithographic printing plate and the positive-working photosensitive lithographic printing plate with the same alkaline negative/positive common developer containing water as the main solvent, which is used repeatedly; In a method for processing a photosensitive lithographic printing plate in which the activity of the developer that decreases due to the development process is compensated for by adding a replenisher, the processing ratio of the negative-working photosensitive lithographic printing plate and the positive-working photosensitive lithographic printing plate is A method for processing a photosensitive lithographic printing plate, which comprises adjusting the content of a surfactant in the replenisher.
、その混合比を変えることにより補充液中の界面活性剤
の含有量を調節することを特徴とする請求項(1)記載
の処理方法。(2) Claim (1) characterized in that a replenisher solution and a surfactant solution are prepared separately, and the content of surfactant in the replenisher solution is adjusted by changing the mixing ratio. processing method.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22875789A JPH0391750A (en) | 1989-09-04 | 1989-09-04 | Processing method for photosensitive planographic plate |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP22875789A JPH0391750A (en) | 1989-09-04 | 1989-09-04 | Processing method for photosensitive planographic plate |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0391750A true JPH0391750A (en) | 1991-04-17 |
Family
ID=16881353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP22875789A Pending JPH0391750A (en) | 1989-09-04 | 1989-09-04 | Processing method for photosensitive planographic plate |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0391750A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5217848A (en) * | 1990-10-29 | 1993-06-08 | Konica Corporation | Method and apparatus for processing presensitized lithographic printing plate |
KR20010058068A (en) * | 1999-12-24 | 2001-07-05 | 신길수 | the winter season street trees garden stuff a sapling prodtection |
-
1989
- 1989-09-04 JP JP22875789A patent/JPH0391750A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5217848A (en) * | 1990-10-29 | 1993-06-08 | Konica Corporation | Method and apparatus for processing presensitized lithographic printing plate |
KR20010058068A (en) * | 1999-12-24 | 2001-07-05 | 신길수 | the winter season street trees garden stuff a sapling prodtection |
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