JPH0371175B2 - - Google Patents
Info
- Publication number
- JPH0371175B2 JPH0371175B2 JP59247433A JP24743384A JPH0371175B2 JP H0371175 B2 JPH0371175 B2 JP H0371175B2 JP 59247433 A JP59247433 A JP 59247433A JP 24743384 A JP24743384 A JP 24743384A JP H0371175 B2 JPH0371175 B2 JP H0371175B2
- Authority
- JP
- Japan
- Prior art keywords
- moo
- catalyst
- butene
- tio
- tetramethyltin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VXKWYPOMXBVZSJ-UHFFFAOYSA-N tetramethyltin Chemical compound C[Sn](C)(C)C VXKWYPOMXBVZSJ-UHFFFAOYSA-N 0.000 claims description 23
- 238000005649 metathesis reaction Methods 0.000 claims description 16
- 229910000476 molybdenum oxide Inorganic materials 0.000 claims description 7
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 claims description 7
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 description 46
- 229910010413 TiO 2 Inorganic materials 0.000 description 30
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 17
- 230000000694 effects Effects 0.000 description 17
- 239000000203 mixture Substances 0.000 description 11
- 150000001336 alkenes Chemical class 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- IAQRGUVFOMOMEM-BDYLZKADSA-N (e)-1,1,1,2,3,4,4,4-octadeuteriobut-2-ene Chemical compound [2H]C([2H])([2H])C(/[2H])=C(\[2H])C([2H])([2H])[2H] IAQRGUVFOMOMEM-BDYLZKADSA-N 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000007306 turnover Effects 0.000 description 3
- IAQRGUVFOMOMEM-VYMTUXDUSA-N 1,1,1,2-tetradeuteriobut-2-ene Chemical compound [2H]C(C(=CC)[2H])([2H])[2H] IAQRGUVFOMOMEM-VYMTUXDUSA-N 0.000 description 2
- YZCKVEUIGOORGS-OUBTZVSYSA-N Deuterium Chemical compound [2H] YZCKVEUIGOORGS-OUBTZVSYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000005865 alkene metathesis reaction Methods 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- -1 chlorine ions Chemical class 0.000 description 2
- IAQRGUVFOMOMEM-ARJAWSKDSA-N cis-but-2-ene Chemical group C\C=C/C IAQRGUVFOMOMEM-ARJAWSKDSA-N 0.000 description 2
- 229910052805 deuterium Inorganic materials 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 238000006317 isomerization reaction Methods 0.000 description 2
- 239000005078 molybdenum compound Substances 0.000 description 2
- 150000002752 molybdenum compounds Chemical class 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- IAQRGUVFOMOMEM-OXUPVTBTSA-N (E)-1,1,1,2-tetradeuteriobut-2-ene Chemical compound [2H]\C(=C/C)C([2H])([2H])[2H] IAQRGUVFOMOMEM-OXUPVTBTSA-N 0.000 description 1
- IAQRGUVFOMOMEM-PIODKIDGSA-N 1,1,1,2,3,4,4,4-octadeuteriobut-2-ene Chemical compound [2H]C(=C([2H])C([2H])([2H])[2H])C([2H])([2H])[2H] IAQRGUVFOMOMEM-PIODKIDGSA-N 0.000 description 1
- QQONPFPTGQHPMA-QNYGJALNSA-N 1,1,2,3,3,3-hexadeuterioprop-1-ene Chemical compound [2H]C([2H])=C([2H])C([2H])([2H])[2H] QQONPFPTGQHPMA-QNYGJALNSA-N 0.000 description 1
- QQONPFPTGQHPMA-DICFDUPASA-N 1,1-dideuterioprop-1-ene Chemical compound C(=CC)([2H])[2H] QQONPFPTGQHPMA-DICFDUPASA-N 0.000 description 1
- QQONPFPTGQHPMA-YODZYWACSA-N C(=C(C[2H])[2H])([2H])[2H] Chemical compound C(=C(C[2H])[2H])([2H])[2H] QQONPFPTGQHPMA-YODZYWACSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 1
- 229940010552 ammonium molybdate Drugs 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- 239000011609 ammonium molybdate Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KYYSIVCCYWZZLR-UHFFFAOYSA-N cobalt(2+);dioxido(dioxo)molybdenum Chemical compound [Co+2].[O-][Mo]([O-])(=O)=O KYYSIVCCYWZZLR-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 125000004431 deuterium atom Chemical group 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000010412 oxide-supported catalyst Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- IAQRGUVFOMOMEM-ONEGZZNKSA-N trans-but-2-ene Chemical compound C\C=C\C IAQRGUVFOMOMEM-ONEGZZNKSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59247433A JPS61125438A (ja) | 1984-11-22 | 1984-11-22 | メタセシス反応用触媒 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59247433A JPS61125438A (ja) | 1984-11-22 | 1984-11-22 | メタセシス反応用触媒 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61125438A JPS61125438A (ja) | 1986-06-13 |
| JPH0371175B2 true JPH0371175B2 (enrdf_load_stackoverflow) | 1991-11-12 |
Family
ID=17163365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59247433A Granted JPS61125438A (ja) | 1984-11-22 | 1984-11-22 | メタセシス反応用触媒 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61125438A (enrdf_load_stackoverflow) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5098876A (en) * | 1990-08-27 | 1992-03-24 | Shell Oil Company | Olefin disproportionation catalyst and process |
| US5114899A (en) * | 1990-08-27 | 1992-05-19 | Shell Oil Company | Olefin disproportionation catalyst and process |
-
1984
- 1984-11-22 JP JP59247433A patent/JPS61125438A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61125438A (ja) | 1986-06-13 |
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