JPH0379636A - Method for impregnating fiber with phenolic resin - Google Patents
Method for impregnating fiber with phenolic resinInfo
- Publication number
- JPH0379636A JPH0379636A JP21576089A JP21576089A JPH0379636A JP H0379636 A JPH0379636 A JP H0379636A JP 21576089 A JP21576089 A JP 21576089A JP 21576089 A JP21576089 A JP 21576089A JP H0379636 A JPH0379636 A JP H0379636A
- Authority
- JP
- Japan
- Prior art keywords
- phenolic resin
- solution
- fiber
- resin
- dispersion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005011 phenolic resin Substances 0.000 title claims abstract description 16
- 229920001568 phenolic resin Polymers 0.000 title claims abstract description 12
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 title claims abstract description 11
- 239000000835 fiber Substances 0.000 title claims abstract description 11
- 238000000034 method Methods 0.000 title claims description 6
- 239000006185 dispersion Substances 0.000 claims abstract description 9
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 9
- 238000005470 impregnation Methods 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 abstract description 5
- 239000002904 solvent Substances 0.000 abstract description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000007598 dipping method Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 239000012466 permeate Substances 0.000 abstract description 2
- 238000001035 drying Methods 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 239000011347 resin Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 14
- 239000000243 solution Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005452 bending Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Landscapes
- Reinforced Plastic Materials (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明はフェノール樹脂の繊維含浸方法に関する。[Detailed description of the invention] [Industrial application field] This invention relates to a method for impregnating fibers with phenolic resin.
従来、フェノール樹脂は、比較的高い難燃性を有し、従
ってこの性質を利用して建材などを製造することが広く
行なわれている。Conventionally, phenolic resins have relatively high flame retardancy, and therefore, this property has been widely used to manufacture building materials and the like.
ところで、フェノール樹脂による成形品はそのままでは
脆い性質を有し、特に発泡体にあってはその性質が顕著
となるため、ガラス繊維等補強繊維により補強すること
が一般に行われる。By the way, molded products made of phenolic resin have brittle properties as they are, and this property is particularly noticeable in foamed products, so it is generally reinforced with reinforcing fibers such as glass fibers.
しかしながら、原料となる液状フェノール樹脂は、一般
にＩＯＰ以上の高粘度であるため、ストランド化された
ガラス繊維内に均一に含浸させることは困難で、例え浸
漬時間を長くしても樹脂含浸状態に疎密ができやすく均
一な製品強度とし難いと言った問題があった。However, since the raw material liquid phenol resin generally has a high viscosity higher than IOP, it is difficult to uniformly impregnate stranded glass fibers, and even if the immersion time is long, the resin impregnation state will not be dense. There was a problem that it was difficult to obtain uniform product strength.
この発明は上記問題点に鑑み、ストランド化された補強
繊維であっても、繊維の東向に均一に、かつ、十分に樹
脂を含浸させ、もって強度に優れた成形品となし得るた
めの液状フェノール樹脂の繊維含浸方法を提供すること
を目的としてなされたものである。In view of the above-mentioned problems, this invention provides liquid phenol to impregnate even stranded reinforcing fibers with resin evenly and sufficiently in the east direction of the fibers, thereby making it possible to form molded products with excellent strength. The purpose of this invention is to provide a method for impregnating fibers with resin.
即ち、この発明のフェノール樹脂の繊維含浸方法は粉末
状フェノール樹脂を溶液中に均−分散させ、該分散液に
ストランド化された補強繊維を浸潰して溶液と共に前記
粉末状フェノール樹脂を浸透させ次いで該含浸補強繊維
を乾燥させて前記溶液のみを揮散除去することを特徴と
するものである。That is, the method of impregnating fibers with phenolic resin of the present invention involves uniformly dispersing a powdered phenolic resin in a solution, soaking reinforcing fibers formed into strands in the dispersion, and impregnating the powdered phenolic resin together with the solution. The method is characterized in that the impregnated reinforcing fibers are dried to volatilize and remove only the solution.
この発明において、補強梃維に均一な樹脂含浸を行なう
にあたり、浸漬する液として粉末樹脂の分散液を使用す
る。In this invention, when uniformly impregnating the reinforcing lever with resin, a powdered resin dispersion is used as the dipping liquid.
この溶液は粉末樹脂の特性に影響を与えず、かつ望まし
くは揮散し易い性質の溶液が使用される。This solution does not affect the properties of the powdered resin and is preferably a solution that easily evaporates.
この樹脂分散溶液にストランド化した補強繊維を浸漬す
れば、樹脂粉末は溶液と共にストランドに浸透して行き
、結果として粉末樹脂はストランド内に含浸された状態
となる。When the reinforcing fibers formed into strands are immersed in this resin dispersion solution, the resin powder permeates into the strands together with the solution, and as a result, the powdered resin becomes impregnated into the strands.
しかる後、上記溶液だけを揮散除去すれば、ストランド
の構成繊維間に樹脂が残留し、もって均一な含浸が可能
となるのである。After that, by volatilizing only the solution, the resin remains between the constituent fibers of the strand, thereby allowing uniform impregnation.
〔実施例〕 次に、この発明の詳細な説明する。〔Example〕 Next, the present invention will be explained in detail.
（スチレンモノマー）を溶液としてこれに平均粒径（２
００）メツシュの粉末状フェノール樹脂を添加し、攪拌
して分散液とした。(styrene monomer) as a solution and add the average particle size (2
00) Metsch's powdered phenolic resin was added and stirred to form a dispersion.
これにガラス繊維ロービングを浸漬し樹脂分散溶液を含
浸させた。A glass fiber roving was dipped into this to impregnate it with the resin dispersion solution.
次いで、このガラス繊維ロービングを乾燥させ、溶液を
揮散させて除去し、これを補強繊維として、以後常法に
より熱硬化フェノール樹脂と共に引抜成形機により成形
品を成形した。Next, this glass fiber roving was dried, the solution was volatilized and removed, and this was used as a reinforcing fiber to form a molded article using a pultrusion molding machine together with a thermosetting phenol resin in a conventional manner.
半径５關、長さ１ｍ＋の棒状成形品につき、曲げ強度を
測定したところ、表１の結果となった。When the bending strength of a rod-shaped molded product with a radius of 5 mm and a length of 1 m+ was measured, the results shown in Table 1 were obtained.
なお、表１中比較例は液状フェノール樹脂を希釈するこ
となく含浸させた繊維を用いて成形したものである。The comparative examples in Table 1 were molded using fibers impregnated with liquid phenol resin without dilution.
表１
〔効果〕
この発明は以上説明したように、含浸の困難な樹脂であ
っても、これを樹脂のＭｉ戊に影響のない溶液に分散さ
せるので樹脂の特性に影響を与えることなく含浸が均一
に行なえ、また溶剤を揮散除去すれば、この溶剤の影響
が無くなるので成形品のマトリックス強度も影響を受け
ることがなく、もって強度の均一な、かつ、強度に優れ
たＦＲＰを成形できるなどの効果を有する。Table 1 [Effects] As explained above, in this invention, even if it is a resin that is difficult to impregnate, it can be impregnated without affecting the properties of the resin because it is dispersed in a solution that does not affect the Mi concentration of the resin. It can be done uniformly, and if the solvent is volatilized and removed, the influence of this solvent is eliminated, so the matrix strength of the molded product is not affected, which makes it possible to mold FRP with uniform strength and excellent strength. have an effect.
Claims (1)
該分散液にストランド化された補強繊維を浸漬して溶液
と共に前記粉末状フェノール樹脂を浸透させ次いで該含
浸補強繊維を乾燥させて前記溶液のみを揮散除去するこ
とを特徴とするフェノール樹脂の繊維含浸方法。(1) Uniformly disperse powdered phenolic resin in a solution,
Fiber impregnation with phenolic resin, characterized in that stranded reinforcing fibers are immersed in the dispersion, the powdered phenol resin is permeated together with the solution, and then the impregnated reinforcing fibers are dried to volatilize and remove only the solution. Method.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21576089A JPH0379636A (en) | 1989-08-21 | 1989-08-21 | Method for impregnating fiber with phenolic resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21576089A JPH0379636A (en) | 1989-08-21 | 1989-08-21 | Method for impregnating fiber with phenolic resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0379636A true JPH0379636A (en) | 1991-04-04 |
Family
ID=16677774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21576089A Pending JPH0379636A (en) | 1989-08-21 | 1989-08-21 | Method for impregnating fiber with phenolic resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0379636A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2245899A (en) * | 1990-05-21 | 1992-01-15 | Shimizu Construction Co Ltd | Composite materials |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60171109A (en) * | 1984-02-15 | 1985-09-04 | Toray Ind Inc | Preparation of yarn prepreg |
| JPH01174535A (en) * | 1987-12-28 | 1989-07-11 | Shin Kobe Electric Mach Co Ltd | Production of laminate |
-
1989
- 1989-08-21 JP JP21576089A patent/JPH0379636A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60171109A (en) * | 1984-02-15 | 1985-09-04 | Toray Ind Inc | Preparation of yarn prepreg |
| JPH01174535A (en) * | 1987-12-28 | 1989-07-11 | Shin Kobe Electric Mach Co Ltd | Production of laminate |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2245899A (en) * | 1990-05-21 | 1992-01-15 | Shimizu Construction Co Ltd | Composite materials |
| GB2245899B (en) * | 1990-05-21 | 1993-12-08 | Shimizu Construction Co Ltd | Composite materials |
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