JPH0362831B2 - - Google Patents

Info

Publication number
JPH0362831B2
JPH0362831B2 JP1219280A JP21928089A JPH0362831B2 JP H0362831 B2 JPH0362831 B2 JP H0362831B2 JP 1219280 A JP1219280 A JP 1219280A JP 21928089 A JP21928089 A JP 21928089A JP H0362831 B2 JPH0362831 B2 JP H0362831B2
Authority
JP
Japan
Prior art keywords
base material
ultraviolet
thread
cutting die
curable resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP1219280A
Other languages
Japanese (ja)
Other versions
JPH02133671A (en
Inventor
Motoyasu Nakanishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzuki Sogyo Co Ltd
Original Assignee
Suzuki Sogyo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzuki Sogyo Co Ltd filed Critical Suzuki Sogyo Co Ltd
Priority to JP21928089A priority Critical patent/JPH02133671A/en
Publication of JPH02133671A publication Critical patent/JPH02133671A/en
Publication of JPH0362831B2 publication Critical patent/JPH0362831B2/ja
Granted legal-status Critical Current

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  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Artificial Filaments (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Decoration Of Textiles (AREA)

Description

【発明の詳細な説明】 本発明は外面に微小な凹凸条を形成した変光型
糸材を中空筒状の抜型を用いて作る様にした製造
方法に関するものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a manufacturing method in which a variable-light thread material having minute irregularities formed on its outer surface is produced using a hollow cylindrical cutting die.

此種糸材はその凹凸外面の分光作用や、乱反射
作用によつて照射光線の性状を変化させ得るため
カーテンや敷物の原料糸として利用出来る。
This kind of thread material can be used as a raw material thread for curtains and rugs because it can change the properties of the irradiated light by the spectroscopy effect and diffuse reflection effect of its uneven outer surface.

この様な糸材の製造方法としては、例えば特開
昭56−123407号に開示されている様に、2種の溶
解性もしくは分解性の異なるポリマーを組合せた
複合紡糸技術を用いるものもあるが、製造工程の
簡便性からすれば、例えば特開昭56−79712号に
開示されている様に、中空筒状の抜型を用いる方
法が良好である。
As a method for manufacturing such thread materials, for example, as disclosed in JP-A-56-123407, there is a method using composite spinning technology that combines two types of polymers with different solubility or degradability. In view of the simplicity of the manufacturing process, a method using a hollow cylindrical cutting die as disclosed in, for example, JP-A-56-79712 is preferable.

しかしながら、従来の此種抜型を用いた製造方
法は、熱可塑性合成線状ポリマーを抜型、即ち紡
糸ノズルオリフイスを通す事により、その表面に
凹凸条を形成するものであるから、下記問題点が
あある。
However, in the conventional manufacturing method using a cutting die, the thermoplastic synthetic linear polymer is passed through a cutting die, that is, a spinning nozzle orifice, to form uneven stripes on its surface, which has the following problems. be.

第1に、この方法では熱可塑性合成線状ポリマ
ーを用いるため、溶剤を必要とし、従つて乾燥工
程で溶剤の揮発による環境汚染が避けられない。
First, since this method uses a thermoplastic synthetic linear polymer, it requires a solvent, and therefore environmental pollution due to volatilization of the solvent during the drying process is unavoidable.

第2に、熱可塑性合成線状ポリマーを用いた糸
製品は乾燥させる事が必要であり、この乾燥に時
間を要する。
Second, yarn products using thermoplastic synthetic linear polymers need to be dried, and this drying takes time.

第3に、この方法で得られた糸製品は、表面の
凹凸条がその侭残るから、この凹条内に塵埃、脂
垢が侵入付着して汚染される。
Thirdly, since the thread products obtained by this method still have the uneven lines on the surface, dust and grease can enter and adhere to the grooves and become contaminated.

第4に、上記糸製品に透明な外層を形成するに
は、溶剤で溶かした合成樹脂液を塗付する必要が
あるから、この合成樹脂液の溶剤により糸製品表
面が侵されて、その凹凸条が消失してしまう虞れ
がある。
Fourthly, in order to form a transparent outer layer on the yarn product, it is necessary to apply a synthetic resin liquid dissolved in a solvent, so the surface of the yarn product is attacked by the solvent of this synthetic resin liquid, causing unevenness. There is a risk that the column may disappear.

本発明においては、糸材は第1の紫外線硬化樹
脂を材料とした糸基材と、この糸基材の上に第2
の紫外線硬化樹脂を材料として形成された透光性
の外層とを有しており、上記糸基材は、多数の微
小条溝を内壁に刻設した中空筒状の抜型に第1の
紫外線硬化樹脂の液体を注入すると共に、この抜
型の排出側に紫外線を照射して、抜型より流出す
る紫外線硬化樹脂を糸状に硬化せしめる第1工程
で作られ、上記外層は、上記糸基材を、例えば第
2の紫外線硬化樹脂液の中を通過させる等して、
その表面に第2の紫外線硬化樹脂液を塗着すると
共に、塗着後にこれに紫外線を照射して硬化した
透光性外層を得る第2工程で作られる。
In the present invention, the thread material includes a first thread base material made of an ultraviolet curing resin, and a second thread base material on this thread base material.
The yarn base material has a first UV-curable outer layer formed from an ultraviolet-curing resin material, and a hollow cylindrical cutting die with a large number of microscopic grooves carved on the inner wall. The outer layer is made in the first step of injecting a resin liquid and irradiating the discharge side of the cutting die with ultraviolet rays to harden the ultraviolet curable resin flowing out from the cutting die into a thread shape. By passing it through the second ultraviolet curing resin liquid, etc.
It is produced in a second step in which a second ultraviolet curable resin liquid is applied to the surface and, after application, ultraviolet rays are irradiated thereto to obtain a cured translucent outer layer.

以下に本発明方法を添付図面につき説明する
と、本発明は第1図に示す如く、糸基材を成形す
るのに中空の抜型1を用いた事を特徴とするもの
で、この抜型1の内壁には第2図に示す如く軸方
向に向けて延びる条溝11が直条や螺旋状に刻設
されている。
The method of the present invention will be explained below with reference to the accompanying drawings. As shown in FIG. As shown in FIG. 2, grooves 11 extending in the axial direction are carved in a straight or spiral shape.

この抜型1にはその内部に液状の紫外線硬化樹
脂材料2を供給する事によつて外面に微小凹凸条
からなる凹凸面21を有する糸基材2′が得られ
る。
By supplying a liquid ultraviolet curing resin material 2 into the cutting die 1, a thread base material 2' having an uneven surface 21 consisting of minute unevenness stripes on the outer surface is obtained.

上記抜型1は例えばアルミニユーム板にレーザ
ー光線で条溝を刻設して型版12を作ると共に、
このアルミニユーム板の型版12を筒状基体の内
面に重着する等して製作すれば良い。
The above-mentioned cutting die 1 is made by carving grooves on an aluminum plate with a laser beam to make a template 12, and
This aluminum plate template 12 may be manufactured by laminating it on the inner surface of a cylindrical base.

上記抜型1の排出口近辺には、樹脂材料2を硬
化させるための紫外線の光源3が配置されてお
り、この光源3からの紫外線照射によつて糸基材
2′は硬化して連続的に排出される事になる。
An ultraviolet light source 3 for curing the resin material 2 is placed near the outlet of the cutting die 1, and the yarn base material 2' is cured and continuously cured by the ultraviolet irradiation from this light source 3. It will be ejected.

上記糸基材2′の断面形状は任意であるが、例
えば透明材料を用いて断面偏平な形状に成形すれ
ば、光反射面を広く出来ると共に分光効果も良く
出来ると云う利点がある。
Although the cross-sectional shape of the thread base material 2' is arbitrary, for example, if it is formed from a transparent material into a flat cross-sectional shape, there is an advantage that the light reflecting surface can be widened and the spectral effect can be improved.

この発明により得られた糸基材2′は、この様
に表面に微小な凹凸条が多数形成されているか
ら、これを使用して編組された生地は光の乱反射
や分光作用によつて特殊な美的効果が得られると
云う利益がある。
Since the yarn base material 2' obtained by this invention has a large number of minute unevenness lines formed on its surface, the fabric braided using this material has a special effect due to diffused reflection of light and spectral action. There is an advantage that a beautiful aesthetic effect can be obtained.

上記型版12の型面121は、フオトエツチン
グ法やレーザー光線による加工方法等により成形
すれば良く、例えばレーザー光線を使用する場合
には、アルミニユーム板に1mm幅600本程度の条
溝を刻設する事が出来るから、糸基材2′に極め
て微小な凹凸条を得る事が出来る。
The mold surface 121 of the mold plate 12 may be formed by a photo-etching method or a processing method using a laser beam. For example, when using a laser beam, approximately 600 grooves with a width of 1 mm are carved on an aluminum plate. Therefore, it is possible to obtain extremely fine unevenness on the yarn base material 2'.

上記型面121の条溝11は、第3図Aの如
く、断面鋸歯型に作るのが、分光効果を上から望
ましいが、場合によつては他の形状、例えば第3
図Bの如く断面段状凹凸型や、第3図Cの如く断
面波形に作つても良い。
It is desirable that the grooves 11 of the mold surface 121 have a sawtooth cross section as shown in FIG.
It may be made to have a stepped uneven cross-section as shown in Figure B, or a corrugated cross-section as shown in Figure 3C.

本発明方法により製造される糸基材2′は上述
の如くその外面に微小な凹凸条であつて、この凹
凸条により光の乱反射や分光を行なうものである
が、上記凹凸条は極めて微小であるため、塵埃や
脂垢で簡単に埋没消失してしまう事を避けられな
い。
As mentioned above, the yarn base material 2' produced by the method of the present invention has minute unevenness lines on its outer surface, and these unevenness lines cause diffuse reflection and spectroscopy of light, but the above unevenness lines are extremely minute. Because of this, it is unavoidable that it is easily buried and lost due to dust and grease.

このために本発明においては、上記糸基材2′
に第4図に示す如き透光性の外層4を重層形成す
ると共に、この外層4の光屈折率を糸基材2′の
光屈折率と異なる様に作つてあり、これによつて
分光、反射特性を変化させ得ると共に光干渉作用
も期待出来る様にしている。
For this reason, in the present invention, the yarn base material 2'
A light-transmitting outer layer 4 as shown in FIG. 4 is formed in a layered manner, and the light refractive index of this outer layer 4 is made to be different from that of the thread base material 2', thereby allowing spectroscopy, Not only can the reflection characteristics be changed, but also optical interference effects can be expected.

この様な外層4は、糸基材2′を例えば第5図
に示す如く第2の紫外線樹脂液5中に浸漬して通
過させると共に糸基材2′に付着した紫外線硬化
樹脂液を通過直後に紫外線光源6によつて紫外線
を照射して硬化させれば良い。
Such an outer layer 4 is formed by immersing the yarn base material 2' in a second ultraviolet resin liquid 5 as shown in FIG. It may be cured by irradiating ultraviolet rays from the ultraviolet light source 6.

以上の処において、糸基材2′と外層4とは、
紫外線硬化樹脂の主成分であるプレポリマーの変
える事により光屈折率を相異させる事が出来る。
In the above, the yarn base material 2' and the outer layer 4 are
The optical refractive index can be varied by changing the prepolymer that is the main component of the ultraviolet curable resin.

即ち紫外線硬化樹脂は、周知される様に光開始
剤の光重合性プレポリマー及び光重合性モノマー
から組成されるが、この内樹脂の骨格をなすもの
は光重合性プレポリマーだからである。
That is, as is well known, an ultraviolet curable resin is composed of a photoinitiator, a photopolymerizable prepolymer, and a photopolymerizable monomer, and among these, the photopolymerizable prepolymer forms the skeleton of the resin.

而して上記糸基材2′の第1紫外線硬化樹脂は、
例えば光開始剤としてベンゾインエチルエーテル
を、また光重合性モノマーとしてヘキサンジオー
ルジアクリレートを用い、主成分であるプレポリ
マーにはアクリルウレタン、例えばフリーマンケ
ミカル社の製造販売に係る商品名チエンポル
(CHEMPOL)19−4827を使用して作る事が出来
る。
The first ultraviolet curing resin of the thread base material 2' is
For example, benzoin ethyl ether is used as a photoinitiator, hexanediol diacrylate is used as a photopolymerizable monomer, and the main component of the prepolymer is acrylic urethane, such as CHEMPOL 19, a product manufactured and sold by Freeman Chemical Company. It can be made using -4827.

そして又上記第2紫外線硬化樹脂は、例えば光
開始剤としてベンゾフエノンを、又光重合性モノ
マーとして2−エチルヘキシルアクリレートと2
−ヒドロキシエチルアクリレートを用い、主成分
であるプレポリマーにはエポキシアクリレート、
例えばシエルケミカル社の製造販売する商品名
DRH303を使用して作る事が出来る。
The second ultraviolet curable resin may contain, for example, benzophenone as a photoinitiator and 2-ethylhexyl acrylate as a photopolymerizable monomer.
-Using hydroxyethyl acrylate, the main component prepolymer is epoxy acrylate,
For example, the name of a product manufactured and sold by Ciel Chemical Co., Ltd.
It can be made using DRH303.

尚上記第1、第2紫外線硬化樹脂は従来公知の
ものからプレポリマーの異なる2種の組成物を随
意選択して使用すれば良く、上記実施例に限定さ
れるものではない。
The first and second ultraviolet curable resins may be selected from two types of compositions with different prepolymers from conventionally known ones, and are not limited to the examples described above.

本発明方法はこの様なものであるから、下記効
果を得る事が出来る。
Since the method of the present invention is as described above, the following effects can be obtained.

第1に、紫外線硬化樹脂は溶剤を含まないから
硬化過程で環境を汚染する事がない。
First, since UV-curable resins do not contain solvents, they do not pollute the environment during the curing process.

第2に、紫外線硬化樹脂は硬化速度が極めて早
いから、糸基材2′の凹凸条を良好に形成出来る
と共に、製造速度が早く大量生産が出来る。
Secondly, since the ultraviolet curable resin has an extremely fast curing speed, it is possible to form the concave and convex stripes on the thread base material 2' well, and the manufacturing speed is fast, allowing for mass production.

第3に、糸基材2′の上に外層4が形成され、
これによつて凹凸条が被覆されるから凹凸条が塵
埃や脂垢等の外部汚染粒子によつて埋没される事
を防止出来、従つて変光効果を永続的に維持出来
る。
Third, an outer layer 4 is formed on the yarn base material 2';
Since the uneven stripes are thereby covered, it is possible to prevent the uneven stripes from being buried by external contaminant particles such as dust and grease, and thus the light-changing effect can be maintained permanently.

第4に、糸基材2′上に形成する外層4が、溶
剤を含まない紫外線硬化樹脂であるため、外層形
成によつて凹凸条が侵蝕される虞れがない。
Fourthly, since the outer layer 4 formed on the thread base material 2' is made of an ultraviolet curing resin that does not contain a solvent, there is no risk that the uneven stripes will be eroded by the formation of the outer layer.

第5に、糸基材2′と外層4との光屈折率が異
なるから、変光効果が格段に良好である。
Fifth, since the fiber base material 2' and the outer layer 4 have different optical refractive indexes, the light-changing effect is much better.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明方法の第1工程を説明する略解
図、第2図は同上方法に使用する抜型の底面図、
第3図は上記抜型の内面を形成する型版の1部の
拡大した断面図、第4図は本発明方法で得られる
糸基材の下方端面図、第5図は本発明方法の工程
を示す略解図である。 図中1は抜型、11は条溝、12は型版、2は
第1の紫外線硬化性樹脂液、2′は糸基材、21
は凹凸面、3は紫外線の光源、4は外層、5は第
2の紫外線硬化樹脂液、6は紫外線の光源を示
す。
FIG. 1 is a schematic diagram explaining the first step of the method of the present invention, FIG. 2 is a bottom view of the cutting die used in the above method,
FIG. 3 is an enlarged cross-sectional view of a part of the mold forming the inner surface of the cutting die, FIG. 4 is a lower end view of the thread base material obtained by the method of the present invention, and FIG. 5 shows the steps of the method of the present invention. FIG. In the figure, 1 is a cutting die, 11 is a groove, 12 is a mold plate, 2 is a first ultraviolet curable resin liquid, 2' is a thread base material, 21
3 is an uneven surface, 3 is an ultraviolet light source, 4 is an outer layer, 5 is a second ultraviolet curing resin liquid, and 6 is an ultraviolet light source.

Claims (1)

【特許請求の範囲】[Claims] 1 予め多数の微小条溝を内壁に刻設した中空筒
状の抜型に第1の紫外線硬化樹脂の液体を注入す
ると共に、この抜型の排出側には紫外線を照射し
て、これにより抜型より流出する紫外線硬化樹脂
を糸状に硬化させて表面に多数の凹凸条を有する
糸基材を得る第1工程と、この工程の後に、上記
糸基材の表面に第2の紫外線硬化樹脂液を重着し
て糸基材の表面にある微小凹凸条を埋没させると
共に、糸基材の表面に重着された第2の紫外線硬
化樹脂液に紫外線の照射して光透過性の外層を得
る第2工程とを有し、上記糸基材と上記外層との
光屈折率が相互に異なる様に上記第1の紫外線硬
化樹脂と第2の紫外線硬化樹脂との光屈折率を選
定した事を特徴とする変光型糸材の製造方法。
1 The first ultraviolet curing resin liquid is injected into a hollow cylindrical cutting die in which a large number of micro grooves have been carved on the inner wall in advance, and the discharge side of the cutting die is irradiated with ultraviolet rays, thereby preventing the liquid from flowing out of the cutting die. A first step of curing the ultraviolet curable resin into a thread form to obtain a thread base material having a large number of uneven stripes on the surface, and after this step, a second ultraviolet curable resin liquid is superimposed on the surface of the thread base material. A second step of burying the minute irregularities on the surface of the yarn base material and irradiating the second ultraviolet curing resin liquid heavily deposited on the surface of the yarn base material with ultraviolet rays to obtain a light-transparent outer layer. and the optical refractive indexes of the first ultraviolet curable resin and the second ultraviolet curable resin are selected so that the optical refractive indexes of the yarn base material and the outer layer are different from each other. A method for producing a variable thread material.
JP21928089A 1989-08-25 1989-08-25 Production of light-variable yarn material Granted JPH02133671A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21928089A JPH02133671A (en) 1989-08-25 1989-08-25 Production of light-variable yarn material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21928089A JPH02133671A (en) 1989-08-25 1989-08-25 Production of light-variable yarn material

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP1585482A Division JPH0247327B2 (en) 1982-02-03 1982-02-03 HENHIKARI FUIRUMUNOSEIZOHOHO

Publications (2)

Publication Number Publication Date
JPH02133671A JPH02133671A (en) 1990-05-22
JPH0362831B2 true JPH0362831B2 (en) 1991-09-27

Family

ID=16733042

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21928089A Granted JPH02133671A (en) 1989-08-25 1989-08-25 Production of light-variable yarn material

Country Status (1)

Country Link
JP (1) JPH02133671A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5679712A (en) * 1979-11-30 1981-06-30 Toyobo Co Ltd Filament yarn having multilobed cross section
JPS56123407A (en) * 1980-03-04 1981-09-28 Toray Ind Inc Fiber having improved color tone

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5679712A (en) * 1979-11-30 1981-06-30 Toyobo Co Ltd Filament yarn having multilobed cross section
JPS56123407A (en) * 1980-03-04 1981-09-28 Toray Ind Inc Fiber having improved color tone

Also Published As

Publication number Publication date
JPH02133671A (en) 1990-05-22

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