JP2738450B2 - Wheat gluten composition - Google Patents

Wheat gluten composition

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Publication number
JP2738450B2
JP2738450B2 JP1226667A JP22666789A JP2738450B2 JP 2738450 B2 JP2738450 B2 JP 2738450B2 JP 1226667 A JP1226667 A JP 1226667A JP 22666789 A JP22666789 A JP 22666789A JP 2738450 B2 JP2738450 B2 JP 2738450B2
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JP
Japan
Prior art keywords
wheat gluten
gluten
wheat
product
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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JP1226667A
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Japanese (ja)
Other versions
JPH0387149A (en
Inventor
賢治 半埜
一雄 上林
洋子 山本
栄 片山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KATAYAMA KAGAKU KOGYO KENKYUSHO KK
Original Assignee
KATAYAMA KAGAKU KOGYO KENKYUSHO KK
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Priority to JP1226667A priority Critical patent/JP2738450B2/en
Publication of JPH0387149A publication Critical patent/JPH0387149A/en
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Publication of JP2738450B2 publication Critical patent/JP2738450B2/en
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  • Meat, Egg Or Seafood Products (AREA)

Description

【発明の詳細な説明】 (イ)産業上の利用分野 この発明は、小麦グルテン組成物に関する。さらに詳
しくは小麦蛋白質である、生グルテン、粉末状の活性グ
ルテンもしくは変性グルテン等(以下、これらを総呼す
るときは、単に小麦グルテンと記す)の水分散性を改良
してなる小麦グルテン組成物に関する。
The present invention relates to a wheat gluten composition. More specifically, a wheat gluten composition obtained by improving the water dispersibility of wheat protein, such as raw gluten, powdered active gluten or modified gluten (hereinafter simply referred to as wheat gluten). About.

(ロ)従来の技術 一般に、小麦蛋白質である生グルテン、粉末状の活性
グルテン、粉末状の変性グルテン等の小麦グルテンは、
加熱されると熱変性を生じ約70℃でゲル化が起こり、そ
の結果強い弾力性のあるゲルを作ることにはよく知られ
ている。そこで、従来からこのような小麦グルテンの特
性を利用して、各種食品を改良することが行われてお
り、例えば水産、畜産の魚畜、肉加工食品に添加して高
温、高圧下における弾力性の低下を防止したり、パンや
めん類の製造時に添加しての腰持ちを向上させ、かつ成
形性を改善し良好な食感を付与することが行われてい
る。
(B) Conventional technology In general, wheat gluten such as raw gluten, which is a wheat protein, powdered active gluten, and powdered modified gluten,
It is well known that when heated, it undergoes thermal denaturation and gelation at about 70 ° C., resulting in a highly elastic gel. Therefore, various kinds of foods have been conventionally improved by utilizing such properties of wheat gluten, for example, when added to fisheries, livestock fish and livestock, and processed meat foods, elasticity under high temperature and high pressure is added. In order to prevent a decrease in the quality of the food, to improve the firmness of the bread and noodles during the production thereof, and to improve the moldability and impart a good texture.

しかしながら、小麦グルテンは、水に対する親和性に
乏しく、中性付近において殆ど水に不溶であるため、水
混和時に所謂、ままこ(fish eye)を形成し、均一な分
散液を得ることが、極めて困難である。小麦グルテンの
このような非水親和性、水難分散性は、食品への添加使
用の際、作業上及びそれにもとづく食品品質の技術改良
面において軽視することのできない制限因子になってい
る。
However, since wheat gluten has poor affinity for water and is almost insoluble in water near neutrality, it is extremely difficult to form a so-called fish eye when mixing with water and to obtain a uniform dispersion. Have difficulty. Such non-water affinity and poor water dispersibility of wheat gluten is a limiting factor that cannot be neglected in terms of workability and technical improvement of food quality based on the addition and use in foods.

そこで、小麦グルテンの水に対する溶解性、分散性を
改良するため多くの提案がなされており、中でも小麦グ
ルテンに対し食品添加物として許容できる各種分散剤や
界面活性剤を配合して小麦グルテンに水分散性を付与す
る方法が知られている。例えば、生グルテン、変性グル
テンに多糖類誘導体を混和する方法(特公昭46−24063
号公報)や50〜80%含水グルテンにレシチンを添加し均
一乳化後、乾燥粉末化する方法(特公昭62−14253号公
報)等である。
Therefore, many proposals have been made to improve the solubility and dispersibility of wheat gluten in water, and among them, various kinds of dispersants and surfactants that are acceptable as food additives are added to wheat gluten, and water is added to wheat gluten. Methods for imparting dispersibility are known. For example, a method of mixing a polysaccharide derivative with raw gluten or modified gluten (Japanese Patent Publication No. 46-24063)
And a method of adding lecithin to 50-80% water-containing gluten, emulsifying the mixture uniformly, and then drying and pulverizing the mixture (Japanese Patent Publication No. 62-14253).

(ハ)発明が解決しようとする課題 しかるに、前述の小麦グルテンの水分散性改良のため
の方法はいずれも、その効果が必ずしも充分とはいえな
いばかりか、多少水分散性を改善できたとしても、本
来、保有している小麦グルテンの特性ことに食品添加時
の弾性付与効果を低下させる場合が多く、食品に添加し
てその品質を改善する目的を充分に果たしているとはい
えない。また用いられている配合剤は特殊の食品添加物
であるため、食品そのものである小麦グルテンの用途を
制限する場合もあった。
(C) Problems to be Solved by the Invention However, all of the above-mentioned methods for improving the water dispersibility of wheat gluten are not always sufficient in effect, and it is considered that the water dispersibility can be somewhat improved. However, in many cases, the properties of wheat gluten, which is possessed, often decrease the elasticity-imparting effect at the time of food addition, and it cannot be said that the purpose of improving the quality by adding it to food is sufficiently fulfilled. Further, since the compounding agent used is a special food additive, the use of wheat gluten, which is a food itself, may be limited.

この発明は、かかる問題点を解消すべくなされたもの
であり、ことに小麦グルテンの有する特性を損なうこと
なく、優れた水分散性を備えた小麦グルテン組成物を提
供しようとするものである。
The present invention has been made to solve such a problem, and an object thereof is to provide a wheat gluten composition having excellent water dispersibility without impairing the properties of wheat gluten.

(ニ)課題を解決するための手段 本発明者らは、上記観点から小麦グルテンに水分散性
を付与すべく、各種配合剤の検討を行った。その結果、
小麦グルテンに対し、小麦グルテン部分分解物を少量添
加することにより、優れた水分散性を備えた小麦グルテ
ン組成物が得られる事実、並びに小麦グルテンの特性を
損なわないばかりか、かかる組成物を食品に添加した際
に、小麦グルテン自体を添加した場合よりも優れた弾性
付与効果が奏される事実を見出しこの発明に到達した。
(D) Means for solving the problem The present inventors have studied various compounding agents in order to impart water dispersibility to wheat gluten from the above viewpoint. as a result,
The fact that by adding a small amount of partially decomposed wheat gluten to wheat gluten, a wheat gluten composition having excellent water dispersibility can be obtained, and not only does the property of wheat gluten not be impaired, but also such a food The present inventors have found out that a more excellent elasticity-imparting effect is exerted than when wheat gluten itself is added, and reached the present invention.

なお、ここで小麦グルテン部分分解物は、従来、界面
活性能、分散能等を示すことは知られている(特開昭64
−14274号公報)が、未分解の小麦グルテンと組合せて
使用することは具体的に知られておらず、ことに、水分
散性を付与するのみならず小麦グルテン自体の有する特
性を改善することは全く知られていない。
It is to be noted that the wheat gluten partially decomposed products heretofore have been known to exhibit surface active ability, dispersing ability, etc.
No. -14274) is not specifically known to be used in combination with undegraded wheat gluten, and in particular, to improve the properties of wheat gluten itself as well as imparting water dispersibility. Is not known at all.

かくしてこの発明によれば、水難分散性の小麦グルテ
ン1重量部に対し、重量平均分子量約670〜110000の小
麦グルテン部分分解物0.03〜0.2重量部を配合してなる
小麦グルテン組成物が提供される。
Thus, according to the present invention, there is provided a wheat gluten composition comprising 0.03 to 0.2 parts by weight of a partially degraded wheat gluten having a weight average molecular weight of about 670 to 110,000 per 1 part by weight of poorly water-dispersible wheat gluten. .

この発明における水難溶性の小麦グルテンとは、一般
に、魚畜肉加工食品の品質、食感の向上、弾性付与用と
して用いられている小麦ゲルを意味し、具体的には、生
グルテン、粉末状の活性グルテンもしくは変性グルテン
と称せられるものが含まれる。ここで、生グルテンは、
小麦粉を水洗して小麦粉中の非水溶性蛋白質を分離し取
り出したそのままの粘結塊状のものでもよいが、これを
乾燥し粉砕して粉末状としたものが均一組成物を得るた
めに望ましい。また活性グルテンは生グルテンを、熱変
性をできるだけ受けないようにフラッシュドライ又はス
プレードライ方式で乾燥粉末化したものであり、また変
性グルテンは生グルテン又は活性グルテンを酸化剤又は
還元剤で化学的性質を変えない程度、ことに分解が生じ
ない程度に処理した後、乾燥、粉末化したものである。
これらの小麦グルテンは何れも高い凝集性と強い弾力性
を呈するが、水に対する親和性が呈く、極めて分散し難
い性質を有する。
The poorly water-soluble wheat gluten in the present invention generally means a wheat gel that has been used for improving the quality of fish and meat processed food, improving texture, and imparting elasticity.Specifically, raw gluten, powdery What is called active gluten or denatured gluten is included. Here, raw gluten is
The water-soluble protein in the flour may be washed and the water-insoluble protein in the flour may be separated and taken out as it is, but it is desirable to obtain a uniform composition by drying and pulverizing the powder into a powder. Active gluten is obtained by dry-pulverizing raw gluten by flash drying or spray drying so as to minimize heat denaturation.Modified gluten is obtained by converting raw gluten or active gluten into a chemical substance using an oxidizing agent or a reducing agent. Is processed to such an extent that does not change, in particular, does not cause decomposition, and then dried and powdered.
All of these wheat glutenes exhibit high cohesiveness and strong elasticity, but exhibit an affinity for water and are extremely difficult to disperse.

上記した小麦グルテンに配合する小麦グルテン部分分
解物は、上記した小麦グルテンを、酸、アルカリ又は酵
素の単独分解処理又はこれら2以上の組合わせに付すか
又はこれらの単独又は組合せ分解処理に加え、還元剤及
び/又は酸化剤による分解処理に付すことにより得られ
る。かかる分解処理により、この発明で用いる重量平均
分子量Mwが約670〜110000(但し、Mwはゲル濾過法によ
って測定した値である)の小麦グルテン部分分解物を簡
便に得ることができる。
The wheat gluten partially decomposed product to be mixed with the above-mentioned wheat gluten, the above-mentioned wheat gluten is subjected to a single decomposition treatment of an acid, an alkali or an enzyme or a combination of two or more thereof, or in addition to a single or combination decomposition treatment thereof, It is obtained by subjecting it to a decomposition treatment with a reducing agent and / or an oxidizing agent. By such a decomposition treatment, a wheat gluten partially decomposed product having a weight average molecular weight Mw of about 670 to 110,000 (where Mw is a value measured by a gel filtration method) used in the present invention can be easily obtained.

酸、アルカリ、酵素による単独又は併用による小麦グ
ルテンの部分分解処理は、何れを採用してもよく又、組
合わせの場合、その処理順序も問わない。しかし還元剤
や酸化剤による単独の分解処理によっては、小麦蛋白質
の−S−S−結合の一部を切断するのみでこの発明で用
いることのできる目的の分子量と特性を有する分解物を
得ることが困難である。従って、酸、アルカリ又は酵素
処理と還元剤又は酸化剤処理を組み合わせて行うことが
望ましい。この際、還元剤処理を組合わせる場合にはさ
らに還元剤処理を先行して実施する方が、小麦蛋白質の
−S−S−結合の切断によりその網目構造が低下、次工
程の酸、アルカリ又は酵素による分解反応が容易に進行
すること及び所望の分子量をより選択的に得るための処
理条件の採用が容易になるなどによる理由でより好まし
い。
Any of the partial decomposition treatments of wheat gluten by an acid, an alkali, or an enzyme alone or in combination may be employed, and in the case of a combination, the treatment order is not limited. However, by a single decomposition treatment with a reducing agent or an oxidizing agent, it is possible to obtain a degraded product having the target molecular weight and characteristics that can be used in the present invention by only cutting a part of the -SS- bond of wheat protein. Is difficult. Therefore, it is desirable to combine acid, alkali or enzyme treatment with reducing agent or oxidizing agent treatment. At this time, when the reducing agent treatment is combined, it is better to carry out the reducing agent treatment in advance, the network structure of the wheat protein is reduced due to cleavage of the -SS- bond of the wheat protein, and the acid, alkali or This is more preferable because the decomposition reaction by the enzyme proceeds easily and the treatment conditions for obtaining a desired molecular weight more selectively become easier.

分解処理は、塩酸、硫酸、硝酸等の無機酸や酢酸等の
有機酸等、酸による分解処理の場合、小麦グルテンを希
酸水溶液中で約60〜120℃以下、約10〜600分撹拌下にお
いて実施するのが適している。アルカリによる分解処理
は、水酸化ナトリウム、水酸化カリウム、炭酸ナトリウ
ム、炭酸カリウムの2〜40重量%の水溶液又は分散液中
で約60〜180℃、約10〜600分撹拌して行うのが適してい
る。酵素による分解処理は、プロテアーゼ活性を有する
酵素の希水溶液中で行うのが適しており、通常、小麦グ
ルテン分散液にペプシン、アルカリプロテアーゼ、パパ
イン等の酵素を少量存在させた状態で、それら酵素の至
適pH条件下、約10〜60℃、約60〜600分行うのが適して
いる。
In the case of a decomposition treatment using an acid such as an inorganic acid such as hydrochloric acid, sulfuric acid, or nitric acid or an organic acid such as acetic acid, wheat gluten is stirred in a dilute aqueous acid solution at about 60 to 120 ° C. or lower for about 10 to 600 minutes. It is suitable to carry out in. The decomposition treatment with an alkali is preferably performed in a 2 to 40% by weight aqueous solution or dispersion of sodium hydroxide, potassium hydroxide, sodium carbonate, and potassium carbonate with stirring at about 60 to 180 ° C. for about 10 to 600 minutes. ing. The decomposition treatment with an enzyme is suitably performed in a dilute aqueous solution of an enzyme having protease activity.Normally, in a state in which a small amount of an enzyme such as pepsin, an alkaline protease, or papain is present in a wheat gluten dispersion, the enzyme is degraded. It is suitable to carry out at about 10 to 60 ° C. for about 60 to 600 minutes under the optimum pH condition.

また、還元剤又は酸化剤による分解処理は亜硫酸ナト
リウム、チオ硫酸ナトリウム、エリソルビン酸又はヒド
ラジン等の還元剤又は過酸化水素、次亜塩素酸塩等の酸
化剤の存在で約10〜100℃、10〜600分間、撹拌下で行う
のが適している。
Further, the decomposition treatment with a reducing agent or an oxidizing agent is performed in the presence of a reducing agent such as sodium sulfite, sodium thiosulfate, erythorbic acid or hydrazine or an oxidizing agent such as hydrogen peroxide or hypochlorite at about 10 to 100 ° C., 10 ° C. Suitably, the stirring is carried out for ~ 600 minutes.

この際、小麦グルテンに対する各処理剤の量的条件と
しては、小麦グルテン20gに対し、酸又はアルカリ処理
のときは各々0.1〜60g、酵素処理のときは0.02〜5g又、
酸化又は還元処理のときは各々0.1〜5gを用いるのが適
している。
At this time, the quantitative conditions of each treatment agent for wheat gluten, for 20 g of wheat gluten, 0.1 to 60 g each for acid or alkali treatment, 0.02 to 5 g for enzyme treatment,
In the case of oxidation or reduction treatment, it is suitable to use 0.1 to 5 g each.

かくして小麦グルテンを上記それぞれの分解処理に付
すことによって小麦グルテン部分分解物を得ることがで
きる。そして小麦グルテンの部分分解の処理条件を適宜
選択することにより平均分子量10,000〜70,000を有する
分解物を得ることができ、このものを小麦グルテンに配
合して得られた本発明の組成物は、充分な水分散性を保
有するとともに小麦グルテン固有の弾力性を損なうこと
なく、むしろ強められることが認められ、より好ましい
部分分解物である。
Thus, wheat gluten is subjected to each of the above-described decomposition treatments, whereby a partially decomposed product of wheat gluten can be obtained. And by appropriately selecting the processing conditions of the partial decomposition of wheat gluten, a decomposition product having an average molecular weight of 10,000 to 70,000 can be obtained, and the composition of the present invention obtained by blending this with wheat gluten is sufficient. It is recognized that it has high water dispersibility and can be strengthened without impairing the elasticity inherent in wheat gluten, and is a more preferable partial decomposition product.

ここで、小麦グルテン部分分解物の平均分子量は小麦
グルテンとの親和性にも関係を有し670以下であるとき
は、水溶性が高すぎるため小麦グルテンとの親和性が低
下し、均一混和が困難になり、また110,000以上になる
と水溶性が低下し、また十分な水分散性を有する組成物
を得難く適さない。とくに、この発明においては、前述
したように原料小麦グルテンより高い弾性を食品に付与
できる小麦グルテン組成物を得ることができるが、平均
分子量が高すぎるときそれを配合した組成物の弾性は、
原料小麦グルテンのそれを同程度となるため適さない。
Here, the average molecular weight of the wheat gluten partially decomposed product has a relationship with the affinity for wheat gluten, and when it is 670 or less, the affinity for wheat gluten is reduced because the water solubility is too high, and the uniform mixing is not achieved. When it is more than 110,000, the water solubility is reduced, and it is difficult to obtain a composition having sufficient water dispersibility. In particular, in the present invention, as described above, it is possible to obtain a wheat gluten composition that can provide food with higher elasticity than raw wheat gluten, but when the average molecular weight is too high, the elasticity of the composition containing the same is
It is not suitable because it is comparable to that of raw wheat gluten.

なお、上記小麦グルテン部分分解物のうち、下記特
性: (a)紫外吸収λmaxが、260〜280nm付近で、かつ赤外
吸収が1400,1630及び3400cm-1付近である。
The wheat gluten partially decomposed product has the following characteristics: (a) UV absorption λmax is around 260 to 280 nm, and infrared absorption is around 1400, 1630 and 3400 cm −1 .

(b)等電点が3.9〜5.0の範囲にある。(B) The isoelectric point is in the range of 3.9 to 5.0.

(c)pH緩衝性(本品の5重量%水溶液100mlのpHを6
から2まで低下させるのに1N−塩酸を2〜25ml必要とす
る)を有する。
(C) pH buffering property (pH of 6
Requires 2 to 25 ml of 1N hydrochloric acid to reduce from 1 to 2.

(d)水に可溶であり、メタノール、エタノール、アセ
トン、エーテルに不溶である。
(D) It is soluble in water and insoluble in methanol, ethanol, acetone and ether.

(e)キサントプロティン反応、ニンヒドリン反応によ
って呈色する。
(E) Color is formed by a xanthoprotein reaction and a ninhydrin reaction.

を有する部分分解物を用いるのが好ましい。 It is preferable to use a partially decomposed product having the following formula:

この発明において、小麦グルテン部分分解物の配合量
は、小麦グルテン1重量部に対して0.03〜0.2重量部と
される。ここで配合量が0.03重量部未満では、水分散性
付与効果や弾性向上効果が不充分であり、0.2重量部を
越えると、小麦グルテン自体の特性ことに弾性付与効果
が阻害されるため適さない。これらのうちことに、小麦
グルテン部分分解物を小麦グルテン1重量部に対し0.05
〜0.15重量部とするのが好ましい。
In the present invention, the amount of the partially decomposed wheat gluten is 0.03 to 0.2 parts by weight based on 1 part by weight of wheat gluten. If the amount is less than 0.03 parts by weight, the effect of imparting water dispersibility and the effect of improving elasticity are insufficient.If the amount exceeds 0.2 parts by weight, the elasticity-imparting effect is impaired in the properties of wheat gluten itself, which is not suitable. . Among these, the wheat gluten partially decomposed product was added to 0.05 part by weight of wheat gluten.
Preferably, it is 0.15 parts by weight.

この発明の小麦グルテン組成物は、通常、水性液体又
は粉末の形態として得ることができる。すなわち、小麦
グルテン部分分解物は、小麦グルテンを酸、アルカリ、
酵素又は還元剤等の処理剤で水性液中の処理によって溶
液とし得られるか、又はこれをさらに乾燥して粉末とし
て得られる。従って、粉末状の小麦生グルテン、小麦活
性グルテン、小麦変性グルテンについては、そのまま添
加混合すればよい。またペースト状の生グルテン又は粉
末状の活性グルテン又は変性グルテンを水で混練りし希
釈した液状物については前記液状の小麦グルテン部分分
解物を加えて均一混合すれば液状の組成物が得られる。
しかして、食品に添加する際の便利を考え、組成物の粉
末状又は液状物の何れかが適宜選択されて使用される。
The wheat gluten composition of the present invention can usually be obtained in the form of an aqueous liquid or powder. That is, wheat gluten partially decomposed product, wheat gluten acid, alkali,
It can be obtained as a solution by treating in an aqueous liquid with a treating agent such as an enzyme or a reducing agent, or it can be further dried to obtain a powder. Therefore, powdery wheat raw gluten, wheat active gluten, and wheat modified gluten may be added and mixed as they are. For a liquid substance obtained by kneading and diluting paste-like raw gluten or powdery active gluten or denatured gluten with water, a liquid composition can be obtained by adding the liquid wheat gluten partially decomposed product and uniformly mixing.
Therefore, considering the convenience of adding to a food, either a powdery or liquid material of the composition is appropriately selected and used.

(ホ)実施例 この発明を以下の参考例及び実施例によりさらに詳し
く説明する。
(E) Examples The present invention will be described in more detail with reference to the following Reference Examples and Examples.

[参考例] この発明に用いる小麦グルテンの部分分解物を下記の
様にして調製した。これら調製物の物性を表−1にまと
めて示す。
Reference Example A partially decomposed product of wheat gluten used in the present invention was prepared as follows. Table 1 summarizes the physical properties of these preparations.

参考例1〜7(小麦グルテンのアルカリによる部分分解
物の調製) 和光純薬工業(株)製小麦グルテン(試薬品)20g
を、苛性ソーダを0.2〜4gの範囲内で各別に溶解した7
個の水溶液100g中に加え、充分混合後、フラスコ又はオ
ートクレーブ中で80℃〜150℃で30〜360分の範囲の温度
及び時間で各別にそれぞれ加熱撹拌した。これらを塩酸
にて中和し、純水で総量200gにして分解物No.1〜7を得
た。
Reference Examples 1 to 7 (Preparation of partially decomposed product of wheat gluten with alkali) 20 g of wheat gluten (reagent product) manufactured by Wako Pure Chemical Industries, Ltd.
Was dissolved separately in a range of 0.2 to 4 g of caustic soda 7
Each of the aqueous solutions was added to 100 g of the aqueous solution, mixed well, and heated and stirred separately in a flask or an autoclave at a temperature of 80 ° C. to 150 ° C. for a temperature and time in a range of 30 to 360 minutes. These were neutralized with hydrochloric acid, and the total amount was adjusted to 200 g with pure water to obtain decomposed products Nos. 1 to 7.

分解条件と分解物の平均分子量(ゲル濾過法でwと
して測定)を表−1に示す。
Table 1 shows the decomposition conditions and the average molecular weight of the decomposition product (measured as w by gel filtration method).

参考例8〜10(小麦グルテンの酸による部分分解物の調
製) 塩化水素換算で1g,2g及び4gに相当する塩酸水溶液100
gの入った3個のフラスコにそれぞれ和光純薬工業
(株)製の小麦グルテン(試薬品)20gを加え、100℃、
60分間加熱撹拌した。その後、苛性ソーダで中和し純水
で総量200gにして、分解物No.8〜10を得た。
Reference Examples 8 to 10 (Preparation of partial decomposition product of wheat gluten with acid) Aqueous hydrochloric acid solution equivalent to 1 g, 2 g and 4 g in terms of hydrogen chloride
20 g of wheat gluten (reagent product) manufactured by Wako Pure Chemical Industries, Ltd. was added to each of the three flasks containing
The mixture was heated and stirred for 60 minutes. Thereafter, the mixture was neutralized with caustic soda to make a total amount of 200 g with pure water to obtain decomposed products Nos. 8 to 10.

表−2の分解条件と分解物の平均分子量を示す。 Table 2 shows the decomposition conditions and the average molecular weight of the decomposition products.

参考例11(小麦グルテンの酵素による部分分解物の調
製) 参考例1で用いた小麦グルテン20gを0.1N−塩酸液150
gが入ったフラスコに加え、pH1.5の水溶液を得、これに
0.2gのペプシンを加え37℃で90分間反応させた。この
後、苛性ソーダで中和し純水で総量200gにして分解物N
o.11を得た。平均分子量は60,000であった。
Reference Example 11 (Preparation of partial decomposition product of wheat gluten by enzyme) 20 g of wheat gluten used in Reference Example 1 was added to a 0.1N-hydrochloric acid solution 150
g was added to the flask to obtain a pH 1.5 aqueous solution.
0.2 g of pepsin was added and reacted at 37 ° C. for 90 minutes. After that, neutralize with caustic soda, make the total amount 200 g with pure water, and decompose N
o.11 was obtained. The average molecular weight was 60,000.

参考例12〜21(小麦グルテンの酸による部分分解と次い
で実施したアルカリによる部分分解による分解物の調
製) 参考例8〜10と同様の条件で小麦グルテンの酸による
部分分解物の10%水溶液を調製し、その各100gをフラス
コもしくはオートクレーブ8個に入れ、これらに苛性ソ
ーダ0.5〜2gの範囲内の量に各別に加え、100又は150℃
にて60又360分間加熱撹拌した。その後、塩酸にて中和
し純水で総量200gにして分解物No.12〜19を得た。苛性
ソーダに換えて炭酸ナトリウムを使用した以外はすべて
上記と同様にして分解物No.20を得た。酸による部分分
解の条件を塩酸添加量0.5g、温度80℃、時間60分、アル
カリによる部分分解の条件を苛性ソーダ添加量0.5g、温
度80℃、時間30分とし上記と同様にして分解物No.21を
得た。
Reference Examples 12 to 21 (Preparation of Degraded Product by Partial Decomposition of Wheat Gluten by Acid and Subsequent Partial Decomposition by Alkaline) Under the same conditions as in Reference Examples 8 to 10, a 10% aqueous solution of the partially decomposed product of wheat gluten by acid was prepared. 100 g of each was placed in a flask or 8 autoclaves, and each was separately added to an amount in the range of 0.5 to 2 g of caustic soda at 100 or 150 ° C.
For 60 or 360 minutes. Thereafter, the mixture was neutralized with hydrochloric acid and the total amount was adjusted to 200 g with pure water to obtain decomposed products Nos. 12 to 19. Decomposition product No. 20 was obtained in the same manner as above except that sodium carbonate was used instead of caustic soda. The conditions for partial decomposition with acid were 0.5 g of hydrochloric acid added, at a temperature of 80 ° C. for 60 minutes, and the conditions for partial decomposition with alkali were 0.5 g of caustic soda, a temperature of 80 ° C., and a period of 30 minutes. .21 was obtained.

表−3に分解条件と分解物の平均分子量を示す。 Table 3 shows the decomposition conditions and the average molecular weight of the decomposition products.

参考例22〜23(小麦グルテンのアルカリによる部分分解
と次いで実施した酸による部分分解による分解物の調
製) 参考例5及び6と同様の条件で小麦グルテンのアルカ
リによる部分分解を実施して得られた部分分解物の10%
水溶液を調製し、その各100gをフラスコ2個に入れこれ
らに塩化水素換算で0.5g及び1gに相当する塩酸を各々に
加え、100℃にて60分間加熱撹拌した。そののち苛性ソ
ーダにて中和し、純水で総量200gにして分解物No.22,23
を得た。
Reference Examples 22 to 23 (Preparation of Degraded Product by Partial Decomposition of Wheat Gluten by Alkaline and Subsequent Partial Decomposition by Acid) Obtained by performing partial decomposition of wheat gluten by alkali under the same conditions as in Reference Examples 5 and 6. 10% of the partial decomposition products
An aqueous solution was prepared, and 100 g of each aqueous solution was placed in two flasks, and 0.5 g and 1 g of hydrochloric acid corresponding to hydrogen chloride were added thereto, and the mixture was heated and stirred at 100 ° C. for 60 minutes. After that, neutralize with caustic soda, make the total amount 200 g with pure water, and decompose products No. 22, 23
I got

表−4に分解条件と分解物の平均分子量を示す。 Table 4 shows the decomposition conditions and the average molecular weight of the decomposition products.

参考例24(小麦グルテンの酵素による部分分解と次いで
実施したアルカリによる部分分解による分解物の調製) 参考例11と同様の条件で小麦グルテンの酵素による部
分分解物の10%水溶液を調製し、その100gに苛性ソーダ
を1g加えフラスコ中で60分間加熱撹拌した。その後塩酸
にて中和して純水で総量200gとし弁解物No.24を得た。
Reference Example 24 (Preparation of Degraded Product by Partial Decomposition of Wheat Gluten by Enzyme and Subsequent Partial Decomposition by Alkali) A 10% aqueous solution of a partially degraded product of wheat gluten by the enzyme was prepared under the same conditions as in Reference Example 11, and 1 g of caustic soda was added to 100 g, and the mixture was heated and stirred in a flask for 60 minutes. Thereafter, the mixture was neutralized with hydrochloric acid to make a total amount of 200 g with pure water, and excuse No. 24 was obtained.

平均分子量は29000であった。 The average molecular weight was 29,000.

参考例25(小麦グルテンの還元剤による部分分解と次い
で実施したアルカリによる部分分解による分解物の調
製) 亜硫酸ナトリウム4gを溶解した水溶液100gに参考例1
で用いた小麦グルテン20gを加え、30℃にて60分間撹拌
後、純水で総量200gにして小麦グルテンの還元剤による
部分分解物の10%水溶液を調製し、その100gに苛性ソー
ダ1gを加え、フラスコ中で100℃で60分間加熱撹拌し
た。その後、塩酸にて中和して純水で総量を200gとし分
解物No.25を得た。平均分子量は39500であった。
Reference Example 25 (Preparation of Decomposed Product of Wheat Gluten by Partial Decomposition with Reducing Agent and Subsequent Partial Decomposition by Alkali) Reference Example 1 in 100 g of an aqueous solution in which 4 g of sodium sulfite was dissolved
After adding 20 g of wheat gluten used in the above and stirring at 30 ° C. for 60 minutes, prepare a 10% aqueous solution of a partially decomposed product of wheat gluten with a reducing agent to make a total amount of 200 g with pure water, add 1 g of caustic soda to 100 g thereof, The mixture was heated and stirred at 100 ° C. for 60 minutes in a flask. Thereafter, the mixture was neutralized with hydrochloric acid to make the total amount 200 g with pure water, and a decomposed product No. 25 was obtained. The average molecular weight was 39,500.

参考例26(小麦グルテンのアルカリによる部分分解と次
いで実施した酵素による部分分解(参考例24と順序が
逆)による分解物の調製) 参考例5と同様の条件で小麦グルテンのアルカリによ
る部分分解物の10%水溶液を調製し、その100gに試薬塩
酸を加えpH1.5の水溶液を得、これをフラスコ内で、0.1
gのペプシンを加えて37℃で90分間反応させた。その
後、苛性ソーダで中和し純水で総量200gにし分解物No.2
6を得た。平均分子量は24500であった。
Reference Example 26 (Partial decomposition of wheat gluten by alkali and partial decomposition of wheat gluten by alkali under the same conditions as in Reference example 5) A 10% aqueous solution was prepared, and 100 g of the resulting solution was added with a hydrochloric acid reagent to obtain an aqueous solution having a pH of 1.5.
g of pepsin was added and reacted at 37 ° C. for 90 minutes. After that, neutralized with caustic soda and made up to 200g in total with pure water.
Got 6. The average molecular weight was 24,500.

参考例27(小麦グルテンのアルカリによる部分分解と次
いで実施した酸化剤による部分分解による分解物の調
製) 参考例5と同様の条件で小麦グルテンのアルカリによ
る部分分解物の10%水溶液を調製し、その100gにH2O2
算で0.5gに相当する過酸化水素水を加え、40℃で60分間
加熱撹拌した。その後、残存しているH2O2と当量のチオ
硫酸ナトリウム(過酸化水素のマスキング用)を加え、
純水で総量200gにして分解物No.27を得た。平均分子量
は37000であった。
Reference Example 27 (Preparation of Decomposed Product by Partial Decomposition of Wheat Gluten by Alkali and Subsequent Partial Decomposition by Oxidizing Agent) Under the same conditions as in Reference Example 5, a 10% aqueous solution of a partially decomposed product of wheat gluten by alkali was prepared. Hydrogen peroxide solution equivalent to 0.5 g in terms of H 2 O 2 was added to 100 g of the mixture, and the mixture was heated with stirring at 40 ° C. for 60 minutes. Then, the remaining H 2 O 2 and an equivalent amount of sodium thiosulfate (for masking hydrogen peroxide) were added,
Decomposed product No. 27 was obtained by adjusting the total amount to 200 g with pure water. The average molecular weight was 37,000.

参考例28(小麦グルテンの還元剤による部分分解と次い
で実施したアルカリによる部分分解による分解物の調
製) 亜硫酸ナトリウム4gを溶解した水溶液100gに参考例1
で用いた小麦グルテン20gを加えて、30℃にて60分間撹
拌後、純水で総量200gにして小麦グルテンの還元剤によ
る部分分解物の10%水溶液を調製し、その100gに苛性ソ
ーダ1gを加え、フラスコ中で100℃で60分間加熱撹拌し
た。その後、塩酸にて中和して純水で総量を200gとして
分解物No.21を得た。平均分子量は39500であった。
Reference Example 28 (Preparation of Decomposed Product by Partial Decomposition of Wheat Gluten by Reducing Agent and Subsequent Partial Decomposition by Alkali) Reference Example 1 in 100 g of an aqueous solution in which 4 g of sodium sulfite was dissolved
After adding 20 g of wheat gluten used in the above and stirring at 30 ° C. for 60 minutes, make a total amount of 200 g with pure water to prepare a 10% aqueous solution of a partially decomposed product of wheat gluten with a reducing agent, and add 1 g of caustic soda to 100 g thereof. The mixture was heated and stirred at 100 ° C. for 60 minutes in a flask. Thereafter, the mixture was neutralized with hydrochloric acid to make the total amount 200 g with pure water, thereby obtaining a decomposition product No. 21. The average molecular weight was 39,500.

以下、参考例1〜28で得た小麦グルテン部分分解物の
特性を表−5に示した。
Hereinafter, the properties of the partially degraded wheat gluten products obtained in Reference Examples 1 to 28 are shown in Table-5.

参考例1〜28で調製した小麦グルテンの部分分解物で
あるNo.1〜28を大川原化工機製スプレードライヤーL−
8型を使用し噴霧乾燥し、得られた粉末品の各種溶媒に
対する溶解性を調査したところ、すべての分解物は水に
溶解した[溶解度(25℃)10%以上]。しかし、メタノ
ール、エタノール、アセトン、エチルエーテルには不溶
であった。
No. 1-28 which is a partially decomposed product of wheat gluten prepared in Reference Examples 1-28 was spray-dried by Okawara Kakoki Co., Ltd.
Spray drying was performed using Form 8, and the solubility of the obtained powder in various solvents was investigated. All the decomposed products were dissolved in water [solubility (25 ° C.) 10% or more]. However, it was insoluble in methanol, ethanol, acetone and ethyl ether.

[実施例1] 参考例1で調製した小麦グルテンの部分分解物である
分解物No.1を上記と同様に噴霧乾燥して得られた粉末品
10gと活性グルテン*190gとをV型混合機を用いて5分
間混合し、この発明の粉末組成物を得た。 1.活性グルテン……グリコ栄養食品(株)製A−グル
P(小麦粉より取り出した生グルテンをアンモニア溶液
中に分散させ、熱変性をできるだけうけないようにして
噴霧乾燥して得られた粉末) [実施例2〜36] 参考例2〜28で調製した小麦グルテンの部分分解物で
ある分解物No.2〜28[以下グルテン部分分解物と記す]
を上記と同様に噴霧乾燥して得られた粉末品と実施例1
に記載の活性グルテンを実施例1と同様に混合して、こ
の発明の粉末組成物を得た。
[Example 1] A powdered product obtained by spray-drying degradation product No. 1 which is a partial degradation product of wheat gluten prepared in Reference Example 1 in the same manner as described above.
10 g and active gluten * 1 90 g were mixed for 5 minutes using a V-type mixer to obtain a powder composition of the present invention. * 1. Activated gluten A-glu P manufactured by Glyco Nutrition Foods Co., Ltd. (powder obtained by dispersing raw gluten extracted from wheat flour in an ammonia solution and spray-drying while minimizing heat denaturation as much as possible) [Examples 2-36] Degraded products No. 2 to 28 which are partially degraded products of wheat gluten prepared in Reference Examples 2 to 28 [hereinafter referred to as gluten partially degraded products]
Example 1 and a powder product obtained by spray-drying
Was mixed in the same manner as in Example 1 to obtain a powder composition of the present invention.

使用したグルテン部分分解物の種類と、活性グルテン
に対する配合割合を併せて表−6に示す。
Table 6 also shows the types of the partially degraded gluten used and the mixing ratio with respect to the active gluten.

[実施例33〜38](生グルテンとの混合) 生グルテン(三和澱粉工業株式会社製)と参考例で得
られた分解物No.9又はNo.12を表7に示す所定の割合で
ミキサー(日本精機製作所製マルチ・ブレンダー・ミル
5−3型)で混合してペースト状とした後に噴霧乾燥し
てこの発明の粉末組成物を得た。
[Examples 33 to 38] (Mixing with raw gluten) Raw gluten (manufactured by Sanwa Starch Kogyo Co., Ltd.) and degraded product No. 9 or No. 12 obtained in Reference Example were mixed at a predetermined ratio shown in Table 7. The resulting mixture was mixed with a mixer (Multi-Blender Mill 5-3, manufactured by Nippon Seiki Seisaku-sho, Ltd.) to form a paste, followed by spray drying to obtain a powder composition of the present invention.

[実施例39〜42](変性グルテンとの混合) 参考例で調製した分解物No.9又はNo.12(粉末品)と
変性グルテン(三和澱粉工業(株)製ニューアプロン
[アンモニア型])を実施例1と同様に表8に示す比率
で混合し、粉末製剤品を得た。
[Examples 39 to 42] (Mixing with modified gluten) Degraded product No. 9 or No. 12 (powder) prepared in Reference Example and modified gluten (New apron manufactured by Sanwa Starch Industry Co., Ltd. [ammonia type]) ) Was mixed at the ratio shown in Table 8 in the same manner as in Example 1 to obtain a powder preparation.

[試験例1]水分散性試験 <試験方法> 実施例1〜42で得られた各粉末製剤品(供試品)1gを
試験管に入れて水道水9gを添加し、すぐにポイントミキ
サーにて30秒間混合する(10%水分散液となる)。混合
終了後、液の外観を観察する。次いで1時間静置後に再
び30秒間混合し、再分散性を確認する。
[Test Example 1] Water dispersibility test <Test method> 1 g of each powder preparation (test sample) obtained in Examples 1 to 42 was placed in a test tube, and 9 g of tap water was added. And mix for 30 seconds (to be a 10% aqueous dispersion). After completion of the mixing, the appearance of the liquid is observed. Then, after leaving still for 1 hour, the mixture is mixed again for 30 seconds, and redispersibility is confirmed.

(ポイントミキサー……Yamato TOUCH MIXER MT−31
を使用) 試験結果を表−9に示す。
(Point mixer ... Yamato TOUCH MIXER MT-31
Table-9 shows the test results.

表中再分散性の欄の記号の意味を下記する。 The meanings of the symbols in the column of redispersibility in the table are as follows.

×……全く再分散しない。×: no re-dispersion.

△……ほぼ均一に再分散する。Δ: Redispersed almost uniformly.

○……均一に再分散する。…: Uniform redispersion.

[試験例2](水分散性試験) 実施例6で得られた粉末製剤品を用いて高濃度水分散
液を調製し、その液の外観及び再分散性を試験した。試
験方法等は試験例1と同様である。試験結果を表−10に
示す。
[Test Example 2] (Water dispersibility test) A high-concentration aqueous dispersion was prepared using the powder preparation obtained in Example 6, and the appearance and redispersibility of the liquid were tested. The test method and the like are the same as in Test Example 1. The test results are shown in Table-10.

実施例43〜45 参考例4で調製し小麦グルテンの部分分解物である分
解物No.4を実施例1と同様に混合して、この発明の粉末
製剤品を得た。但し、活性グルテンに対する配合割合5w
/w%のものを実施例43、同じく15、20w/w%のものをそ
れぞれ実施例44、45とした。
Examples 43 to 45 The degradation product No. 4 which is a partial degradation product of wheat gluten prepared in Reference Example 4 was mixed in the same manner as in Example 1 to obtain a powder preparation of the present invention. However, the mixing ratio to active gluten is 5w
/ w% was Example 43, and those of 15, 20 w / w% were Examples 44 and 45, respectively.

[試験例3](グルテン生地の弾性向上効果) 実施例4及び実施例43〜45で得られた各粉末製剤品
(供試品)と水道水を1:1で混合し、手で混捍して生地
状態にし、その弾性力をレオメーター[不動工業(株)
製]を用いて以下の様にして試験した。
[Test Example 3] (Effect of improving the elasticity of gluten dough) Each powder preparation (test sample) obtained in Example 4 and Examples 43 to 45 and tap water were mixed at a ratio of 1: 1 and the stick was mixed by hand. To a dough state, and the elastic force is measured with a rheometer [Fudo Industry Co., Ltd.
The following test was conducted using the following method.

レオメーターによる測定方法を第1図に示した。この
ように容器1(直径38mm、深さ16mm)に生地2(長径38
mm、短径25mmの偏平塊)を入れ(第1図(イ))圧縮弾
性アダプタ3(20mmφ)に対し、容器(1)を押し上
げ、生地(2)の厚さが6mmになったらレオメーターが
ストップするので(第1図(ロ))その時の強度(Kg)
を読み取る。
FIG. 1 shows a measurement method using a rheometer. In this way, the container 2 (diameter 38 mm, depth 16 mm) is filled with the dough 2 (long diameter 38).
(Fig. 1 (a)) Push the container (1) up against the compression elastic adapter 3 (20mmφ), and when the thickness of the dough (2) becomes 6mm, the rheometer Stops (Fig. 1 (b)) and the intensity at that time (Kg)
Read.

レオメーターによる圧縮強度の測定結果を表−11に示
す。
Table 11 shows the measurement results of the compressive strength by the rheometer.

なお、発明品を添加した生地は活性グルテン単独に比
べベタツキがほとんどなく取り扱い易いものとなり、活
性グルテン単独の場合に見られた生地の緑変も改善され
ていた。(*無添加……実施例1で用いた活性グルテン
のみ) [実施例46〜48] 参考例6で調製した小麦グルテンの部分分解物である
分解物No.6を実施例1と同様に噴霧乾燥して得られた粉
末10g、20g、40gの実施例1で用いた活性グルテンとを
合計100gなるようにV型混合機に添加し、5分間混合し
てこの発明の粉末製剤品を得た。分解物No.6の粉末が10
g含有している製剤品を実施例46、同じく20g、40g含有
している製剤品をそれぞれ実施例47、48とした。
The dough to which the invention product was added had little stickiness compared to the active gluten alone and was easy to handle, and the greening of the dough which was observed when the active gluten was used alone was also improved. (* No addition: only active gluten used in Example 1) [Examples 46 to 48] Spraying degradation product No. 6 which is a partial degradation product of wheat gluten prepared in Reference Example 6 in the same manner as in Example 1 10 g, 20 g, and 40 g of the powder obtained by drying and the active gluten used in Example 1 were added to a V-type mixer in a total amount of 100 g and mixed for 5 minutes to obtain a powder preparation of the present invention. . Decomposition product No.6 powder is 10
The formulation containing g was designated as Example 46, and the formulations containing 20 g and 40 g were designated as Examples 47 and 48, respectively.

[試験例4](ソーセージに対する品質向上効果試験) 小麦グルテンは、ソーセージの粘弾性向上、結着性増
加等の目的で使用されている。小麦グルテン単独、実施
例46〜48で得られたこの発明の各粉末製剤品及び分解物
No.6の噴霧乾燥品を用いてソーセージに対する品質向上
効果試験を行った。
[Test Example 4] (Test for improving quality of sausage) Wheat gluten is used for the purpose of improving the viscoelasticity of sausage and increasing the binding property. Wheat gluten alone, each powder preparation and degradation product of the present invention obtained in Examples 46 to 48
A quality improvement effect test on sausages was conducted using the spray dried product of No. 6.

試験方法 1.ソーセージの製造方法 一晩塩漬処理を施した豚ミンチ肉をミキサーでペー
スト状にする。
Test method 1. Sausage production method Pork minced meat that has been salted overnight is made into a paste using a mixer.

ビーカーにの肉と砕氷(対肉20%)を入れ、スリ
ーワンモータで混合しながら、更に各供試品、そして香
辛料(予め粉体混合済み)を添加する。
Put meat and crushed ice (20% of meat) in a beaker, add each test sample, and spices (premixed in powder) while mixing with a three-one motor.

サランラップでケーシングをつくり、これにの肉
を充填する。
Make a casing with Saran wrap and fill it with meat.

乾燥機中で乾燥処理(45℃,1時間)を行った後、70
〜75℃の湯で1時間煮る。
After drying (45 ° C, 1 hour) in the dryer,
Simmer for 1 hour in ~ 75 ° C hot water.

流水中で充分冷却し、製品を得る。 Cool sufficiently in running water to obtain the product.

2.ソーセージの処方 豚ミンチ肉 100g(赤身70%) 食 塩 2g(対肉2.0%) 硝 石 0.07g 香 辛 料 0.3g 供 試 品 5g(対肉5.0%) 3.評価試験 (1)圧縮重量(Kg) 厚さ5mmに切ったソーセージをジャッキの上に乗せ
る。
2.Sausage formula Pork minced meat 100g (lean 70%) Food salt 2g (2.0% meat) Salt 0.07g Spice 0.3g Sample 5g (5.0% meat) 3.Evaluation test (1) Compression Weight (Kg) Put sausage cut to thickness of 5mm on the jack.

ジャッキの上方に測定機を固定し、徐々にジャッキを
上げて行く。
Fix the measuring machine above the jack and gradually raise the jack.

ソーセージが濱れた時の重量(圧縮重量)を読み取
る。
Read the weight (compressed weight) of sausage when it sags.

*測定機:昌新商事株式会社製 CHATILLON (2)縮小率(%) 500mlメスシリンダーにソーセージを入れた状態で、
水を注ぎ込んで500mlに要する水量(ml)を読みとり、
加熱前後のソーセージの体積を測定する。(各々a,b(m
l)とする) 試験結果を表−12に示す。
* Measuring machine: CHATILLON manufactured by Shoshin Shoji Co., Ltd. (2) Reduction rate (%) With sausage put in a 500 ml measuring cylinder,
Pour in water, read the amount of water (ml) required for 500 ml,
Measure the volume of the sausage before and after heating. (Each a, b (m
l)) The test results are shown in Table-12.

このように、分解物No.6及び活性グルテン単独でも圧
縮重量(結着力の目安)は大きくなるが、実施例より得
られた製剤品の方がより大きい。まだ、縮小率(保水性
の目安)についても、実施例により得られた製剤品が良
好であった。
As described above, the decomposed product No. 6 and the active gluten alone increase the compression weight (a measure of the binding force), but the preparation obtained from the example is larger. As for the reduction ratio (a measure of water retention), the preparations obtained in Examples were still good.

特に実施例47で得られた製剤品は、物性、食感、作業
性の点において、最も良好な結果を示した。
In particular, the preparation obtained in Example 47 showed the best results in terms of physical properties, texture, and workability.

(ヘ)発明の効果 このようにして得られるこの発明の小麦グルテン組成
物はそれ自体、難水溶性、水難分散性である小麦グルテ
ンの性状に良好な親水性、水分散性の特性が付与された
ものであり、しかも、小麦グルテンの特性を損なわない
ものである。従って、従来の食品素材である小麦グルテ
ン自体と同様な用途に用いることができ、取り扱い上極
めて有利なものである。
(F) Effect of the Invention The thus obtained wheat gluten composition of the present invention itself has good hydrophilicity and water dispersibility properties to the properties of wheat gluten, which is poorly water-soluble and hardly dispersible in water. And do not impair the properties of wheat gluten. Therefore, it can be used for applications similar to wheat gluten itself, which is a conventional food material, and is extremely advantageous in handling.

そして、小麦グルテンは、それ自体一種の食品変性物
であり毒性がないこと、とくに強い弾性があることによ
って食品に配合してその弾性品質を補強・改良する有用
なものであるが、この発明の小麦グルテン組成物を用い
ればそれらの特性が阻害されないばかりか、却って向上
することができる。
Wheat gluten is itself a kind of food modified product and has no toxicity, and it is useful for reinforcing and improving its elastic quality by blending it into foods because it has particularly strong elasticity. The use of a wheat gluten composition not only does not impair their properties, but rather improves them.

かくして、この発明の小麦グルテン組成物は、食品工
業における、パン、ケーキ、油脂加工食品又は粉状イン
スタント食品に添加配合するにあたり容易に水性液中に
溶解分散し取扱いが便利であるとともに、小麦グルテン
の特性をそのまま、あるいはそれ以上に発揮して食品品
質を改善向上させることができる。ことにパンについて
は、弾力性の向上や生地生成の迅速化を図ることがで
き、さらにソーセージへ添加することにより、結着性、
保水性、混和性等を向上することも可能である。
Thus, the wheat gluten composition of the present invention is easy to dissolve and disperse in an aqueous liquid for easy handling when added to and blended with bread, cake, processed oil and fat foods or powdered instant foods in the food industry, and the wheat gluten composition is convenient. Can be used as it is or more to improve and improve food quality. In particular, for bread, it is possible to improve the elasticity and speed up the production of dough, and by adding it to sausage, the binding property,
It is also possible to improve water retention, miscibility and the like.

従って、この発明の小麦グルテン組成物の食品工業に
おける有用性は極めて大なるものである。
Therefore, the utility of the wheat gluten composition of the present invention in the food industry is extremely large.

【図面の簡単な説明】[Brief description of the drawings]

第1図(イ)及び(ロ)は、各々この発明の小麦グルテ
ン組成物についての弾性向上効果の評価方法を示す説明
図である。
FIGS. 1 (a) and 1 (b) are explanatory diagrams each showing a method for evaluating the elasticity improving effect of the wheat gluten composition of the present invention.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 片山 栄 大阪府大阪市東淀川区東淡路2丁目10番 15号 株式会社片山化学工業研究所内 (56)参考文献 特開 昭64−47353(JP,A) 特開 昭52−125662(JP,A) 特開 昭63−216437(JP,A) ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Sakae Katayama 2-10-15 Higashiawaji, Higashiyodogawa-ku, Osaka-shi, Osaka Inside Katayama Chemical Industry Laboratory Co., Ltd. (56) References JP-A-64-47353 (JP, A JP-A-52-125662 (JP, A) JP-A-63-216437 (JP, A)

Claims (5)

(57)【特許請求の範囲】(57) [Claims] 【請求項1】水難分散性の小麦グルテン1重量部に対
し、重量平均分子量670〜110000の小麦グルテン部分分
解物0.03〜0.2重量部を配合してなる小麦グルテン組成
物。
1. A wheat gluten composition comprising 1 part by weight of poorly dispersible wheat gluten and 0.03 to 0.2 part by weight of a partially degraded wheat gluten having a weight average molecular weight of 670 to 110,000.
【請求項2】水難分散性の小麦グルテンが、生グルテ
ン、活性グルテン又は変性グルテンである請求項1の小
麦グルテン組成物。
2. The wheat gluten composition according to claim 1, wherein the poorly water-dispersible wheat gluten is fresh gluten, active gluten or modified gluten.
【請求項3】小麦グルテン部分分解物の重量平均分子量
が約10000〜70000である請求項1の小麦グルテン組成
物。
3. The wheat gluten composition according to claim 1, wherein the weight-average molecular weight of the partially decomposed wheat gluten is about 10,000 to 70,000.
【請求項4】小麦グルテン部分分解物が、小麦グルテン
を、酸、アルカリ又は酵素による分解処理又はこれらの
二以上の組合せに付して得られたものである請求項1の
小麦グルテン組成物。
4. The wheat gluten composition according to claim 1, wherein the partially decomposed wheat gluten is obtained by subjecting wheat gluten to a decomposition treatment with an acid, an alkali or an enzyme or a combination of two or more thereof.
【請求項5】小麦グルテン部分分解物が、さらに還元剤
及び/又は酸化剤による分解処理を経て得られたもので
ある請求項4の小麦グルテン組成物。
5. The wheat gluten composition according to claim 4, wherein the partially decomposed wheat gluten is obtained through a decomposition treatment with a reducing agent and / or an oxidizing agent.
JP1226667A 1989-08-31 1989-08-31 Wheat gluten composition Expired - Lifetime JP2738450B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1226667A JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1226667A JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Publications (2)

Publication Number Publication Date
JPH0387149A JPH0387149A (en) 1991-04-11
JP2738450B2 true JP2738450B2 (en) 1998-04-08

Family

ID=16848773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1226667A Expired - Lifetime JP2738450B2 (en) 1989-08-31 1989-08-31 Wheat gluten composition

Country Status (1)

Country Link
JP (1) JP2738450B2 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6494823B2 (en) * 2017-09-07 2019-04-03 長田産業株式会社 Food modifier and method for producing the same
JP7370181B2 (en) * 2019-07-05 2023-10-27 グリコ栄養食品株式会社 Quality improver for flour foods
CN115413731B (en) * 2022-08-10 2024-05-28 西北农林科技大学 High-water-holding-capacity gluten protein-based plant meat and manufacturing method thereof

Also Published As

Publication number Publication date
JPH0387149A (en) 1991-04-11

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