JPH0357973B2 - - Google Patents
Info
- Publication number
- JPH0357973B2 JPH0357973B2 JP60085377A JP8537785A JPH0357973B2 JP H0357973 B2 JPH0357973 B2 JP H0357973B2 JP 60085377 A JP60085377 A JP 60085377A JP 8537785 A JP8537785 A JP 8537785A JP H0357973 B2 JPH0357973 B2 JP H0357973B2
- Authority
- JP
- Japan
- Prior art keywords
- hollow
- polyester
- crimp
- nozzle
- crimps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000728 polyester Polymers 0.000 claims description 27
- 239000012530 fluid Substances 0.000 claims description 26
- 239000002131 composite material Substances 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 16
- 239000000835 fiber Substances 0.000 claims description 15
- 238000002074 melt spinning Methods 0.000 claims description 11
- 238000009987 spinning Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 238000002788 crimping Methods 0.000 claims description 7
- 238000011161 development Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 22
- 238000011084 recovery Methods 0.000 description 19
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 13
- -1 alkylene glycol Chemical compound 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 9
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 230000037303 wrinkles Effects 0.000 description 6
- 239000004744 fabric Substances 0.000 description 5
- 229910010413 TiO 2 Inorganic materials 0.000 description 4
- 239000012510 hollow fiber Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000006224 matting agent Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 241000283153 Cetacea Species 0.000 description 2
- 229920008651 Crystalline Polyethylene terephthalate Polymers 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ZRPKEUVFESZUKX-UHFFFAOYSA-N 2-(2-hydroxyethoxy)benzoic acid Chemical compound OCCOC1=CC=CC=C1C(O)=O ZRPKEUVFESZUKX-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 235000013351 cheese Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- KYTZHLUVELPASH-UHFFFAOYSA-N naphthalene-1,2-dicarboxylic acid Chemical compound C1=CC=CC2=C(C(O)=O)C(C(=O)O)=CC=C21 KYTZHLUVELPASH-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- IBBQVGDGTMTZRA-UHFFFAOYSA-N sodium;2-sulfobenzene-1,3-dicarboxylic acid Chemical compound [Na].OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O IBBQVGDGTMTZRA-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、中空であつて、かつ捲縮率が高く、
嵩高性、保温性に優れ、高弾性回復率を有するポ
リエステル系中空捲縮加工糸及びその製造方法に
関する。Detailed Description of the Invention (Industrial Application Field) The present invention is hollow and has a high crimp rate,
The present invention relates to a polyester hollow crimped yarn having excellent bulkiness, heat retention, and high elastic recovery rate, and a method for producing the same.
（従来の技術）
従来、中空繊維に仮撚捲縮加工や押込捲縮加工
を施すことが知られている。また、サイド・バ
イ・サイド型複合中空繊維を用い、複合成分の熱
収縮差を利用して捲縮を発現させ、中空捲縮加工
糸とすることも知られている。(Prior Art) It has been known to perform false twist crimp processing and push crimp processing on hollow fibers. It is also known to use side-by-side type composite hollow fibers to develop crimping by utilizing the difference in heat shrinkage of the composite components to obtain a hollow crimped yarn.
（発明が解決しようとする問題点）
ところが、中空繊維に仮撚捲縮加工や押込捲縮
加工を施すと、捲縮加工時の応力によつて中空部
がつぶれてしまい、嵩高性、保温性が劣つたもの
になつてしまう。一方、サイド・バイ・サイド型
複合中空繊維では、高度の捲縮を発現させること
が極めて困難である。従つて、中空であり、かつ
捲縮率が高い捲縮加工糸は、これまで得られてい
なかつた。(Problems to be Solved by the Invention) However, when hollow fibers are subjected to false twist crimping or push crimping, the stress during the crimping process collapses the hollow portions, resulting in poor bulkiness and heat retention. becomes inferior. On the other hand, it is extremely difficult to develop a high degree of crimp in side-by-side type composite hollow fibers. Therefore, a crimped yarn that is hollow and has a high crimp rate has not been obtained so far.
本発明は、このような従来技術の問題点を解決
し、中空で、かつ捲縮率が高く、嵩高性、保温性
に優れ、弾性回復率の高い捲縮加工糸を提供せん
とするものである。 The present invention solves the problems of the prior art and provides a crimped yarn that is hollow, has a high crimp rate, has excellent bulk and heat retention, and has a high elastic recovery rate. be.
（問題点を解決するための手段）
本発明は、中空率が３〜20％、捲縮率が12％以
上、捲縮数が10〜45ケ／cmであることを特徴とす
るポリエステル系中空捲縮加工糸であり、かかる
ポリエステル系中空捲縮加工糸は、サイド・バ
イ・サイド型複合中空ポリエステル系繊維を溶融
紡糸し、延伸熱処理後、加熱流体押込ノズルによ
り捲縮を発現させることにより得ることができ
る。(Means for Solving the Problems) The present invention provides a polyester hollow material having a hollow ratio of 3 to 20%, a crimp ratio of 12% or more, and a crimp number of 10 to 45 strands/cm. It is a crimped yarn, and the polyester hollow crimped yarn is obtained by melt-spinning side-by-side composite hollow polyester fibers, drawing heat treatment, and then developing crimp with a heated fluid pushing nozzle. be able to.
本発明でいうポリエステルは、テレフタル酸を
主たる酸成分とし、少なくとも１種のグリコー
ル、好ましくはエチレングリコール、トリメチレ
ングリコール、テトラメチレングリコールから選
ばれた少なくとも１種のアルキレングリコールを
主たるグリコール成分とするポリエステルを主た
る対象とする。 The polyester in the present invention is a polyester having terephthalic acid as the main acid component and at least one type of glycol, preferably at least one alkylene glycol selected from ethylene glycol, trimethylene glycol, and tetramethylene glycol as the main glycol component. The main target is
また、テレフタル酸成分の一部を他の二官能性
カルボン酸成分で置換えたポリエステルであつて
もよく、グリコール成分の一部を主成分以外の上
記グリコール、若しくは他のジオール成分で置換
えたポリエステルであつてもよい。 It may also be a polyester in which part of the terephthalic acid component is replaced with another difunctional carboxylic acid component, or a polyester in which part of the glycol component is replaced with the above glycol other than the main component or another diol component. It's okay to be hot.
ここで使用されるテレフタル酸以外の二官能性
カルボン酸としては、例えばイソフタル酸、ナフ
タリンジカルボン酸、ジフエニルジカルボン酸、
ジフエノキシエタンジカルボン酸、β−ヒドロキ
シエトキシ安息香酸、ｐ−オキシ安息香酸、５−
ナトリウムスルホイソフタル酸、アジピン酸、セ
バシン酸、１，４−シクロヘキサンジカルボン酸
の如き芳香族、脂肪族、脂環族の二官能性カルボ
ン酸をあげることができる。また、上記グリコー
ル以外のジオール化合物としては例えばシクロヘ
キサン−１、４−ジメタノール、ネオペンチルグ
リコール、ビスフエノールＡ、ビスフエノールＳ
の如き脂肪族、脂環族、芳香族のジオール化合物
およびポリオキシアルキレングリコール等をあげ
ることができる。 Examples of difunctional carboxylic acids other than terephthalic acid used here include isophthalic acid, naphthalene dicarboxylic acid, diphenyl dicarboxylic acid,
Diphenoxyethanedicarboxylic acid, β-hydroxyethoxybenzoic acid, p-oxybenzoic acid, 5-
Examples include aromatic, aliphatic, and alicyclic difunctional carboxylic acids such as sodium sulfoisophthalic acid, adipic acid, sebacic acid, and 1,4-cyclohexanedicarboxylic acid. In addition, examples of diol compounds other than the above-mentioned glycols include cyclohexane-1,4-dimethanol, neopentyl glycol, bisphenol A, and bisphenol S.
Examples include aliphatic, alicyclic, and aromatic diol compounds such as, and polyoxyalkylene glycols.
かかるポリエステルは任意の方法によつて合成
したものでよい。例えばポリエチレンテレフタレ
ートについて説明すれば、通常、テレフタル酸と
エチレングリコールとを直接エステル化反応させ
るか、テレフタル酸ジメチルの如きテレフタル酸
の低級アルキルエステルとエチレングリコールと
をエステル交換反応させるか又はテレフタル酸と
エチレンオキサイドとを反応させるかしてテレフ
タル酸のグリコールエステル及び／又はその低重
合体を生成させる第１段階の反応と、第１段階の
生成物を減圧下加熱して所望の重合度になるまで
重縮合反応させる第２段階の反応によつて製造さ
れる。 Such polyesters may be synthesized by any method. For example, in the case of polyethylene terephthalate, usually terephthalic acid and ethylene glycol are directly esterified, a lower alkyl ester of terephthalic acid such as dimethyl terephthalate is transesterified with ethylene glycol, or terephthalic acid and ethylene glycol are transesterified. The first stage reaction involves reacting with terephthalic acid glycol ester and/or its low polymer, and the first stage product is heated under reduced pressure and polymerized until the desired degree of polymerization is reached. It is produced by a second step of condensation reaction.
本発明のポリエステル系中空捲縮加工糸は、中
空率が３〜20％であることが必要である。中空率
３％未満では、嵩高性、保温性、弾性回復率が低
下し、20％を超えると弾性回復率が低下するので
不適当である。また、捲縮率は12％以上、捲縮数
は10〜45ケ／cmであることが必要で、この範囲外
では、風合、嵩高性が悪くなり、ペーパーライク
となつてしまう。 The polyester hollow crimped yarn of the present invention needs to have a hollowness ratio of 3 to 20%. If the hollowness ratio is less than 3%, the bulkiness, heat retention, and elastic recovery rate will decrease, and if it exceeds 20%, the elastic recovery rate will decrease, which is inappropriate. In addition, the crimp rate must be 12% or more, and the number of crimp must be 10 to 45 crimps/cm. Outside this range, the texture and bulkiness will be poor, resulting in a paper-like appearance.
本発明のポリエステル系中空捲縮加工糸として
は、サイド・バイ・サイド型複合繊維を用いるの
が好ましい。この場合、サイド・バイ・サイド成
分の高収縮成分には、固有粘度0.64以上の高
〔η〕ポリエステルを、低収縮成分には固有粘
度0.45以下の低〔η〕ポリエステルを用いるの
が望ましい。また、高収縮成分にイソフタル酸、
ジエチレングリコール等を共重合させた低結晶性
ポリエチレンテレフタレートを、低収縮成分にポ
リエチレンテレフタレートあるいはこれにアルキ
ルスルホン酸ナトリウムやポリエチレン等の配向
結晶促進剤を添加した高結晶性ポリエチレンテレ
フタレートを用いるのも好ましい実施態様であ
る。通常、紡糸速度が低速である場合（700〜
1300ｍ／分）は、前者の組み合わせが適してお
り、紡糸速度が高速である場合（2500ｍ／分以
上）は、後者の組み合わせが好適である。 As the polyester hollow crimped yarn of the present invention, it is preferable to use a side-by-side type composite fiber. In this case, it is desirable to use a high [η] polyester with an intrinsic viscosity of 0.64 or more as the high shrinkage component of the side-by-side components, and a low [η] polyester with an intrinsic viscosity of 0.45 or less as the low shrinkage component. In addition, isophthalic acid is a high shrinkage component,
It is also a preferred embodiment to use low-crystalline polyethylene terephthalate copolymerized with diethylene glycol or the like, and use polyethylene terephthalate as the low-shrinkage component, or high-crystalline polyethylene terephthalate to which an oriented crystal accelerator such as sodium alkyl sulfonate or polyethylene is added. It is. Usually when the spinning speed is low (700~
1300 m/min), the former combination is suitable, and when the spinning speed is high (2500 m/min or more), the latter combination is suitable.
サイド・バイ・サイド型複合繊維の複合形態は
任意であり、特に限定されない。第１図〜第３図
は本発明のポリエステル系中空捲縮加工糸のう
ち、サイド・バイ・サイド型複合繊維の例を示す
横断面図であり、１は低収縮成分、２は高収縮成
分を表す。 The composite form of the side-by-side type composite fiber is arbitrary and not particularly limited. Figures 1 to 3 are cross-sectional views showing examples of side-by-side type composite fibers among the polyester hollow crimped yarns of the present invention, where 1 is a low shrinkage component and 2 is a high shrinkage component. represents.
また、本発明のポリエステル系中空捲縮加工糸
は、実質的に撚を有していないものであることが
望ましい。 Further, it is desirable that the polyester hollow crimped yarn of the present invention has substantially no twist.
かかる本発明のポリエステル系中空捲縮加工糸
は、サイド・バイ・サイド型複合中空ポリエステ
ル系繊維を溶融紡糸に依つて製造し、それを延伸
熱処理した後、加熱流体押込ノズルにより捲縮を
発現させることにより得られる。 The hollow crimped polyester yarn of the present invention is produced by melt spinning a side-by-side composite hollow polyester fiber, subjecting it to drawing heat treatment, and then crimping it using a heated fluid pushing nozzle. It can be obtained by
溶融紡糸で使用する中空複合紡糸装置には、従
来から使用されている装置を使えばよい。 The hollow composite spinning device used in melt spinning may be any conventionally used device.
例えば、第１図の複合繊維を紡糸するには、第
４図に示した紡糸口金ノズルを、第２図の複合繊
維を得るには第５図の紡糸口金ノズルを、第３図
の複合繊維を紡糸するには第６図に示した紡糸口
金ノズルを用いればよい。第４図〜第６図におい
て、１′の部分から低収縮成分が、また２′の部分
から高収縮成分が紡出される。ここで、紡糸口金
ノズルの、形状寸法は、紡出糸条の中空率が３〜
20％となるように選定される。固有粘度差のある
サイド・バイ・サイド型複合繊維を紡糸する場合
は、両成分間の固有粘度差を0.20〜0.30とするの
が好ましい。また、複合両成分を接合させるの
に、特開昭58−13720号公報に示されているよう
に、両成分を口金ノズルから別々に吐出させ、吐
出後、口金面又は口金面直下で衝突させて接合さ
せる方法が好適に用いられる。 For example, to spin the composite fiber shown in Figure 1, use the spinneret nozzle shown in Figure 4, to obtain the composite fiber shown in Figure 2, use the spinneret nozzle shown in Figure 5, and to obtain the composite fiber shown in Figure 3, use the spinneret nozzle shown in Figure 4. For spinning, the spinneret nozzle shown in FIG. 6 may be used. In FIGS. 4 to 6, a low shrinkage component is spun from a portion 1', and a high shrinkage component is spun from a portion 2'. Here, the shape and dimensions of the spinneret nozzle are such that the hollowness ratio of the spun yarn is 3 to 3.
20%. When spinning side-by-side composite fibers with a difference in intrinsic viscosity, it is preferable that the difference in intrinsic viscosity between the two components is 0.20 to 0.30. In addition, in order to bond both composite components, as shown in Japanese Patent Application Laid-Open No. 58-13720, both components are separately discharged from a nozzle of the nozzle, and after being discharged, they are caused to collide on the nozzle surface or just below the nozzle surface. A method in which the two parts are bonded together is preferably used.
更に、延伸熱処理、加熱流体押込ノズルによる
捲縮発現加工も、従来公知の装置、条件により行
われる。特に延伸後の熱処理温度は170℃〜230℃
として、熱処理時間を0.05秒以上として、延伸熱
処理後の糸条伸度を８％〜18％にするのが好まし
い。加熱流体押込ノズルとしては、米国特許第
4115989号明細書、米国特許第4118534号明細書、
実公昭46−9535号公報、特公昭45−37576号公報、
特開昭54−42441号公報、特開昭56−108812号公
報、特開昭56−169830号公報等に記載されている
ものを用いることができ、加熱流体の温度は210
℃〜260℃とするのが好ましい。 Furthermore, the stretching heat treatment and the crimp forming process using a heated fluid pushing nozzle are also performed using conventionally known equipment and conditions. In particular, the heat treatment temperature after stretching is 170℃~230℃
As such, it is preferable that the heat treatment time is 0.05 seconds or more, and the yarn elongation after the drawing heat treatment is 8% to 18%. As a heated fluid forcing nozzle, U.S. Patent No.
4115989, U.S. Patent No. 4118534,
Utility Model Publication No. 46-9535, Special Publication No. 45-37576,
Those described in JP-A-54-42441, JP-A-56-108812, JP-A-56-169830, etc. can be used, and the temperature of the heated fluid is 210
It is preferable to set it as ℃~260℃.
これらの溶融紡糸、延伸熱処理、及び加熱流体
押込ノズルによる捲縮発現処理は、一旦巻取つた
りして中断することなく、連続して行うのが好ま
しい。 It is preferable that these melt spinning, drawing heat treatment, and crimp development treatment using a heated fluid forcing nozzle are performed continuously without being interrupted by winding or the like.
また、本発明のポリエステル系中空捲縮加工糸
は、サイド・バイ・サイド型複合中空ポリエステ
ル系繊維を4000ｍ／分以上の高速溶融紡糸によつ
て製造し、延伸することなくそのまま加熱流体押
込ノズルにより捲縮を発現させることによつても
得られる。 In addition, the polyester hollow crimped yarn of the present invention is produced by side-by-side composite hollow polyester fibers by high-speed melt spinning at a speed of 4000 m/min or more, and is directly passed through a heated fluid intrusion nozzle without being stretched. It can also be obtained by developing crimp.
この場合も、溶融紡糸と加熱流体押込ノズルに
よる捲縮発現処理を、中断することなく連続して
行うのが好ましい。 In this case as well, it is preferable to carry out melt spinning and crimp development treatment using a heated fluid forcing nozzle continuously without interruption.
（実施例）
以下、実施例により本発明を説明するが、実施
例における全捲縮率（TC）、捲縮数、捲縮曲率半
径、カーペツト厚さ減少率は、次に述べる方法で
測定したものである。(Example) The present invention will be explained below with reference to Examples. In the Examples, the total crimp rate (TC), number of crimps, crimp curvature radius, and carpet thickness reduction rate were measured by the following methods. It is something.
(イ) 全捲縮率（TC）
TC＝lo−l1／lo×100（％）
loはde当り２mgの荷重を掛け沸水中で20分間
処理し、この状態で１昼夜40℃以下で乾燥後
de当り200mgの荷重を掛けて１分後の長さであ
る。l1はlo測定後３分後にde当り２mgの荷重を
掛け１分後の長さである。(b) Total crimp ratio (TC) TC = lo-l 1 /lo x 100 (%) lo is treated in boiling water for 20 minutes with a load of 2 mg per de, and dried in this state at 40℃ or less for one day and night. rear
This is the length after 1 minute with a load of 200 mg per de. l 1 is the length after 1 minute when a load of 2 mg per de is applied 3 minutes after lo measurement.
(ロ) 捲縮数、捲縮曲率半径
捲縮加工糸から20本の単糸を採取し、無加重
下で25倍に拡大した写真を撮影して、捲縮数及
び捲縮の曲率半径を測定し、単糸20本の平均値
を求めた。(b) Number of crimps, radius of curvature of crimps 20 single yarns were sampled from the crimped yarn, and photographs were taken at 25 times magnification under no load to calculate the number of crimps and the radius of curvature of the crimps. The average value of 20 single yarns was determined.
(ハ) カーペツト厚さ減少率
JIS L1021、ロータリー形ダイナミツクロー
デイングテストにより測定した。(c) Carpet thickness reduction rate Measured by JIS L1021, rotary type dynamic loading test.
実施例 １
高収縮成分としてイソフタル酸5mol％を共重
合した極限粘度0.74のポリエチレンテレフタレー
テ（艶消剤としてTiO2を0.5％含有する）を、低
収縮成分として極限粘度0.4のポリエチレンテレ
フタレートをそれぞれ別々に溶融し、第４図〜第
６図に示した紡糸口金ノズルを用い、１′，２′か
らそれぞれ単独に、285℃のポリマー温度にて、
吐出量比１：１で吐出した後、口金直下で衝突接
合させ、次いで冷却、オイリングを施し、750
ｍ／分で引取り、一旦巻取ることなく、95℃で予
熱して3.87倍に延伸した。次いで160℃で熱処理
した後、12％のオーバーフイードで加熱流体押込
ノズルに供給し、捲縮発現処理を施して巻取り、
300デニール／96フイラメントの捲縮加工糸を得
た。この時の加熱流体押込ノズルにおける加熱流
体圧は3.5Kg／cm2、加熱流体温度は180℃であつ
た。尚、No.１では、一対の円形紡糸口金ノズルか
ら両成分を吐出した後、口金面直下で衝突接合さ
せた中実のサイド・バイ・サイド型複合繊維であ
つた。また、No.８は加熱流体押込ノズルによる処
理を行わず、No.９は、流体押込ノズルにおける流
体を加熱せずに室温とし、No.10は加熱流体温度を
120℃とした。Example 1 Polyethylene terephthalate with an intrinsic viscosity of 0.74 (containing 0.5% TiO 2 as a matting agent) copolymerized with 5 mol% of isophthalic acid as a high-shrinkage component, and polyethylene terephthalate with an intrinsic viscosity of 0.4 as a low-shrinkage component. 1' and 2' separately at a polymer temperature of 285°C using the spinneret nozzles shown in Figures 4 to 6.
After discharging at a discharge ratio of 1:1, collision bonding was performed directly below the mouthpiece, then cooling and oiling were performed.
The film was taken up at a speed of m/min, and without being wound up, it was preheated at 95°C and stretched 3.87 times. Next, after heat treatment at 160°C, it is supplied to a heated fluid push nozzle with an overfeed of 12%, subjected to crimp development treatment, and wound up.
A crimped yarn of 300 denier/96 filaments was obtained. At this time, the heating fluid pressure in the heating fluid pushing nozzle was 3.5 Kg/cm 2 and the heating fluid temperature was 180°C. In No. 1, after both components were discharged from a pair of circular spinneret nozzles, they were impact-bonded directly below the spinneret surface to form a solid side-by-side type composite fiber. In addition, No. 8 does not perform treatment with the heated fluid push nozzle, No. 9 does not heat the fluid in the fluid push nozzle and keeps it at room temperature, and No. 10 does not heat the fluid at room temperature.
The temperature was 120℃.
得られた各捲縮加工糸を用いて、２／２ツイル
織物（経糸：46羽×２本／鯨、下撚S300T／Ｍ；
緯糸：82越／鯨、下撚S300T／Ｍ）をつくり高圧
染色（110℃×60分）を行つた。 Using each of the obtained crimped yarns, a 2/2 twill fabric (warp: 46 threads x 2/whale, first twist S300T/M;
Weft: 82 Koshi/Whale, first twisted S300T/M) was made and subjected to high pressure dyeing (110℃ x 60 minutes).
捲縮加工糸の各特性及び織物の特性は表１に示
す通りであつた。 The properties of the crimped yarn and the properties of the fabric were as shown in Table 1.
表１から明らかなように、No.１は中空部を含ま
ない比較例でクリンプの曲率半径が小さく、ヴオ
リユーム感が不充分で、中空部がないために、皺
回復性（弾性回復性）、保温性も不充分である。 As is clear from Table 1, No. 1 is a comparative example that does not include a hollow part, and the radius of curvature of the crimp is small, the voluminous feel is insufficient, and because there is no hollow part, wrinkle recovery (elastic recovery), Heat retention is also insufficient.
No.５は中空率が低い場合の比較例であるが、中
空率が低いため、中空効果が劣り、ヴオリユーム
感、皺回復性（弾性回復性）共に不充分で保温性
も低い。 No. 5 is a comparative example with a low hollowness ratio, but because the hollowness ratio is low, the hollowness effect is poor, the woolen feel and wrinkle recovery properties (elastic recovery properties) are insufficient, and the heat retention is also low.
No.６は中空率が高い場合の比較例であるが、中
空率が高過ぎるとヴオリユーム感は良好なるも、
繰返し歪を与えた場合中空部がつぶれるために、
皺回復性（弾性回復性）は不充分となる。 No. 6 is a comparative example where the hollowness ratio is high, but if the hollowness ratio is too high, the volume feeling will be good, but
Because the hollow part collapses when subjected to repeated strain,
Wrinkle recovery properties (elastic recovery properties) become insufficient.
No.８は加熱流体押込処理を行わない場合の比較
例であるが、捲縮特性が不充分となり、ヴオリユ
ーム感が不充分で風合の悪いものしか得ることが
出来ない。 No. 8 is a comparative example in which no heated fluid intrusion treatment is performed, but the crimp properties are insufficient, the woolen feel is insufficient, and only a poor texture can be obtained.
また、No.９は、流体押込ノズルによる捲縮発現
処理が不充分であるため、捲縮特性が劣り、ヴオ
リユーム感が不足し、風合の劣つたものであつ
た。 In addition, No. 9 had poor crimp characteristics, lacked a sense of volume, and had a poor hand because the crimp development treatment using the fluid forcing nozzle was insufficient.
これに対して、本発明の中空捲縮加工糸を用い
た場合（No.２〜４、７、10）は、ヴオリユーム
感、皺回復性（弾性回復性）、風合が良好で、保
温性の高い織物が得られた。 On the other hand, when the hollow crimped yarn of the present invention was used (Nos. 2 to 4, 7, and 10), the woolen feel, wrinkle recovery (elastic recovery), and texture were good, and the heat retention was good. A high quality fabric was obtained.
実施例 ２
高収縮成分として、イソフタル酸10mol％を共
重合した極限粘度0.64のポリエチレンテレフタレ
ート（艶消剤としてTiO20.5％含有）を、低収縮
成分として、極限粘度0.74のポリエチレンテレフ
タレート（艶消剤としてTiO20.5％を含有）をそ
れぞれ別々に溶融し、第４図〜第６図に示した紡
糸口金ノズルを用い、１′，２′からそれぞれ単独
に、285℃のポリマー温度にて、吐出量比１：１
で吐出した後、口金面直下で衝突・接合させ、次
いで冷却、オイリングを施し、4500ｍ／分で引取
り、一旦巻取ることなく、８％のオーバーフイー
ドで加熱流体押込ノズルに供給し、捲縮発現処理
を施して巻取り、300デニール／96フイラメント
の捲縮加工糸を得た。この時の加熱流体押込ノズ
ルにおける加熱流体圧は4.5Kg／cm2、加熱流体温
度は180℃であつた。尚、No.１では、一対の円形
紡糸口金ノズルから両成分を吐出した後、口金面
直下で衝突・接合させた中実のサイド・バイ・サ
イド型複合繊維であつた。Example 2 Polyethylene terephthalate with an intrinsic viscosity of 0.64 copolymerized with 10 mol% of isophthalic acid (contains 0.5% TiO 2 as a matting agent) was used as a high-shrinkage component, and polyethylene terephthalate with an intrinsic viscosity of 0.74 (contains 0.5% of TiO 2 as a matting agent) was used as a low-shrinkage component. (containing 0.5% TiO 2 ) were separately melted and discharged from 1' and 2' individually at a polymer temperature of 285°C using the spinneret nozzles shown in Figures 4 to 6. Quantity ratio 1:1
After discharging, the material is collided and joined just below the mouth surface, then cooled and oiled, taken off at 4500 m/min, and without being wound up, is supplied to a heated fluid push nozzle with an overfeed of 8% and crimped. The yarn was subjected to development treatment and wound to obtain a crimped yarn of 300 denier/96 filaments. At this time, the heating fluid pressure in the heating fluid pushing nozzle was 4.5 Kg/cm 2 and the heating fluid temperature was 180°C. In No. 1, after both components were discharged from a pair of circular spinneret nozzles, they were collided and joined just below the spinneret surface to produce a solid side-by-side type composite fiber.
得られた各捲縮加工糸を用いて、実施例１と同
様にして織物を作つた。 A woven fabric was made in the same manner as in Example 1 using each of the obtained crimped yarns.
捲縮加工糸の各特性及び織物の特性は表２に示
す通りであつた。 The properties of the crimped yarn and the properties of the fabric were as shown in Table 2.
表２より明らかなように、No.１は中空部を含ま
ない比較例で、クリンプの曲率半径が小さく、ヴ
オリユーム感が不充分で、中空部がないために皺
回復性（弾性回復性）、保温性も悪かつた。 As is clear from Table 2, No. 1 is a comparative example that does not include a hollow part, and the radius of curvature of the crimp is small, the voluminous feel is insufficient, and the wrinkle recovery (elastic recovery) is poor due to the lack of a hollow part. The heat retention was also poor.
これに対して、本発明の中空捲縮加工糸を用い
た場合（No.２〜４）はヴオリユーム感、皺回復性
（弾性回復性）、風合が良好で、保温性の高い織物
が得られた。 On the other hand, when the hollow crimped yarns of the present invention are used (Nos. 2 to 4), fabrics with good voriyuum feel, wrinkle recovery (elastic recovery), and texture, and high heat retention can be obtained. It was done.
実施例 ３
実施例１において、デニール構成を800デニー
ル／95フイラメントとして、表３に示した紡糸口
金ノズル形状で溶融紡糸を行い、捲縮加工糸を得
た。この捲縮加工糸にチーズ染色（130℃×60分）
を施した後、２本合糸してパイル糸とし、以下の
タフト規格によりベロアカーペツトを作成した。
その結果を捲縮加工糸の特性と共に表３に示す。Example 3 In Example 1, the denier configuration was changed to 800 denier/95 filaments, and melt spinning was performed using the spinneret nozzle shape shown in Table 3 to obtain a crimped yarn. Cheese dyeing on this crimped yarn (130℃ x 60 minutes)
After that, the two yarns were combined to make a pile yarn, and a velor carpet was made according to the following tuft specifications.
The results are shown in Table 3 along with the characteristics of the crimped yarn.
タフト規格
ゲージ 1/10cm、ステツチ 12.0cm
パイル長 7.5cm、目付 660ｇ／cm2
表３より明らかなように、No.１は中空部のない
比較例であり、カーペツトにしたときの厚さ減少
率が大きく、弾性回復性が劣り、いわゆるヘタリ
の大きいカーペツトであり、風合も劣つていた。Tuft standard Gauge 1/10cm, stitch 12.0cm Pile length 7.5cm, basis weight 660g/cm 2 As is clear from Table 3, No. 1 is a comparative example without hollow parts, and the thickness reduction rate when made into a carpet. The carpet had a large amount of elasticity, poor elastic recovery, and had a large amount of stiffness, and the texture was also poor.
これに対して、本発明の中空捲縮加工糸を用い
た場合（No.２〜４）は、カーペツト厚さ減少率が
小さく、弾性回復性に優れ、風合の良好なカーペ
ツトが得られた。 On the other hand, when the hollow crimped yarns of the present invention were used (Nos. 2 to 4), the carpet thickness reduction rate was small, the elastic recovery was excellent, and carpets with good texture were obtained. .
（発明の効果）
本発明のポリエステル系中空捲縮加工糸によれ
ば、中空であるために、嵩高性、保温性、弾性回
復性に優れ、ヘタリにくく、更に捲縮率が高いた
めに、嵩高性が一段と向上して、風合が良好であ
り、いわゆるペーパーライクな感触がなく、織
物、カーペツト用途に極めて有用である。(Effects of the Invention) Since the polyester hollow crimped yarn of the present invention is hollow, it has excellent bulkiness, heat retention, and elastic recovery properties, and is resistant to sagging, and has a high crimp rate. It has improved properties, has a good texture, and does not have a so-called paper-like feel, making it extremely useful for textiles and carpets.
第１図〜第３図は本発明のポリエステル系中空
捲縮加工糸の例を示す横断面図、第４図〜第６図
は、それぞれ第１図〜第３図の加工糸を紡糸する
際に使用する紡糸口金ノズルの平面図である。
１……低収縮成分、２……高収縮成分、１′…
…低収縮成分紡出部、２′……高収縮成分紡出部。
FIGS. 1 to 3 are cross-sectional views showing examples of polyester hollow crimped yarns of the present invention, and FIGS. 4 to 6 are cross-sectional views when spinning the processed yarns shown in FIGS. 1 to 3, respectively. 1 is a plan view of a spinneret nozzle used in FIG. 1...Low shrinkage component, 2...High shrinkage component, 1'...
...Low shrinkage component spinning section, 2'...High shrinkage component spinning section.
【表】
※ 比較例
[Table] * Comparative example
【表】
※ 比較例
[Table] * Comparative example
【表】
※ 比較例
[Table] * Comparative example
Claims (1)
数が10〜45ケ／cmであることを特徴とするポリエ
ステル系中空捲縮加工糸。 ２ サイド・バイ・サイド型複合繊維からなつて
いる特許請求の範囲第１項記載のポリエステル系
中空捲縮加工糸。 ３ 実質的に撚を有していない特許請求の範囲第
１項又は第２項記載のポリエステル系中空捲縮加
工糸。 ４ サイド・バイ・サイド型複合中空ポリエステ
ル系繊維を溶融紡糸し、延伸熱処理後、加熱流体
押込ノズルにより捲縮を発現させることを特徴と
する中空率３〜20％、捲縮率12％以上、捲縮数10
〜45ケ／cmのポリエステル系中空捲縮加工糸の製
造方法。 ５ 溶融紡糸、延伸熱処理、及び加熱流体押込ノ
ズルによる捲縮発現処理を連続して行う特許請求
の範囲第４項記載の方法。 ６ サイド・バイ・サイド型複合中空ポリエステ
ル系繊維を4000ｍ／分以上の紡糸速度で溶融紡糸
した後、加熱流体押込ノズルにより捲縮を発現さ
せることを特徴とする中空率３〜20％、捲縮率12
％以上、捲縮数10〜45ケ／cmのポリエステル系中
空捲縮加工糸の製造方法。 ７ 溶融紡糸及び加熱流体押込ノズルによる捲縮
発現処理を連続して行う特許請求の範囲第６項記
載の方法。[Scope of Claims] 1. A hollow crimped polyester yarn characterized by having a hollowness ratio of 3 to 20%, a crimp ratio of 12% or more, and a number of crimps of 10 to 45 crimps/cm. 2. The polyester hollow crimped yarn according to claim 1, which is made of side-by-side composite fibers. 3. The polyester hollow crimped yarn according to claim 1 or 2, which has substantially no twist. 4. A hollow ratio of 3 to 20% and a crimp ratio of 12% or more, characterized by melt-spinning a side-by-side type composite hollow polyester fiber, and after drawing heat treatment, crimping is caused by a heated fluid pushing nozzle. Number of crimps: 10
A method for manufacturing polyester hollow crimped yarn of ~45 strands/cm. 5. The method according to claim 4, wherein melt spinning, drawing heat treatment, and crimp development treatment using a heated fluid forcing nozzle are performed continuously. 6 Hollowness ratio of 3 to 20%, crimping characterized by melt-spinning side-by-side type composite hollow polyester fibers at a spinning speed of 4000 m/min or more and then developing crimps using a heated fluid pushing nozzle. rate 12
% or more, and the number of crimps is 10 to 45 crimps/cm. 7. The method according to claim 6, wherein melt spinning and crimp development treatment using a heated fluid forced nozzle are performed continuously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8537785A JPS61245327A (en) | 1985-04-23 | 1985-04-23 | Polyester hollow crimped yarn and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8537785A JPS61245327A (en) | 1985-04-23 | 1985-04-23 | Polyester hollow crimped yarn and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61245327A JPS61245327A (en) | 1986-10-31 |
| JPH0357973B2 true JPH0357973B2 (en) | 1991-09-04 |
Family
ID=13857032
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8537785A Granted JPS61245327A (en) | 1985-04-23 | 1985-04-23 | Polyester hollow crimped yarn and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61245327A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2908454B2 (en) * | 1988-05-20 | 1999-06-21 | 東洋紡績株式会社 | Thermally bonded nonwoven fabric with excellent bulkiness, easy compressibility, and easy recovery from compression |
| CN108239794A (en) * | 2016-12-23 | 2018-07-03 | 东丽纤维研究所（中国）有限公司 | A kind of hollow long fibre of polyester |
| CN109137098B (en) * | 2018-09-28 | 2021-01-01 | 浙江恒澜科技有限公司 | Self-crimping far infrared hollow composite filament and preparation method thereof |
| JP7197326B2 (en) * | 2018-11-02 | 2022-12-27 | 帝人フロンティア株式会社 | hollow deformed crimped filament |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496237A (en) * | 1972-05-23 | 1974-01-19 | ||
| JPS5374134A (en) * | 1976-12-14 | 1978-07-01 | Asahi Chem Ind Co Ltd | Multihollow fibers with polygonal cross section and falsetwisted yarns therefrom |
| JPS5653223A (en) * | 1979-10-05 | 1981-05-12 | Mitsubishi Acetate Co Ltd | Production of crimped fiber bundle |
| JPS5818417A (en) * | 1981-07-27 | 1983-02-03 | Nippon Ester Co Ltd | Polyester hollow composite fiber |
| JPS5831132A (en) * | 1981-08-18 | 1983-02-23 | 大和紡績株式会社 | Production of bulky crimp filament yarn |
| JPS5936714A (en) * | 1982-08-26 | 1984-02-29 | Teijin Ltd | Crimped modified hollow yarn |
| JPS6059144A (en) * | 1983-09-05 | 1985-04-05 | 東レ株式会社 | Discontinuous crimp synthetic yarn staple |
-
1985
- 1985-04-23 JP JP8537785A patent/JPS61245327A/en active Granted
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS496237A (en) * | 1972-05-23 | 1974-01-19 | ||
| JPS5374134A (en) * | 1976-12-14 | 1978-07-01 | Asahi Chem Ind Co Ltd | Multihollow fibers with polygonal cross section and falsetwisted yarns therefrom |
| JPS5653223A (en) * | 1979-10-05 | 1981-05-12 | Mitsubishi Acetate Co Ltd | Production of crimped fiber bundle |
| JPS5818417A (en) * | 1981-07-27 | 1983-02-03 | Nippon Ester Co Ltd | Polyester hollow composite fiber |
| JPS5831132A (en) * | 1981-08-18 | 1983-02-23 | 大和紡績株式会社 | Production of bulky crimp filament yarn |
| JPS5936714A (en) * | 1982-08-26 | 1984-02-29 | Teijin Ltd | Crimped modified hollow yarn |
| JPS6059144A (en) * | 1983-09-05 | 1985-04-05 | 東レ株式会社 | Discontinuous crimp synthetic yarn staple |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61245327A (en) | 1986-10-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| WO2002086211A1 (en) | False twist yarn of polyester composite fiber and method for production thereof | |
| EP1500730B1 (en) | Polyester conjugate filament thick-fine yarn fabric and method for production thereof | |
| JPH0357973B2 (en) | ||
| JPH11158724A (en) | Polyester hollow fiber | |
| JP4385448B2 (en) | Composite crimped yarn, method for producing the same and fabric | |
| JP3598027B2 (en) | Special composite crimped yarn | |
| JP4506130B2 (en) | Dyed yarn and method for producing the same | |
| JPH073554A (en) | Production of false-twisted hollow polyester yarn | |
| JP4890479B2 (en) | Polyester composite fiber and woven / knitted fabric | |
| JPH09302545A (en) | Spun yarn having multi-layered structure, hollow fiber obtained therefrom, production thereof and woven or knitted fabric | |
| JPH0978382A (en) | Polyester combined filament yarn | |
| JP2002249938A (en) | Aliphatic polyester composite false-twist textured yarn and method for producing the same | |
| JP4667632B2 (en) | Fibrilized fiber and method for producing fibrillated fiber | |
| JP3301534B2 (en) | Mixed fiber yarn with excellent elastic recovery | |
| JPH10130971A (en) | Conjugate yarn | |
| JPH1018136A (en) | Polyester-based composite false twist textured yarn and polyester-based woven and knitted fabric | |
| JPH08113870A (en) | Production of cloth made of combined polyester filament yarn having fluff | |
| JP2022040590A (en) | Woven or knitted fabric | |
| JP3029682B2 (en) | Composite fiber aggregate having excellent retardation crimp | |
| JP3484822B2 (en) | Polyester multifilament composite yarn and method for producing the same | |
| JPH10121348A (en) | Alternately arranged woven fabric | |
| JP3491716B2 (en) | Method for producing latent micro-crimp developing polyester multifilament yarn and method for producing mixed yarn | |
| JP3452154B2 (en) | Method for producing polyester composite yarn and polyester woven / knitted fabric | |
| JP2003193343A (en) | Plied yarn and knitted or woven fabric | |
| JPS5971416A (en) | Composite polyester yarn |