JPH0342008A - Filter sheet used for removing suspended matter in distilled liquor - Google Patents
Filter sheet used for removing suspended matter in distilled liquorInfo
- Publication number
- JPH0342008A JPH0342008A JP1174242A JP17424289A JPH0342008A JP H0342008 A JPH0342008 A JP H0342008A JP 1174242 A JP1174242 A JP 1174242A JP 17424289 A JP17424289 A JP 17424289A JP H0342008 A JPH0342008 A JP H0342008A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- fibers
- filtration
- filter
- hydrophobic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 claims abstract description 54
- 238000001914 filtration Methods 0.000 claims abstract description 45
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 21
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 229920000098 polyolefin Polymers 0.000 claims abstract description 4
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 3
- 239000000126 substance Substances 0.000 claims description 20
- 239000010419 fine particle Substances 0.000 claims description 15
- 235000015096 spirit Nutrition 0.000 claims description 14
- -1 fatty acid esters Chemical class 0.000 abstract description 15
- 239000000203 mixture Substances 0.000 abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 8
- 239000005909 Kieselgur Substances 0.000 abstract description 7
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 6
- 239000000194 fatty acid Substances 0.000 abstract description 6
- 229930195729 fatty acid Natural products 0.000 abstract description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 4
- 229920002678 cellulose Polymers 0.000 abstract description 2
- 239000001913 cellulose Substances 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 14
- 239000010451 perlite Substances 0.000 description 10
- 235000019362 perlite Nutrition 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000002994 raw material Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 8
- 239000004698 Polyethylene Substances 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 229920003043 Cellulose fiber Polymers 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 239000003348 petrochemical agent Substances 0.000 description 4
- 235000015041 whisky Nutrition 0.000 description 4
- 238000010009 beating Methods 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013532 brandy Nutrition 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 206010061592 cardiac fibrillation Diseases 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- SHFGJEQAOUMGJM-UHFFFAOYSA-N dialuminum dipotassium disodium dioxosilane iron(3+) oxocalcium oxomagnesium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[Na+].[Na+].[Al+3].[Al+3].[K+].[K+].[Fe+3].[Fe+3].O=[Mg].O=[Ca].O=[Si]=O SHFGJEQAOUMGJM-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000002600 fibrillogenic effect Effects 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- AYOOGWWGECJQPI-NSHDSACASA-N n-[(1s)-1-(5-fluoropyrimidin-2-yl)ethyl]-3-(3-propan-2-yloxy-1h-pyrazol-5-yl)imidazo[4,5-b]pyridin-5-amine Chemical compound N1C(OC(C)C)=CC(N2C3=NC(N[C@@H](C)C=4N=CC(F)=CN=4)=CC=C3N=C2)=N1 AYOOGWWGECJQPI-NSHDSACASA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 235000020083 shōchū Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Distillation Of Fermentation Liquor, Processing Of Alcohols, Vinegar And Beer (AREA)
- Filtering Materials (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、蒸留酒中に含まれる混濁物質及び浮遊微粒子
を濾過操作によって除去する際に用いる濾過シートに関
するものである。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a filter sheet used for removing cloudy substances and suspended particles contained in distilled spirits through a filtration operation.
（従来の技術）
蒸留法によるアルコール系飲料、例えばウィスキー、ブ
ランデー、焼酎などは、その製造工程において脂肪酸エ
ステルが産出することは広く知られている。(Prior Art) It is widely known that fatty acid esters are produced during the manufacturing process of alcoholic beverages produced by distillation, such as whisky, brandy, and shochu.
この脂肪酸エステルは、過剰に存在すれば混濁などの発
生原因となるため、その含有量を適度の範囲内に調整す
ることが必要である。If this fatty acid ester is present in excess, it will cause turbidity, so it is necessary to adjust its content within an appropriate range.
これを目的として、過剰の脂肪酸エステルを除去するた
めの具体的な方法が各種提案、実施されているがその中
でも精密濾過シート等で濾過して浮遊微粒子と共に混濁
物質を除去する方法がよく行なわれている。For this purpose, various specific methods have been proposed and implemented to remove excess fatty acid esters, but among them, the most commonly used method is to filter with a microfiltration sheet or the like to remove suspended particles and turbid substances. ing.
この場合の濾過シートとしては、セルロース繊維とケイ
ソウ土を混抄したもの、更に、これにブラス或いはマイ
ナスに荷電処理を施したもの等が用いられている。しか
しながら従来のこの種の濾過シートは、各種液体の清澄
滅菌濾過用等に広く利用されているものであり、蒸留酒
中の混濁物質の除去用としては、濾過抵抗、除去効率環
、濾過性能の上で不充分であった。In this case, the filtration sheet used is a mixture of cellulose fibers and diatomaceous earth, or a sheet made of a mixture of cellulose fibers and diatomaceous earth, which is treated with brass or a negative charge. However, conventional filtration sheets of this type are widely used for clarifying and sterilizing filtration of various liquids, and for removing turbid substances from distilled spirits, they are difficult to measure due to filtration resistance, removal efficiency, and filtration performance. The above was insufficient.
（発明が解決しようとする課題）
現在、使用されている蒸留酒中の混濁物質及び浮遊微粒
子を、濾過法により除去する際の濾過シートは、濾過抵
抗が高くまた目詰りが早いため、シート交換が頻繁にな
り、経済性１作業性の点からその改善が強く望まれてい
る。(Problem to be solved by the invention) The filtration sheets currently used to remove turbid substances and suspended particles from distilled spirits by filtration have high filtration resistance and get clogged quickly, so the sheets must be replaced. This has become more frequent, and its improvement is strongly desired from the viewpoints of economy and workability.
本発明はこの様な点に鑑み、シートによる濾過法におい
て、より能率的かつ実際的に蒸留酒中の混濁物質の除去
性能にすぐれ、処理量が大きく操作しやすい新規の濾過
シートを提供することを目的とする。In view of these points, it is an object of the present invention to provide a new filter sheet that is more efficient and practical in removing turbid substances from distilled spirits, has a large throughput, and is easy to operate in a sheet filtration method. With the goal.
（課題を解決するための手段）
セルロース繊維にケイソウ上等の濾過助剤を混抄した従
来の濾過シートは、混濁物質を機械的に除去するのみで
あり、除去能を高めるためには、濾過シートの孔径を小
さくしたり、空隙率を小さくする等の調整が必要であっ
た。しかし、この反面濾過抵抗が大きくなり、濾紙寿命
は短くなる。(Means for solving the problem) Conventional filter sheets made by mixing cellulose fibers with filter aids such as diatomaceous materials only mechanically remove turbid substances. It was necessary to make adjustments such as reducing the pore diameter and porosity. However, on the other hand, the filtration resistance becomes large and the life of the filter paper becomes short.
本発明者らは、鋭意研究した結果、少なくとも疎水性繊
維及び微粒子、好ましくは更に親水性繊維を混抄して作
った新規の濾過シートで、蒸留酒を濾過することによっ
て、液中の浮遊微粒子と共に混濁物質を効率的に除去で
きることを見出し、本発明をなすに至った。As a result of extensive research, the present inventors have discovered that by filtering distilled spirits using a new filter sheet made by mixing at least hydrophobic fibers and fine particles, preferably further hydrophilic fibers, the suspended fine particles in the liquid can be filtered. It was discovered that turbid substances can be efficiently removed, and the present invention was completed.
即ち本発明濾過シートは、疎水結合的吸着力を持つこと
を一つの特徴とする新規な濾過シートであり、その要旨
とするところは下記のとおりである。That is, the filtration sheet of the present invention is a novel filtration sheet characterized by having hydrophobic binding adsorption power, and its gist is as follows.
（１）疎水性繊維及び微粒子からなることを特徴とする
蒸留酒中の混濁物質の除去に用いる濾過シート。(1) A filtration sheet used for removing turbid substances in distilled spirits, characterized by comprising hydrophobic fibers and fine particles.
（２）少なくとも親水性繊維と疎水性繊維及び微粒子か
らなることを特徴とする蒸留酒中の混濁物質の除去に用
いる濾過シート。(2) A filter sheet used for removing turbid substances in distilled spirits, characterized by comprising at least hydrophilic fibers, hydrophobic fibers, and fine particles.
（３）疎水性繊維がポリオレフィン系、ポリエステル系
、アクリル系繊維の１種以上であることを特徴とする前
項ｌ又は２記載の蒸留酒中の混濁物質の除去に用いる濾
過シート。(3) The filtration sheet used for removing turbid substances in distilled spirits as described in item 1 or 2 above, wherein the hydrophobic fibers are one or more of polyolefin, polyester, and acrylic fibers.
（４）疎水性繊維が１０〜７５重量％、親水性繊維が０
〜５０重量％、濾過助剤として用いる微粒子が２５〜９
０重量％からなることを特徴とする前項１．２又は３記
載の蒸留酒中の混濁物質の除去に用いる濾過シート。(4) 10-75% by weight of hydrophobic fibers, 0% of hydrophilic fibers
~50% by weight, 25-9% fine particles used as filter aids
The filter sheet used for removing turbid substances in distilled spirits according to item 1.2 or 3 above, characterized in that the sheet contains 0% by weight.
本発明に従い、濾過シートに、疎水結合的吸着力を有す
るこれらの繊維を含有さ゛せることによって、脂肪酸エ
ステルからなる蒸留酒中の混濁物質を、機械的濾過の他
に、疎水結合的吸着作用によって除去することが可能に
なる。According to the present invention, by including these fibers having hydrophobic adsorption power in the filter sheet, cloudy substances in distilled spirits made of fatty acid esters can be removed not only by mechanical filtration but also by hydrophobic adsorption action. It becomes possible to remove it.
更に、本発明の場合、疎水性繊維と微粒子だけの構成で
も、目的の濾過シートを作ることは可能であるが、親水
性繊維の含有によって′ａ、過シート自体に親水性が付
加されるため、蒸留酒濾過作業時にシート自体の濾過抵
抗を低減するのに有効である。Furthermore, in the case of the present invention, although it is possible to make the desired filtration sheet even with a composition of only hydrophobic fibers and fine particles, the inclusion of hydrophilic fibers adds hydrophilicity to the filtration sheet itself. , is effective in reducing the filtration resistance of the sheet itself during distilled liquor filtration work.
本発明の濾過シートの構成要素の内、疎水性繊維とは、
水との親和性の小さい（水にぬれにくい）繊維のことで
、ポリオレフィン系、ポリエステル系、アクリル系の疎
水性繊維等があるが、本発明の場合には特にポリエチレ
ン繊維、ポリプロピレン繊維、ポリエステル繊維等疎水
性で、かつ親油性のある合成繊維が好ましい、繊維形状
としては長繊維を所定長さにカットしたものや、フィブ
リル化繊維等種々あり、特にフィブリル化繊維はフィプ
リド法１重合剪断法、ポリマーブレンド法等、各種の方
法により作られるが何れの方法でつくられたものでもか
まわない。Among the constituent elements of the filter sheet of the present invention, hydrophobic fibers are:
Fibers with low affinity for water (hard to get wet with water) include polyolefin, polyester, and acrylic hydrophobic fibers, but in the case of the present invention, polyethylene fibers, polypropylene fibers, and polyester fibers are particularly Equihydrophobic and lipophilic synthetic fibers are preferred.There are various fiber shapes such as long fibers cut to a predetermined length and fibrillated fibers.In particular, fibrillated fibers are produced by the fibrid method, one polymerization shearing method, It can be made by various methods such as a polymer blend method, but any method may be used.
特に湿式法で濾過シートを作る場合には、抄紙用原料と
して使用可能な形状のものであることが好ましい。これ
ら疎水性物質の形状としては、繊維形状以外に粉末、粒
子状いずれでも混濁物質除去性を持っているが、本発明
の濾過シート用としては繊維状が好適である。Particularly when making a filter sheet by a wet method, it is preferably in a shape that can be used as a raw material for papermaking. In addition to fibers, these hydrophobic substances may be in powder or particulate form, which have the ability to remove turbid substances, but fibers are suitable for use in the filter sheet of the present invention.
本発明の濾過シートのもう一つの構成要素である微粒子
には、その粒子径が２ｍｍ以下のケイソウ土、パーライ
ト、活性炭、チタン酸繊維、アスベスト等の無機系微粒
子および無機系微細繊維、またセルロース粉末、セルロ
ース誘導体ビーズ、イオン交換樹脂等の有機系微粒子等
があるが、中でもケイソウ土、パーライト等の無機系濾
過助剤が本発明の目的に好適である。これらの微粉末は
濾過シートの孔径、空隙率等を調節する重要な役割を持
ち、本発明の場合少なくともケイソウ土、パーライトの
何れか又は両者を混合して用いることが望ましい。The fine particles, which are another component of the filter sheet of the present invention, include inorganic fine particles and inorganic fine fibers such as diatomaceous earth, perlite, activated carbon, titanate fibers, and asbestos, and cellulose powder with a particle size of 2 mm or less. Among them, inorganic filter aids such as diatomaceous earth and perlite are suitable for the purpose of the present invention. These fine powders play an important role in adjusting the pore diameter, porosity, etc. of the filter sheet, and in the case of the present invention, it is desirable to use at least diatomaceous earth, perlite, or a mixture of both.
また、親水性繊維とは水との親和性の大きい（水にぬれ
やすい）繊維のことを言い、これには例エバ天然セルロ
ース繊維、レーヨン、ポリビニルアルコール繊維などが
あるが、本発明ではその目的上、天然セルロース、特に
精製リンターパルプや晒クラフトパルプの様な精製木材
パルプ等でα−セルロース分９０％以上のものが好まし
い。In addition, hydrophilic fibers refer to fibers that have a high affinity for water (easily wetted by water), and examples thereof include EVA natural cellulose fibers, rayon, and polyvinyl alcohol fibers. Preferably, natural cellulose, especially purified wood pulp such as purified linter pulp or bleached kraft pulp, having an α-cellulose content of 90% or more is preferable.
湿式法で本発明の濾過シートを作る場合、これらの繊維
を１種又は２種以上混合し、叩解度、繊維長、フィブリ
ル化度を調整して用いるが、この場合も天然セルロース
繊維は濾過シート製造時の抄紙性を向上すると共に、他
の構成成分をシート中に保持し、シートに強度を与える
上で極めて有効である。When making the filtration sheet of the present invention by a wet method, one or more of these fibers are mixed and used while adjusting the degree of beating, fiber length, and degree of fibrillation. In this case, too, natural cellulose fibers are used in the filtration sheet. It is extremely effective in improving papermaking properties during production, retaining other constituent components in the sheet, and imparting strength to the sheet.
本発明のシートは、乾式法或は湿式法の何れでも製作可
能だが、シート性質の均一性、製作能率の上から湿式法
がより好ましい。この場合の製造方法は次の手順によっ
て行なわれる。水を張ったビータ−中に所定量の親水性
繊維を添加、分散する。ビータ−の刃を下して所定の叩
解度に調整後、微粒子を加え、均一に混合する。更にあ
らかじめ離解しておいた所定量の疎水性繊維を添加し充
分撹拌混合して抄紙原料とする。The sheet of the present invention can be produced by either a dry method or a wet method, but the wet method is more preferable in terms of uniformity of sheet properties and production efficiency. The manufacturing method in this case is carried out by the following steps. Add and disperse a predetermined amount of hydrophilic fibers into a beater filled with water. After lowering the beater blade to adjust the degree of beating to a predetermined level, fine particles are added and mixed uniformly. Furthermore, a predetermined amount of hydrophobic fibers that have been disintegrated in advance are added and sufficiently stirred and mixed to obtain a papermaking raw material.
この場合、疎水性繊維の分散性を良くするために、界面
活性剤等の抄紙用分散剤を加えることが好ましい、この
抄紙原料を用いて常法により抄紙、乾燥して所望の濾過
シートを得る。In this case, in order to improve the dispersibility of the hydrophobic fibers, it is preferable to add a papermaking dispersant such as a surfactant. Using this papermaking raw material, paper is made by a conventional method and dried to obtain the desired filter sheet. .
濾過シート中の各成分の好ましい含有比率は、親水性繊
維０〜５０重量％、疎水性繊維１０〜７５重量％、微粒
子２５〜９０重量％の範囲である。The preferable content ratio of each component in the filter sheet is in the range of 0 to 50% by weight of hydrophilic fibers, 10 to 75% by weight of hydrophobic fibers, and 25 to 90% by weight of fine particles.
本発明の濾過シートの厚さは、２〜１ｔｍ、特に３〜５
ＩＩＩＩ１１程度が好ましい。薄すぎると液体の透過流
路が短すぎて、混濁物質の吸着除去作用が不完全になり
やすいし、一方厚すぎると濾過シートからの脇漏れ量の
増加が懸念される。The thickness of the filter sheet of the present invention is 2 to 1 tm, especially 3 to 5 tm.
About III11 is preferable. If it is too thin, the liquid permeation channel will be too short, and the adsorption and removal effect of turbid substances will tend to be incomplete. On the other hand, if it is too thick, there is a concern that the amount of side leakage from the filter sheet will increase.
通常、本発明の゛濾過シートは１枚のシートで作られる
が、場合によっては薄いものを２枚以上積層して所望の
厚さにしてもよい。Usually, the filtration sheet of the present invention is made of one sheet, but in some cases, two or more thin sheets may be laminated to obtain the desired thickness.
本発明の濾過シートの重量は８００−１５００ ｇ ／
ｒｒｆ程度で、その時の水通過速度は濾過面積１９．
０ ｃｄ、減圧度７３ｃｍＨｇの条件下で水１００ｓｆ
を流す時間として３〜１０秒が好ましい。The weight of the filter sheet of the present invention is 800-1500 g/
rrf, the water passing rate at that time is 19.
0 cd, water 100sf under the conditions of reduced pressure 73cmHg
The time for flowing is preferably 3 to 10 seconds.
本発明の濾過シートは、紙力を向上させるためにおよび
または電気的吸着能を付与するためにポリアミドエピク
ロロヒドリン樹脂、メラミンホルマリン系樹脂等の合成
樹脂を添加することも可能である。The filter sheet of the present invention may contain synthetic resins such as polyamide epichlorohydrin resin and melamine-formalin resin in order to improve paper strength and/or impart electrical adsorption ability.
本発明の濾過シートは強度向上及び構成物である微粒子
のリークを防止するためにシートの裏側に不織布、濾紙
等を接着或はホットメルト法等で貼り付けることも可能
である。In order to improve the strength of the filter sheet of the present invention and to prevent the leakage of constituent fine particles, nonwoven fabric, filter paper, etc. can be attached to the back side of the sheet by adhesive or hot melt method.
以下濾過シート製作実施例及び試験実施例により本発明
を具体的に説明する。The present invention will be specifically explained below with reference to filter sheet production examples and test examples.
（濾過シート製作例及び比較例）
（実施例−１）
精製リンターパルプ（東洋特祇工業製 ５Ｆ−１３Ｏ３
）１５部を水に張ったビータ−に約１％濃度に添加し、
離解後叩解を行ない、ケイソウ±（マンビル社製 ス
タンダードスーパーセル）３５部、パーライト（東興パ
ーライト社製＃３４）２０部を添加し充分混合する。そ
こに、あらがしめ水中に離解しておいてフィブリル化ポ
リエチレン繊維（三井石油化学社製５ＷＰ）３０部を加
え均一に撹拌した後、水分を調節し固形分濃度０．５％
の抄紙原料とした。(Filter sheet production example and comparative example) (Example-1) Refined linter pulp (manufactured by Toyo Tokki Kogyo 5F-13O3
) to a beater filled with water to a concentration of approximately 1%,
After disintegration, beating is performed, and 35 parts of diatomaceous material ± (Standard Super Cell manufactured by Manville) and 20 parts of perlite (#34 manufactured by Toko Perlite) are added and thoroughly mixed. To this, 30 parts of fibrillated polyethylene fibers (5WP manufactured by Mitsui Petrochemicals) were added after roughening and disintegrating in water, and after stirring uniformly, the water content was adjusted and the solid content concentration was 0.5%.
It was used as a raw material for paper making.
この抄紙原料を用い、乾燥重量１０００ ｇ ／ ｎ（
、厚さ４調の濾過シートを得た。Using this papermaking raw material, the dry weight was 1000 g/n (
A filter sheet with four different thicknesses was obtained.
（実施例−２）
ケイソウ±（マンビル社製スタンダードスーパ−セル）
１６部、パーライト（東興パーライト社製＃３４） ９
部、フィブリル化ポリエチレン繊維（三井石油化学社製
５ＷＰ）７５部の組成の抄紙原料を用いて、実施例−１
と同様の操作により、乾燥量１ｉ１０００ ｇ ／ ｎ
ｆ、厚さ４．３ｍｍ（Ｄ濾過シートを得た。(Example-2) Diatom ± (Standard Super Cell manufactured by Manville)
16 parts, perlite (manufactured by Toko Perlite Co., Ltd. #34) 9
Example-1 Using a papermaking raw material having a composition of 75 parts of fibrillated polyethylene fiber (5WP manufactured by Mitsui Petrochemicals)
By the same operation as above, dry amount 1i1000 g/n
f, thickness 4.3 mm (D filtration sheet was obtained.
（実施例−３）
リンターパルプ（東洋特紙工業製 ５Ｆ−１３Ｏ３）３
５部、ケイソウ±（マンビル社製スタンダードスーパー
セル）３５部、パーライト（東興パーライト社製 ＃３
４）２０部、フィブリル化ポリエチレン繊維（三井石油
化学社製５ＷＰ）１０部の組成の抄紙原料を用いて、実
施例−１と同様の操作により、乾燥重量１０００ ｇ
／ポ、厚さ３．８ ｍの濾過シートを得た。(Example-3) Linter pulp (manufactured by Toyo Tokushi Kogyo 5F-13O3) 3
5 parts, Diaiso ± (Standard Super Cell manufactured by Manville) 35 parts, Perlite (#3 manufactured by Toko Perlite)
4) Using a papermaking raw material having a composition of 20 parts and 10 parts of fibrillated polyethylene fiber (5WP manufactured by Mitsui Petrochemicals), the dry weight was 1000 g by the same operation as in Example-1.
A filter sheet with a thickness of 3.8 m was obtained.
（実施例−４）
リンターパルプ（東洋特紙工業製 ５Ｆ−１３Ｏ８）１
０部、ケイソウ土（マンビル社製スタンダードスーパー
セル）５１部、パーライト（東興パーライト社製 ＃３
４）２９部、フィブリル化ポリエチレン繊維（三井石油
化学社製５ＷＰ）１０部の組成の抄紙原料を用いて、実
施例−１と同様の操作により、乾燥重量１０００ ｇ
／ｎｆ、厚さ４ｍｍの濾過シートを得た。(Example-4) Linter pulp (manufactured by Toyo Tokushi Kogyo 5F-13O8) 1
0 parts, diatomaceous earth (Standard Super Cell manufactured by Manville) 51 parts, perlite (manufactured by Toko Perlite #3
4) Using a papermaking raw material having a composition of 29 parts and 10 parts of fibrillated polyethylene fiber (5WP manufactured by Mitsui Petrochemicals), a dry weight of 1000 g was obtained by the same operation as in Example-1.
/nf, a 4 mm thick filter sheet was obtained.
（実施例−５）
リンターパルプ（東洋特紙工業製 ５Ｆ−１３Ｏ３）を
木材バルブ（シンプソン社製ＮＢＫＰ）に代えた他は、
全て実施例−１と同様の操作により乾燥量１１０００ｇ
／ｒｄ、厚さ４閣の濾過シートを得た。(Example-5) The linter pulp (5F-13O3 manufactured by Toyo Tokushi Kogyo) was replaced with a wood valve (NBKP manufactured by Simpson).
The dry amount was 11000g by the same operation as in Example-1.
/rd, a filtration sheet with a thickness of 4 mm was obtained.
（実施例−６）
フィブリル化ポリエチレン繊維（三井石油化学社製ｓｗ
ｐ）をポリプロピレン繊維（大和紡績社製０．５ｄＸ３
ａｗｍ）に代えた他は、全て実施例−１と同様の操作に
より乾燥量１１１０００ｇ／ｆｆｒ、厚さ４■の濾過シ
ートを得た。(Example-6) Fibrillated polyethylene fiber (manufactured by Mitsui Petrochemical Co., Ltd. sw
p) with polypropylene fiber (0.5dX3 manufactured by Daiwabo Co., Ltd.
A filtration sheet with a dry weight of 111,000 g/ffr and a thickness of 4 cm was obtained by the same procedure as in Example 1, except that awm) was used instead.
（比較例−１）
フィブリル化ポリエチレン繊維（三井石油化学社製５Ｗ
Ｐ）３０部をリンターパルプに代え、リンターパルプ（
東洋特低工業製５Ｆ−１３Ｏ３）を４５部とした他は全
て実施例−１と同様の操作にて、乾燥量ｆｉｌｏ００
ｇ ／ ｏｆ、厚さ３．７ ｍ （７）濾過シートを得
た。(Comparative Example-1) Fibrillated polyethylene fiber (manufactured by Mitsui Petrochemical Co., Ltd. 5W
P) Replace 30 parts with linter pulp, and add linter pulp (
The dry amount filo 00 was carried out in the same manner as in Example 1 except that 45 parts of 5F-13O3 (manufactured by Toyo Tokulow Kogyo Co., Ltd.) was used.
g/of, thickness 3.7 m (7) A filter sheet was obtained.
（比較例−２）
リンターパルプ（東洋特低工業製 ５Ｆ−１３Ｏ３）４
５部、ケイソウ±（マンビル社製 スタンダードスーパ
ーセル）３５部、ケイソウ±（マンビル社製 セライト
５０５）２０部の組成の抄紙原料を用いて、実施例−１
と同様の操作により、乾燥重量１０００ ｇ ／ポ、厚
さ３．７ ｍの濾過シートを得た。(Comparative example-2) Linter pulp (manufactured by Toyo Tokulow Kogyo 5F-13O3) 4
Example-1 Using a papermaking raw material having a composition of 5 parts of diatomaceous material, 35 parts of diatomaceous material ± (Standard Super Cell, manufactured by Manville Corporation), and 20 parts of diatomaceous material ± (Celite 505, manufactured by Manville Corporation).
A filter sheet with a dry weight of 1000 g/po and a thickness of 3.7 m was obtained by the same operation as above.
（ウィスキー濾過試験）
実施例及び比較例により得られた濾過シートについて、
下記条件でウィスキーを濾過し、その除去効率、濾過抵
抗及び濾過寿命を測定した。(Whiskey filtration test) Regarding the filter sheets obtained in Examples and Comparative Examples,
Whiskey was filtered under the following conditions, and its removal efficiency, filtration resistance, and filtration life were measured.
試験条件
１、使用液体 アルコール分４３％ウィスキー２、流速
４５±３１Ｉｌ／ｌｌ１ｎ３、有効濾過面積 １
９．０ｃｎ
４、濾過温度 ０部２°Ｃ
５、測 定 初期濾過抵抗及び濾過した濾液の混濁成分
量（ガスクロマトグラフィー
法で測定）差圧 ２．０ ｋｇ／ｃｄまでの濾過時間
６、混濁物質成分除去率計算
除去率（％）＝（ｌ−濾液の成分濃度
／原液成分濃度）Ｘ１００
結果を下記表に示す。Test conditions 1, liquid used: alcohol content 43% whiskey 2, flow rate 45±31Il/ll1n3, effective filtration area 1
9.0cn 4. Filtration temperature 0 parts 2°C 5. Measurement Initial filtration resistance and amount of turbidity in the filtered filtrate (measured by gas chromatography) Differential pressure Filtration time up to 2.0 kg/cd 6. Turbidity Material component removal rate Calculation Removal rate (%) = (l - component concentration of filtrate/concentration of stock solution component) x 100 The results are shown in the table below.
上記の様に実施例−１〜６では、いずれも高い除去率で
しかも実施例−４以外は濾過寿命が５０時間以上と長い
結果を得た。従来の技術では比較例−１の様に除去率が
不十分であり、この除去率を高めるために比較例−２の
様により細かい微粒子を使用すると除去率はある程度向
上するが、高い濾過抵抗で濾過寿命が８時間と短くなる
。また、微粒子の配合比を８０％とした実施例−４では
、濾過寿命が他の実施例に比べ２５時間とやや短くなる
が、除去率は比較例−１よりもはるかに優れ、また濾過
寿命も比較例−２よりはかなり長い結果であった。As mentioned above, Examples 1 to 6 all had high removal rates, and all except Example 4 had long filtration lives of 50 hours or more. With the conventional technology, the removal rate is insufficient as in Comparative Example 1, and if finer particles are used to increase the removal rate as in Comparative Example 2, the removal rate can be improved to some extent, but the removal rate is high and the filtration resistance is high. Filtration life is shortened to 8 hours. In addition, in Example 4 where the blending ratio of fine particles was 80%, the filtration life was slightly shorter at 25 hours compared to other examples, but the removal rate was much better than Comparative Example 1, and the filtration life was 25 hours. The length was also considerably longer than that of Comparative Example-2.
（発明の効果）
以上詳細に説明した如く、従来の技術では高い除去能を
得るためには、高い濾過抵抗で濾過寿命を短くする必要
が有ったが、本発明によれば蒸留酒中の混濁物質を、高
い除去率、低い濾過抵抗でより効率的に除去可能な濾過
シートが得られ、産業界に益するところ極めて大である
。(Effects of the Invention) As explained in detail above, in order to obtain high removal ability with the conventional technology, it was necessary to shorten the filtration life with high filtration resistance, but according to the present invention, A filter sheet that can remove turbid substances more efficiently with a high removal rate and low filtration resistance can be obtained, which is extremely beneficial to industry.
Claims (4)
蒸留酒中の混濁物質の除去に用いる濾過シート。(1) A filtration sheet used for removing turbid substances in distilled spirits, characterized by comprising hydrophobic fibers and fine particles.
らなることを特徴とする蒸留酒中の混濁物質の除去に用
いる濾過シート。(2) A filter sheet used for removing turbid substances in distilled spirits, characterized by comprising at least hydrophilic fibers, hydrophobic fibers, and fine particles.
、アクリル系繊維の１種以上であることを特徴とする請
求項１又は２記載の蒸留酒中の混濁物質の除去に用いる
濾過シート。(3) The filter sheet used for removing turbid substances in distilled spirits according to claim 1 or 2, wherein the hydrophobic fibers are one or more of polyolefin, polyester, and acrylic fibers.
〜５０重量％、濾過助剤として用いる微粒子が２５〜９
０重量％からなることを特徴とする請求項１、２又は３
記載の蒸留酒中の混濁物質の除去に用いる濾過シート。(4) 10-75% by weight of hydrophobic fibers, 0% of hydrophilic fibers
~50% by weight, 25-9% fine particles used as filter aids
Claim 1, 2 or 3, characterized in that it consists of 0% by weight.
A filtration sheet used for removing turbid substances from the above-mentioned distilled spirits.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1174242A JPH0342008A (en) | 1989-07-07 | 1989-07-07 | Filter sheet used for removing suspended matter in distilled liquor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1174242A JPH0342008A (en) | 1989-07-07 | 1989-07-07 | Filter sheet used for removing suspended matter in distilled liquor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0342008A true JPH0342008A (en) | 1991-02-22 |
Family
ID=15975202
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1174242A Pending JPH0342008A (en) | 1989-07-07 | 1989-07-07 | Filter sheet used for removing suspended matter in distilled liquor |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0342008A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04122615U (en) * | 1991-04-10 | 1992-11-04 | 日本濾器株式会社 | pleated filter cartridge |
| US5290454A (en) * | 1992-11-12 | 1994-03-01 | Pump And Paper Research Institute Of Canada | Process for removal of suspended solids from pulp and paper mill effluents |
| WO1998004348A1 (en) * | 1996-07-30 | 1998-02-05 | Cuno Incorporated | Filter sheet and process for purifying photoresist composition employing the filter sheet |
| EP0847784A1 (en) * | 1996-12-12 | 1998-06-17 | Elf Antar France | Paper filter for charged liquids |
| WO2006114847A1 (en) * | 2005-04-08 | 2006-11-02 | Otsuka Foods Co., Ltd. | Method of purifying liquor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54112071A (en) * | 1978-02-22 | 1979-09-01 | Mitsui Petrochemical Ind | Method of filtering liquid |
| JPS61289876A (en) * | 1985-06-17 | 1986-12-19 | Teijin Eng Kk | Removal of oily substance from pot-stilled shochu |
-
1989
- 1989-07-07 JP JP1174242A patent/JPH0342008A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54112071A (en) * | 1978-02-22 | 1979-09-01 | Mitsui Petrochemical Ind | Method of filtering liquid |
| JPS61289876A (en) * | 1985-06-17 | 1986-12-19 | Teijin Eng Kk | Removal of oily substance from pot-stilled shochu |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04122615U (en) * | 1991-04-10 | 1992-11-04 | 日本濾器株式会社 | pleated filter cartridge |
| US5290454A (en) * | 1992-11-12 | 1994-03-01 | Pump And Paper Research Institute Of Canada | Process for removal of suspended solids from pulp and paper mill effluents |
| WO1998004348A1 (en) * | 1996-07-30 | 1998-02-05 | Cuno Incorporated | Filter sheet and process for purifying photoresist composition employing the filter sheet |
| AU725939B2 (en) * | 1996-07-30 | 2000-10-26 | 3M Innovative Properties Company | Filter sheet and process for purifying photoresist composition employing the filter sheet |
| EP0847784A1 (en) * | 1996-12-12 | 1998-06-17 | Elf Antar France | Paper filter for charged liquids |
| FR2757079A1 (en) * | 1996-12-12 | 1998-06-19 | Elf Antar France | LIQUID FILTRATION FILM LOADED |
| WO2006114847A1 (en) * | 2005-04-08 | 2006-11-02 | Otsuka Foods Co., Ltd. | Method of purifying liquor |
| US7794602B2 (en) | 2005-04-08 | 2010-09-14 | Otsuka Foods Co., Ltd. | Method of purifying liquor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4288462A (en) | Method for removing cationic contaminants from beverages | |
| US5114537A (en) | Dry sheet-like filtering material for liquid depth filtration | |
| US4859340A (en) | Filter sheet | |
| US4645567A (en) | Filter media and method of making same | |
| US4305782A (en) | Filter and method of making same | |
| US4366068A (en) | Filter and method of making same | |
| US4309247A (en) | Filter and method of making same | |
| GB2043734A (en) | Filter and method of making same | |
| JPH0749088B2 (en) | Edible oil filter | |
| CN110585773A (en) | Filtering paperboard and preparation method thereof | |
| JPH0342008A (en) | Filter sheet used for removing suspended matter in distilled liquor | |
| WO2024160040A1 (en) | Depth filter medium and preparation method therefor | |
| GB2045828A (en) | Filter and method of making same | |
| US4344846A (en) | Filtration using expanded styrene-polymer and polyolefin micro-bits | |
| CN115652689A (en) | Deep filtering paperboard for bio-pharmaceutical filtration and preparation method thereof | |
| JP2004508180A (en) | Use of polyisocyanate resin in filter layer | |
| EP1689510B1 (en) | Fiber-fiber composites | |
| GB2056485A (en) | Beverage Filtration Process | |
| CN116180494B (en) | Depth filter paperboard and preparation method thereof | |
| JPH06312133A (en) | Shaped adsorbent | |
| RU2075329C1 (en) | Fine filtering material for cleaning air | |
| JPS6338206B2 (en) | ||
| RU2225874C1 (en) | Porous material | |
| GB2033406A (en) | Cellulosic Filter Aids | |
| GB2098590A (en) | Filter aid |