JPH0345130B2 - - Google Patents

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Publication number
JPH0345130B2
JPH0345130B2 JP60228881A JP22888185A JPH0345130B2 JP H0345130 B2 JPH0345130 B2 JP H0345130B2 JP 60228881 A JP60228881 A JP 60228881A JP 22888185 A JP22888185 A JP 22888185A JP H0345130 B2 JPH0345130 B2 JP H0345130B2
Authority
JP
Japan
Prior art keywords
fibers
fiber
flame
retardant
wool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP60228881A
Other languages
Japanese (ja)
Other versions
JPS6290349A (en
Inventor
Masao Hironaka
Yoshikatsu Kato
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Keori KK
Original Assignee
Nippon Keori KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Keori KK filed Critical Nippon Keori KK
Priority to JP60228881A priority Critical patent/JPS6290349A/en
Publication of JPS6290349A publication Critical patent/JPS6290349A/en
Publication of JPH0345130B2 publication Critical patent/JPH0345130B2/ja
Granted legal-status Critical Current

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  • Woven Fabrics (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

[産業上の利用分野] 本発明は、航空機用シートクツシヨンのフアイ
ヤーブロツキングレイヤー等に適した防火繊維布
に関する。 [従来の技術] 航空機用シートクツシヨンの表の椅子張地と難
燃ウレタンフオームの中間層として使用されるフ
アイヤーブロツキングレイヤーとしてこれまでに
提案されたものは、顕著な耐炎性を示すポリベン
ズイミダゾール繊維[商品名PBI]とメタ型芳香
族ポリアミド繊維[商品名コーネツクス(登録商
標)、ノメツクス(登録商標)]やパラ型芳香族ポ
リアミド繊維[アラミド繊維、商品名ケブラー
(登録商標)]と他の合成繊維、例えば炭化繊維
[商品名パイロメツクス(登録商標)]とを混合し
たものであつた。しかし、これらの合成繊維のみ
よりなるものは、天然繊維のものに比べると、原
料コストが高く又吸湿性に欠けるため、座り心地
等の快適性に劣ることはさけられなかつた。そこ
で、熱遮断性、コスト、快適性の点から、羊毛を
チタニウム又はジルコニウムの金属錯塩で処理し
たザプロ(登録商標)羊毛(以下防炎処理羊毛と
呼ぶ)とガラス繊維を混合し、その裏面にアルミ
箔を添着したものや、防炎処理羊毛にポリベンズ
イミダゾール繊維又は炭化繊維を混合したものも
提案されている。 [発明が解決しようとする課題] 航空機用シートクツシヨンは、激しいFAAケ
ロシンバーナテスト(FAR.25853C)に耐えるも
のでなくてはならないが、経済性も考慮する必要
があることはいうまでもない。顕著な防火性を示
すポリベンズイミダゾール繊維は非常に高価であ
るから、これを成分とするものは経済性の点で問
題がある。ポリベンズイミダゾール繊維程ではな
いにしても、芳香族ポリアミド繊維も比較的高価
であるから、これを主成分としたものはやはり経
済的に問題がある。炭化繊維やガラス繊維は価格
の点で問題はないが、他の繊維に比較すると加工
性がよくないという問題がある。又、アルミ箔を
添着したものは、こわばつて、快適性が損なわ
れ、又、使用時に不快な音を発生するという問題
がある。 本発明は上記問題を解決するためになされたも
のであり、その目的とするところは、着用感ない
し使用感が快適であると共に、比較的安価で経済
性があり、その上、優れた繊維布特性を具備しな
がら航空機用シートクツシヨンを構成するフアイ
ヤーブロツキングレイヤーとしても使用すること
ができる防火性を備えた繊維布を提供することに
ある。 [問題点を解決するための手段] 前記目的を達成するため本発明の繊維布は、防
炎処理羊毛40〜70重量%を含み、残りはフエノー
ル樹脂繊維と、芳香族ポリアミド繊維とからなる
ことを特徴とする。その繊維布はフエルトでも織
布でもよいが、織布の場合は、緩和や縮絨により
糸間の空隙を埋めておくことが望ましい。 ここで、防炎処理羊毛を混合する理由は、火炎
暴露前すなわち通常使用時においては、防炎処理
羊毛の天然繊維としての良好な風合と着用性を、
火炎暴露時においては防炎処理羊毛の嵩高で熱遮
断性の炭化層生成能をそれぞれ利用することにあ
る。 防炎処理羊毛は羊毛をチタニウム又はジルコニ
ウム金属錯塩処理したものであり、防炎性、低発
煙性があり、接炎しても溶融せずに炭化層を生成
するが、羊毛としての快適性すなわち、吸湿性、
温度調節機能、保温性、風合等はほとんど損なわ
れずに保持している。又、顕著な防火耐熱性を示
す合成樹脂、例えば、ポリベンズイミダゾール繊
維、パラ型芳香族ポリアミド繊維に比べると著し
く安価であるから経済的でもある。防炎処理羊毛
の混入量を40%以下にすると、通常使用時の快適
性と火炎暴露時の熱遮断性が低下するため、40%
が混入率の下限である。逆に、防炎処理羊毛を70
%以上混入すると、先に述べたFAAケロシンバ
ーナテストに合格しないおそれがあるので、70%
を上限とする。 フエノール樹脂繊維を混入する理由は、通常使
用時においては、炭素含有量が多いが、炭素繊維
のように折損、汚れなどの問題がなく、比較的良
好な繊維特性を示すこと、火炎暴露時において
は、発煙やガス発生が少なく、寸法変化を伴わず
に炭素繊維化(炭素化率約80%)して、嵩高で方
向性がなく、外力により比較的こわれやすい防炎
処理羊毛炭化層を保持することにある。混入量が
15%以下になると、防炎処理羊毛炭化層保護の効
果が期待できなくなるので、下限は15%とする。
しかし、40%以上になると、フエノール樹脂繊維
特有のパンキング(酸化発熱)を発生するおそれ
があり、又、耐光堅牢度も著しく低下するので、
上限は40%とする。 芳香族ポリアミド繊維を混入する理由は、通常
使用時においてはフエノール樹脂繊維の混入を伴
う強力と糸特性の低下を補い、十分な強度と耐摩
耗性を得ることにあり、火炎暴露時において、フ
エノール樹脂繊維と同様に寸法変化のない比較的
形状安定性のよい炭化繊維として防炎処理羊毛炭
化層を保護することにある。その混入量が15%以
下になると、十分な強度と耐摩耗性が得られない
ので、15%を下限とする。しかし、芳香族ポリア
ミド繊維は他の二者に比べて高価であり、又、火
炎暴露時に生成する炭素繊維の耐熱性はフエノー
ル樹脂繊維よりも劣るので、上限は30%とする。 なお、芳香族ポリアミド繊維のメタ型のものは
パラ型のものより耐熱性が低く、又、火炎暴露時
に収縮するため、シートクツシヨンのフアイヤブ
ロツキングレイヤーに使用した場合、接炎すると
形状安定性と炭化層の保持力が十分でなく、パラ
型に比較して防熱性が劣り、場合によつては開裂
や繊維間の隙が多くなり、内部の溶融したウレタ
ンが滴下するおそれがある。したがつて、芳香族
ポリアミド繊維はパラ型を使用することが望まし
い。 [作用] 本発明の防火繊維布は防炎処理羊毛、フエノー
ル樹脂繊維、芳香族ポリアミド繊維からなる複合
素材であるから、混合作用により、各繊維単独の
ものよりも、布としての寸法変化や変形が少な
い。通常の使用時において、本発明の繊維布は天
然繊維としての防炎処理羊毛を70〜40%含むた
め、着心地ないし座り心地は非常に快適である。
又、強力な芳香族ポリアミド繊維を15〜30%含む
ため、十分な強度と耐摩耗性を有する。 接炎時においては、混入されている繊維はいず
れも低発煙性でガスの発生もわずかで、接炎によ
り溶融することなく炭化に至るため、重量損失も
全体として少ない。防炎処理羊毛に添着している
フエノール樹脂繊維と芳香族ポリアミド繊維が炭
化繊維を生成して、熱遮断性に富む嵩高な多量の
防炎処理羊毛炭化層を捕捉して保護するから、全
体としてまとまり、崩れることはない。防炎処理
羊毛の炭化層は比較的充実しているから、内部の
溶融したウレタンホームが防火繊維布を透過する
ことは困難である。したがつて、溶融ウレタンホ
ームの滴下は軽減される。 [発明の効果] 本発明の防火繊維布は天然繊維の特性を保持す
る防炎処理羊毛が主成分であるため、従来の合成
繊維を主成分とするものに比べると、着用性ない
し使用感が良好であり、必要な強度と耐摩耗性は
防炎処理羊毛により得られるが、15〜30%混入さ
れた芳香族ポリアミド繊維によりさらに補強され
る。又、防炎処理羊毛は他の耐熱性繊維に比べる
と比較的安価であるから、経済的にも優れてい
る。防炎処理羊毛は火炎暴露時に嵩高で熱遮断性
に富む方向性のない炭化層を生成するが、反面、
外力に比較的もろい。しかし、その炭化層は火炎
暴露時に変形しない炭素繊維を生成するフエノー
ル樹脂繊維により保護されるから、繊維布は形崩
れも開裂も発生することなく、厳しいFAAケロ
シンバーナテストにも耐える卓抜した防火効果を
有する。 [実施例] 本発明の繊維布を実施例に基づいて説明する。
先ず、羊毛をチタニウム又はジルコニウムの錯塩
化合物で処理して得られた防炎処理羊毛と、3デ
ニール繊維長50〜70mmのフエノール樹脂繊維[商
品名カイノール(登録商標)]と、1.5デニールカ
ツト長2インチのパラ型芳香族ポリアミド繊維
[商品名ケブラー(登録商標)29]を混合し、梳
毛紡績又は紡毛紡績により製糸し、防炎処理羊毛
50%(フエノール樹脂繊維30%、パラ型芳香族ポ
リアミド繊維20%)及び防炎処理羊毛60%(フエ
ノール樹脂繊維20%、パラ型芳香族ポリアミド繊
維20%)の二種類の混紡糸とした。この中の防炎
処理羊毛50%混紡糸の一部には100デニールのガ
ラスフイラメントを交撚した。各混紡糸を製織し
整理工程において縮絨処理を施した。又、防炎処
理羊毛50%混紡糸織物及び、防炎処理羊毛50%ガ
ラス繊維フイラメント混紡交撚糸織物の一部には
裏面に耐熱性樹脂[商品名パイロキープ(登録商
標)]をコートした。このようにして、4種類の
テスト布を作成した。 これらのテスト布は、防炎処理羊毛を主成分と
するため、風合がよく使い心地は快適である。し
かし、極めて難染性の耐熱性フエノール樹脂繊維
とパラ型芳香族ポリアミド繊維を相当量含むた
め、表地には不向きであるが、裏地、特に航空機
用椅子張地の下に使用するフアイヤブロツキング
レイヤーとしては、座り心地、耐摩耗性、強度の
点だけでなく、防火性能の点においても最適であ
るといえる。 これらのテスト布に低発煙性防炎処理羊毛100
%の表地(目付470g/m2)と航空機用難燃ポリ
ウレタンを組合せて航空機用シートクツシヨンと
し、FAA規格ケロシンバーナテストを行つた。
その結果は次表に示すとおりである。この表は、
本発明の防火繊維布がケロシンバーナテストに合
格し得ることを示す。
[Industrial Application Field] The present invention relates to a fireproof fiber cloth suitable for a fire blocking layer of an aircraft seat cushion. [Prior Art] Fire-blocking layers that have been proposed so far for use as an intermediate layer between the front upholstery of aircraft seat cushions and flame-retardant urethane foam have shown remarkable flame resistance. Polybenzimidazole fiber [trade name PBI], meta aromatic polyamide fiber [trade name Konex (registered trademark), Nomex (registered trademark)] and para aromatic polyamide fiber [aramid fiber, trade name Kevlar (registered trademark)] and other synthetic fibers, such as carbonized fiber [trade name: Pyromex (registered trademark)]. However, compared to those made of natural fibers, these synthetic fibers have higher raw material costs and lack hygroscopicity, so they are inevitably inferior in comfort such as sitting comfort. Therefore, from the standpoint of heat insulation, cost, and comfort, we mixed Zapro (registered trademark) wool (hereinafter referred to as flame-retardant treated wool), which is made by treating wool with metal complex salts of titanium or zirconium, with glass fiber, and added There have also been proposals that include aluminum foil attached and flame-retardant wool mixed with polybenzimidazole fibers or carbonized fibers. [Problem to be solved by the invention] Aircraft seat cushions must be able to withstand the rigorous FAA kerosene burner test (FAR.25853C), but it goes without saying that economic efficiency must also be considered. . Polybenzimidazole fibers that exhibit remarkable fire retardant properties are very expensive, so products containing this fiber as a component have problems in terms of economic efficiency. Aromatic polyamide fibers are also relatively expensive, although not as expensive as polybenzimidazole fibers, so products containing this as the main component are still economically problematic. Carbonized fibers and glass fibers have no problem in terms of price, but they have a problem in that they are not easy to process compared to other fibers. In addition, those with aluminum foil attached thereto have problems in that they are stiff, impair comfort, and generate unpleasant sounds when used. The present invention has been made in order to solve the above problems, and its purpose is to provide a fabric that is comfortable to wear or use, is relatively inexpensive and economical, and is also an excellent fiber fabric. It is an object of the present invention to provide a fiber cloth having fire retardant properties and which can also be used as a fire blocking layer constituting an aircraft seat cushion. [Means for Solving the Problems] In order to achieve the above object, the fiber cloth of the present invention contains 40 to 70% by weight of flame-retardant wool, and the remainder consists of phenolic resin fibers and aromatic polyamide fibers. It is characterized by The fiber cloth may be felt or a woven cloth, but in the case of a woven cloth, it is desirable to fill the voids between the yarns by relaxing or shrinking. Here, the reason why flame-retardant treated wool is mixed is that before exposure to flame, that is, during normal use, the flame-retardant treated wool has good texture and wearability as a natural fiber.
The aim is to take advantage of the ability of fire-retardant wool to form a bulky, heat-insulating carbonized layer when exposed to flame. Flame-retardant treated wool is wool treated with titanium or zirconium metal complex salts, and has flame-retardant properties and low smoke-emitting properties, and does not melt even when exposed to flames, producing a carbonized layer. , hygroscopic,
The temperature control function, heat retention, texture, etc. are maintained with almost no loss. Furthermore, it is economical because it is significantly cheaper than synthetic resins that exhibit remarkable fire and heat resistance properties, such as polybenzimidazole fibers and para-aromatic polyamide fibers. If the amount of flame-retardant wool mixed in is less than 40%, the comfort during normal use and the heat insulation property when exposed to flame will decrease.
is the lower limit of the contamination rate. On the other hand, flame-retardant treated wool is 70
If it is mixed with more than 70%, there is a risk that it will not pass the FAA kerosene burner test mentioned earlier.
is the upper limit. The reason for mixing phenolic resin fibers is that although they have a high carbon content during normal use, they do not have problems such as breakage or staining unlike carbon fibers, and exhibit relatively good fiber properties, and when exposed to flame. produces less smoke and gas, and is made into carbon fiber (carbonization rate approximately 80%) without dimensional changes, and retains a flame-retardant carbonized wool layer that is bulky, has no directionality, and is relatively easily broken by external forces. It's about doing. The amount of contamination
If it is less than 15%, the effect of protecting the carbonized layer of flame-retardant wool cannot be expected, so the lower limit is set at 15%.
However, if it exceeds 40%, there is a risk of puncturing (oxidation heat generation) characteristic of phenolic resin fibers, and the light fastness will also decrease significantly.
The upper limit is 40%. The reason for mixing aromatic polyamide fibers is to compensate for the decrease in strength and yarn properties that accompanies the mixing of phenolic resin fibers during normal use, and to obtain sufficient strength and abrasion resistance. The objective is to protect the flame-retardant carbonized wool layer as a carbonized fiber that does not change in size and has relatively good shape stability like resin fibers. If the mixed amount is less than 15%, sufficient strength and wear resistance cannot be obtained, so 15% is set as the lower limit. However, aromatic polyamide fibers are more expensive than the other two, and the heat resistance of carbon fibers produced when exposed to flame is inferior to that of phenolic resin fibers, so the upper limit is set at 30%. Note that meta-type aromatic polyamide fibers have lower heat resistance than para-type fibers, and also shrink when exposed to flame, so when used in the fire-blocking layer of a sheet cushion, the shape becomes stable when exposed to flame. The heat resistance is poorer than that of the para-type, and in some cases there may be more cleavage or gaps between the fibers, which may cause the molten urethane inside to drip. Therefore, it is desirable to use para-type aromatic polyamide fibers. [Function] Since the fire-retardant fiber cloth of the present invention is a composite material consisting of flame-retardant treated wool, phenolic resin fibers, and aromatic polyamide fibers, due to the mixing action, the fabric is more susceptible to dimensional changes and deformation than each fiber alone. Less is. During normal use, the fiber fabric of the present invention contains 70 to 40% of flame-retardant wool as a natural fiber, so it is very comfortable to wear or sit on.
In addition, it contains 15-30% strong aromatic polyamide fibers, so it has sufficient strength and wear resistance. When exposed to flame, all of the mixed fibers have low smoke emitting properties and generate only a small amount of gas, and the fibers are carbonized without being melted by flame exposure, resulting in less overall weight loss. The phenolic resin fibers and aromatic polyamide fibers attached to the flame-retardant wool generate carbonized fibers that capture and protect the bulky carbonized layer of the flame-retardant wool, which has excellent heat-insulating properties. It stays together and doesn't fall apart. Since the carbonized layer of flame-retardant wool is relatively thick, it is difficult for the molten urethane foam inside to penetrate through the fire-retardant fiber cloth. Therefore, dripping of molten urethane foam is reduced. [Effects of the Invention] Since the fire-retardant fiber cloth of the present invention is mainly composed of flame-retardant treated wool that retains the characteristics of natural fibers, it is easier to wear and feel when used than conventional cloths whose main component is synthetic fibers. Good, necessary strength and abrasion resistance are obtained by flame-retardant wool, which is further reinforced by aromatic polyamide fibers mixed in at 15-30%. Furthermore, since flame-retardant treated wool is relatively inexpensive compared to other heat-resistant fibers, it is economically superior. When flame-retardant treated wool is exposed to flame, it forms a bulky, non-directional carbonized layer with excellent heat-insulating properties, but on the other hand,
Relatively fragile to external forces. However, because the carbonized layer is protected by phenolic resin fibers that produce carbon fibers that do not deform when exposed to flame, the fiber fabric does not lose its shape or tear, and has excellent fire protection properties that can withstand the rigorous FAA kerosene burner test. has. [Example] The fiber cloth of the present invention will be explained based on an example.
First, flame-retardant wool obtained by treating wool with a complex salt compound of titanium or zirconium, a phenolic resin fiber with a 3-denier fiber length of 50 to 70 mm [trade name Kynol (registered trademark)], and a 1.5-denier cut length 2 Para-type aromatic polyamide fiber [trade name Kevlar (registered trademark) 29] of 1.5 inches is mixed and spun by worsted spinning or wool spinning to produce flame-retardant wool.
Two types of blended yarns were made: 50% (phenolic resin fiber 30%, para-type aromatic polyamide fiber 20%) and flame-retardant treated wool 60% (phenolic resin fiber 20%, para-type aromatic polyamide fiber 20%). A portion of the 50% flame-retardant wool blend yarn was twisted with 100-denier glass filaments. Each blended yarn was woven and subjected to a fulling process in the organizing process. In addition, a part of the flame-retardant treated wool 50% blend yarn fabric and the flame-retardant treated wool 50% glass fiber filament blend intertwisted yarn fabric was coated with a heat-resistant resin [trade name: PyroKeep (registered trademark)] on the back side. In this way, four types of test cloths were created. These test fabrics are mainly made of flame-retardant wool, so they have a good texture and are comfortable to use. However, since it contains a considerable amount of extremely dye-resistant heat-resistant phenolic resin fibers and para-type aromatic polyamide fibers, it is unsuitable for outer fabrics, but fire blocking is used for linings, especially under aircraft seat upholstery. As a layer, it can be said to be optimal not only in terms of comfort, wear resistance, and strength, but also in terms of fire protection performance. These test fabrics are coated with low smoke flame retardant wool 100%
An aircraft seat cushion was made by combining a 200% outer material (with a basis weight of 470 g/m 2 ) and flame-retardant polyurethane for aircraft, and an FAA standard kerosene burner test was conducted.
The results are shown in the table below. This table is
It is shown that the fire retardant fabric of the present invention can pass the kerosene burner test.

【表】【table】

【表】【table】

Claims (1)

【特許請求の範囲】 1 フエノール樹脂繊維と芳香族ポリアミド繊維
を合計で30〜60%重量含み、残部がチタニウム又
はジルコニウムの金属錯塩で処理された羊毛から
なる混合繊維を製布してなる繊維布において、前
記フエノール樹脂繊維の混合率を15〜40重量%
に、前記芳香族ポリアミド繊維の混合率を15〜30
重量%にしたことを特徴とする防火繊維布。 2 混合繊維から製糸した混紡糸を製織して製布
したことを特徴とする特許請求の範囲第1項記載
の防火繊維布。 3 混紡糸にガラス繊維フイラメントを交撚した
混紡交撚糸から製織されたことを特徴とする特許
請求の範囲第2項記載の防火繊維布。 4 裏面が耐熱性樹脂で被覆されたことを特徴と
する特許請求の範囲第1項記載の防火繊維布。 5 芳香族ポリアミド繊維はパラ型であることを
特徴とする特許請求の範囲第1項記載の防火繊維
布。
[Scope of Claims] 1. A fiber cloth made from a mixed fiber containing 30 to 60% by weight of phenolic resin fibers and aromatic polyamide fibers, with the remainder being wool treated with a metal complex salt of titanium or zirconium. , the mixing ratio of the phenolic resin fibers is 15 to 40% by weight.
The mixing ratio of the aromatic polyamide fiber is 15 to 30.
A fire-retardant fiber cloth characterized by weight percent. 2. The fireproof fiber cloth according to claim 1, which is made by weaving a blended yarn spun from mixed fibers. 3. The fire-retardant fiber cloth according to claim 2, which is woven from a mixed twisted yarn obtained by twisting a mixed yarn with glass fiber filaments. 4. The fireproof fiber cloth according to claim 1, wherein the back surface is coated with a heat-resistant resin. 5. The fireproof fiber cloth according to claim 1, wherein the aromatic polyamide fiber is of a para-type.
JP60228881A 1985-10-16 1985-10-16 Fire-proof fiber cloth Granted JPS6290349A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60228881A JPS6290349A (en) 1985-10-16 1985-10-16 Fire-proof fiber cloth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60228881A JPS6290349A (en) 1985-10-16 1985-10-16 Fire-proof fiber cloth

Publications (2)

Publication Number Publication Date
JPS6290349A JPS6290349A (en) 1987-04-24
JPH0345130B2 true JPH0345130B2 (en) 1991-07-10

Family

ID=16883324

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60228881A Granted JPS6290349A (en) 1985-10-16 1985-10-16 Fire-proof fiber cloth

Country Status (1)

Country Link
JP (1) JPS6290349A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4900613A (en) * 1987-09-04 1990-02-13 E. I. Du Pont De Nemours And Co. Comfortable fabrics of high durability
JP2562953B2 (en) * 1988-09-02 1996-12-11 シルバー株式会社 Heat-resistant material for wicks for combustion appliances
JPH0268326A (en) * 1988-09-02 1990-03-07 Silver Kogyo Kk Heat-resistant sewing thread
JPH03199448A (en) * 1989-12-27 1991-08-30 J F Corp:Kk Ceramic-containing knitted fabric and production thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60155445A (en) * 1984-01-26 1985-08-15 日本毛織株式会社 Special cloth

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60155445A (en) * 1984-01-26 1985-08-15 日本毛織株式会社 Special cloth

Also Published As

Publication number Publication date
JPS6290349A (en) 1987-04-24

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