JPH0342186A - Electric resistance welding electrode - Google Patents

Electric resistance welding electrode

Info

Publication number
JPH0342186A
JPH0342186A JP17776089A JP17776089A JPH0342186A JP H0342186 A JPH0342186 A JP H0342186A JP 17776089 A JP17776089 A JP 17776089A JP 17776089 A JP17776089 A JP 17776089A JP H0342186 A JPH0342186 A JP H0342186A
Authority
JP
Japan
Prior art keywords
electrode
film
welding
metal
pure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17776089A
Other languages
Japanese (ja)
Inventor
Shigechika Kosuge
小菅 茂義
Makoto Kabasawa
樺沢 真事
Yasunori Matsuda
松田 恭典
Yukio Shinpo
幸雄 真保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Engineering Corp
Original Assignee
NKK Corp
Nippon Kokan Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NKK Corp, Nippon Kokan Ltd filed Critical NKK Corp
Priority to JP17776089A priority Critical patent/JPH0342186A/en
Publication of JPH0342186A publication Critical patent/JPH0342186A/en
Pending legal-status Critical Current

Links

Landscapes

  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

PURPOSE:To obtain an electrode for welding galvanized steel sheets having the long service life by forming a metallic film having high hardness at the high temperature and low reactivity with Zn on the surface of the electrode base material tip made of a Cu-base alloy. CONSTITUTION:The metallic film 3 having high hardness at the high tempera ture and low reactivity with Zn is formed on the surface of the electrode base material tip 1 made of the Cu-base alloy. In addition, a film 4 made of pure Cu-base metal is formed and further, the film 3 made of the metal having high hardness at the high temperature and low reactivity with Zn is formed on the above-mentioned pure Cu film surface to form the welding electrode. The above- mentioned metal is one of W, Mo and a Mo alloy and the above-mentioned metal film has 50 - 500 mum thickness. By this method, in the case of welding the galvanized steel sheets, the electric resistance welding electrode showing the very long service life can be obtained.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、Zn、 Zn合金めっき鋼板用の電気抵抗
溶接用電極に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an electrode for electric resistance welding for Zn or Zn alloy plated steel sheets.

〔従来の技術〕[Conventional technology]

スポント溶接等、電気抵抗)6接用電極は、被溶接物に
溶接電流を供給することと、その部分に必要な加圧力を
伝達することを目的とする。従って、前記電極において
は、溶接に必要な大電流を溶接個所に集中させる必要か
ら、これに耐える良導電性と形状および)容接中の加圧
力に対抗する高温硬さ、さらに先端の冷却を高める良熱
伝導性が必要である。
The purpose of the grounding electrode (for spont welding, etc.) is to supply welding current to the object to be welded and to transmit the necessary pressing force to that part. Therefore, in order to concentrate the large current required for welding at the welding point, the electrode must have good conductivity and shape to withstand this, high temperature hardness to withstand the pressure during welding, and cooling of the tip. Good thermal conductivity is required.

第3図は、JISに規格されたC型(円錐台型)電極に
よってスポント溶接を行なう場合の1例を示す説明図で
ある。図面において、2は電極、5は被溶接材である。
FIG. 3 is an explanatory diagram showing an example of spot welding using a C-type (truncated cone-shaped) electrode standardized by JIS. In the drawings, 2 is an electrode, and 5 is a material to be welded.

このような電極材料には、電気および熱の良導体である
と同時に、高温において硬いことが要求されるが、両特
性は、一般に相反する性質があるので、用途によってそ
の材料は適宜選択されているが、一般に、Cr −Cu
合金、AlxOx分散Cu合金等の、Cuベースの金属
が使用されている。
Such electrode materials are required to be good electrical and thermal conductors as well as being hard at high temperatures, but since these two properties are generally contradictory, the material must be selected appropriately depending on the application. However, in general, Cr-Cu
Cu-based metals have been used, such as alloys, AlxOx dispersed Cu alloys.

〔発明が解決しようとする課題] 上述したCuベースの電極を使用して、Zn、 Zn合
金めっき防錆鋼板(以下’Znめっき鋼板」という)を
電気抵抗溶接によって溶接する場合において、CuとZ
nの反応によって、電極先端の拡大、変形が生じ、溶接
品質の早期低下を招(問題がある。
[Problems to be Solved by the Invention] When welding Zn and Zn alloy-plated anticorrosive steel sheets (hereinafter referred to as 'Zn-plated steel sheets') by electric resistance welding using the above-mentioned Cu-based electrode, Cu and Z
The reaction of n causes expansion and deformation of the electrode tip, leading to early deterioration of welding quality (problematic).

このため、Znとの反応性が小さく、しかも、前述した
良導体であるための低抵抗化および高温での高い硬さを
実現することができる電気抵抗溶接用電極が望まれてお
り、従来から、下記の電極が提案されている。
For this reason, there is a demand for an electric resistance welding electrode that has low reactivity with Zn and can achieve low resistance and high hardness at high temperatures due to its good conductivity as described above. The following electrodes have been proposed.

■ Cuベースの電極基材先端の表面に、Ni、 Co
■ Ni and Co are added to the surface of the tip of the Cu-based electrode base material.
.

Feを電気めっきすることによって、電極基材の表面を
コーティングした電極。
An electrode whose surface is coated with an electrode base material by electroplating Fe.

この電極は、コーティングしたNi、 Co、 Fcと
Znとの反応性がCuよりも小さいものの、全< Zn
と反応しないというわけではなく、また、高温での硬さ
も不足している問題がある。
Although the reactivity of coated Ni, Co, and Fc with Zn is lower than that of Cu, total < Zn
This does not mean that it does not react with other materials, but it also has the problem of insufficient hardness at high temperatures.

■ Cuヘースの電極基材先端の表面に、TiN  (
チタンナイトライド)等の低電気抵抗、且つ、高mでの
高い硬さを有するセラミックスをイオンブレーティング
等によってコーティングした電極。
■ TiN (
An electrode coated with a ceramic material such as titanium nitride (titanium nitride) that has low electrical resistance and high hardness at high m by ion blating or the like.

この電極においては、コーティングされたセラミックス
は良導体であり、且つ、Znと反応しない。
In this electrode, the coated ceramic is a good conductor and does not react with Zn.

しかしながらセラミックス材料は高価でありまた、イオ
ンブレーティング加工はコストが高く、しかも、セラミ
ックス皮膜は剥離しやすいという問題がある。
However, there are problems in that ceramic materials are expensive, ion-blating processing is expensive, and the ceramic film is easy to peel off.

■ Znと反応しに<<、Feよりも電気抵抗の少ない
W、MoあるいはMoを98w t 、 Z以上含有す
る10合金(以下rMo合金」という)等の金属を第4
図に示すように、Cuベースの電極基材先端に埋設した
電極。第4図において、1は電極基材、6は埋設された
金属である。
■ Metals such as W, Mo, or 10 alloys containing Z or more (hereinafter referred to as rMo alloys) containing 98 wt or more of Mo, which react with Zn and have lower electrical resistance than Fe, are used as the fourth metal.
As shown in the figure, an electrode embedded in the tip of a Cu-based electrode base material. In FIG. 4, 1 is an electrode base material, and 6 is a buried metal.

この電極においては、埋設された金属に厚みがあるので
、電気抵抗が大きくなり、連Vt溶接時に埋設された金
属と口板とが溶着する問題が生じる。
In this electrode, since the buried metal is thick, the electrical resistance becomes large, causing a problem that the buried metal and the mouth plate are welded together during continuous Vt welding.

従って、この発明の目的は、Znめっき鋼板の溶接にお
いて、上述の問題点を解決し、さらに、低電気抵抗、且
つ、高温での高い硬さを有する、電気抵抗溶接用電極を
提供することにある。
Therefore, an object of the present invention is to solve the above-mentioned problems in welding Zn-plated steel sheets, and to provide an electrode for electric resistance welding that has low electric resistance and high hardness at high temperatures. be.

〔課題を解決するための手段〕[Means to solve the problem]

この発明の要旨は、下記からなっている。 The gist of this invention consists of the following.

■ Cu系合金からなる電極基材先端の表面に、高温で
の硬さが高く、しかも、Znとの反応性が小さい金属か
らなる皮膜が形成されていることを特徴とする電気抵抗
)6接用電極。
■Electrical resistance) 6 contact, characterized by the fact that a film made of a metal that is highly hard at high temperatures and has low reactivity with Zn is formed on the surface of the tip of the electrode base material made of a Cu-based alloy. electrode.

■ Cu系金属からなる′:rL極基材先、瑞の表面に
、純Cuからなる皮膜が形成され、さらに、前記純Cu
からなる皮膜の表面に、:質屋での硬さが高く、しかも
、Znとの反応性が小さい金属からなる皮膜が形成され
ていることを特徴とする電気抵抗溶接用電極。
■ A film made of pure Cu is formed on the tip of the rL electrode base material made of Cu-based metal, and on the surface of the rust, and furthermore, the pure Cu
An electric resistance welding electrode characterized in that a film made of a metal having high hardness at a pawn shop and low reactivity with Zn is formed on the surface of the film.

次に、この発明を図面を参照しながら説明する。Next, the present invention will be explained with reference to the drawings.

第1図は、第1の発明を示す断面図である。第1図に示
すように、Cu系金属からなる電pi 基材1の先端の
表面には、金属皮膜3が形成されている。
FIG. 1 is a sectional view showing the first invention. As shown in FIG. 1, a metal film 3 is formed on the surface of the tip of an electric pi base material 1 made of a Cu-based metal.

金属皮膜3としては、高温での硬さが著しく高く、且つ
、Znとの反応性が・IXさい金属、即ち、W、M。
As the metal film 3, metals having extremely high hardness at high temperatures and low reactivity with Zn, ie, W and M, are used.

またはMo含有量が98wt、%以上のHO合金を使用
する。
Alternatively, an HO alloy with a Mo content of 98 wt.% or more is used.

W、MoおよびMo合金は、いずれも電気めっきを施す
ことが不可能な金属なので、これらの金属皮膜3はプラ
ズマ溶射によって形成される。W、M。
Since W, Mo, and Mo alloy are all metals that cannot be electroplated, the metal coating 3 of these is formed by plasma spraying. W,M.

および旧合金は、その導電性がCuよりは悪いものの、
Feよりは良好である。従って、金冗皮1]莫3の厚み
を適当に薄くすることにより、溶接性J、9 :3化す
るまでに導電性が悪化することはない。たた5、形成さ
れる金属皮膜3の厚さが500μmを超えると、金属皮
膜3中において熱が発生し1.・星りよよ)I率が大き
くなる。一方、金属皮膜3の厚さが、5Q、、、m未満
で:よ、前記皮膜に割れが入る。従って、金属皮膜3の
厚さは50〜500=vの■フ囲が好ま5い。
Although the conductivity of the old alloy and the old alloy is worse than that of Cu,
It is better than Fe. Therefore, by appropriately reducing the thickness of the metal layer, the conductivity will not deteriorate until the weldability J is 9:3. 5. If the thickness of the metal film 3 to be formed exceeds 500 μm, heat will be generated in the metal film 3.・Star Riyoyo) I rate increases. On the other hand, if the thickness of the metal film 3 is less than 5Q, the film cracks. Therefore, the thickness of the metal film 3 is preferably 50 to 500=v.

金属皮膜3を形成するためのプラズマ’t8 It方法
としては、低圧プラズマ溶射が、緻密で、且つ、密着力
が高い皮膜を形成することができるので好ましい。ただ
し、常圧プラズマ溶射であっても皮膜形成は可能である
As the plasma 't8 It method for forming the metal film 3, low-pressure plasma spraying is preferred because it can form a dense film with high adhesion. However, film formation is possible even with normal pressure plasma spraying.

電極基材Iとしては、前述したように、Cu系金属を使
用するが、金属皮膜3を溶射するときに、前記基材が高
温になるので、M2O3分散Cuを使用することが好ま
しい。ただし、Cr −Cu合金等、熱処理強化合金を
使用することも可能である。この場合には、金属皮膜3
を形成後、もう−度再熱処理強化を行なうことが必要で
ある。
As the electrode base material I, Cu-based metal is used as described above, but since the base material becomes high temperature when the metal coating 3 is thermally sprayed, it is preferable to use M2O3 dispersed Cu. However, it is also possible to use heat-treated strengthened alloys such as Cr-Cu alloys. In this case, the metal film 3
After forming, it is necessary to perform another heat treatment for strengthening.

第2図は、第2の発明を示す断面図である。第2図に示
すように、Cu系金属からなる電極基材lの先端の表面
には、純Cuからなる純Cu皮膜4が形成されている。
FIG. 2 is a sectional view showing the second invention. As shown in FIG. 2, a pure Cu film 4 made of pure Cu is formed on the surface of the tip of an electrode base material l made of Cu-based metal.

さらに、純Cu皮膜4の表面シこは、第1の発明に使用
された金属皮膜3、即ち、W。
Furthermore, the surface roughness of the pure Cu film 4 is the same as that of the metal film 3 used in the first invention, that is, W.

3oまたはMo合金からなる金属皮膜が形成されている
。純Cu皮膜4は、溶射およびめっきのいずれの方法に
よっても形成することができる。
A metal film made of 3o or Mo alloy is formed. The pure Cu film 4 can be formed by either thermal spraying or plating.

溶接初期の電極先端形状自己安定化のためには、電極先
端の表面はある程度の変形態によって形成されることが
好ましい。そこで、純Cu皮膜4を金属皮膜3と基材1
との間に形成させることにより、溶接初期の電極形状自
己安定化を図ることができる。純Cuは基材1、金属皮
膜3よりも著しく軟かいからである。ただし、純Cu皮
膜4の厚さが50μm未満では、薄すぎて所望の変形が
得られない。
In order to self-stabilize the shape of the electrode tip at the initial stage of welding, it is preferable that the surface of the electrode tip be formed with some degree of deformation. Therefore, pure Cu film 4 is combined with metal film 3 and base material 1.
By forming the electrode between the two electrodes, it is possible to achieve self-stabilization of the electrode shape at the initial stage of welding. This is because pure Cu is significantly softer than the base material 1 and the metal film 3. However, if the thickness of the pure Cu film 4 is less than 50 μm, it is too thin and the desired deformation cannot be obtained.

方、純Cu皮膜4の厚さが500−を超えると、溶接初
期の加圧により、潰れた純Cuの形状異常拡大によって
、電流密度の低下を招来する。従って、純Cu皮膜4の
厚さは、50〜500nの範囲に限定することが好まし
い。
On the other hand, if the thickness of the pure Cu film 4 exceeds 500 mm, the current density will decrease due to the expansion of the crushed pure Cu due to the pressurization at the initial stage of welding. Therefore, the thickness of the pure Cu film 4 is preferably limited to a range of 50 to 500 nm.

〔実施例〕〔Example〕

次に、この発明を実施例によって更に詳細に説明する。 Next, the present invention will be explained in more detail with reference to examples.

下記からなる電極作成法によって、本発明電極N(L 
1〜4、および、比較電極Nα1〜4を製造した。
The electrode of the present invention N (L
1 to 4 and comparative electrodes Nα1 to 4 were manufactured.

そして、製造した各電極を使用して、被溶接材に対して
連続溶接を行ない、電極の寿命を試験し、その結果を第
1表に示した。被溶接材、溶接条件及び電極寿命の試験
方法は下記に示す通りである。
Using each of the manufactured electrodes, continuous welding was performed on materials to be welded, and the life of the electrodes was tested. The results are shown in Table 1. The materials to be welded, welding conditions, and electrode life test methods are as shown below.

(1)  電極作成法 コーティング原料:第1表に示す、 原ギ4粒径:20〜100ハ、 溶!l↑法:低圧プラズマ溶射法、 溶射条件: 溶射雰囲気圧; 80Torr、 溶射入熱; 60KW、 フ゛ラズマガス;Ar+lOえ)(2 プラズマガス流量: 20 ?、 /lin溶射厚;第
1表に示す、 基 材;第1表に示す、 純Cu皮膜:j7さ100μi。
(1) Electrode production method Coating raw materials: Shown in Table 1, raw wood 4 Particle size: 20-100cm, melted! l↑ method: Low pressure plasma spraying method, Spraying conditions: Spraying atmosphere pressure: 80Torr, Spraying heat input: 60KW, Plasma gas: Ar+IO) (2 Plasma gas flow rate: 20?, /lin Spraying thickness: As shown in Table 1. Material: as shown in Table 1 Pure Cu film: j7 thickness 100μi.

(2)  彼苓接材 電気亜鉛めっきzt′I板: 淳さ; 0.8mmX 2枚重ね、 奸i(″i付着里;40g/+Tf。(2) Herei welding material Electrogalvanized zt'I plate: Junsa; 0.8mmX 2 sheets stacked, 40g/+Tf.

(3)  冷接条件 電  j″ii: 形 状;C型(JIS C9304)、先端径; 4.
7mm、 加圧力;200kg、 通電時間: 10150秒、 溶接速度=1点/秒、 溶接電流: 12KA。
(3) Cold welding conditions Electricity j″ii: Shape: C type (JIS C9304), tip diameter; 4.
7mm, Pressure force: 200kg, Current application time: 10150 seconds, Welding speed = 1 point/second, Welding current: 12KA.

(4)  試験方法 連続溶接を行ない、200点毎に溶接された箇所の引張
剪断試験片を作製し、JIS Z 3136に規定され
た引張剪断試験を行ない、引張剪断強さを求めた。そし
て、その強さが300kg以下となるまでの溶接点数を
求め、その点数を電極の寿命とした。
(4) Test method Continuous welding was performed, and tensile shear test pieces were prepared at every 200 welded points, and a tensile shear test specified in JIS Z 3136 was conducted to determine the tensile shear strength. Then, the number of welding points until the strength became 300 kg or less was determined, and the number of welding points was determined as the life of the electrode.

第 1 表 第1表から明らかなように、本発明型Bi No、 1
〜4は、いずれも8000点以上と長寿命を示した。
Table 1 As is clear from Table 1, the present invention type Bi No. 1
-4 all showed a long life of 8000 points or more.

一方、電極先端の表面にr′Ioからなるコーティング
を施した比較電tEiNlllは、その溶射厚が500
−を超える700μmであったために、寿命が短かかっ
た。
On the other hand, the comparison electrode tEiNlll, which has a coating made of r'Io on the surface of the electrode tip, has a thermal spraying thickness of 500 mm.
- 700 μm, which exceeded 700 μm, so the life span was short.

電極先端の表面にコーティングを施さない比較電極Nα
2,3.および、Niめっきを施した比較電極No、 
4は、本発明電極No、 1〜4と比べて寿命が短かか
った。
Reference electrode Nα without coating on the surface of the electrode tip
2,3. and comparison electrode No. with Ni plating,
Electrode No. 4 had a shorter lifespan than electrode No. 1 to 4 of the present invention.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、この発明によれば、Znめっき鋼
板を溶接する場合において、極めて長寿命を示す電気抵
抗溶接用電極を得ることができる。卒業上有用な効果が
得られる。
As explained above, according to the present invention, it is possible to obtain an electric resistance welding electrode that exhibits an extremely long life when welding Zn-plated steel sheets. A useful effect on graduation can be obtained.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は第1の発明を示す断面図、第2i21は第2の
発明を示す断面図、第3図はスボッ)?8接を行なう場
合の1例を示す説明図、第4図は従来の電極の1例を示
す断面図である。図面において、l・・・電極基材、 
  2・・・電極、3・・・金属皮膜、   4・・・
純Cu皮膜、5・・・被溶接材、   6・・・埋設金
属。
Fig. 1 is a sectional view showing the first invention, No. 2i21 is a sectional view showing the second invention, and Fig. 3 is a sectional view showing the second invention. FIG. 4 is an explanatory diagram showing an example of a case where 8 contacts are made, and FIG. 4 is a sectional view showing an example of a conventional electrode. In the drawings, l...electrode base material,
2... Electrode, 3... Metal film, 4...
Pure Cu film, 5... Material to be welded, 6... Buried metal.

Claims (1)

【特許請求の範囲】 1 Cu系合金からなる電極基材先端の表面に、高温で
の硬さが高く、しかも、Znとの反応性が小さい金属か
らなる皮膜が形成されていることを特徴とする電気抵抗
溶接用電極。 2 前記金属は、W、Mo、Mo合金のうちのいずれか
1つであり、前記金属皮膜の厚さは50〜500μmで
ある請求項1記載の電気抵抗溶接用電極。 3 Cu系金属からなる電極基材先端の表面に、純Cu
からなる皮膜が形成され、さらに、前記純Cuからなる
皮膜の表面に、高温での硬さが高く、しかも、Znとの
反応性が小さい金属からなる皮膜が形成されていること
を特徴とする電気抵抗溶接用電極。
[Claims] 1. A coating made of a metal that has high hardness at high temperatures and has low reactivity with Zn is formed on the surface of the tip of an electrode base material made of a Cu-based alloy. Electrode for electric resistance welding. 2. The electric resistance welding electrode according to claim 1, wherein the metal is any one of W, Mo, and Mo alloy, and the metal film has a thickness of 50 to 500 μm. 3 Pure Cu is applied to the surface of the tip of the electrode base material made of Cu-based metal.
Further, a film made of a metal having high hardness at high temperatures and low reactivity with Zn is formed on the surface of the pure Cu film. Electrode for electric resistance welding.
JP17776089A 1989-07-10 1989-07-10 Electric resistance welding electrode Pending JPH0342186A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17776089A JPH0342186A (en) 1989-07-10 1989-07-10 Electric resistance welding electrode

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17776089A JPH0342186A (en) 1989-07-10 1989-07-10 Electric resistance welding electrode

Publications (1)

Publication Number Publication Date
JPH0342186A true JPH0342186A (en) 1991-02-22

Family

ID=16036650

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17776089A Pending JPH0342186A (en) 1989-07-10 1989-07-10 Electric resistance welding electrode

Country Status (1)

Country Link
JP (1) JPH0342186A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5736073A (en) * 1980-07-15 1982-02-26 Hitachi Ltd Safety device of welding robot
JPS60227997A (en) * 1984-04-26 1985-11-13 Sumitomo Electric Ind Ltd Electrode material for welding

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5736073A (en) * 1980-07-15 1982-02-26 Hitachi Ltd Safety device of welding robot
JPS60227997A (en) * 1984-04-26 1985-11-13 Sumitomo Electric Ind Ltd Electrode material for welding

Similar Documents

Publication Publication Date Title
EP0001173B1 (en) A process for the diffusion welding of copper and stainless steel
US8444042B2 (en) Method for producing steel pipe plated with metal by thermal spraying
US6722002B1 (en) Method of producing Ti brazing strips or foils
JP3065674B2 (en) Protective layer for base and method for forming protective layer
JP6939393B2 (en) Al plated steel pipe parts
US8833633B2 (en) Rotary tool
CN110312589A (en) Not solderable metal is welded with thermal spraying interlayer resistance
US4014417A (en) Conductor rail
JP6006846B1 (en) Conductive member, conductive member for gas insulated switchgear, and manufacturing method of conductive member for gas insulated switchgear
JPH0342186A (en) Electric resistance welding electrode
US5334814A (en) Electrode for spot welding
JP3843042B2 (en) Aluminum-plated steel sheet with excellent resistance weldability and machined parts using it
JPS60227997A (en) Electrode material for welding
JPS60227998A (en) Electrode material for welding
JPS61266189A (en) Ceramic contact tip for arc welding and its production
JP2005048254A (en) Galvanized steel having excellent film peeling resistance for hot forming
JPS60231597A (en) Material of electrode for welding
JP4342700B2 (en) COATING MEMBER FOR ELECTRIC DEVICE AND MANUFACTURING METHOD THEREOF
JP2002004017A (en) HOT-DIP Zn-Al-Mg-Si PLATED STEEL MATERIAL EXCELLENT IN SURFACE CHARACTERISTIC AND ITS PRODUCTION METHOD
JPH0772332B2 (en) Method for producing alloyed molten zinc plated steel sheet with excellent spot weldability
JPH01113182A (en) Electrode for resistance welding
JP2004002931A (en) Aluminum plated steel sheet having excellent resistance weldability and worked parts obtained by using the same
JPS61226190A (en) Electrode for spot welding
JPS62170466A (en) Formation of thermally sprayed heat resistant film on copper alloy as base material
JPH0841627A (en) Zn-mg alloy plated steel sheet excellent in spot weldability