JPH0362864A - Aqueous black pigment ink - Google Patents
Aqueous black pigment inkInfo
- Publication number
- JPH0362864A JPH0362864A JP1197816A JP19781689A JPH0362864A JP H0362864 A JPH0362864 A JP H0362864A JP 1197816 A JP1197816 A JP 1197816A JP 19781689 A JP19781689 A JP 19781689A JP H0362864 A JPH0362864 A JP H0362864A
- Authority
- JP
- Japan
- Prior art keywords
- pigment ink
- ink
- water
- growth inhibitor
- black pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000049 pigment Substances 0.000 title claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000003966 growth inhibitor Substances 0.000 claims abstract description 9
- 238000010521 absorption reaction Methods 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- 238000002835 absorbance Methods 0.000 claims abstract description 6
- 230000000813 microbial effect Effects 0.000 claims description 17
- 239000000538 analytical sample Substances 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 abstract description 5
- 244000005700 microbiome Species 0.000 abstract description 5
- 239000000976 ink Substances 0.000 description 19
- 239000003112 inhibitor Substances 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 239000000523 sample Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 1
- 101000581803 Homo sapiens Lithostathine-1-beta Proteins 0.000 description 1
- 102100027338 Lithostathine-1-beta Human genes 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- YAMHXTCMCPHKLN-UHFFFAOYSA-N imidazolidin-2-one Chemical compound O=C1NCCN1 YAMHXTCMCPHKLN-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、分散安定性がよく、微生物発生のない水性黒
色顔料インキに関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an aqueous black pigment ink that has good dispersion stability and does not generate microorganisms.
（従来の技術）
従来、一般に筆記具及び記録計用などの水性顔料インキ
には、微生物が発生することを防ぐため、微生物発生抑
制剤が添加されている。この方法として、添加量が多い
と、分散安定性が悪く、微生物発生抑制剤の析出や顔料
が凝集して、筆跡の力スレ、インキ切れが生じ、添加量
が少ないと、十分な効果が得られないため、経験的に添
加量を設定し、配合時、この添加量の範囲内の微生物発
生抑制剤を適宜添加していたものであった。(Prior Art) Conventionally, microbial generation inhibitors are generally added to aqueous pigment inks for writing instruments and recorders in order to prevent the generation of microorganisms. For this method, if the amount added is too large, the dispersion stability will be poor, and the microbial generation inhibitor will precipitate and the pigment will coagulate, resulting in scratches in the handwriting and ink breakage.If the amount added is too small, the effect will not be sufficient. Therefore, the amount to be added was determined empirically, and at the time of compounding, a microbial generation inhibitor within the range of this amount was added as appropriate.
（解決しようとする課題）
しかし、配合した後の微生物発生抑制剤の含有量の確認
ができず、そのため、実際に作用している微生物発生抑
制剤がどれくらいあるか、添加量が配合するインキに対
し適当であるのかわからないものである。特に、顔料と
してカーボンブランクを用いると、微生物発生抑制剤が
吸着され、実際に作用する微生物発生抑制剤は、配合時
添加した量より、少なくなっている。加えて、微生物発
生抑制剤の吸着量や吸着する量の経時的変化がカボンブ
ラックの種類により異なり、経時的に微生物が発生した
としても、微生物発生抑制剤がどれくらい減っているの
かわからないことより、配合した後、微生物発生抑制剤
の含有量を、特定することか要望される。(Problem to be solved) However, it is not possible to confirm the content of the microbial generation inhibitor after it has been blended, and as a result, it is difficult to determine how much of the microbial generation inhibitor is actually working in the ink. However, I am not sure if it is appropriate. In particular, when a carbon blank is used as a pigment, the microbial generation inhibitor is adsorbed, and the amount of the microbial generation inhibitor that actually acts is smaller than the amount added at the time of formulation. In addition, the amount of microbial growth inhibitor adsorbed and changes over time in the adsorbed amount vary depending on the type of carbon black, and even if microorganisms occur over time, it is unknown how much the microbial growth inhibitor has decreased. After blending, it is required to specify the content of the microbial growth inhibitor.
（課題を解決するための手段）
本発明は、少なくともカーボンブラックと、水と、微生
物発生抑制剤を含有してなる水性黒色顔料インキであっ
て、顔料を分離除去し、紫外分光光度計を用いて、分析
試料濃度０．０２５ｇ／Ｑとし、測定した吸収ピークが
２４５〜３５０ｎｍの範囲にあり、この吸収ピークでの
吸光度ＡＢＳ値が０．０５〜１．５である水性黒色顔料
インキを要旨とするものである。(Means for Solving the Problems) The present invention is an aqueous black pigment ink containing at least carbon black, water, and a microbial generation inhibitor, in which the pigment is separated and removed, and an ultraviolet spectrophotometer is used to remove the pigment. The analysis sample concentration is 0.025 g/Q, the measured absorption peak is in the range of 245 to 350 nm, and the absorbance ABS value at this absorption peak is 0.05 to 1.5. It is something to do.
以下、本発明による水性黒色顔料インキの微生物発生抑
制剤の測定方法を先ず詳細に説明する。Hereinafter, the method for measuring the microbial generation inhibitor in aqueous black pigment ink according to the present invention will be described in detail.
水性顔料インキに溶剤を加え、顔料を凝集させ、遠心分
離により、除去する。次いで、上澄液を分析試料濃度０
．０２５ｇ／Ｑに調整する。希釈液として、メタノール
などが用いられる。A solvent is added to the water-based pigment ink to aggregate the pigment, which is then removed by centrifugation. Next, the supernatant liquid was reduced to an analytical sample concentration of 0.
．． Adjust to 025g/Q. Methanol or the like is used as a diluent.
この試料について、紫外分光光度計を用いて、波長１９
０〜４００ ｎ ｍまでの吸収を測定し、２４５〜３５
０ｎｍまでの間にピークが認められた場合（ピークが複
数の場合には、最も吸光度の高い値を選択する）、吸光
度Ａ、ＢＳ値を測定する。Regarding this sample, using an ultraviolet spectrophotometer, a wavelength of 19
Measure absorption from 0 to 400 nm, from 245 to 35
If a peak is observed up to 0 nm (if there are multiple peaks, select the value with the highest absorbance), measure the absorbance A and BS values.
吸光度ＡＢＳ値は０．０５へ−１，５がよい。０゜０５
より小さいと、効果が小さく、↓、５より大きいと分散
安定性が悪い。The absorbance ABS value is preferably 0.05 to -1.5. 0゜05
When it is smaller, the effect is small, and when it is larger than ↓, the dispersion stability is poor.
次いで、水性黒色顔料インキの組成について説明する。Next, the composition of the aqueous black pigment ink will be explained.
本発明の水性黒色顔料インキの爪木組成はカーボンブラ
ックと、水と、微生物発生抑制剤とよりなる。The aqueous black pigment ink composition of the present invention consists of carbon black, water, and a microbial inhibitor.
カーボンブラックは、着色剤として使用するもので、具
体例としては、５ｐｅｃｉａ］ Ｂａａｃｋ ４、
同５、同６、同２５、ＣＯ］ Ｏｕ Ｂ ］ａｃｋ、
ＦＷ１８、同ＦＷ２００． Ｐ ｒ ｉ ｎ ｔ ｅ
ｘ ９５、同４５、同Ｌ６（デグサジャパン曲製）、
＃８５０．＃２４．ＯＯＢ、＃１０００．ＭＡ６００、
ＭＡｌｏｏ、＃４５、＃１０Ｂ、１４００Ｂ（三菱化成
■製）、ＭＯＮＡＲＣＨ１０００、同１３００、同８０
０．ＢＬＡＣＫ ＰＥＡＲＬＳ ７００．ＶＵＬＣ
ＡＮ ＸＣ−７２Ｒ，ＲＥＧＬ ３３０Ｒ１同８９
Ｒ，ＥＬＦＴＥＸ １．２．５ＴＥＲＬＩＮＧ Ｖ
（キャボッ１〜コーポレーション製）、ＲＥＶＥＮ
ｉ５０．ＰＥＥＲＬＥｓＳ １５５、 ＲＯＹＡＬ
５ＰＥＣＴＲＡ、ＮＥ○ ５ＰＥＣＴＲＡ
ＭＡＲＫ １、５ＵＰＥＲＢＡ（コロンビアンカー
ボンジャパン■製）などが挙げられ、使用量はインキ全
量に対して２〜３０重量％が好ましい。Carbon black is used as a coloring agent, and specific examples include 5pecia] Baack 4,
5, 6, 25, CO] Ou B ] ack,
FW18, same FW200. Printe
x 95, 45, L6 (manufactured by Degussa Japan),
#850. #24. OOB, #1000. MA600,
MAloo, #45, #10B, 1400B (manufactured by Mitsubishi Kasei ■), MONARCH1000, 1300, 80
0. BLACK PEARLS 700. VULC
AN XC-72R, REGL 330R1 89
R,ELFTEX 1.2.5TERLING V
(manufactured by Cabo 1 ~ Corporation), REVEN
i50. PEERLEsS 155, ROYAL
5PECTRA, NE○ 5PECTRA
Examples include MARK 1, 5 UPERBA (manufactured by Columbian Carbon Japan), and the amount used is preferably 2 to 30% by weight based on the total amount of ink.
水は主溶剤として使用するものである。Water is used as the main solvent.
微生物発生抑制剤としては、バイオホープ、バイオエー
ス、カビカットに２、カビカット４００（以上、ケイ・
アイ化成曲製）、ブロクセルＧＸＬ（ＩＣＩジャパン＠
製）、サンパック Ｐｌｏｏ、サンアイゾール ５００
．ＢＣＡ ＸＳ−１５０（三愛石油■製）、ヒビラン
グリコール（住友化学工業曲製）等が挙げられる。Microbial growth inhibitors include Biohope, Bioace, Kabicut 2, Kabicut 400 (all above, K.
manufactured by Ai Kaseikyoku), Broxel GXL (ICI Japan @
), Sunpac Ploo, Sun Isol 500
．． Examples include BCA
必要に応して分散剤を添加可能である。A dispersant can be added if necessary.
分散剤としては一般に用いられている樹脂や界面活性剤
等顔料の分散剤として使用されているものが使用可能で
あり、具体例としては、スチレン−アクリル酸の共重合
体の塩、 スチレン−マレイン酸の共重合体の塩等の樹
脂や、ポリオキシエチレンアルキルエステル、アルキル
アリルスルホン酸塩等の界面活性剤等が挙げられ、その
使用量はインキ全量に対して０〜２０重量％が好ましい
。As the dispersant, commonly used resins and surfactants that are used as dispersants for pigments can be used. Specific examples include salts of styrene-acrylic acid copolymers, styrene-malein, etc. Examples include resins such as salts of acid copolymers, surfactants such as polyoxyethylene alkyl esters and alkylaryl sulfonates, and the amount used is preferably 0 to 20% by weight based on the total amount of the ink.
尚、上記各成分以外に必要に応して、グリセリン、エチ
レングリコール、ジエチレングリコール、トリエチレン
グリコール、プロピレンブレコール、低分子量ポリエチ
レングリコール、尿素、エチレン尿素、チオ尿素又はこ
れらの誘導体、アミン類、アルコール類、エーテル類、
エステル類等の公知の溶剤、又は、補色剤の染料等の種
々添加剤を適宜選択して使用可能である。In addition to the above ingredients, if necessary, glycerin, ethylene glycol, diethylene glycol, triethylene glycol, propylene brecol, low molecular weight polyethylene glycol, urea, ethylene urea, thiourea or derivatives thereof, amines, alcohols. , ethers,
Known solvents such as esters or various additives such as complementary color dyes can be appropriately selected and used.
（実施例）
以下、実施例により本発明を更に詳細に説明する。表中
単に「部Ｊとあるのは「重量部」を示す。(Example) Hereinafter, the present invention will be explained in more detail with reference to Examples. In the table, "part J" simply indicates "part by weight."
以下に示す各成分を配合し、約１時間、室温にて撹拌し
て、水性顔料インキを得た。こうして得た試料を市販の
水性顔料インキ使用のボールペン（スーパーボールＢ
Ｔ（１６、ぺんてる■製）と同様の筆記具に２．０ｇ充
填し、５０℃、湿度３０％の条件下に１ケ月間放置した
後、インキを抽出−
し、メタノール及び塩酸を加え、顔料を凝集させた後、
工万回／分、１０分間遠心分離し、得られた上澄液につ
いて、インキ時の４０倍希釈の濃度に調整（溶液はメタ
ノール）後、紫外分光光度計（自記分光光度計ＵＶ−２
４０，島津製作所■製）により、測定した。The components shown below were blended and stirred at room temperature for about 1 hour to obtain a water-based pigment ink. The sample obtained in this way was applied to a commercially available ballpoint pen (Super Ball B) using water-based pigment ink.
Fill a writing instrument similar to T (16, manufactured by Pentel ■) with 2.0g, leave it for one month at 50℃ and 30% humidity, then extract the ink, add methanol and hydrochloric acid, and remove the pigment. After flocculating,
After centrifugation at 1,000 times/min for 10 minutes, the resulting supernatant liquid was adjusted to a concentration 40 times diluted with the ink (the solution was methanol), and then measured using an ultraviolet spectrophotometer (self-recording spectrophotometer UV-2).
40, manufactured by Shimadzu Corporation).
表エ アー 表２ （効 果） 実施例工〜４及び比較例１゜ ２について。Table E Ah Table 2 (Effective fruit) Example work~4 and comparative example 1゜ About 2.
筆記
−
表３
※１筆記テスト・・・・・・ 試料を市販の水性顔料イ
ンキ使用のボールペン（スーパーボ
ールＢＨ１６、ぺんてる■製）と
同様の筆記具に２．０ｇ充填し、
ＪＩＳ Ｐ４Ｏ１０、筆記用紙Ａ
に、荷重１００ｇ／ａｎ、筆記角度
６０°にて、８００ｍ螺旋筆記し、
カスレ有無、インキ切れを判定
※２経時試験・・・・・・ 試料を市販の水性顔料イ
ンキ使用のボールペン（スーパーボ
ールＢＨ１６、ぺんてる■製）と
同様の筆記具に２．０ｇ充填し、
５０℃、湿度３０％の条件下で、
ｌ夕月間放置し、微生物発生有無
を確認
以上のように、本発明の水性黒色顔料インキは、分散安
定性がよく、微生物発生がないものとなる。Writing - Table 3 *1 Writing test... 2.0g of the sample was filled into a writing instrument similar to a commercially available ballpoint pen (Super Ball BH16, manufactured by Pentel) using water-based pigment ink, and JIS P4O10, writing paper A was used. A spiral writing was performed for 800 m at a load of 100 g/an and a writing angle of 60 degrees, and the presence or absence of smearing and ink running out were judged. *2 Time-lapse test... The sample was used with a commercially available ballpoint pen (Super Ball BH16) using water-based pigment ink. , Pentel ■) was filled with 2.0 g of writing utensil, and left at 50°C and 30% humidity for one evening to check for the presence of microorganisms.As described above, the water-based black pigment ink of the present invention was has good dispersion stability and no microbial generation.
Claims (1)
剤を含有してなる水性黒色顔料インキであって、顔料を
分離除去した溶液における微生物発生抑制剤が、紫外分
光光度計を用いて、分析試料濃度０．０２５ｇ／ｌとし
、測定した吸収ピークが２４５〜３５０ｎｍの範囲にあ
り、この吸収ピークでの吸光度ＡＢＳ値が０．０５〜１
．５である水性黒色顔料インキ。An aqueous black pigment ink containing at least carbon black, water, and a microbial growth inhibitor, wherein the microbial growth inhibitor in a solution from which the pigment has been separated and removed is determined to have an analytical sample concentration of 0 using an ultraviolet spectrophotometer. .025 g/l, the measured absorption peak is in the range of 245 to 350 nm, and the absorbance ABS value at this absorption peak is 0.05 to 1.
．． 5, an aqueous black pigment ink.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1197816A JPH0362864A (en) | 1989-07-29 | 1989-07-29 | Aqueous black pigment ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1197816A JPH0362864A (en) | 1989-07-29 | 1989-07-29 | Aqueous black pigment ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0362864A true JPH0362864A (en) | 1991-03-18 |
Family
ID=16380820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1197816A Pending JPH0362864A (en) | 1989-07-29 | 1989-07-29 | Aqueous black pigment ink |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0362864A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06136944A (en) * | 1992-10-26 | 1994-05-17 | Tokai Kogyo Kk | Construction method of duct piping and actual pipe corresponding type sleeve |
| EP1394226A1 (en) * | 2002-07-31 | 2004-03-03 | Degussa AG | Aqueous, colloidal, storage and freezing stable gas black suspension |
-
1989
- 1989-07-29 JP JP1197816A patent/JPH0362864A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06136944A (en) * | 1992-10-26 | 1994-05-17 | Tokai Kogyo Kk | Construction method of duct piping and actual pipe corresponding type sleeve |
| EP1394226A1 (en) * | 2002-07-31 | 2004-03-03 | Degussa AG | Aqueous, colloidal, storage and freezing stable gas black suspension |
| JP2004149764A (en) * | 2002-07-31 | 2004-05-27 | Degussa Ag | Aqueous colloidal freeze-resistant and storage-stable gas black suspension, manufacturing method therefor, its use and ink containing the suspension |
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