JPH0387149A - Wheat gluten composition - Google Patents

Wheat gluten composition

Info

Publication number
JPH0387149A
JPH0387149A JP1226667A JP22666789A JPH0387149A JP H0387149 A JPH0387149 A JP H0387149A JP 1226667 A JP1226667 A JP 1226667A JP 22666789 A JP22666789 A JP 22666789A JP H0387149 A JPH0387149 A JP H0387149A
Authority
JP
Japan
Prior art keywords
wheat gluten
gluten
wheat
water
product
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1226667A
Other languages
Japanese (ja)
Other versions
JP2738450B2 (en
Inventor
Kenji Hanno
賢治 半埜
Kazuo Kamibayashi
上林 一雄
Yoko Yamamoto
洋子 山本
Sakae Katayama
栄 片山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Katayama Chemical Inc
Original Assignee
Katayama Chemical Inc
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Filing date
Publication date
Application filed by Katayama Chemical Inc filed Critical Katayama Chemical Inc
Priority to JP1226667A priority Critical patent/JP2738450B2/en
Publication of JPH0387149A publication Critical patent/JPH0387149A/en
Application granted granted Critical
Publication of JP2738450B2 publication Critical patent/JP2738450B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PURPOSE:To obtain the title composition imparted with hydrophilicity and water dispersibility, to be formulated into breads, cakes, fat processed foods, etc., by incorporating a wheat gluten hard to disperse in water with a specified amount of a partially degraded product of wheat gluten with specified molecular weight. CONSTITUTION:The objective composition can be obtained by incorporating (A) 1 pt.wt. of wheat gluten hard to disperse in water (pref. raw gluten. activated gluten or modified gluten) with (B) 0.03-0.2 (pref. 0.05-0.15) pts.wt. of a partially degraded product of wheat gluten with a weight-average molecular weight of 3000-110000 (pref. 10000-70000). It is preferable that the component B be prepared by degradation treatment of wheat gluten with an acid, alkali or enzyme.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 この発明は、小麦グルテン組成物に関する。さらに詳し
くは小麦蛋白質である、生グルテン、粉末状の活姓グル
テンらしくは変性グルテン等(以下、これらを総呼する
ときは、単に小麦グルテンと記す)の水分散性を改良し
てなる小麦グルテン組成物に関する。
DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application This invention relates to a wheat gluten composition. More specifically, wheat gluten is made by improving the water dispersibility of wheat proteins such as raw gluten, powdered active gluten, and modified gluten (hereinafter referred to collectively as wheat gluten). Regarding the composition.

(ロ)従来の技術 一般に、小麦蛋白質である生グルテン、粉末状の活性グ
ルテン、粉末状の変性グルテン等の小麦グルテンは、加
熱されると熱変性を生し約70℃でゲル化が起こり、そ
の結果強い弾力性のあるゲルを作ることはよく知られて
いる。そこで、従来からこのような小麦グルテンの特性
を利用して、各種食品を改良することが行われており、
例えば水産、畜産の魚畜、肉加工食品に添加して高温、
高圧下における弾力性の低下を防止したり、パンやめん
類の製造時に添加しての腰持ちを向上させ、2− かっ成形性を改善し良好な食感を付与することが行われ
ている。
(b) Conventional technology In general, wheat gluten, which is a wheat protein such as raw gluten, active gluten in powder form, and modified gluten in powder form, undergoes thermal denaturation when heated and gels at about 70°C. It is well known that the result is a strong and elastic gel. Therefore, various foods have been improved by utilizing these characteristics of wheat gluten.
For example, it can be added to fisheries, livestock, and processed meat foods at high temperatures.
It is used to prevent a decrease in elasticity under high pressure, to improve the chewiness of breads and noodles by adding them during production, and to improve moldability and impart a good texture.

しかしながら、小麦グルテンは、水に対する親和性に乏
しく、中性付近において殆と水に不溶であるため、水混
和時に所謂、ままこ(「ish eye)を形成し、均
一な分散波を得ることが、極めて困難である。小麦グル
テンのこのような非水親和性、水難分散性は、食品への
添加使用の際、作業上及びそれにもとづく食品品質の技
術改良面において軽視することのできない制限因子にな
っている。
However, wheat gluten has poor affinity for water and is almost insoluble in water near neutrality, so it forms so-called "ish eyes" when mixed with water, making it difficult to obtain uniform dispersion waves. This water-incompatibility and water-difficulty of wheat gluten's dispersibility make it a limiting factor that cannot be ignored when adding it to foods and improving the technology of food quality based on it. It has become.

そこで、小麦グルテンの水に対する溶解性、分散性を改
良するため多くの提案がなされており、中てら小麦グル
テンに対し食品添加物として許容できる各種分散剤や界
面活性剤を配合して小麦グルテンに水分散性を付与する
方性が知られている。
Therefore, many proposals have been made to improve the solubility and dispersibility of wheat gluten in water. A method of imparting water dispersibility is known.

例えば、生グルテン、変性グルテンに多糖類誘導体を混
和する方法(特公昭46−24083号公報)や50〜
80%含水グルテンにレシチンを添加し均−乳化後、乾
燥粉末化する方法(特公昭62−14253号公報)等
である。
For example, a method of mixing polysaccharide derivatives with raw gluten or modified gluten (Japanese Patent Publication No. 46-24083),
This method includes adding lecithin to 80% hydrated gluten, homogenizing it, and then drying it into powder (Japanese Patent Publication No. 14253/1983).

(ハ)発明か解決しようとする課題 しかるに、前述の小麦グルテンの水分散性改良のための
方法はいずれら、その効果か必ずしし充分とはいえない
ばかりか、多少水分散性を改善てきたとしても、本来、
保有している小麦グルテンの特性ことに食品添加時の弾
性付与効果を低下させる場合が多く、食品に添加してそ
の品質を改善する目的を充分に果たしているとはいえな
い。また用いられている配合剤は特殊な食品添加物であ
るため、食品そのものである小麦グルテンの用途を制限
する場合もあった。
(c) Invention or problem to be solved However, none of the above-mentioned methods for improving the water dispersibility of wheat gluten can be said to be effective, and not only can the water dispersibility be improved to some extent. Even so, originally,
Due to the characteristics of wheat gluten, it often reduces the elasticity imparting effect when added to foods, and it cannot be said that it sufficiently fulfills the purpose of adding it to foods to improve their quality. Furthermore, since the compounding agents used are special food additives, there are cases in which the uses of wheat gluten, which is a food itself, are restricted.

この発明は、かかる問題点を解消すべくなされたちのて
あり、ことに小麦クルテンの有する特性を損なうことな
く、優れた水分散性を備えた小麦グルテン組成物を提供
しようとするものである。
The present invention has been made to solve these problems, and particularly to provide a wheat gluten composition that has excellent water dispersibility without impairing the properties of wheat gluten.

(ニ)課題を解決するための手段 本発明者らは、上記照点から小麦グルテンに水分散性を
付与すべく、各種配合剤の検討を行った。
(d) Means for Solving the Problems The present inventors studied various compounding agents in order to impart water dispersibility to wheat gluten from the above-mentioned point of view.

その結果、小麦グルテンに対し、小麦グルテン部分分解
物を少量添加することにより、優れた水分散性を備えた
小麦グルテン組成物が得られる事実、並びに小麦グルテ
ンの特性を損なわないばかりか、かかる組成物を食品に
添加した際に、小麦グルテン自体を添加した場合よりも
優れた弾性付与効果が奏される事実を見出しこの発明に
到達した。
As a result, it was found that a wheat gluten composition with excellent water dispersibility can be obtained by adding a small amount of wheat gluten partial decomposition product to wheat gluten, and that such a composition not only does not impair the properties of wheat gluten, but also The present invention was achieved by discovering the fact that when wheat gluten is added to foods, a superior elasticity imparting effect is achieved than when wheat gluten itself is added.

なお、ここで小麦グルテン部分分解物は、従来、界面活
性能、分散能等を示すことは知られている(特開昭64
−14274号公報)が、未分解の小麦グルテンと組合
せて使用することは具体的に知られておらず、ことに、
水分散性を付与するのみならず小麦グルテン自体の有す
る特性を改善することは全く知られていない。
It should be noted that wheat gluten partial decomposition products have been known to exhibit surface activity, dispersion ability, etc. (Japanese Patent Application Laid-Open No. 64
-14274) is not specifically known to be used in combination with undegraded wheat gluten, and in particular,
It is completely unknown that it not only imparts water dispersibility but also improves the properties of wheat gluten itself.

かくしてこの発明によれば、水難分散性の小麦グルテン
1重量部に対し、重量平均分子量約3000〜1100
.00の小麦グルテン部分分解物0.03〜0.2重量
部を配合してなる小麦グルテン組成物が提供される。
Thus, according to the present invention, 1 part by weight of water-resistant wheat gluten has a weight average molecular weight of about 3000 to 1100.
.. A wheat gluten composition containing 0.03 to 0.2 parts by weight of wheat gluten partially decomposed product No. 00 is provided.

この発明における水難溶性の小麦グルテンとは、一般に
、魚畜肉加工食品の品質、食感の向上、弾性付与用とし
て用いられている小麦グルテンを意味し、具体的には、
生グルテン、粉末状の活性クルテンらしくは変性グルテ
ンと称せられる乙のが含まれる。ここで、生グルテンは
、小麦粉を水性して小麦粉中の非水溶性蛋白質を分離し
取り出したそのままの粘結塊状のものでもよいが、これ
を乾燥し粉砕して粉末状としたものが均−組成物を得る
ために望ましい。また活性グルテンは生グルテンを、熱
変性をできるたけ受けないようフラッシュドライ又はス
プレートライ方式等て乾燥粉末化したちのてあり、また
変性グルテンは生グルテン又は活性グルテンを酸化剤又
は還元剤で化学的性質を変えない程度、ことに分解が生
じない程度に処理した後、乾燥、粉末化したものである
。これらの小麦グルテンは何れも高い凝集性と強い弾力
性を呈するが、水に対する親和性が低く、極めて分散し
難い性質を有する。
In this invention, the poorly water-soluble wheat gluten refers to wheat gluten that is generally used to improve the quality and texture of processed fish and meat foods, and to impart elasticity, and specifically,
Raw gluten, active gluten in powder form, and denatured gluten are included. Here, the raw gluten may be in the form of a coagulated lump that has been obtained by diluting wheat flour and separating the water-insoluble proteins in the flour, but it is better to dry and crush this into a uniform powder. desirable for obtaining compositions. In addition, active gluten is obtained by drying raw gluten into powder using a flash drying or spray-try method to avoid heat denaturation as much as possible, and modified gluten is obtained by drying raw gluten or active gluten by chemically processing raw gluten or active gluten with an oxidizing agent or reducing agent. It is processed to the extent that its properties do not change, especially to the extent that decomposition does not occur, and then dried and powdered. All of these wheat glutens exhibit high cohesiveness and strong elasticity, but have a low affinity for water and are extremely difficult to disperse.

上記した小麦グルテンに配合する小麦グルテン部分分解
物は、上記した小麦グルテンを、酸、アルカリ又は酵素
の単触分解処理又はこれら2以上の組合わせに付すか又
はこれらの単独又は組合せ分解処理に加え、還元剤及び
/又は酸化剤による分解処理に付すことにより得られる
。かかる分解処理により、この発明で用いる重量平均分
子量Mwか約3000−110000 (但し、Mwは
ゲル濾過法によって測定した値である)の小麦クルテン
部分分解物を簡便に得ることがてきる。
The wheat gluten partial decomposition product to be blended with the wheat gluten described above is obtained by subjecting the above wheat gluten to monocatalytic decomposition treatment with acid, alkali or enzyme, or a combination of two or more of these, or in addition to these decomposition treatments alone or in combination. , by subjecting it to decomposition treatment with a reducing agent and/or an oxidizing agent. By such decomposition treatment, it is possible to easily obtain a partial decomposition product of wheat kurten having a weight average molecular weight Mw of about 3,000 to 110,000 (where Mw is a value measured by gel filtration method) used in the present invention.

酸、アルカリ、酵素による単独又は併用による小麦グル
テンの部分分解処理は、何れを採用してもよく又、組合
わせの場合、その処理順序ら問わない。しかし還元剤や
酸化剤による単独の分解処理によっては、小麦蛋白質の
−8−8−結合の一部を切断するのみてこの発明で用い
ることのできる目的の分子量と特性を有する分解物を得
ることが困難である。従って、酸、アルカリ又は酵素処
理と還元剤又は酸化剤処理を組み合わせて行うことが望
ましい。この際、還元剤処理を組合わせる場合にはさら
に還元剤処理を先行して実施する方が、小麦蛋白質の−
8−3−結合の切断によりその網目構造が低下、次工程
の酸、アルカリ又は酵素による分解反応が容易に進行す
ること及び所望=7 の分子量をより選択的に得るための処理条件の採用が容
易になるなどによる理由てより好ましい。
Any partial decomposition treatment of wheat gluten by acid, alkali, or enzyme, either alone or in combination, may be employed, and in the case of a combination, the order of treatment does not matter. However, by a single decomposition treatment using a reducing agent or an oxidizing agent, only a part of the -8-8- bond of wheat protein is cleaved, and a decomposed product having the desired molecular weight and characteristics that can be used in the present invention cannot be obtained. is difficult. Therefore, it is desirable to perform acid, alkali or enzyme treatment in combination with reducing agent or oxidizing agent treatment. At this time, when combining reducing agent treatment, it is better to perform the reducing agent treatment in advance to reduce the amount of wheat protein.
The network structure decreases due to the cleavage of the 8-3-bond, the decomposition reaction by acid, alkali or enzyme in the next step progresses easily, and it is necessary to adopt treatment conditions to more selectively obtain the desired molecular weight of 7. This is more preferable because it becomes easier.

分解処理は、塩酸、硫酸、硝酸等の無賎酸や酢酸等の有
機酸等、酸による分解処理の場合、小麦グルテンを希酸
水溶液中で約60−120°C以下、約lO〜600分
撹拌下において実施するのか適している。
In the case of decomposition treatment using acids, such as non-diabetic acids such as hydrochloric acid, sulfuric acid, and nitric acid, and organic acids such as acetic acid, wheat gluten is heated in a dilute acid aqueous solution at about 60-120°C or less for about 10 to 600 minutes. It is suitable to carry out under stirring.

アルカリによる分解処理は、水酸化ナトリウム、水酸化
カリウム、炭酸ナトリウム、炭酸カリウムの2〜40重
量%の水溶液又は分散液中で約60〜180℃、約10
〜600分撹拌して行うのが適している。
The decomposition treatment with alkali is carried out in an aqueous solution or dispersion of 2 to 40% by weight of sodium hydroxide, potassium hydroxide, sodium carbonate, or potassium carbonate at about 60 to 180°C for about 10 minutes.
It is suitable to carry out stirring for ~600 minutes.

酵素による分解処理は、プロテアーゼ活性を有する酵素
の冷水溶液中で行うのが適しており、通常、小麦グルテ
ン分散液にペプシン、アルカリプロテアーゼ、パパイン
等の酵素を少量存在させた状態で、それら酵素の至適p
H条件下、約(0〜60°C1約60〜600分行うの
が適している。
It is suitable for enzymatic decomposition treatment to be carried out in a cold aqueous solution of an enzyme with protease activity.Usually, a small amount of enzymes such as pepsin, alkaline protease, papain, etc. are present in the wheat gluten dispersion, and these enzymes are Optimal p
It is suitable to carry out the reaction under H conditions for about 60 to 600 minutes at 0 to 60°C.

また、還元剤又は酸化剤による分解処理は亜硫酸ナトリ
ウム、チオ亜硫酸ナトリウム、エリソルビン酸又はヒド
ラジン等の還元剤又は過酸化水素、次亜塩素酸塩等の酸
化剤の存在て約10〜100°Cd08 〜600分間、撹拌下で行うのが適している。
In addition, the decomposition treatment using a reducing agent or an oxidizing agent is performed in the presence of a reducing agent such as sodium sulfite, sodium thiosulfite, erythorbic acid, or hydrazine, or an oxidizing agent such as hydrogen peroxide or hypochlorite, at a temperature of about 10 to 100°Cd08 ~ Suitably it is carried out under stirring for 600 minutes.

この際、小麦グルテンに対する各処理剤の量的条件とし
ては、小麦グルテン20i7に対し、酸又はアルカリ処
理のときは各々0.1〜6o9、酵素処理のときは00
2〜5g又、酸化又は還元処理のときは各々0.1〜5
gを用いるのが適している。
At this time, the quantitative conditions of each treatment agent for wheat gluten are 0.1 to 6o9 for wheat gluten 20i7 when acid or alkali treatment, and 0.00 to 0.09 for enzyme treatment.
2 to 5g, or 0.1 to 5g each during oxidation or reduction treatment
It is suitable to use g.

かくして小麦グルテンを上記それぞれの分解処理に付す
ことによって小麦グルテン部分分解物を得ることができ
る。そして小麦グルテンの部分分解の処理条件を適宜選
択することにより平均分子量10,000〜70,00
0を有する分解物を得ることができ、このものを小麦グ
ルテンに配合して得られた本発明の組成物は、充分な水
分散性を保有するとともに小麦グルテン固有の弾力性を
損なうことな。
Thus, by subjecting wheat gluten to each of the above decomposition treatments, a partially decomposed product of wheat gluten can be obtained. By appropriately selecting the processing conditions for partial decomposition of wheat gluten, the average molecular weight is 10,000 to 70,000.
The composition of the present invention obtained by blending this product with wheat gluten has sufficient water dispersibility and does not impair the elasticity inherent to wheat gluten.

く、むしろ強められることが認められ、より好ましい部
分分解物である。
This is a more preferable partial decomposition product, as it is recognized that the decomposition product is not strong, but is rather strengthened.

ここで、小麦グルテン部分分解物の平均分子量は小麦グ
ルテンとの親和性にも関係を有し3000以下であると
きは、水溶性が高すぎるため小麦グルテンとの親和性が
低下し、均一混和が困難になり、また110,000以
上になると水溶性か低下し、また十分な水分散性を有す
る組成物を得難く適さない。
Here, the average molecular weight of the wheat gluten partial decomposition product is also related to the affinity with wheat gluten, and if it is less than 3000, the water solubility is too high, the affinity with wheat gluten decreases, and uniform mixing becomes impossible. If it exceeds 110,000, water solubility decreases, and it is difficult to obtain a composition with sufficient water dispersibility, making it unsuitable.

とくに、この発明においては、前述したように原料小麦
グルテンより高い弾性を食品に付与できる小麦グルテン
組成物を得ることかてきるが、平均分子量が高すぎると
きそれを配合した組成物の弾性は、原料小麦グルテンの
それを同程度となるため適さない。
In particular, in this invention, as mentioned above, it is possible to obtain a wheat gluten composition that can impart higher elasticity to foods than raw wheat gluten, but when the average molecular weight is too high, the elasticity of the composition containing it is It is not suitable because it has the same level as that of wheat gluten as a raw material.

なお、上記小麦グルテン部分分解物のうち、下記特性 (a)紫外吸収λmaxが、260−280nm付近で
、かつ赤外吸収が1400.1630及び3400cm
−’付近である。
In addition, among the above wheat gluten partial decomposition products, the following characteristics (a) ultraviolet absorption λmax is around 260-280 nm, and infrared absorption is 1400, 1630 and 3400 cm
It is around -'.

(b)等電点が3.9〜50の範囲にある。(b) The isoelectric point is in the range of 3.9 to 50.

(c)pH緩衝性(本島の5重量%水溶肢100zi2
のpHを6から2まで低下させるのにIN−塩酸を2〜
25m12必要とする)を有する。
(c) pH buffering property (5% water solution of the main island 100zi2
To lower the pH of from 6 to 2, IN-hydrochloric acid
25m12).

(d)水に可溶であり、メタノール、エタノール、アセ
トン、エーテルに不溶である。
(d) Soluble in water and insoluble in methanol, ethanol, acetone, and ether.

(e)キサントプロティン反応、ニンヒドリン反応によ
って呈色する。
(e) Color develops due to xanthoprotein reaction and ninhydrin reaction.

を有する部分分解物を用いるのが好ましい。It is preferable to use a partially decomposed product having

この発明において、小麦グルテン部分分解物の配合量は
、小麦グルテン1重量部に対して0.03〜0.2重量
部とされる。ここで配合量か0.03重量部未満では、
水分散性付与効果や弾性向上効果が不充分であり、0.
2重量部を越えると、小麦グルテン自体の特性ことに弾
性付与効果が阻害されるため適さない。これらのうちこ
とに、小麦グルテン部分分解物を小麦グルテン1重量部
に対し0.05〜Q、15重量部とするのが好ましい。
In this invention, the amount of wheat gluten partial decomposition product is 0.03 to 0.2 parts by weight per 1 part by weight of wheat gluten. Here, if the blending amount is less than 0.03 parts by weight,
Water dispersibility imparting effect and elasticity improving effect are insufficient, and 0.
If it exceeds 2 parts by weight, it is not suitable because the properties of wheat gluten itself and the effect of imparting elasticity are inhibited. Among these, it is particularly preferable that the wheat gluten partial decomposition product is 0.05 to Q, 15 parts by weight per 1 part by weight of wheat gluten.

この発明の小麦グルテン組成物は、通常、水性液体又は
粉末の形態として得ることができる。すなわち、小麦グ
ルテン部分分解物は、小麦グルテンを酸、アルカリ、酵
素又は還元剤等の処理剤で水性液中の処理によって溶液
とし得られるか、又はこれをさらに乾燥して粉末として
得られる。従って、粉末状の小麦生グルテン、小麦活性
グルテン、小麦変成グルテンについては、そのまま添加
混合すればよい。またペースト状の生グルテン又は粉末
状の活性グルテン又は変性グルテンを水て混練1 りし希釈した液状物については前記液状の小麦グルテン
部分分解物を加えて均一混合すれば液状の組成物が得ら
れる。しかして、食品に添加する際の便利を考え、組成
物の粉末状又は液状物の何れかが適宜選択されて使用さ
れる。
The wheat gluten compositions of this invention can generally be obtained in the form of an aqueous liquid or a powder. That is, the wheat gluten partial decomposition product can be obtained by treating wheat gluten in an aqueous liquid with a treatment agent such as an acid, alkali, an enzyme, or a reducing agent to form a solution, or it can be further dried to obtain a powder. Therefore, powdered raw wheat gluten, activated wheat gluten, and denatured wheat gluten may be added and mixed as they are. In addition, for a liquid product obtained by kneading paste-like raw gluten, powder-like active gluten, or modified gluten with water and diluting it with water, a liquid composition can be obtained by adding the above-mentioned liquid wheat gluten partial decomposition product and mixing uniformly. . Therefore, considering the convenience of adding the composition to foods, either a powdered or liquid composition is appropriately selected and used.

(ホ)実施例 この発明を以下の参考例及び実施例によりさらに詳しく
説明する。
(e) Examples This invention will be explained in more detail with reference to the following reference examples and examples.

[参考例] この発明に用いろ小麦グルテンの部分分前物を下記の様
にして調製した。これら調製物の物性を表−1にまとめ
て示す。
[Reference Example] A partial precursor of wheat gluten used in the present invention was prepared as follows. The physical properties of these preparations are summarized in Table 1.

参考例I〜7(小麦グルテンのアリカリによる部分分解
物の調製) 和光純薬工業(株)製小麦グルテン(試薬品)20gを
、苛性ソーダを02〜4gの範囲内で各別に溶解した7
個の水溶液100g中に加え、充分混合後、フラスコ又
はオートクレーブ中で80℃〜150℃で30〜360
分の範囲の湯度及び時間で各別にそれぞれ加熱撹拌した
。これらを塩酸にて中和し、純水て総量200gにして
分解物No、1〜7を得た。
Reference Examples I to 7 (Preparation of partial decomposition product of wheat gluten with alkali) 20 g of wheat gluten (reagent) manufactured by Wako Pure Chemical Industries, Ltd. was dissolved separately in the range of 0.2 to 4 g of caustic soda.
Add to 100g of aqueous solution of
Each mixture was heated and stirred separately at a hot water temperature and time within a range of minutes. These were neutralized with hydrochloric acid and diluted with pure water to a total amount of 200 g to obtain decomposed products Nos. 1 to 7.

分解条件と分解物の平均分子量(ケル濾過法で「Wとし
て測定)を表−■に示す。
The decomposition conditions and the average molecular weight of the decomposed product (measured as "W" by the Kell filtration method) are shown in Table -■.

表 ■ 参考例8〜10(小麦グルテンの酸による部分分解物の
調製) 塩化水素換算で19.2g及び49に相当する塩酸水溶
液100gの入った3個のフラスコにそれぞれ和光純薬
工業(株)製の小麦グルテン(試薬品)209を加え、
100℃、60分間加熱撹拌した。その後、苛性ソーダ
て中和し純水で総量2009にして、分解物No、8〜
10を得た。
Table ■ Reference Examples 8 to 10 (Preparation of partially decomposed products of wheat gluten with acid) Wako Pure Chemical Industries, Ltd. (Wako Pure Chemical Industries, Ltd.) Add wheat gluten (reagent) 209 manufactured by
The mixture was heated and stirred at 100°C for 60 minutes. After that, it was neutralized with caustic soda and the total amount was made up to 2009 with pure water, and the decomposition product No. 8 ~
Got 10.

表−2の分解条件と分解物の平均分子量を示す。Table 2 shows the decomposition conditions and the average molecular weight of the decomposed products.

表−2 参考例II(小麦グルテンの酵素による部分分解物の調
製) 参考例1で用いた小麦グルテン209を0.1N−塩酸
’It 150gが入ったフラスコに加え、pH1,5
の水溶液を得、これに0.2gのペプシンを加え37℃
で90分間反応させた。この後、苛性ソーダで中和し純
水で総量200gにして分解物No、11を得た。平均
分子量は60,000であった。
Table 2 Reference Example II (Preparation of enzymatic partial decomposition product of wheat gluten) Wheat gluten 209 used in Reference Example 1 was added to a flask containing 150 g of 0.1N-hydrochloric acid, and the pH was 1.5.
An aqueous solution of
The reaction was carried out for 90 minutes. Thereafter, the mixture was neutralized with caustic soda and added with pure water to a total amount of 200 g to obtain decomposed product No. 11. The average molecular weight was 60,000.

参考例12〜21(小麦グルテンの酸による部分分解と
次いで実施したアルカリによる部分分解による分解物の
調製) 参考例8〜IOと同様の条件で小麦クルテンの酸による
部分分解物の10%水溶液を調製し、その310041
をフラスコらしくはオートクレーブ8個に入れ、これら
に苛性ソーダ05〜2gの範囲内の量に各別に加え、l
OO又は150℃にて60又は360分間加熱撹拌した
。その後、塩酸にて中和し純水で総量200gにして分
解物No、12〜19を得た。苛性ソーダに換えて炭酸
ナトリウムを使用した以外はすへて上記と同様にして分
解物No、20を得た。酸による部分分解の条件を塩酸
添加量0.5g、温度80℃、時間60分、アルカリに
よる部分分解の条件を苛性ソーダ添加量05g、温度8
0°C1時間30分とし上記と同様にして分解物No、
21を得た。
Reference Examples 12 to 21 (Preparation of decomposition product by partial decomposition of wheat gluten with acid and subsequent partial decomposition with alkali) A 10% aqueous solution of the partial decomposition product of wheat gluten with acid was prepared under the same conditions as Reference Examples 8 to IO. Prepared and its 310041
Put it into 8 autoclaves that look like flasks, add 05 to 2 g of caustic soda to each of them, and add 1 liter of caustic soda to each autoclave.
The mixture was heated and stirred at OO or 150°C for 60 or 360 minutes. Thereafter, the mixture was neutralized with hydrochloric acid and diluted with pure water to a total amount of 200 g to obtain decomposed products Nos. 12 to 19. Decomposed product No. 20 was obtained in the same manner as above except that sodium carbonate was used instead of caustic soda. The conditions for partial decomposition with acid are 0.5 g of hydrochloric acid added, temperature 80°C, time 60 minutes, and the conditions of partial decomposition with alkali are 05 g added amount of caustic soda, temperature 8
At 0°C for 1 hour and 30 minutes, the decomposition product No.
I got 21.

表−3に分解条件と分解物の平均分子量を示す。Table 3 shows the decomposition conditions and the average molecular weight of the decomposed products.

(以下余白) 15− 表 参考例22〜23(小麦グルテンのアルカリによる部分
分解と次いて実施した酸による部分分解による分解物の
調製) 参考例5及び6と同様の条件で小麦グルテンのアルカリ
による部分分解を実施して得られた部分18 分解物の10%水溶液を調製し、その各1002をフラ
スコ2個に入れこれらに塩化水素換算で0.5g及びI
gに相当する塩酸を各々に加え、100℃にて60分間
加熱撹拌した。そののち苛性ソーダにて中和し、純水で
総量200gにして分解物No、22.23を得た。
(Leaving space below) 15- Table Reference Examples 22 to 23 (Preparation of decomposed product by partial decomposition of wheat gluten with alkali and subsequent partial decomposition with acid) Wheat gluten with alkali under the same conditions as Reference Examples 5 and 6. Part 18 obtained by partial decomposition Prepare a 10% aqueous solution of the decomposed product, put each 1002 into two flasks, and add 0.5 g in terms of hydrogen chloride and I
gram of hydrochloric acid was added to each, and the mixture was heated and stirred at 100° C. for 60 minutes. Thereafter, it was neutralized with caustic soda, and the total amount was adjusted to 200 g with pure water to obtain decomposed product No. 22.23.

表−4に分解条件と分解物の平均分子量を示す。Table 4 shows the decomposition conditions and the average molecular weight of the decomposed products.

参考例24(小麦グルテンの酵素による部分分解と次い
て実施したアルカリによる部分分解による分解物の調製
) 参考例11と同様の条件で小麦グルテンの酵素による部
分分解物の10%水溶液を調製し、その1009に苛性
ソーダをIIF加えフラスコ中で60分間加熱撹拌した
。その後塩酸にて中和して純水で総量200gとし分解
物No、24を得た。
Reference Example 24 (Preparation of decomposed product by enzymatic partial decomposition of wheat gluten followed by alkali partial decomposition) A 10% aqueous solution of enzymatic partial decomposition product of wheat gluten was prepared under the same conditions as Reference Example 11, Caustic soda was added to 1009 using IIF, and the mixture was heated and stirred in the flask for 60 minutes. Thereafter, the mixture was neutralized with hydrochloric acid, and the total amount was adjusted to 200 g with pure water to obtain decomposed product No. 24.

平均分子量は29000であった。The average molecular weight was 29,000.

参考例25(小麦グルテンの還元剤による部分分解と次
いで実施したアルカリによる部分分解による分解物の調
製) 亜硫酸ナトリウム4gを溶解した水溶液100gに参考
例1て用いた小麦クルテン20gを加え、30℃にて6
0分間撹拌後、純水で総量200gにして小麦グルテン
の還元剤による部分分解物の10%水溶液を調製し、そ
の1009に苛性ソーダ1gを加え、フラスコ中で10
0℃で60分間加熱撹拌した。その後、塩酸にて中和し
て純水で総量を200gとし分解物No、25を得た。
Reference Example 25 (Preparation of decomposed product by partial decomposition of wheat gluten with a reducing agent and subsequent partial decomposition with an alkali) 20 g of the wheat gluten used in Reference Example 1 was added to 100 g of an aqueous solution in which 4 g of sodium sulfite was dissolved, and the mixture was heated to 30°C. Te6
After stirring for 0 minutes, the total amount was 200 g with pure water to prepare a 10% aqueous solution of partially decomposed wheat gluten with a reducing agent, and 1 g of caustic soda was added to the 1009, and the solution was diluted with 100 g in a flask.
The mixture was heated and stirred at 0°C for 60 minutes. Thereafter, the mixture was neutralized with hydrochloric acid and the total amount was adjusted to 200 g with pure water to obtain decomposed product No. 25.

平均分子量は39500てあった。The average molecular weight was 39,500.

参考例26(小麦グルテンのアルカリによる部分分解と
次いで実施した酵素による部分分解(参考例24と順序
が逆)による分解物の調製)参考例5と同様の条件て小
麦グルテンのアルカリによる部分分解物の10%水溶液
を調製し、その100gに試薬塩酸を加えpH1,5の
水溶液を得、これをフラスコ内で、Q、1gのペプシン
を加えて37°Cで90分間反応させた。その後、苛性
ソーダで中和し純水で総量2009にし分解物No、2
6を得た。平均分子量は24500であった。
Reference Example 26 (Preparation of a decomposition product by partial decomposition of wheat gluten with an alkali and subsequent partial decomposition with an enzyme (reverse order from Reference Example 24)) A partial decomposition product of wheat gluten with an alkali under the same conditions as Reference Example 5. A 10% aqueous solution of Q was prepared, and the reagent hydrochloric acid was added to 100 g to obtain an aqueous solution with a pH of 1.5, which was reacted in a flask with 1 g of pepsin at 37°C for 90 minutes. After that, it was neutralized with caustic soda and the total amount was adjusted to 2009 with pure water.
I got 6. The average molecular weight was 24,500.

参考例27(小麦グルテンのアルカリによる部分分解と
次いで実施した酸化剤による部分分解による分解物の調
製) 参考例5と同様の条件で小麦グルテンのアルカリによる
部分分解物のlO%水溶肢を調製し、その100gにH
2O2換算で0.59に相当する過酸化水素水を加え、
40℃で60分間加熱撹拌した。その後、残存している
HtOvと当量のチオ硫酸ナトリウム(過酸化水素のマ
スキング用)を加え、純水て総量200gにして分解物
No、27を得た。平均分子量は37000であった。
Reference Example 27 (Preparation of decomposed product by partial decomposition of wheat gluten with alkali and subsequent partial decomposition with oxidizing agent) A lO% aqueous solution of wheat gluten partially decomposed with alkali was prepared under the same conditions as in Reference Example 5. , H to that 100g
Add hydrogen peroxide solution equivalent to 0.59 in terms of 2O2,
The mixture was heated and stirred at 40°C for 60 minutes. Thereafter, an amount of sodium thiosulfate (for masking hydrogen peroxide) equivalent to the remaining HtOv was added, and the total amount was adjusted to 200 g with pure water to obtain decomposed product No. 27. The average molecular weight was 37,000.

参考例28(小麦グルテンの還元剤による部分分解と次
いで実施したアルカリによる部分分解による分解物の調
製) 亜硫酸ナトリウム4gを溶解した水溶液100gに参考
fil 1で用いた小麦グルテン20gを加えて、30
℃にて60分間撹拌後、純水で総量2009にして小麦
グルテンの還元剤による部分分解物の10%水溶肢を調
製し、その100gに苛性ソーダ1gを加え、フラスコ
中で1oo0cて60分間加熱撹拌した。その後、塩酸
にて中和して純水で総量を200gとして分解物No、
21を得た。平均分子量は39500であっIこ。
Reference Example 28 (Preparation of decomposed product by partial decomposition of wheat gluten with a reducing agent and then partial decomposition with an alkali) 20 g of the wheat gluten used in reference fil 1 was added to 100 g of an aqueous solution in which 4 g of sodium sulfite was dissolved, and 30 g of wheat gluten was added.
After stirring at ℃ for 60 minutes, prepare a 10% aqueous solution of partially decomposed wheat gluten with a reducing agent by adding pure water to a total volume of 2009, add 1 g of caustic soda to 100 g, and heat and stir in a flask at 100℃ for 60 minutes. did. After that, it was neutralized with hydrochloric acid and the total amount was adjusted to 200g with pure water, and the decomposition product No.
I got 21. The average molecular weight was 39,500.

以下、参考例1〜28で得た小麦グルテン部分分解物の
特性を表−5に示した。
Table 5 below shows the characteristics of the partially degraded wheat gluten products obtained in Reference Examples 1 to 28.

(以下余白) 参考例1〜28て調製した小麦グルテンの部分分解物で
あるNo、 I〜28を犬用原化工機製スプレードライ
ヤーI、−8型を使用し噴霧乾燥し、得られた粉末品の
各種溶媒に対する冶解性を凋査したところ、すべての分
解物は水に溶解した[溶解度(25℃)lO%以上]。
(Left below) Powder products obtained by spray drying Nos. I to 28, which are partially degraded wheat gluten products prepared in Reference Examples 1 to 28, using a spray dryer I, model -8 manufactured by Inuyo Hara Kakoki Co., Ltd. When the solubility of the compound in various solvents was examined, all decomposed products were dissolved in water [solubility (25° C.) 10% or more].

しかし、メタノール、エタノール、アセトン、エチルエ
ーテルには不溶であった。
However, it was insoluble in methanol, ethanol, acetone, and ethyl ether.

[実施例I] 参考例1で調製した小麦グルテンの部分分解物である分
解物No、lを上記と同様に噴霧乾燥して得られた粉末
品109と活性グルテン*’  909と□を■型混合
機を用いて5分間混合し、この発明の粉末組成物を得た
[Example I] Powder product 109 obtained by spray-drying decomposition product No. 1, which is a partial decomposition product of wheat gluten prepared in Reference Example 1, in the same manner as above, and active gluten *' 909 and □ were shaped into ■ A powder composition of the present invention was obtained by mixing for 5 minutes using a mixer.

(以下余白) 3 *l 活性グルテン グリコ栄養食品(株)製 A−グルP(小麦粉よ り取り出した生グルテ ンをアンモニア溶酸中 に分散させ、熱変性を できるたけうけないよ うにして噴霧乾燥して 得られた粉末) [実施例2〜36] 参考例2〜28で調製した小麦グルテンの部分分解物で
ある分解物NO12〜28[以下グルテン部分分解物と
記す]を上記と同様に噴霧乾燥して得られた粉末品と実
施VllIlに記載の活性グルテンを実施例1と同様に
混合して、この発明の粉末組成物を得た。
(Margins below) 3 *l Active Gluten A-Glue P manufactured by Glico Nutritional Foods Co., Ltd. (Raw gluten extracted from wheat flour is dispersed in ammonia solution and spray-dried to avoid thermal denaturation as much as possible. Obtained Powder) [Examples 2 to 36] The decomposition products No. 12 to 28 [hereinafter referred to as gluten partial decomposition products], which are the partial decomposition products of wheat gluten prepared in Reference Examples 2 to 28, were spray-dried in the same manner as above. The obtained powder product and the active gluten described in Example VllIl were mixed in the same manner as in Example 1 to obtain a powder composition of the present invention.

使用したグルテン部分分解物の種類と、活性クルテンに
対する配合割合を併せて表−6に示す。
Table 6 shows the type of partially degraded gluten product used and its blending ratio with respect to active kurten.

4 表 表 6(続き) [実施料33〜38」 (生グルテンとの混合)生グル
テン(三和澱粉工業株式会社製)と参考例で得られた分
解物NO49はNo、12を表7に示す所定の割合てミ
キサー(日本精機製作所製マルチ・ブレンダー・ミル5
−3型)で混合してペースト伏とした後に噴霧乾燥して
この発明の粉末組成物を得た。
4 Table Table 6 (Continued) [Executive materials 33 to 38] (Mixture with raw gluten) Degraded products obtained from raw gluten (manufactured by Sanwa Starch Industries Co., Ltd.) and reference example No. 49 is No. 12 is shown in Table 7 Mixer (Multi Blender Mill 5 manufactured by Nippon Seiki Seisakusho Co., Ltd.)
A powder composition of the present invention was obtained by mixing the powder composition (type 3) to form a paste and then spray drying it.

表−7 [実施例39〜42](変性グルテンとの混合)参考例
で調製した分解物N009又はNo、12(粉末品)と
変性グルテン(三相澱粉工業(株)製ニューアブロン[
アンモニア型コ)を実施例1と同様に表8に示す比率で
混合し、粉末製剤品を得た。
Table 7 [Examples 39 to 42] (Mixing with modified gluten) Degraded product N009 or No. 12 (powder product) prepared in the reference example and modified gluten (New Avron manufactured by Sanso Starch Industries Co., Ltd.)
Ammonia type (c) was mixed in the same manner as in Example 1 at the ratio shown in Table 8 to obtain a powdered product.

表 [試験例1]水分散性試験 〈試験方法〉 実施例1〜42で得られた各粉末製剤品(供試品)1g
を試験管に入れて水道水9gを添加し、すぐにポイント
ミキサーにて30秒間混合する(10%水分散肢となる
)。混合終了後、液の外観を観察する。次いで1時間静
置後に再び30秒間混合し、再分散性を確認する。
Table [Test Example 1] Water dispersibility test <Test method> 1 g of each powder formulation (sample) obtained in Examples 1 to 42
into a test tube, add 9 g of tap water, and immediately mix for 30 seconds with a point mixer (resulting in a 10% water dispersion). After mixing, observe the appearance of the liquid. Then, after standing for 1 hour, the mixture was mixed again for 30 seconds and redispersibility was confirmed.

(ポイントミキサー−・−Yamato TOUCHM
IXERMT−31を使用) 試験結果を表−9に示す。
(Point mixer - Yamato TOUCHM
(using IXERMT-31) The test results are shown in Table-9.

表中再分散性の欄の記号の意味を下記する。The meanings of the symbols in the redispersibility column in the table are as follows.

×・・・・全く再分散しない。×: Not redispersed at all.

△・・・・・・はぼ均一に再分散する。Δ...Redispersion is almost uniform.

○・・・・・・均一に再分散する。○・・・Redisperse uniformly.

(以下余白) 表 表 9 (続き1) 1 (続き2) 無添加1・・ 無添加2・ 無添加3 ・・・実施例1〜32て用いた活 性クルテンのみ ・・実施例33〜38で用いた 生グルテンのみ 実施例39〜42で用いた 変性グルテンのみ 2 [試験例2] (水分散性試験) 実施例6て得られた粉末製剤品を用いて高濃度水分散肢
を調製し、その液の外観及び再分散性を試験した。試験
方法等は試験例1と同様である。
(Leaving space below) Table 9 (Continued 1) 1 (Continued 2) No additives 1... No additives 2/ No additives 3...Only the activated kurten used in Examples 1 to 32...In Examples 33 to 38 Only the raw gluten used was the modified gluten used in Examples 39 to 42 2 [Test Example 2] (Water dispersibility test) A highly concentrated water dispersion product was prepared using the powder formulation obtained in Example 6, The appearance and redispersibility of the liquid were tested. The test method etc. are the same as Test Example 1.

試験結果を表−IOに示す。The test results are shown in Table-IO.

実施例43〜45 参考例4で調製し小麦グルテンの部分分解物である分解
物No、4を実施例1と同様に混合して、この発明の粉
末製剤品を得た。但し、活性グルテンに対する配合割合
5w/w%のものを実施例43、同じ<15.20w/
w%のものをそれぞれ実施例44.45とした。
Examples 43 to 45 The decomposition product No. 4, which is a partially decomposed product of wheat gluten prepared in Reference Example 4, was mixed in the same manner as in Example 1 to obtain a powder formulation of the present invention. However, Example 43 has a compounding ratio of 5 w/w% to active gluten, the same <15.20 w/w
w% was designated as Example 44 and 45, respectively.

[試験例3コ (グルテン生地の弾性向上効果)実施例
4及び実施例43〜45て得られた各粉末製剤品(供試
品)と水道水を1−1で混合し、手て混捏して生地状態
にし、その弾性力をレオメータ−[不動工業(株)製]
を用いて以下の様にして試験した。
[Test Example 3 (Effect of improving elasticity of gluten dough) Each powder preparation (sample) obtained in Examples 4 and 43 to 45 was mixed with tap water in a ratio of 1:1, and kneaded by hand. The elastic force is measured using a rheometer [manufactured by Fudo Kogyo Co., Ltd.]
The test was conducted using the following method.

レオメータ−による測定方法を第1図に示した。The measurement method using a rheometer is shown in FIG.

このように容器I(直径38zi、 ?I&さ1811
z)に生地2(長径38關、短径25mmの偏平塊)を
入れ(第1図(イ))圧縮弾性力アダプタ3 (20x
iφ)に対し、容器(1)を押し上げ、生地(2)の厚
さか6尻劇こなったらレオメータ−がストップするので
(第1図(ロ))その時の強度(Kg)を読み取る。
In this way, container I (diameter 38zi, ?I & size 1811
Place the dough 2 (a flat block with a major axis of 38 mm and a minor axis of 25 mm) into the compressive elastic force adapter 3 (20 x
iφ), push the container (1) up, and when the thickness of the dough (2) reaches 60 degrees, the rheometer will stop (Figure 1 (b)) and read the strength (Kg) at that time.

レオメータ−による圧縮強度の測定結果を表11に示す
Table 11 shows the measurement results of compressive strength using a rheometer.

(以下余白) 表 1 (レオメータ−測定結果) なお、発明品を添加した生地は活性グルテン単独に比へ
ヘタツキがほとんどなく取り扱い易いものとなり、活性
グルテン単独の場合に見られた生地の緑変ら改善されて
いた。(*無添加・・・実施例1で用いた活性グルテン
のみ) [実施列46〜48コ 参考例6で調製した小麦グルテンの部分分解物である分
解物NO46を実施例1と同様に噴霧乾燥して得られた
粉末10g、209.409と実施%J 1て用いた活
性グルテンとを合計1009となるようにV型混合機に
添加し、5分間混合してこの発明の粉末製剤品を得た。
(Margin below) Table 1 (Results of rheometer measurement) The dough to which the invention was added had almost no stiffness compared to active gluten alone and was easier to handle, improving the green discoloration of the dough that was observed when active gluten alone was used. It had been. (*No additives... only the active gluten used in Example 1) [Rows 46 to 48] Spray-dry the decomposed product NO46, which is a partial decomposed product of wheat gluten prepared in Reference Example 6, in the same manner as in Example 1. 10 g of the powder, 209.409, and the active gluten used in Example 1 were added to a V-type mixer so that the total amount was 1009, and mixed for 5 minutes to obtain the powder formulation of the present invention. Ta.

分解物N016の粉末が10g含有している製剤品を実
施例46、同しく209.40g含有している製剤品を
それぞれ実施例47.48としf二。
A pharmaceutical product containing 10 g of decomposition product N016 powder was designated as Example 46, and a pharmaceutical product containing 209.40 g was designated as Example 47.48, f2.

[試験例4コ (ソーセージに対する品質向上効果試験
) 小麦グルテンは、ソーセージの粘弾性向上、結着性増加
等の目的で使用されている。小麦グルテン単独、実施例
46〜48で得られたこの発明の各粉末製剤品及び分解
物No、6の噴霧屹燥品を用いてソーセージに対する品
質向上効果試験を行っfコ。
[Test Example 4 (Test on quality improvement effect on sausages) Wheat gluten is used for the purpose of improving the viscoelasticity and binding property of sausages. A quality improvement effect test was conducted on sausages using wheat gluten alone, each powder preparation of the present invention obtained in Examples 46 to 48, and the spray-dried product of decomposition product No. 6.

試験方法 1、ソーセージの製造方性 ■−晩塩漬処理を施した豚ミンチ肉をミギザーでペース
ト状にする。
Test method 1: Sausage production ■ - Minced pork that has been salted overnight is made into a paste using a mixer.

■ヒーカーに■の肉と砕氷(対内20%)を入れ、スリ
ーワンモータで混合しながら、更に各供試品、そして香
辛料(予め粉体混合済み)を添加する。
■Put the meat from ■ and crushed ice (20% internal) into a heater, and while mixing with a three-one motor, add each sample and spices (previously mixed in powder form).

■サランランプてケーシングをつくり、これに■の肉を
充填する。
■Make a casing using a saran lamp and fill it with the meat from ■.

■乾燥機中で乾燥処理(45℃、1時間)を行つた後、
70〜75℃の湯で1時間煮る。
■After drying in a dryer (45℃, 1 hour),
Boil in 70-75℃ water for 1 hour.

■流水中で充分冷却し、製品を得る。■ Cool thoroughly under running water to obtain the product.

2 ソーセージの処方 豚ミンチ肉     100g(赤身70%)食   
 塩         2g(対内2.0%)硝   
 石       0.07ft香辛料  0.3g 供試品   5g(対内5.0%) 3、評価試験 (1)圧縮重量(Kg) ■厚さ5ffJI+に切ったソーセージをジヤツキの上
に乗せる。
2 Sausage recipe minced pork 100g (70% lean) meal
Salt 2g (2.0%) Salt
Stone 0.07ft Spices 0.3g Sample 5g (5.0% of weight) 3.Evaluation test (1) Compressed weight (Kg) ■Put the sausage cut to a thickness of 5ffJI+ on top of the jackpot.

■ジヤツキの上方に測定機を固定し、徐々にジヤツキを
上げて行く。
■Fix the measuring device above the jack and gradually raise the jack.

■ソーセージが濱れた時の重量(圧縮重量)を読み取る
■Read the weight (compressed weight) of the sausage when it weighs.

*測定機二昌新商事株式会社製 CHATILLON(
2)縮小率(%) ■500mQメスシリンダーにソーセージを入れた状態
で、水を注ぎ込んて500if!に要する水tl(u1
2)を読みとり、 加熱前後のソーセージの体積を測定 する。
*Measuring device CHATILLON (manufactured by Nishoshin Shoji Co., Ltd.)
2) Reduction rate (%) ■Pour sausage into a 500mQ graduated cylinder and pour water into it for 500if! Water tl (u1
Read 2) and measure the volume of the sausage before and after heating.

(各々a、b (110とする) ■縮小率(%)− ×100で算出する。(respectively a, b (Supposed to be 110) ■Reduction rate (%) - Calculate by ×100.

試験結果を表 12に示す。Show test results 12.

表 2 このように、 分解物No、6及び活性グルテン単独 でも圧縮重量(結着力の目安)は大きくなるが、実施例
により得られた製剤品の方がより大きい。
Table 2 As shown, the compressed weight (a measure of binding strength) is large even when decomposed product No. 6 and active gluten are used alone, but the formulation obtained in the example is larger.

まだ、縮小率(保水性の目安)についてら、実施例によ
り得られた製剤品が良好であった。
However, in terms of shrinkage rate (a measure of water retention), the formulations obtained in Examples were good.

特に実施例47で得られん製剤品は、物性、食感、作業
性の点において、最も良好な結果を示しノこ。
In particular, the formulation obtained in Example 47 showed the best results in terms of physical properties, texture, and workability.

(へ)発明の効果 このようにして得られるこの発明の小麦グルテン組成物
はそれ自体、難水溶性、水難分散性である小麦グルテン
の性状に良好な親水性、水分散性の特性が付与された乙
のであり、しかも、小麦グルテンの特性を損なわないも
のである。従って、従来の食品素材である小麦グルテン
自体と同様な用途に用いることができ、取り扱い上極め
テ有利なものである。
(f) Effects of the Invention The wheat gluten composition of the present invention obtained in this way has good hydrophilicity and water dispersibility properties added to the properties of wheat gluten, which is poorly water soluble and water dispersible. Moreover, it does not impair the properties of wheat gluten. Therefore, it can be used for the same purposes as wheat gluten itself, which is a conventional food material, and is extremely advantageous in terms of handling.

そして、小麦グルテンは、それ自体一種の食品変性物で
あり毒性が啄いこと、とくに強い弾性があることによっ
て食品に配合してその弾性品質を補強・改良する有用な
ものであるが、この発明の小麦グルテン組成物を用いれ
ばそれらの特性が阻害されないばかりか、却って向上す
ることができる。
Wheat gluten itself is a type of food denatured product, and is highly toxic and has particularly strong elasticity, making it useful for reinforcing and improving the elasticity of foods by adding it to foods. By using the wheat gluten composition, these properties are not only not inhibited but can even be improved.

かくして、この発明の小麦グルテン組成物は、食品工業
?こおける、パン、ケーキ、油脂加工食品又は粉状イン
スタント食品に添加配合するにあたり容易に水性液中に
溶解分散し取扱いが便利であるとともに、小麦グルテン
の特性をそのまま、あるいはそれ以上に発揮して食品品
質を改善向上させることかできる。ことにパンについて
は、弾力性の向上や生地生成の迅速化を図ることができ
、さらにソーセージへ添加することにより、結着性、保
水性、混和性等を向上することも可能である。
Thus, is the wheat gluten composition of this invention suitable for the food industry? It is easily dissolved and dispersed in aqueous liquids and is convenient to handle when added to breads, cakes, oil-processed foods, or powdered instant foods. Food quality can be improved. In particular, for bread, it is possible to improve elasticity and speed up dough formation, and by adding it to sausages, it is also possible to improve binding properties, water retention, miscibility, etc.

従って、この発明の小麦グルテン組成物の食品工業にお
ける有用性は極めて大なるものである。
Therefore, the wheat gluten composition of the present invention is extremely useful in the food industry.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(イ)及び(ロ)は、各々この発明の小麦グルテ
ン組成物についての弾性向上効果の評価方法を示す説明
図である。 第 (ロ)
FIGS. 1(A) and 1(B) are explanatory diagrams each showing a method for evaluating the elasticity improving effect of the wheat gluten composition of the present invention. Part (b)

Claims (1)

【特許請求の範囲】 1、水難分散性の小麦グルテン1重量部に対し、重量平
均分子量約3000〜110000の小麦グルテン部分
分解物0.03〜0.2重量部を配合してなる小麦グル
テン組成物。 2、水難分散性の小麦グルテンが、生グルテン、活性グ
ルテン又は変性グルテンである請求項1の小麦グルテン
組成物。 3、小麦グルテン部分分解物の重量平均分子量が約10
000〜70000である請求項1の小麦グルテン組成
物。 4、小麦グルテン部分分解物が、小麦グルテンを、酸、
アルカリ又は酵素による分解処理又はこれらの二以上の
組合せに付して得られたものである請求項1の小麦グル
テン組成物。 5、小麦グルテン部分分解物が、さらに還元剤及び/又
は酸化剤による分解処理を経て得られたものである請求
項4の小麦グルテン組成物。
[Claims] 1. A wheat gluten composition comprising 0.03 to 0.2 parts by weight of partially decomposed wheat gluten having a weight average molecular weight of approximately 3,000 to 110,000 to 1 part by weight of water-resistant wheat gluten. thing. 2. The wheat gluten composition according to claim 1, wherein the water-resistant wheat gluten is fresh gluten, activated gluten, or modified gluten. 3. The weight average molecular weight of wheat gluten partially degraded product is approximately 10
The wheat gluten composition according to claim 1, wherein the wheat gluten composition has a molecular weight of 0.000 to 70,000. 4. Partial decomposition product of wheat gluten converts wheat gluten into acid,
2. The wheat gluten composition according to claim 1, which is obtained by subjecting to a decomposition treatment using an alkali or an enzyme, or a combination of two or more thereof. 5. The wheat gluten composition according to claim 4, wherein the wheat gluten partial decomposition product is obtained through further decomposition treatment with a reducing agent and/or an oxidizing agent.
JP1226667A 1989-08-31 1989-08-31 Wheat gluten composition Expired - Lifetime JP2738450B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1226667A JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1226667A JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Publications (2)

Publication Number Publication Date
JPH0387149A true JPH0387149A (en) 1991-04-11
JP2738450B2 JP2738450B2 (en) 1998-04-08

Family

ID=16848773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1226667A Expired - Lifetime JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Country Status (1)

Country Link
JP (1) JP2738450B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019047772A (en) * 2017-09-07 2019-03-28 長田産業株式会社 Food product modifier and method for producing the same
CN115413731A (en) * 2022-08-10 2022-12-02 西北农林科技大学 High-water-holding-capacity gluten protein-based vegetable meat and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2019047772A (en) * 2017-09-07 2019-03-28 長田産業株式会社 Food product modifier and method for producing the same
CN115413731A (en) * 2022-08-10 2022-12-02 西北农林科技大学 High-water-holding-capacity gluten protein-based vegetable meat and preparation method thereof

Also Published As

Publication number Publication date
JP2738450B2 (en) 1998-04-08

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