JPH0341594B2 - - Google Patents
Info
- Publication number
- JPH0341594B2 JPH0341594B2 JP63177733A JP17773388A JPH0341594B2 JP H0341594 B2 JPH0341594 B2 JP H0341594B2 JP 63177733 A JP63177733 A JP 63177733A JP 17773388 A JP17773388 A JP 17773388A JP H0341594 B2 JPH0341594 B2 JP H0341594B2
- Authority
- JP
- Japan
- Prior art keywords
- sericin
- raw silk
- fibers
- products
- crotonaldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108010013296 Sericins Proteins 0.000 claims description 18
- 239000000835 fiber Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- UDVPQRRWUGKGQY-SQQVDAMQSA-N but-2-enal (E)-but-2-enal Chemical compound CC=CC=O.C\C=C\C=O UDVPQRRWUGKGQY-SQQVDAMQSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 3
- MLUCVPSAIODCQM-NSCUHMNNSA-N crotonaldehyde Chemical compound C\C=C\C=O MLUCVPSAIODCQM-NSCUHMNNSA-N 0.000 description 5
- MLUCVPSAIODCQM-UHFFFAOYSA-N crotonaldehyde Natural products CC=CC=O MLUCVPSAIODCQM-UHFFFAOYSA-N 0.000 description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 241000255789 Bombyx mori Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- SXRSQZLOMIGNAQ-UHFFFAOYSA-N Glutaraldehyde Chemical compound O=CCCCC=O SXRSQZLOMIGNAQ-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000834 fixative Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- -1 saturated aliphatic aldehydes Chemical class 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
【発明の詳細な説明】
ａ 産業上の利用分野
本発明は、生糸絹繊維又はその製品にセリシン
を付着させたまま不溶性とし、セリシンを定着せ
しめる改質法に関するものである。このアルデヒ
ドを生糸絹繊維のセリシン定着へ応用することに
よる所望量のセリシンを安定に定着した生糸絹繊
維又はその製品として得ることができる。DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a method for modifying raw silk fibers or their products by making them insoluble while keeping sericin attached thereto and fixing sericin therein. By applying this aldehyde to sericin fixation on raw silk fibers, it is possible to obtain raw silk fibers or products thereof with a desired amount of sericin stably fixed thereon.
一般に生糸絹繊維又はその製品中のセリシン含
有量は25％前後と高く、セリシンを廃棄せずに適
当量のセリシンを定着させうれば資源の有効利用
から鑑みて染色加工上、重要視されうる。 Generally, the content of sericin in raw silk fibers or their products is high, around 25%, and if it is possible to fix an appropriate amount of sericin without discarding sericin, it would be important in dyeing processing from the standpoint of effective resource utilization.
ｂ 従来の技術
セルロースの改質剤やタンパク質の組織固定剤
に広く利用されてきたホルムアルデヒド法、グル
タルアルデヒド法は比較的簡易な方法として生糸
絹繊維、又はその製品のセリシン定着に使用され
てきた。これらのアルデヒド類は生糸絹繊維など
と共に加温、反応させることにより一層架橋化が
促進される。本発明についても、その応用であ
り、飽和脂肪族アルデヒドでは僅かな効果しか得
られなかつた。b. Prior Art The formaldehyde method and glutaraldehyde method, which have been widely used as cellulose modifiers and protein tissue fixatives, have been used as relatively simple methods to fix sericin on raw silk fibers or their products. Crosslinking of these aldehydes is further promoted by heating and reacting them with raw silk fibers and the like. The present invention is also an application of this, and only slight effects were obtained with saturated aliphatic aldehydes.
ｃ 発明の目的
湖沼ならびに河川の汚染源ともなりかねない生
糸絹繊維又はその製品中のセリシンを廃棄せずに
定着させる処理方法で、２−ブテナール（クロト
ンアルデヒド）を含有する水溶液中へ浸漬処理す
ることにより、セリシンを繊維上に不溶化定着さ
せることを特徴とする生糸絹繊維又はその製品の
セリシン定着による改質を提供するものである。c. Purpose of the invention A treatment method that fixes sericin in raw silk fibers or their products without discarding them, which can be a source of pollution in lakes and rivers, by immersion treatment in an aqueous solution containing 2-butenal (crotonaldehyde). The present invention provides a method for modifying raw silk fibers or products thereof by fixing sericin on the fibers, which is characterized by insolubilizing and fixing sericin on the fibers.
ｄ 発明の構成
すなわち、２−ブテナール（クロトンアルデヒ
ド）は液状の化合物でCH3CH＝CHCHOで表さ
れ、鉱物油の精製、樹脂の製造、ゴムの抗酸化
剤、殺虫剤などに使用されている。本発明はこの
２−ブテナール（クロトンアルデヒド）を含有す
る水溶液で生糸あるいは絹製品を浸浸処理するこ
とにより、適量のセリシンを生糸絹繊維又はその
製品に不溶化定着させるセリシン定着による改質
である。クロトンアルデヒド中の二重結合がセリ
シン定着の反応に関与しているものと考えられ
る。d. Structure of the invention In other words, 2-butenal (crotonaldehyde) is a liquid compound represented by CH 3 CH = CHCHO, and is used for refining mineral oil, manufacturing resin, antioxidant for rubber, insecticide, etc. . The present invention is a modification by sericin fixation in which an appropriate amount of sericin is insolubilized and fixed on raw silk fibers or products thereof by soaking the raw silk or silk products in an aqueous solution containing 2-butenal (crotonaldehyde). It is thought that the double bond in crotonaldehyde is involved in the sericin fixation reaction.
以下実施例により本発明の結果を具体的に示
す。 The results of the present invention will be specifically shown in Examples below.
実施例 １
エーテルとアルコールで洗浄した27中生糸（昭
和56年春蚕）を使用して、試料生糸に対して浴比
（１：50）とした。この浴比に対して２−ブテナ
ール（クロトンアルデヒド）の濃度を３％にして
常温で４時間浸漬処理したのち、常温のアセトン
で２回洗浄し、蒸留水で軽く洗浄したあと絞つて
常温で乾燥し、さらにデシケータ中で再乾燥を行
つた。Example 1 Using 27 medium raw silk (1981 spring silkworm) washed with ether and alcohol, the bath ratio (1:50) was adjusted to the sample raw silk. After adjusting the concentration of 2-butenal (crotonaldehyde) to 3% of this bath ratio and immersing it at room temperature for 4 hours, it was washed twice with acetone at room temperature, washed lightly with distilled water, then wrung out and dried at room temperature. Then, it was further dried again in a desiccator.
通常、未処理生糸のセリシン含有量は25％前後
とかなり高い数値を示しているが、本法の２−ブ
テナール（クロトンアルデヒド）処理では練減率
は10％前後を示す。 Normally, the sericin content of untreated raw silk is quite high, around 25%, but when treated with 2-butenal (crotonaldehyde) in this method, the reduction rate is around 10%.
強伸度としては、未処理生糸の強度は4.0ｇ／
ｄで伸度は25％であり、一方の２−ブテナール
（クロトンアルデヒド）による処理生糸の強度と
伸度は4.2ｇ／ｄと23.6％である。 In terms of strength and elongation, the strength of untreated raw silk is 4.0g/
The strength and elongation of raw silk treated with 2-butenal (crotonaldehyde) are 4.2 g/d and 23.6%.
したがつて、この処理方法により、15％前後の
セリシンを生糸上に不溶化定着させうる。これら
の処理生糸は輝黄色化しているが、漂白せずにそ
のままの処理生糸でも、染色時の黒色染めなどに
も応用できる。 Therefore, by this treatment method, approximately 15% of sericin can be insolubilized and fixed on raw silk. These treated raw silks have a bright yellow color, but even treated raw silks without bleaching can be used for black dyeing during dyeing.
Claims (1)
（クロトンアルデヒド）を含有する水溶液で処理
することにより、セリシンを繊維上に不溶化定着
させることを特徴とする生糸絹繊維のセリシン定
着による改質法。1. A method for modifying raw silk fibers by sericin fixation, which comprises treating raw silk fibers or their products with an aqueous solution containing 2-butenal (crotonaldehyde) to insolubilize and fix sericin on the fibers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17773388A JPH0284549A (en) | 1988-07-15 | 1988-07-15 | Modification of raw silk fiber by sericin fixing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17773388A JPH0284549A (en) | 1988-07-15 | 1988-07-15 | Modification of raw silk fiber by sericin fixing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0284549A JPH0284549A (en) | 1990-03-26 |
| JPH0341594B2 true JPH0341594B2 (en) | 1991-06-24 |
Family
ID=16036171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17773388A Granted JPH0284549A (en) | 1988-07-15 | 1988-07-15 | Modification of raw silk fiber by sericin fixing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0284549A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100448131B1 (en) * | 2002-05-22 | 2004-09-10 | 현대자동차주식회사 | Driver seat back having independent right and left frame |
| DE102014220693A1 (en) | 2014-10-13 | 2016-04-14 | Haworth Gmbh | Lumbar support for a chair and chair with the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5881681A (en) * | 1981-11-02 | 1983-05-17 | 工業技術院長 | Sericin fixing weight increasing process of raw silk fiber |
| JPS59150172A (en) * | 1983-02-14 | 1984-08-28 | 工業技術院長 | Sericine fixing and weight increasing process of silk fiber |
| JPS60155772A (en) * | 1984-01-19 | 1985-08-15 | 工業技術院長 | Serisine deposition and weight addition processing of raw silk fiber |
-
1988
- 1988-07-15 JP JP17773388A patent/JPH0284549A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5881681A (en) * | 1981-11-02 | 1983-05-17 | 工業技術院長 | Sericin fixing weight increasing process of raw silk fiber |
| JPS59150172A (en) * | 1983-02-14 | 1984-08-28 | 工業技術院長 | Sericine fixing and weight increasing process of silk fiber |
| JPS60155772A (en) * | 1984-01-19 | 1985-08-15 | 工業技術院長 | Serisine deposition and weight addition processing of raw silk fiber |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0284549A (en) | 1990-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |