JPH0362862A - Liquid composition - Google Patents
Liquid compositionInfo
- Publication number
- JPH0362862A JPH0362862A JP1198811A JP19881189A JPH0362862A JP H0362862 A JPH0362862 A JP H0362862A JP 1198811 A JP1198811 A JP 1198811A JP 19881189 A JP19881189 A JP 19881189A JP H0362862 A JPH0362862 A JP H0362862A
- Authority
- JP
- Japan
- Prior art keywords
- black
- parts
- colorant
- titanium oxide
- liquid composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000049 pigment Substances 0.000 claims abstract description 21
- 239000003086 colorant Substances 0.000 claims abstract description 18
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000002904 solvent Substances 0.000 claims abstract description 10
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000000976 ink Substances 0.000 abstract description 18
- 239000011248 coating agent Substances 0.000 abstract description 12
- 238000000576 coating method Methods 0.000 abstract description 12
- 239000003973 paint Substances 0.000 abstract description 11
- 238000000926 separation method Methods 0.000 abstract description 5
- 239000002989 correction material Substances 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 5
- 239000006229 carbon black Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 4
- -1 modified glycerin ester Chemical class 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- 230000005653 Brownian motion process Effects 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000005537 brownian motion Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OIMSQJSIOCWEJU-UHFFFAOYSA-N tributoxy phosphate Chemical compound CCCCOOP(=O)(OOCCCC)OOCCCC OIMSQJSIOCWEJU-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- BGJSXRVXTHVRSN-UHFFFAOYSA-N 1,3,5-trioxane Chemical compound C1OCOCO1 BGJSXRVXTHVRSN-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 229920002433 Vinyl chloride-vinyl acetate copolymer Polymers 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003429 antifungal agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、着色紙用修正液、パステルカラーインキ、パ
ステルカラーペイント等の着色剤に酸化チタンと有色顔
料とを各々主・副着色剤として併用する液状組成物に関
し、更に詳細には、塗膜が均一な色調となる液状組成物
に関する。Detailed Description of the Invention (Industrial Field of Application) The present invention is a coloring agent for coloring paper correction fluid, pastel color ink, pastel color paint, etc., in which titanium oxide and colored pigments are used as main and secondary colorants, respectively. The present invention relates to a liquid composition used in combination, and more particularly to a liquid composition that provides a uniform color tone to the coating film.
（従来の技術）
従来、酸化チタンと有色顔料とを併用した液状組成物と
しては、着色紙用修正液、パステルカラーインキ、パス
テルカラーペイント等が知られている。(Prior Art) Conventionally, correction fluids for colored paper, pastel color inks, pastel color paints, and the like are known as liquid compositions using a combination of titanium oxide and colored pigments.
（発明が解決しようとする課題）
上記した液状組成物は、塗膜を形成する際、溶剤の蒸発
に伴い液状組成物内の顔料微粒子のブラウン運動が激し
くなることにより酸化チタンと有色顔料とが分離を生じ
、塗膜に色の筋が生してしまうという現象が発生し易く
、灰色系液状組成物を得るために黒色顔料として一般的
に使用されるカーボンブラックを用いた場合特に顕著で
あった。(Problems to be Solved by the Invention) When the liquid composition described above forms a coating film, titanium oxide and colored pigments are separated by intense Brownian motion of the pigment particles in the liquid composition as the solvent evaporates. Separation is likely to occur, resulting in colored streaks on the coating film, which is particularly noticeable when carbon black, which is commonly used as a black pigment, is used to obtain a gray liquid composition. Ta.
そこで、本発明は、上記問題に鑑み、塗膜形成時に酸化
チタンと有色顔料との分離を防止し、均一な色調の塗膜
を形成する灰色系の液状組成物を得ることを目的とした
ものである。Therefore, in view of the above problems, the present invention aims to obtain a gray liquid composition that prevents separation of titanium oxide and colored pigments during coating film formation and forms a coating film with a uniform tone. It is.
（課題を解決するための手段）
本発明は、主着色剤として酸化チタン、副着色剤として
黒色顔料からなる着色剤と、樹脂と、溶剤とより少なく
ともなる液状組成物において、前記黒色顔料が鉄黒であ
る事を特徴とする液状組成物を要旨とするものである。(Means for Solving the Problems) The present invention provides a liquid composition comprising at least a coloring agent consisting of titanium oxide as a main coloring agent and a black pigment as an auxiliary coloring agent, a resin, and a solvent, wherein the black pigment is iron. The gist is a liquid composition characterized by its black color.
以下本発明の各成分について詳細に説明する。Each component of the present invention will be explained in detail below.
本発明の液状組成物に使用する着色剤は、主着色剤であ
る酸化チタンと、副着色剤であるフタロシアニンブルー
及び黄色顔料とよりなっている。The coloring agent used in the liquid composition of the present invention consists of titanium oxide as the main coloring agent, and phthalocyanine blue and yellow pigment as secondary coloring agents.
主顔料である酸化チタンとしては、溶剤中に良好に分散
し得るものであれば、ルチル型、アナターゼ型の何れも
使用可能であり特に限定は無いが、具体的には、タイト
ーン５Ｒ−１、同Ｒ−６５０、同Ｒ−３Ｌ、同Ｒ−３１
０、同Ａ−１１０、同Ａ−１５０、同Ｒ−５Ｎ （以上
、堺化学工業■製）タイベークＲ−５８０，同Ｒ−５５
０Ｘ、同Ｒ−９３０、同Ａ−１００、同Ａ−２２０（以
上、石原産業曲製）クロノスＫＲ−３１０、同ＫＲ−３
８０、同ＫＲ−４８０、同ＫＡ、−１０、同ＫＡ−２０
、同ＫＡ−３０（以上、チタン工業■製）等や、表面を
有機処理したものとして、ＢａｙｅｒｔｉｔａｎＲ−Ｆ
Ｄ−１、同Ｒ−ＦＤ−２、同Ｒ−ＦＢ１、同Ｒ−ＦＢ−
３、同Ｒ−ＫＢ−３、同Ｒ−ＣＫ−２０（以上、西ドイ
ツ、バイエル社製） ＴＩＰＡＱＵＥＲ−６３０、同Ｒ
−６１５、同Ｒ−８３０（以上、石原産業■製） Ｕｎ
ｉｔａｎ ＯＲ−３４２（米国、アメリカン・サイアナ
ミド社製） Ｔｉ−ｐｕｒｅＲ−９００、同Ｒ−９０↓
（以上、米国、デュポン社製）等が用いられ、その使用
量は、着色紙用修正液の場合、修正液全量に対して２０
〜５０重量％、パステルカラーインキの場合、インキ全
量に対して１０〜４０重量部、パステルカラーペイント
の場合、ペイント全量に対して２０〜５０重量％が好ま
しく用いられる。As the main pigment, titanium oxide, either rutile type or anatase type can be used as long as it can be well dispersed in a solvent, and there is no particular limitation. Same R-650, Same R-3L, Same R-31
0, A-110, A-150, R-5N (manufactured by Sakai Chemical Industry ■) Tybake R-580, R-55
0X, R-930, A-100, A-220 (all manufactured by Ishihara Sangyo Koku) Kronos KR-310, KR-3
80, KR-480, KA, -10, KA-20
, KA-30 (manufactured by Titan Kogyo ■), etc., and Bayertitan R-F with organic surface treatment.
D-1, R-FD-2, R-FB1, R-FB-
3. R-KB-3, R-CK-20 (manufactured by Bayer, West Germany) TIPAQUER-630, R
-615, R-830 (manufactured by Ishihara Sangyo ■) Un
itan OR-342 (manufactured by American Cyanamid, USA) Ti-pure R-900, Ti-pure R-90↓
(manufactured by DuPont, USA), etc. are used, and in the case of correction fluid for colored paper, the amount used is 20% of the total amount of correction fluid.
In the case of pastel color ink, it is preferably used in an amount of 10 to 40 parts by weight based on the total amount of the ink, and in the case of pastel color paint, it is preferably used in an amount of 20 to 50 parts by weight based on the total amount of the paint.
本発明の骨子である、副着色剤として用いる鉄黒は酸化
チタンと併用して灰色系に発色し、塗膜形成時、酸化チ
タンと分離を生ぜず、塗膜が均一な色調を保つための有
色顔料として選択したものである。その具体例としては
、パイフェロツクスブラック３０６、同３１６、同３〕
８、同３２０、同３１８Ｍ、同３０３Ｊ （以上、西独
、バイエル社製）、軟化ブラック（戸田工業曲製）等が
挙げられる。The essence of the present invention is that the iron black used as a secondary coloring agent develops a gray color when used in combination with titanium oxide, and does not separate from titanium oxide during coating film formation, so that the coating film maintains a uniform color tone. It was selected as a colored pigment. Specific examples include Pyferox Black 306, Pyferox Black 316, and Pyferox Black 3]
8, 320, 318M, and 303J (manufactured by Bayer AG, West Germany), Softening Black (manufactured by Toda Kogyoku Kyoto), and the like.
樹脂は、顔料分散剤として、更に、皮膜形成能付与、被
筆記面への付着性付与、インキの粘度調整として使用す
るものであって、使用する溶剤に可溶なものである事は
勿論であるが、着色紙用修正液
圧液の場合、アクリル樹脂、アルキッド樹脂、ビニル樹
脂、ポリエステル樹脂などを単独又は混合して用いるこ
とができ、その使用量は、修正液全量に対し５〜２０重
量％が好ましく、パステルカラーインキ又はパステルカ
ラーペイントの場合、ロジン、ロジンエステル、ロジン
変性グリセリンエステル、ロジン変性マレイン酸樹脂、
ロジン変性フェノール樹脂、ロジン変性フェノールグリ
セリンエステル等のロジン系樹脂、エチルセルロース、
ニトロセルロース等のセルロース樹脂、石油系樹脂、ケ
トン樹脂、ポリビニルブチラール、塩化ビニル−酢酸ビ
ニル共重合体などが挙げられ、これらの使用量はインキ
又はペイント全量に対して３０〜６０重量％が好ましい
。The resin is used as a pigment dispersant, as well as to impart film-forming ability, impart adhesion to the writing surface, and adjust the viscosity of the ink, and of course it must be soluble in the solvent used. However, in the case of correction hydraulic fluid for colored paper, acrylic resin, alkyd resin, vinyl resin, polyester resin, etc. can be used alone or in combination, and the amount used is 5 to 20% by weight based on the total amount of correction fluid. % is preferred, and in the case of pastel color ink or pastel color paint, rosin, rosin ester, rosin modified glycerin ester, rosin modified maleic acid resin,
Rosin-based resins such as rosin-modified phenol resin, rosin-modified phenol glycerin ester, ethyl cellulose,
Examples include cellulose resins such as nitrocellulose, petroleum resins, ketone resins, polyvinyl butyral, vinyl chloride-vinyl acetate copolymers, and the amount used is preferably 30 to 60% by weight based on the total amount of the ink or paint.
有機溶剤としては、着色紙用修正液の場合、トルエン、
キシレン、ｎ−へブタン、ｎ−オクタン、シクロヘキサ
ン、メチルシクロヘキサン等の炭化水素系、１，１．１
−トリクロルエタン、テトラクロルエチレン等のハロゲ
ン化炭化水素系、ｌ。In the case of correction fluid for colored paper, toluene,
Hydrocarbons such as xylene, n-hebutane, n-octane, cyclohexane, methylcyclohexane, 1,1.1
-Halogenated hydrocarbons such as trichloroethane and tetrachloroethylene, l.
４−ジオキサン、ｎ−ブチルエーテル、トリオキサン等
のエーテル系、メチルエチルケトン、メチル−ｎ−プロ
ピルケトン等のケトン系、ギ酸プロピル、酢酸エチル等
のエステル系溶剤が挙げられ、修正した個所の乾燥時間
を考慮すれば沸点が７０〜１５０℃のものを単独若しく
は混合して修正液全量に対して３０〜６０重量％使用す
ることが好ましく、パステルカラーインキ又はパステル
カラーペイントの場合、エタノール、プロパツール、イ
ソプロパツール、ブタノール等のアルコール系、メチル
エチルケトン、メチルイソブチルケトン等のケトン系、
酢酸エチル、酢酸ブチル等のエステル系、ベンゼン、ト
ルエン、キシレン等の芳香族炭化水素系、シクロヘキサ
ン、エチルシクロヘキサン等の脂環族炭化水素系、ヘキ
サン、ヘプタン等の脂肪族炭化水素系、エチレングリコ
ールモノエチルエーテル等のセロソルブ系、ジエチレン
グリコールモノブチルエーテル等のカービトール系溶剤
などが挙げられ、これらを単独若しくは複数混合してイ
ンキ又はペイント全量に対して４０〜７０重量％使用す
ることが好ましい。Examples include ether solvents such as 4-dioxane, n-butyl ether, and trioxane, ketone solvents such as methyl ethyl ketone and methyl-n-propyl ketone, and ester solvents such as propyl formate and ethyl acetate. It is preferable to use those having a boiling point of 70 to 150° C. singly or as a mixture in an amount of 30 to 60% by weight based on the total amount of correction fluid.In the case of pastel color ink or pastel color paint, ethanol, propatool, isopropatool , alcohols such as butanol, ketones such as methyl ethyl ketone, methyl isobutyl ketone,
Ester systems such as ethyl acetate and butyl acetate, aromatic hydrocarbon systems such as benzene, toluene, and xylene, alicyclic hydrocarbon systems such as cyclohexane and ethylcyclohexane, aliphatic hydrocarbon systems such as hexane and heptane, and ethylene glycol monomers. Examples include cellosolve solvents such as ethyl ether, carbitol solvents such as diethylene glycol monobutyl ether, and it is preferable to use these alone or in combination in an amount of 40 to 70% by weight based on the total amount of the ink or paint.
尚、上記成分以外に必要に応じて、防腐・防黴剤、消泡
剤等種々の添加剤を適宜使用できる。In addition to the above-mentioned components, various additives such as antiseptic/antifungal agents and antifoaming agents can be used as necessary.
又、本発明の液状組成物は、従来公知のロールミル、ホ
モミキサー、ボールミル及びサンドグラインダー等の分
散機にて混合分散することにより容易に得ることができ
る。Further, the liquid composition of the present invention can be easily obtained by mixing and dispersing with a conventionally known dispersing machine such as a roll mill, homomixer, ball mill, or sand grinder.
（作用）
本発明の液状組成物が、何故に塗膜形成時、酸化チタン
と、有色顔料である鉄黒との分離が無く、塗膜が均一な
色調を保つのかについては、以下のように推察される。(Function) The reason why the liquid composition of the present invention does not separate titanium oxide and iron black, which is a colored pigment, during coating film formation and maintains a uniform color tone of the coating film is as follows. It is inferred.
即ち、本液状組成物を塗布した直後、液状組成物表面か
らは、溶剤が蒸発していき、その為液状組成物内の顔料
微粒子のブラウン運動が激しくなり複数の種類の顔料微
粒′子の混合系では異なる顔料間の分離が発生し易い状
態となる。That is, immediately after applying this liquid composition, the solvent evaporates from the surface of the liquid composition, and as a result, the Brownian motion of the pigment particles in the liquid composition becomes intense, resulting in mixing of multiple types of pigment particles. In this system, separation between different pigments is likely to occur.
しかしながら、分散状態に有る酸化チタンと鉄黒とは分
散粒子としての挙動が類似しているので分離しにくく、
従って、均一な色調の塗膜となる。However, titanium oxide and iron black in a dispersed state behave similarly as dispersed particles, so it is difficult to separate them.
Therefore, the coating film has a uniform color tone.
（実施例）
以下、実施例により本発明をより詳細に説明するが、実
施例中単に「部」とあるのは「重量部」を示す。(Example) Hereinafter, the present invention will be explained in more detail with reference to Examples. In the Examples, the term "parts" simply indicates "parts by weight."
ヌ」１例」−（着色紙用修正液）
クロノスＫＲ−３８０６０，０部
（ルチル型酸化チタン、チタン工業曲製）パイフェロッ
クスブラック３１６ ３．０部（鉄黒、西独、バイエ
ル社製）
アクリロイドＢ−６６１２，０部
（アクリル樹脂、米国、ローム＆ハース社製）１．１．
１−１−リクロルエタン １２０．０部酪酸
３．０部ジオクチルアジペート
２．０部ミズカシルＰ−８０１１，０部
（＊細シリカ、水沢化学工業曲製）
エフトップＥＦ−１２２Ｂ ０．５部（フッ
素系活性剤、東北肥料■製）
ホモゲノールＬ−１８０，５部
（分散剤、花王石鹸ｆｅｌｌ製）
上記各成分をボールミルにて２４時間分散処理して修正
液を得た。1 example - (correction liquid for colored paper) Kronos KR-38060, 0 parts (rutile type titanium oxide, manufactured by Titanium Kogyo) Piferox Black 316 3.0 parts (iron black, West Germany, manufactured by Bayer AG) Acryloid B-6612, 0 parts (acrylic resin, manufactured by Rohm & Haas, USA) 1.1.
1-1-lichloroethane 120.0 parts butyric acid
3.0 parts dioctyl adipate
2.0 parts Mizukashiru P-8011, 0 parts (*fine silica, manufactured by Mizusawa Chemical Industry Co., Ltd.) FTOP EF-122B 0.5 parts (fluorinated activator, manufactured by Tohoku Fertilizer ■) Homogenol L-180, 5 parts ( Dispersant, manufactured by Kao Soap Fell) Each of the above components was dispersed in a ball mill for 24 hours to obtain a correction liquid.
失凰椴茎（着色紙用修正液）
クロノスＫＲ−３８０６０，０部
パイフェロックスブラック３１８Ｍ １０．０部（
鉄黒、西独、バイエル社製）
アクリロイドＢ−６７１２，０部
（アクリル樹脂、米国、ローム＆ハース社製）メチルシ
クロヘキサン １００．０部メタアニリンスル
ホン酸 ２．５部トリブトキシホスフェート
１．０部ミズカシルＰ−８０１１，０部
ホモゲノールＬ−１８０，５部
上記各成分を実施例１と同様の方法で分散処理して修正
液を得た。Piferox Black 318M 10.0 parts Cronos KR-38060, 0 parts (correction fluid for colored paper)
Tetsukuro, manufactured by Bayer, West Germany) Acryloid B-6712, 0 parts (acrylic resin, manufactured by Rohm & Haas, USA) Methylcyclohexane 100.0 parts Metaaniline sulfonic acid 2.5 parts Tributoxyphosphate 1.0 parts Mizukashiru P-8011, 0 parts Homogenol L-180, 5 parts The above components were dispersed in the same manner as in Example 1 to obtain a correction liquid.
失蓋鮭主（インキ）
クロノスＫＲ−３８０３５，０部
鉄化ブラック ０．４５部（戸田工
業＠製）
アクリロイドＢ−６６１０，０部
キシレン １２０．０部乳酸
２．５部トリブトキシホス
フェート ３．０部ミズカシルＰ−８０１１，
０部
ホモゲノールＬ−１８０，５部
上記各戒分を実施例１と同様の方法で分散処理してイン
キを得た。Lost Salmon Lord (ink) Cronos KR-38035, 0 parts Ferrous black 0.45 parts (manufactured by Toda Kogyo@) Acryloid B-6610, 0 parts Xylene 120.0 parts Lactic acid
2.5 parts tributoxy phosphate 3.0 parts Mizukashiru P-8011,
0 parts of homogenol L-180 and 5 parts of each of the above ingredients were dispersed in the same manner as in Example 1 to obtain an ink.
１夷１４例づ、（修正液）
実施例１において、パイフエロックスブラック３１６を
カーボンブラックＭＡ１００（カーボンブラック、三菱
化成■製）に替えた以外は実施例１と同様になして修正
液を得た。1.14 Examples (Correction liquid) A correction liquid was obtained in the same manner as in Example 1, except that in Example 1, Paifelox Black 316 was replaced with carbon black MA100 (carbon black, manufactured by Mitsubishi Kasei ■). .
里艶虹主（インキ）
実施例３において、鉱化ブラックをプリンテックス７５
（カーボンブラック、西独、デグツサ社製）に替えた以
外は実施例３と同様になしてインキを得た。In Example 3, mineralized black was printed with Printex 75.
An ink was obtained in the same manner as in Example 3 except that carbon black (manufactured by Degutsa, West Germany) was used.
（発明の効果）
以上、実施例１〜３、比較例１，２で得られた修正液及
びインキを、修正液は、弁付塗布具（ペン修正液、ぺん
てる■製）に充填し、インキは、繊維製ペン先と生イン
キ式インキ貯蔵室とを有する筆記具（ペイントマーカー
、ぺんてる■製）に充填しサンプルとし、試験を行なっ
た。結果を表１に示す。尚、実施例１，２、比較例１は
、上質紙に塗布を行ない、実施例３及び比較例２はプラ
スチックフィルムに筆記を行なった。(Effect of the invention) As described above, the correction liquid and ink obtained in Examples 1 to 3 and Comparative Examples 1 and 2 were filled into an applicator with a valve (pen correction liquid, manufactured by Pentel ■), and the ink was A writing instrument (Paint Marker, manufactured by Pentel ■) having a fiber nib and a raw ink storage chamber was filled with the sample and tested. The results are shown in Table 1. In Examples 1 and 2 and Comparative Example 1, high-quality paper was coated, and in Example 3 and Comparative Example 2, writing was done on plastic film.
表土
更に、実施例１〜３、比較例１．２で得られた修正液及
びインキを、キャップ付きのガラス製ビンに入れ、３力
月間室温に静置し、状態を観察した。結果を表２に示す
。Topsoil Furthermore, the correction fluids and inks obtained in Examples 1 to 3 and Comparative Example 1.2 were placed in a glass bottle with a cap, left standing at room temperature for 3 months, and the condition was observed. The results are shown in Table 2.
以上詳細に説明したように、本発明に係る液状組成物は
、修正液、インキ・ペイントとして使用して均一な塗膜
が得られる実用上優れた特性を有する灰色系の液状組成
物であり、組成物状態に於いても酸化チタンと黒色顔料
との分離が発生しないものである。As explained in detail above, the liquid composition according to the present invention is a grayish liquid composition that has excellent practical properties that allow it to be used as a correction fluid, ink or paint to obtain a uniform coating film, Even in the composition state, separation of titanium oxide and black pigment does not occur.
Claims (1)
らなる着色剤と、樹脂と、溶剤とより少なくともなる液
状組成物において、前記黒色顔料が鉄黒である事を特徴
とする液状組成物。A liquid composition comprising at least a colorant consisting of titanium oxide as a main colorant and a black pigment as a sub-colorant, a resin, and a solvent, characterized in that the black pigment is iron black.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1198811A JPH0362862A (en) | 1989-07-31 | 1989-07-31 | Liquid composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1198811A JPH0362862A (en) | 1989-07-31 | 1989-07-31 | Liquid composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0362862A true JPH0362862A (en) | 1991-03-18 |
Family
ID=16397306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1198811A Pending JPH0362862A (en) | 1989-07-31 | 1989-07-31 | Liquid composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0362862A (en) |
-
1989
- 1989-07-31 JP JP1198811A patent/JPH0362862A/en active Pending
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