JPH0352789B2 - - Google Patents
Info
- Publication number
- JPH0352789B2 JPH0352789B2 JP58029212A JP2921283A JPH0352789B2 JP H0352789 B2 JPH0352789 B2 JP H0352789B2 JP 58029212 A JP58029212 A JP 58029212A JP 2921283 A JP2921283 A JP 2921283A JP H0352789 B2 JPH0352789 B2 JP H0352789B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- cleaning
- carbon atoms
- present
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004140 cleaning Methods 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 9
- 125000003342 alkenyl group Chemical group 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 150000001412 amines Chemical class 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- 230000007797 corrosion Effects 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000004744 fabric Substances 0.000 description 7
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- 238000005108 dry cleaning Methods 0.000 description 6
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 244000060011 Cocos nucifera Species 0.000 description 4
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- -1 polyoxyethylene Polymers 0.000 description 4
- 229950011008 tetrachloroethylene Drugs 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- QGLWBTPVKHMVHM-KTKRTIGZSA-N (z)-octadec-9-en-1-amine Chemical compound CCCCCCCC\C=C/CCCCCCCCN QGLWBTPVKHMVHM-KTKRTIGZSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229940077388 benzenesulfonate Drugs 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- VVXPDWRMIXEULT-UHFFFAOYSA-N octadecan-1-amine;oxirane Chemical compound C1CO1.CCCCCCCCCCCCCCCCCCN VVXPDWRMIXEULT-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- NKFNBVMJTSYZDV-UHFFFAOYSA-N 2-[dodecyl(2-hydroxyethyl)amino]ethanol Chemical compound CCCCCCCCCCCCN(CCO)CCO NKFNBVMJTSYZDV-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 235000001671 coumarin Nutrition 0.000 description 1
- 229960000956 coumarin Drugs 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- VVTGHWARMCSPKY-UHFFFAOYSA-N dodecan-1-amine;oxirane Chemical compound C1CO1.CCCCCCCCCCCCN VVTGHWARMCSPKY-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- OEHSKKFHHQVEHY-UHFFFAOYSA-N octadecan-1-amine;phosphoric acid Chemical class OP(O)(O)=O.CCCCCCCCCCCCCCCCCCN OEHSKKFHHQVEHY-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- UBOXGVDOUJQMTN-UHFFFAOYSA-N trichloroethylene Natural products ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Description
本発明は衣料等の洗浄時に帯電防止効果、柔軟
効果をも付与できるいわゆる複合効果を有する洗
浄剤組成物に関し、特にドライクリーニング用に
好適な洗浄剤組成物を提供するものである。
近年ドライクリーニング洗浄工程の短縮化、合
理化のために洗浄と同時に帯電防止加工、柔軟処
理を付与できる組成が種々開発されてきた。これ
らは第４級アンモニウム塩型カチオン界面活性剤
を主剤とし、これに洗浄力向上のためにポリオキ
シエチレンアルキルフエニルエーテルや脂肪酸ジ
エタノールアミド等の非イオン界面活性剤を配合
したもの（特開昭50−76108、特開昭52−94306）
または両性界面活性剤を配合したもの（特開昭54
−139907）などがある。しかし前記の組成物は、
帯電防止効果、柔軟付与効果はすぐれるものの洗
浄力は未だ十分とはいえなかつた。それに加え、
第４級アンモニウム塩型カチオン界面活性剤中に
存在する微量の未反応アミンの作用によりドライ
クリーニング洗浄機の銅部材が腐食するという欠
点であつた。
一方、アミンまたはジアミンと有機酸との塩も
上記目的のために用いられているが、未だ洗浄力
が十分とはいえず、またくり返し使用するとドラ
イクリーニング洗浄機の鉄部材を腐食するという
欠点があつた。
本発明者らは上記欠点を解決するために研究を
続けた結果、アミンの特定の２種類の塩を用いる
ことにより、洗浄機や衣料等の付属品などの金属
部材を腐食させることがなく、すぐれた洗浄力と
帯電防止効果とを発揮することを見出し本発明を
なすに至つた。
すなわち、本発明は(A)下記一般式（）で表わ
されるモノアミンと６〜９の炭素数を有する芳香
族スルホン酸との塩及び(B)下記一般式（）で表
わされるモノアミンとリン酸との塩とを含有し、
成分(A)と成分(B)とが(A)／(B)＝10／0.5〜８／10（重
量比）の範囲内にあることを特徴とする洗浄剤組
成物である。
本発明における成分(A)、(B)のアミン成分として
は、炭素数８〜22のアルキル基またはアルケニル
基を分子内に少なくとも１個有するモノアミンで
あつて、式（）により表わされるものである。
（式中、R1は炭素数８〜22のアルキル基または
アルケニル基、R2、R3は水素、炭素数１〜22の
アルキル基またはアルケニル基、（−CH2CH2O）
nH〔ｎ＝１〜20〕で示される基であり、R2、R3
は同一でも異なつていても良い。）
これらのうち、帯電防止性の点から式（）に
おけるR1が炭素数12〜18のアルキル基またはア
ルケニル基、R2、R3が（−CH2CH2O）nH〔ｎ＝１
〜10〕であるアミンが特に好ましい。
本発明の成分(A)は、上記アミンと６〜９の炭素
数を有する芳香族スルホン酸との塩である。具体
的にはラウリルジエタノールアミン・パラトルエ
ンスルホン酸塩、ステアリルアミンのエチレンオ
キシド（＝４）付加物・キシレンスルホン酸
塩、オレイルアミンのエチレンオキシド（＝
10）付加物・ベンゼンスルホン酸塩、ヤシアルキ
ルアミンのエチレンオキシド（＝６）付加物・
パラトルエンスルホン酸塩、ヤシアルキルアミ
ン・ベンゼンスルホン酸塩、ステアリルアミン・
パラトルエンスルホン酸塩、ジラウリルアミン・
パラトルエンスルホン酸塩などであり、これらの
１種または２種以上の混合物が使用される。
一方本発明の成分(B)は、前記アミンとリン酸と
の塩であり、具体的にはヤシアルキルジエタノー
ルアミン・リン酸塩、ラウリルアミンのエチレン
オキシド（＝４）付加物・リン酸塩、ステアリ
ルアミンのエチレンオキシド（＝６）付加物・
リン酸塩、オレイルアミンのエチレンオキシド
（＝８）付加物・リン酸塩、ヤシアルキルアミ
ン・リン酸塩、ステアリルアミン・リン酸塩など
である。これらは１種または２種以上の混合物と
して使用される。なお上記化合物中はエチレン
オキシドの平均付加モル数を表わす（以下におい
ても同じ）。本発明においては成分(A)及び(B)の併
用により洗浄力が相乗的に向上するとともに成分
(B)の作用により洗浄機の鉄部材の腐食をも防止す
るものであつて、成分(A)のみでは鉄部材の腐食が
生じまた洗浄力も未だ十分でなく、成分(B)のみで
は鉄部材の腐食は生じないものの洗浄力は低いと
いう欠点がある。成分(A)と成分(B)の配分比は任意
に選ぶことができるが成分(A)／(B)＝10／0.5〜
８／10（重量比）、好ましくは10／0.5〜10／８、
更に好ましくは10／１〜10／６であり、また成分
(A)、成分(B)の配合量は５〜30重量％が好適であ
る。
なお、本発明の成分(A)、(B)は、前記アミンと６
〜９の炭素数を有する芳香族スルホン酸またはリ
ン酸とを混合し、それぞれ塩の形として容易に配
合されるが、前記アミンと６〜９の炭素数を有す
る芳香族スルホン酸またはリン酸とを別々に溶媒
に添加し、系中で塩の形として用いても良い。
本発明の洗浄剤組成物には上記成分のほかに、
帯電防止効果を増強させ、柔軟効果、泡水能を付
与するために脂肪酸アルカノールアミドを３〜10
重量％配合するのが望ましい。このような脂肪酸
アルカノールアミドとして、例えばヤシ脂肪酸ジ
エタノールアミド、ラウリン酸ジエタノールアミ
ド、ステアリン酸ジエタノールアミド、オレイン
酸ジエタノールアミド、ヤシ脂肪酸モノエタノー
ルアミド等の炭素数10〜20の脂肪酸アミドのエチ
レンオキシド（＝１〜10）付加物をあげること
ができる。
本発明の洗浄剤組成物は、ナフテン、パラフイ
ン含量の多い石油系溶剤やテトラクロロエチレ
ン、トリクロロエチレン、トリクロロエタン、ト
リクロロトリフルオロエタン等の合成系溶剤に溶
解させて、ドライクリーニング用に好ましく使用
される。これは洗浄機の多くが金属部分を露出し
ているために、金属部材の腐食が生じないという
大きなメリツトが活かせるからである。しかし、
本発明品はドライクリーニング用に限定されるも
のではなく、水に溶解させてランドリー用や一般
の家庭用洗剤としても使用可能である。
本発明においては、更に通常の洗浄剤に配合さ
れる成分をその目的に応じて配合することができ
る。すなわちメタノール、エタノール等の低級ア
ルコール、グリセリン、エチレングリコール、プ
ロピレングリコール、尿素等の可溶化剤、ビフエ
ニル系またはクマリン系の蛍光剤や香料を添加す
ることができる。
本発明の洗浄剤を適用する対象繊維は天然の動
植物繊維に限らず、各種の合成繊維並びにこれら
の混紡品、パルプ繊維などである。
次に本発明を実施例により説明する。なお性能
は下記の方法により評価した。
Γ洗浄力
洗浄力をパークロルエチレン溶剤にて0.5％
濃度となるように調整した後、油化学協会法カ
ーボン汚垢を付着したウールの汚染布（５×５
cm）を入れて、scrub−ｏ−meter洗浄機で25
℃、10分間洗浄し、色差計（日本電色製）によ
り洗浄前後の反射率を測定し、次式から洗浄力
を求めた。
洗浄力（％）＝汚染布の洗浄後の反射
率−汚染布の反射率／汚染前の白布の反射率−汚染布の
反射率×100
Γ帯電防止力
アクリル布（５×10cm）を用い、洗浄剤0.5
％パークロルエチレン溶液にて、振とう処理を
25℃、10分間行ない、絞り率40％owfまで絞
り、タンブラー乾燥（70℃、20分）した後、20
℃、40％RHで表面固有抵抗値を測定した。
1012Ω未満 ◎
1012〜1013Ω ○
1013Ωより大 ×
Γ金属腐食性
洗浄剤60ml、蒸留水60ml、パークロルエチレ
ン180mlの混合液に鉄を浸漬し、120℃９時間／
日×５日間加熱した後の腐食量を測定した。
腐食量が10mg／cm2未満は○
〃 10mg／cm2以上は×
実施例 １
成分(A)と成分(B)の配合比率を種々かえたドライ
クリーニング洗浄剤組成物を配合して性能を評価
した。組成及び性能をまとめて表−１に示す。
なお表中の配合量はすべて重量％である（以下
同じ）。
The present invention relates to a detergent composition having a so-called combined effect that can also provide an antistatic effect and a softening effect when washing clothes, etc., and provides a detergent composition particularly suitable for dry cleaning. In recent years, in order to shorten and streamline the dry cleaning process, various compositions have been developed that can provide antistatic and softening treatments at the same time as cleaning. These products have a quaternary ammonium salt type cationic surfactant as the main ingredient, and are blended with nonionic surfactants such as polyoxyethylene alkyl phenyl ether and fatty acid diethanolamide to improve detergency (JP-A-Show). 50-76108, Japanese Patent Publication No. 52-94306)
Or one containing an amphoteric surfactant (Japanese Unexamined Patent Application Publication No. 1989-1998)
-139907). However, the said composition
Although the antistatic effect and the softening effect were excellent, the detergency was still not sufficient. In addition to that,
The drawback was that the copper members of the dry cleaning machine were corroded by the action of a trace amount of unreacted amine present in the quaternary ammonium salt type cationic surfactant. On the other hand, salts of amines or diamines and organic acids are also used for the above purpose, but they still do not have sufficient cleaning power and have the disadvantage that repeated use corrodes the iron parts of dry cleaning machines. It was hot. The present inventors continued their research to solve the above drawbacks, and found that by using two specific types of amine salts, metal members such as accessories for washing machines and clothing will not corrode. The inventors discovered that it exhibits excellent cleaning power and antistatic effect, and have come up with the present invention. That is, the present invention provides (A) a salt of a monoamine represented by the following general formula () and an aromatic sulfonic acid having 6 to 9 carbon atoms; and (B) a salt of a monoamine represented by the following general formula () and phosphoric acid. containing the salt of
A cleaning composition characterized in that component (A) and component (B) are in a range of (A)/(B)=10/0.5 to 8/10 (weight ratio). The amine component of components (A) and (B) in the present invention is a monoamine having at least one alkyl group or alkenyl group having 8 to 22 carbon atoms in the molecule, and is represented by the formula (). . (In the formula, R 1 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, R 2 and R 3 are hydrogen, an alkyl group or alkenyl group having 1 to 22 carbon atoms, (-CH 2 CH 2 O)
A group represented by nH [n=1-20], R 2 , R 3
may be the same or different. ) Among these, from the viewpoint of antistatic properties, R 1 in formula () is an alkyl group or alkenyl group having 12 to 18 carbon atoms, R 2 and R 3 are (-CH 2 CH 2 O) nH [n = 1
-10] are particularly preferred. Component (A) of the present invention is a salt of the above amine and an aromatic sulfonic acid having 6 to 9 carbon atoms. Specifically, lauryl diethanolamine/paratoluene sulfonate, stearylamine ethylene oxide (=4) adduct/xylene sulfonate, oleylamine ethylene oxide (=
10) Adduct・benzenesulfonate, ethylene oxide (=6) adduct of coconut alkylamine・
Para-toluene sulfonate, coconut alkylamine benzene sulfonate, stearylamine
Para-toluene sulfonate, dilaurylamine,
para-toluene sulfonate, etc., and one or a mixture of two or more of these may be used. On the other hand, component (B) of the present invention is a salt of the above-mentioned amine and phosphoric acid, and specifically, coconut alkyldiethanolamine phosphate, laurylamine ethylene oxide (=4) adduct/phosphate, stearylamine Ethylene oxide (=6) adduct of
These include phosphates, ethylene oxide (=8) adducts of oleylamine, phosphates, coconut alkylamine phosphates, and stearylamine phosphates. These may be used alone or as a mixture of two or more. In addition, the average number of moles of ethylene oxide added in the above compound is expressed (the same applies below). In the present invention, by using components (A) and (B) in combination, the cleaning power is synergistically improved and the components
The action of (B) also prevents corrosion of the iron parts of the washer. Component (A) alone causes corrosion of iron parts and cleaning power is still insufficient, while component (B) alone causes corrosion of iron parts. Although it does not cause corrosion, it has the disadvantage of low cleaning power. The distribution ratio of component (A) and component (B) can be selected arbitrarily, but component (A) / (B) = 10 / 0.5 ~
8/10 (weight ratio), preferably 10/0.5 to 10/8,
More preferably, the ratio is 10/1 to 10/6, and the component
The blending amounts of (A) and component (B) are preferably 5 to 30% by weight. In addition, components (A) and (B) of the present invention are the above-mentioned amine and 6
The amine and the aromatic sulfonic acid or phosphoric acid having 6 to 9 carbon atoms are easily blended in the form of a salt. may be added separately to a solvent and used in the system as a salt. In addition to the above components, the cleaning composition of the present invention includes:
3 to 10 fatty acid alkanolamides are added to enhance antistatic effect, softening effect, and foaming ability.
It is desirable to mix it in weight%. Examples of such fatty acid alkanolamides include ethylene oxide (=1 to 10) Can give additions. The cleaning composition of the present invention is preferably used for dry cleaning by dissolving it in a petroleum solvent containing a high content of naphthene or paraffin, or a synthetic solvent such as tetrachlorethylene, trichloroethylene, trichloroethane, or trichlorotrifluoroethane. This is because most cleaning machines have exposed metal parts, which has the great advantage of preventing metal parts from corroding. but,
The product of the present invention is not limited to use in dry cleaning, but can also be used as a laundry or general household detergent by dissolving it in water. In the present invention, components that are commonly used in detergents can be added depending on the purpose. That is, lower alcohols such as methanol and ethanol, solubilizers such as glycerin, ethylene glycol, propylene glycol, and urea, biphenyl-based or coumarin-based fluorescent agents, and fragrances can be added. The target fibers to which the cleaning agent of the present invention is applied are not limited to natural animal and plant fibers, but also various synthetic fibers, blends thereof, pulp fibers, and the like. Next, the present invention will be explained by examples. The performance was evaluated by the following method. Γ Cleaning power: 0.5% cleaning power with perchlorethylene solvent
After adjusting the concentration, use a contaminated wool cloth (5 x 5
cm) and scrub-o-meter washer for 25 minutes.
℃ for 10 minutes, the reflectance before and after washing was measured using a color difference meter (manufactured by Nippon Denshoku), and the detergency was determined from the following formula. Cleaning power (%) = Reflectance of contaminated cloth after cleaning - Reflectance of contaminated cloth / Reflectance of white cloth before contamination - Reflectance of contaminated cloth x 100 Γ Antistatic power Using acrylic cloth (5 x 10 cm), Cleaning agent 0.5
% perchlorethylene solution, shaking treatment
After squeezing at 25℃ for 10 minutes, squeezing to a squeezing rate of 40% owf, and drying in a tumbler (70℃, 20 minutes),
The surface resistivity value was measured at ℃ and 40%RH. Less than 10 12 Ω ◎ 10 12 - 10 13 Ω ○ Greater than 10 13 Ω × Γ Metal corrosiveness Immerse iron in a mixture of 60 ml of cleaning agent, 60 ml of distilled water, and 180 ml of perchlorethylene, and heat at 120°C for 9 hours.
The amount of corrosion after heating for 5 days was measured. If the amount of corrosion is less than 10 mg/cm 2 ○ If it is 10 mg/cm 2 or more, × did. The composition and performance are summarized in Table-1. All compounding amounts in the table are weight % (the same applies hereinafter).
【表】
＊１ 比較例
＊２ EOはエチレンオキシドの略(以下同じ)
表−１より成分(A)と(B)とを併用すると洗浄力及
び帯電防止力がすぐれるうえ、金属腐食性も向上
することがわかる。また洗浄力は成分(A)／(B)が
10／0.5〜８／10（重量比）の範囲内、とくに10／
0.5〜10／８の範囲内がすぐれていることがわか
る。なお洗浄後のアクリル布はやわらかな風合い
を示した。
実施例 ２
成分(A)、(B)の種類をかえて性能を評価した。組
成及び性能をまとめて表−２に示す。[Table] *1 Comparative example *2 EO is an abbreviation for ethylene oxide (same below)
From Table 1, it can be seen that when components (A) and (B) are used in combination, the cleaning power and antistatic power are excellent, and the metal corrosion resistance is also improved. In addition, the cleaning power is due to ingredients (A)/(B).
Within the range of 10/0.5 to 8/10 (weight ratio), especially 10/
It can be seen that the range of 0.5 to 10/8 is excellent. The acrylic cloth after washing had a soft texture. Example 2 Performance was evaluated by changing the types of components (A) and (B). The composition and performance are summarized in Table 2.
Claims (1)
と６〜９の炭素数を有する芳香族スルホン酸との
塩及び(B)下記一般式（）で表わされるモノアミ
ンとリン酸との塩とを含有し、成分(A)と成分(B)と
が(A)／(B)＝10／0.5〜８／10（重量比）の範囲内に
あることを特徴とする洗浄剤組成物。 （式中、R1は炭素数８〜22のアルキル基または
アルケニル基、R2、R3は水素、炭素数１〜22の
アルキル基またはアルケニル基、（−CH2CH2O）o
Ｈ＝〔ｎ＝１〜20〕で示される基であり、R2、R3
は同一でも異なつていても良い。） ２ 成分(A)と成分(B)とが(A)／(B)＝10／0.5〜10／
８（重量比）の範囲内にある特許請求の範囲第１
項記載の洗浄剤組成物。[Scope of Claims] 1 (A) A salt of a monoamine represented by the following general formula () and an aromatic sulfonic acid having 6 to 9 carbon atoms, and (B) a monoamine represented by the following general formula () and phosphorus. Component (A) and component (B) are in the range of (A)/(B)=10/0.5 to 8/10 (weight ratio). agent composition. (In the formula, R 1 is an alkyl group or alkenyl group having 8 to 22 carbon atoms, R 2 and R 3 are hydrogen, an alkyl group or alkenyl group having 1 to 22 carbon atoms, (-CH 2 CH 2 O) o
H = a group represented by [n = 1 to 20], R 2 , R 3
may be the same or different. ) 2 Component (A) and component (B) are (A)/(B)=10/0.5~10/
Claim 1 falling within the range of 8 (weight ratio)
The cleaning composition described in .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2921283A JPS59155498A (en) | 1983-02-25 | 1983-02-25 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2921283A JPS59155498A (en) | 1983-02-25 | 1983-02-25 | Detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59155498A JPS59155498A (en) | 1984-09-04 |
| JPH0352789B2 true JPH0352789B2 (en) | 1991-08-13 |
Family
ID=12269881
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2921283A Granted JPS59155498A (en) | 1983-02-25 | 1983-02-25 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59155498A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52126409A (en) * | 1976-04-16 | 1977-10-24 | Daikin Ind Ltd | Solvent composition for dry creaning |
| JPS57193575A (en) * | 1981-05-22 | 1982-11-27 | Hakuyoushiya Kk | Garment hand modifier composition for dry cleaning |
-
1983
- 1983-02-25 JP JP2921283A patent/JPS59155498A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52126409A (en) * | 1976-04-16 | 1977-10-24 | Daikin Ind Ltd | Solvent composition for dry creaning |
| JPS57193575A (en) * | 1981-05-22 | 1982-11-27 | Hakuyoushiya Kk | Garment hand modifier composition for dry cleaning |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59155498A (en) | 1984-09-04 |
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