JPH0349888B2 - - Google Patents
Info
- Publication number
- JPH0349888B2 JPH0349888B2 JP30720387A JP30720387A JPH0349888B2 JP H0349888 B2 JPH0349888 B2 JP H0349888B2 JP 30720387 A JP30720387 A JP 30720387A JP 30720387 A JP30720387 A JP 30720387A JP H0349888 B2 JPH0349888 B2 JP H0349888B2
- Authority
- JP
- Japan
- Prior art keywords
- coom
- hydrocarbon group
- shampoo composition
- formula
- hydrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 claims description 26
- 239000002453 shampoo Substances 0.000 claims description 21
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 239000003945 anionic surfactant Substances 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229930195735 unsaturated hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical group 0.000 claims 3
- -1 fatty acid esters Chemical class 0.000 description 10
- 239000000975 dye Substances 0.000 description 6
- 238000005562 fading Methods 0.000 description 5
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000001312 palmitoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 239000004094 surface-active agent Substances 0.000 description 5
- 239000012190 activator Substances 0.000 description 4
- 239000013543 active substance Substances 0.000 description 4
- FPVVYTCTZKCSOJ-UHFFFAOYSA-N Ethylene glycol distearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOC(=O)CCCCCCCCCCCCCCCCC FPVVYTCTZKCSOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical group CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- AOMUHOFOVNGZAN-UHFFFAOYSA-N N,N-bis(2-hydroxyethyl)dodecanamide Chemical compound CCCCCCCCCCCC(=O)N(CCO)CCO AOMUHOFOVNGZAN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229940031957 lauric acid diethanolamide Drugs 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- YBRJTUFWBLSLHY-UHFFFAOYSA-N 2-[2-(2-octadecanoyloxyethoxy)ethoxy]ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCOCCOC(=O)CCCCCCCCCCCCCCCCC YBRJTUFWBLSLHY-UHFFFAOYSA-N 0.000 description 1
- FJGTUOZNRTVJGO-UHFFFAOYSA-N 2-[bis(2-hydroxyethyl)amino]ethanol;2-[2-(dodecanoylamino)ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCC(=O)NCCN(CCO)CC(O)=O FJGTUOZNRTVJGO-UHFFFAOYSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- JPIYZTWMUGTEHX-UHFFFAOYSA-N auramine O free base Chemical compound C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 JPIYZTWMUGTEHX-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229920006317 cationic polymer Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 230000000774 hypoallergenic effect Effects 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- SXQCTESRRZBPHJ-UHFFFAOYSA-M lissamine rhodamine Chemical compound [Na+].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=C(S([O-])(=O)=O)C=C1S([O-])(=O)=O SXQCTESRRZBPHJ-UHFFFAOYSA-M 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229950001046 piroctone Drugs 0.000 description 1
- BTSZTGGZJQFALU-UHFFFAOYSA-N piroctone olamine Chemical compound NCCO.CC(C)(C)CC(C)CC1=CC(C)=CC(=O)N1O BTSZTGGZJQFALU-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
〔産業上の利用分野〕
本発明は、アミドアミン型両性活性剤を含有
し、しかも透明容器中に包装した場合においても
染料の変色ないし褪色をきたさないシヤンプー組
成物に関する。
〔従来の技術およびその問題点〕
アミドアミン型両性活性剤は低刺激性であるこ
とからシヤンプー組成物の成分として広く使用さ
れている。
しかしながら、アミドアミン型両性活性剤及び
染料を含有するシヤンプー組成物においては、色
素が光に対して不安定で、保存中に変色ないし褪
色するという欠点があつた。
そこで、従来これを防止するために、紫外線吸
収剤又は酸化防止剤を配合するとか、容器を不透
明にするなどの方法がとられているが、光による
色素の変色ないし褪色を充分に防止することがで
きなかつた。
〔問題点を解決するための手段〕
斯かる実状において、本発明者は鋭意研究を行
つた結果、驚くべきことに、アミドアミン型活性
剤とアニオン性活性剤の比が1/1〜1/3の界面活性
剤を使用し、パール化剤としての脂肪酸エステル
類を配合すれば、色素の光安定性に優れたシヤン
プー組成物が得られることを見出し、本発明を完
成した。
すなわち、本発明は、次の成分(A)，(B)及び(C)
(A) (a)次の一般式（）又は（）
（式中、R1及びR3は各々炭素数７〜19の飽和
又は不飽和炭化水素基を、R2及びR4は−
CH2COOM又は−CH2CH2COOMを、R5は水
素、−CH2COOM又は−CH2CH2COOMを、Ｍ
は水素、アルカリ金属又はアルカノールアミン
を示す）で表わされるアミドアミン型両性活性
剤の１種又は２種以上及び(b)アニオン性活性剤
をａ／ｂが重量比で1/1〜1/3になるように含有
する界面活性剤。
(B) 次の一般式（）
R6COO−（（CH2）oＯ）n−R7（）
〔式中、R6は炭素数15〜19の飽和炭化水素基
を、R7は水素又はR6CO−（R6は炭素数15〜19
の飽和炭化水素基を示す）を、ｎは２〜４の整
数を、ｍは１〜３の整数を示す〕
で表わされる脂肪酸エステルの１種又は２種以
上を１〜５重量％、
(C) アゾ系又はキサンテン系水溶性染料
を含有することを特徴とするシヤンプー組成物を
提供するものである。
本発明の(A)成分の界面活性剤において、(a)のア
ミドアミン型両性活性剤の好ましいものとして
は、Ｎ−ラウロイル（又はミリストイル、パルミ
トイル等）−N′−（２−ヒドロキシエチル）エチ
レンジアミン、Ｎ−ラウロイル（又はミリストイ
ル、パルミトイル等）−N′−カルボキシエチル−
N′−（２−ヒドロキシエチル）エチレンジアミン
等の（）式で表わされるもの；並びにＮ−ラウ
ロイル（又はミリストイル、パルミトイル等）−
Ｎ−（２−ヒドロキシエチル）−N′−カルボキシ
メチルエチレンジアミン、Ｎ−ラウロイル（又は
ミリストイル、パルミトイル等）−Ｎ−（２−ヒド
ロキシエチル）−Ｎ，N′−ビス（カルボキシメチ
ル）エチレンジアミン、Ｎ−ラウロイル（又はミ
リストイル、パルミトイル等）−Ｎ−（２−ヒドロ
キシエチル）−Ｎ，N′−ビス（カルボキシエチ
ル）エチレンジアミン等の（）式で表わされる
ものが挙げられる。
また、(b)のアニオン性活性剤としては、一般に
シヤンプーに用いられるアニオン性活性剤はすべ
て使用できるが、特に好ましい具体例としては、
ポリオキシエチレンラウリルエーテル硫酸ナトリ
ウム、ポリオキシエチレンラウリルエーテル硫酸
トリエタノールアミン、ポリオキシエチレンラウ
リルエーテル硫酸アンモニウム、ラウリル硫酸ト
リエタノールアミン、ラウリル硫酸アンモニウム
等が挙げられる。
本発明において、(A)成分の界面活性剤は、ａ／
ｂの割合が重量比で1/1〜1/3、好ましくは2/3〜
１／３になるようにすることが必要であり、(a)がこ
れより多くなると水溶性染料の変色ないし褪色が
惹起し好ましくない。斯かる界面活性剤の配合量
は全組成の５〜45重量％（以下、単に％で示す）、
特に10〜25％が好ましい。
本発明の(B)成分の脂肪酸エステルとしては、例
えばエチレングリコールモノステアレート、エチ
レングリコールジステアレート、トリエチレング
リコールジステアレート等が挙げられ、これらは
全組成の１〜５％、好ましくは２〜４％配合され
る。
また、(C)成分の水溶性染料の好ましいものとし
ては、例えば黄色４号、黄色５号、赤色401号等
が挙げられる。
本発明のシヤンプー組成物には以上の必須成分
の他の公知のシヤンプー組成物の配合成分、例え
ば、カチオン性活性剤、非イオン性活性剤、さら
にプロピレングリコール、グリセリン、尿素等の
溶解剤、エチルアルコール、イソプロピルアルコ
ール、ヒドロキシエチルセルロース、メチルセル
ロース、プロピルメチルセルロース、高級アルコ
ール等の粘度調整剤、香料、紫外線吸収剤、酸化
防止剤、防腐剤、外観調整剤等をその必要に応じ
て配合できる。
上記組成の本発明シヤンプー組成物は光によつ
て変色ないし褪色を生じないので透明容器に充填
して包装することができる。透明容器は何れのも
のでもよいが、就中特に、塩化ビニル、ポリエチ
レンテレフタレート、ポリエチレン等に、チヌビ
ン326、チヌビンＰ等の紫外線吸収剤を0.15PHR
以下含有させたものが好ましい。
〔発明の効果〕
叙上の如く、本発明シヤンプー組成物は光に対
して安定で、透明容器に包装して長期間保存して
も変色したり褪色したりすることがないので、常
に外観を美麗に保持することができるという利点
を有する。
〔実施例〕
以下、実施例を挙げて本発明を詳細に説明する
が、本発明はこれら実施例に限定されるものでは
ない。
尚、実施例において検討した試験法は次の通り
である。
露光試験
シヤンプー組成物を透明ボトル（材質：PVC、
紫外線吸収剤；チヌビン326／0.15PHR含有）に
いれ、45度の傾斜柵上に吊るし、20日間の耐光性
試験を行い、肉眼判定により色素の脱色を判定し
た。その際、以下に示すシヤンプー組成物の褪色
性を比較対照とした。
ラウリル硫酸トリエタノールアミン 20％
ラウリン酸ジエタノールアミド ３％
黄色４号 微量
精製水 バランス量（PH７）
〇：比較シヤンプー組成物と同程度の褪色
△：比較シヤンプー組成物よりやや褪色
×：比較シヤンプー組成物より褪色
実施例 １
第１表に示す組成のシヤンプー組成物を調製
し、露光試験を行つた。結果を第１表に示す。
[Industrial Application Field] The present invention relates to a shampoo composition containing an amidoamine type amphoteric surfactant and which does not cause discoloration or fading of the dye even when packaged in a transparent container. [Prior Art and its Problems] Amidoamine-type amphoteric active agents are widely used as components of shampoo compositions because they are hypoallergenic. However, shampoo compositions containing amidoamine type amphoteric active agents and dyes have the disadvantage that the dyes are unstable to light and change or fade during storage. In order to prevent this, conventional methods have been taken such as adding ultraviolet absorbers or antioxidants or making the container opaque. I couldn't do it. [Means for Solving the Problems] Under such circumstances, the inventors of the present invention have conducted intensive research and have surprisingly found that the ratio of amidoamine type activator to anionic activator is 1/1 to 1/3. The present invention was completed based on the discovery that a shampoo composition with excellent photostability of pigments can be obtained by using a surfactant and adding fatty acid esters as a pearlizing agent. That is, the present invention comprises the following components (A), (B) and (C) (A) (a) the following general formula () or () (In the formula, R 1 and R 3 each represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R 2 and R 4 represent -
CH 2 COOM or -CH 2 CH 2 COOM, R 5 is hydrogen, -CH 2 COOM or -CH 2 CH 2 COOM, M
(represents hydrogen, alkali metal or alkanolamine) and (b) an anionic surfactant at a weight ratio of 1/1 to 1/3. Contains surfactant. (B) The following general formula () R 6 COO− ((CH 2 ) o O) n −R 7 () [In the formula, R 6 is a saturated hydrocarbon group having 15 to 19 carbon atoms, and R 7 is hydrogen or R 6 CO− (R 6 is carbon number 15-19
(represents a saturated hydrocarbon group), n represents an integer of 2 to 4, and m represents an integer of 1 to 3. ) The present invention provides a shampoo composition characterized by containing an azo or xanthene water-soluble dye. In the surfactant component (A) of the present invention, preferred amidoamine type amphoteric surfactants (a) include N-lauroyl (or myristoyl, palmitoyl, etc.)-N'-(2-hydroxyethyl)ethylenediamine; N-lauroyl (or myristoyl, palmitoyl, etc.)-N'-carboxyethyl-
Those represented by the formula ( ) such as N'-(2-hydroxyethyl)ethylenediamine; and N-lauroyl (or myristoyl, palmitoyl, etc.)-
N-(2-hydroxyethyl)-N'-carboxymethylethylenediamine, N-lauroyl (or myristoyl, palmitoyl, etc.)-N-(2-hydroxyethyl)-N,N'-bis(carboxymethyl)ethylenediamine, N- Examples include those represented by the formula ( ), such as lauroyl (or myristoyl, palmitoyl, etc.)-N-(2-hydroxyethyl)-N,N'-bis(carboxyethyl)ethylenediamine. Furthermore, as the anionic activator (b), any anionic activator commonly used in shampoos can be used, but particularly preferred examples include:
Examples include sodium polyoxyethylene lauryl ether sulfate, polyoxyethylene lauryl ether triethanolamine sulfate, ammonium polyoxyethylene lauryl ether sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate. In the present invention, the surfactant as component (A) is a/
The proportion of b is 1/1 to 1/3, preferably 2/3 to 1/3 by weight.
It is necessary that the amount of (a) be 1/3, and if the amount of (a) is more than this, the water-soluble dye will discolor or fade, which is not preferable. The blending amount of such surfactant is 5 to 45% by weight of the total composition (hereinafter simply expressed as %),
Particularly preferred is 10 to 25%. Examples of the fatty acid ester of component (B) of the present invention include ethylene glycol monostearate, ethylene glycol distearate, triethylene glycol distearate, etc., and these account for 1 to 5%, preferably 2% of the total composition. ~4% is blended. Preferred examples of the water-soluble dye of component (C) include Yellow No. 4, Yellow No. 5, and Red No. 401. In addition to the above-mentioned essential ingredients, the shampoo composition of the present invention contains ingredients of known shampoo compositions, such as cationic active agents, nonionic active agents, solubilizers such as propylene glycol, glycerin, urea, etc. Viscosity modifiers such as alcohol, isopropyl alcohol, hydroxyethylcellulose, methylcellulose, propylmethylcellulose, and higher alcohols, fragrances, ultraviolet absorbers, antioxidants, preservatives, appearance modifiers, and the like can be added as necessary. The shampoo composition of the present invention having the above composition does not discolor or fade when exposed to light, so it can be filled and packaged in transparent containers. Any transparent container may be used, but especially vinyl chloride, polyethylene terephthalate, polyethylene, etc., and UV absorbers such as Tinuvin 326 and Tinuvin P at 0.15 PHR.
Those containing the following are preferred. [Effects of the Invention] As mentioned above, the shampoo composition of the present invention is stable against light and does not discolor or fade even if it is packaged in a transparent container and stored for a long period of time. It has the advantage of being able to be held beautifully. [Examples] Hereinafter, the present invention will be explained in detail with reference to Examples, but the present invention is not limited to these Examples. The test methods examined in the examples are as follows. Exposure test Shampoo composition was poured into a transparent bottle (Material: PVC,
They were placed in ultraviolet absorber (containing Tinuvin 326/0.15 PHR) and hung on a 45-degree inclined fence, and a light resistance test was conducted for 20 days, and decolorization of the pigment was determined by visual judgment. At that time, the fading properties of the following shampoo compositions were used as a comparison control. Lauryl sulfate triethanolamine 20% Lauric acid diethanolamide 3% Yellow No. 4 Micro-purified water Balance amount (PH7) 〇: Same degree of fading as the comparative shampoo composition △: Slightly fading than the comparative shampoo composition ×: Comparative shampoo composition More Fading Example 1 A shampoo composition having the composition shown in Table 1 was prepared and an exposure test was conducted. The results are shown in Table 1.
【表】
実施例 ２
第２表に示す組成のシヤンプー組成物を調製
し、露光試験を行つた。結果を第２表に示す。[Table] Example 2 A shampoo composition having the composition shown in Table 2 was prepared and an exposure test was conducted. The results are shown in Table 2.
【表】
実施例 ３
第３表に示す組成のシヤンプー組成物を調製
し、露光試験を行つた。結果を第３表に示す。[Table] Example 3 A shampoo composition having the composition shown in Table 3 was prepared and an exposure test was conducted. The results are shown in Table 3.
【表】【table】
【表】
実施例 ４
コンデイシヨニングシヤンプー組成物
Ｎ−ラウロイル−N′−カルボキシメチル−
N′−（２−ヒドロキシエチル）エチレンジアミ
ン（トリエタノールアミン） ６重量％
ポオキシエチレンラウリルエーテル硫酸トリエ
タノールアミン 12
ラウリン酸ジエタノールアミド ３
カチオン性ポリマー（ポリマーJR−400：UCC
社製） 0.5
エチレングリコールジステアレート ２
防腐剤 0.1
香 料 0.4
赤色504 微量
精製水 全100バランス
実施例 ５
抗フケシヤンプー組成物
Ｎ−ラウロイル−N′−カルボキシメチル−
N′−（２−ヒドロキシエチル）エチレンジアミ
ントリエタノール ３重量％
ポリオキシエチレンラウリルエーテル硫酸トリ
エタノールアミン 20
ラウリン酸ジエタノールアミド ３
ピラクトンオーラミン（オクトピロツクス）
0.5
エチレングリコールジステアレート ２
防腐剤 0.1
香 料 0.4
赤色106号 微量
精製水 全100バランス[Table] Example 4 Conditioning shampoo composition N-lauroyl-N'-carboxymethyl-
N'-(2-hydroxyethyl)ethylenediamine (triethanolamine) 6% by weight Polyoxyethylene lauryl ether sulfate triethanolamine 12 Lauric acid diethanolamide 3 Cationic polymer (Polymer JR-400: UCC
) 0.5 Ethylene glycol distearate 2 Preservative 0.1 Fragrance 0.4 Red 504 Micro-purified water Total 100 Balance Example 5 Anti-dandruff shampoo composition N-lauroyl-N'-carboxymethyl-
N'-(2-hydroxyethyl)ethylenediamine triethanol 3% by weight Polyoxyethylene lauryl ether sulfate triethanolamine 20 Lauric acid diethanolamide 3 Piractone auramine (Octopirox)
0.5 Ethylene glycol distearate 2 Preservative 0.1 Flavor 0.4 Red No. 106 Micro-purified water Total 100 balance
Claims (1)
又は不飽和炭化水素基を、R2及びR4は−
CH2COOM又は−CH2CH2COOMを、R5は水
素、−CH2COOM又は−CH2CH2COOMを、Ｍ
は水素、アルカリ金属又はアルカノールアミン
を示す） で表わされるアミドアミン型両性活性剤の１種
又は２種以上及び(b)アニオン性活性剤をａ／ｂ
が重量比で1/1〜1/3になるように含有する界面
活性剤、 (B) 次の一般式（） R6COO−（（CH2）oＯ）n−R7 （） 〔式中、R6は炭素数15〜19の飽和炭化水素基
を、R7は水素又はR8CO−（R8は炭素数15〜19
の飽和炭化水素基を示す）を、ｎは２〜４の整
数を、ｍは１〜３の整数を示す〕 で表わされる脂肪酸エステルの１種又は２種以
上を１〜５重量％、 (C) アゾ系又はキサンテン系水溶性染料 を含有することを特徴とするシヤンプー組成物。[Claims] 1. The following components (A), (B) and (C) (A) (a) The following general formula () or () (In the formula, R 1 and R 3 each represent a saturated or unsaturated hydrocarbon group having 7 to 19 carbon atoms, and R 2 and R 4 represent -
CH 2 COOM or -CH 2 CH 2 COOM, R 5 is hydrogen, -CH 2 COOM or -CH 2 CH 2 COOM, M
represents hydrogen, an alkali metal or an alkanolamine) and (b) an anionic surfactant.
(B) The following general formula () R 6 COO− ((CH 2 ) o O) n −R 7 () [Formula Among them, R 6 is a saturated hydrocarbon group having 15 to 19 carbon atoms, R 7 is hydrogen or R 8 CO− (R 8 is a saturated hydrocarbon group having 15 to 19 carbon atoms,
(represents a saturated hydrocarbon group), n represents an integer of 2 to 4, and m represents an integer of 1 to 3. ) A shampoo composition characterized by containing an azo or xanthene water-soluble dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30720387A JPH01149709A (en) | 1987-12-04 | 1987-12-04 | Shampoo composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30720387A JPH01149709A (en) | 1987-12-04 | 1987-12-04 | Shampoo composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01149709A JPH01149709A (en) | 1989-06-12 |
| JPH0349888B2 true JPH0349888B2 (en) | 1991-07-31 |
Family
ID=17966281
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30720387A Granted JPH01149709A (en) | 1987-12-04 | 1987-12-04 | Shampoo composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01149709A (en) |
-
1987
- 1987-12-04 JP JP30720387A patent/JPH01149709A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01149709A (en) | 1989-06-12 |
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