JPH0339647B2 - - Google Patents
Info
- Publication number
- JPH0339647B2 JPH0339647B2 JP62114974A JP11497487A JPH0339647B2 JP H0339647 B2 JPH0339647 B2 JP H0339647B2 JP 62114974 A JP62114974 A JP 62114974A JP 11497487 A JP11497487 A JP 11497487A JP H0339647 B2 JPH0339647 B2 JP H0339647B2
- Authority
- JP
- Japan
- Prior art keywords
- fishing
- fishing nets
- antifouling
- nets
- fishing net
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 claims description 36
- 239000002184 metal Substances 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 24
- 239000002245 particle Substances 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 16
- 238000000576 coating method Methods 0.000 claims description 16
- 230000003373 anti-fouling effect Effects 0.000 claims description 15
- 238000005507 spraying Methods 0.000 claims description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 11
- 239000010949 copper Substances 0.000 claims description 11
- 239000003973 paint Substances 0.000 claims description 11
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 9
- 239000000919 ceramic Substances 0.000 claims description 8
- 239000002923 metal particle Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000013535 sea water Substances 0.000 claims description 6
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 3
- 241000195493 Cryptophyta Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000843 powder Substances 0.000 description 7
- 235000015170 shellfish Nutrition 0.000 description 7
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000003746 surface roughness Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000011342 resin composition Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000012209 synthetic fiber Substances 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- 238000007751 thermal spraying Methods 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- 229910001111 Fine metal Inorganic materials 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 229920006122 polyamide resin Polymers 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000238586 Cirripedia Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- APQHKWPGGHMYKJ-UHFFFAOYSA-N Tributyltin oxide Chemical compound CCCC[Sn](CCCC)(CCCC)O[Sn](CCCC)(CCCC)CCCC APQHKWPGGHMYKJ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- -1 acrylic polyol Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000036244 malformation Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Description
【発明の詳細な説明】
本発明は、漁網類、つまり漁網や養殖用のロー
プ類（以下単に漁網やロープと称する）が、海中
で藻や貝類の附着によつて汚れると、種々の不都
合が生ずるため、その防止手段として提案されて
いる多数の技術が、何れも不満足なものであるの
に鑑み、従来手段の欠点を解消し、使用者の満足
する優れた製品を提供せんとするものである。こ
れをさらに詳しく説明すると、従来漁網やロープ
類に藻や、かき、ふじつぼ等の貝類の附着を防止
（防汚）する手段として、漁網やロープに、何ら
かの方法で銅、錫等の金属を附着させ、海水中で
金属イオンを発生させることにより、附着を予防
するか、又は各種毒薬を混入した塗料を漁網やロ
ープに塗つて置き、その溶解により防汚する手段
がとられ、或程度の効果はあげている。しかし、
金属利用も、毒物塗布も、持続性に欠け、短時日
で防汚効果が無くなり、藻や貝類が附着し初める
ので、時々漁網やロープを引き上げ、藻、貝類の
除去をする必要があり、この工程が甚だ手数を要
するものであり、また、除去のタイミングが遅れ
ると定置網の場合は海水の流通が悪くなり、漁網
内に酸素欠乏という非常事態を生じ、大損害につ
ながるので、もつと持続性のある防汚手段が強く
望まれている。本発明は極めて長時間防汚効果を
有し、且つ小量の金属で大きな効果を上げること
に成功したものである。DETAILED DESCRIPTION OF THE INVENTION The present invention provides various inconveniences when fishing nets, that is, fishing nets and ropes for aquaculture (hereinafter simply referred to as fishing nets and ropes) become dirty due to adhesion of algae and shellfish in the sea. However, in view of the fact that many of the techniques that have been proposed as means for preventing this phenomenon are unsatisfactory, the present invention aims to eliminate the shortcomings of the conventional means and provide an excellent product that satisfies the users. be. To explain this in more detail, in the past, fishing nets and ropes were coated with metals such as copper and tin in some way as a means of preventing (antifouling) the adhesion of algae, oysters, barnacles, and other shellfish to fishing nets and ropes. Measures have been taken to prevent fouling by causing metal ions to adhere to the seawater, or to coat fishing nets and ropes with paints mixed with various poisons and to dissolve them to prevent fouling. It is having an effect. but,
Both the use of metals and the application of poisonous substances lack sustainability, and the antifouling effect wears off in a short period of time, and algae and shellfish begin to attach, so it is sometimes necessary to pull up fishing nets and ropes to remove algae and shellfish. In addition, if the timing of removal is delayed, the flow of seawater will deteriorate in the case of fixed nets, creating an emergency situation of oxygen deficiency within the fishing nets, which will lead to large losses, so it is difficult to maintain sustainability. Some antifouling means are highly desired. The present invention has an extremely long-lasting antifouling effect and has succeeded in achieving a large effect with a small amount of metal.
（従来の技術）
従来から各種防汚剤を塗布したり、漁網の原糸
中に極めて細い銅線を混在した素材で作つた漁網
やロープはあつた。しかし、前者塗料について
は、薬剤が海水中に解け出さねば防汚効果が無い
から、塗料自体溶解性のものとする必要から、半
年も持続させることは困難である。後者金属細線
撚込み方式のものは、金属線が切断し易く、手な
どを損傷する危険性があり、又漁網やロープが重
くなるので、取扱いが不便である。これらとは別
に銅、錫等の金属粉を混入した塗料を塗る方法も
あるが、金属粉の殆んどのものが塗料中に埋没
し、金属イオンの発生に寄与するものが極めて少
ないため、実際の効果は得られない。又金属微粒
子を混入した合成繊維を用いて漁網をつくる試み
もあるが、この場合も粒子は殆んど維持中に埋没
し、イオン発生効果は得られないし、重くなる欠
点や、紡糸技術が難かしく、高価なものとなる欠
点があつた。(Prior Art) Fishing nets and ropes have traditionally been coated with various antifouling agents or made from materials in which extremely thin copper wire is mixed into the fishing net thread. However, the former type of paint has no antifouling effect unless the drug dissolves in seawater, so the paint itself must be soluble, making it difficult to maintain it for more than six months. In the latter type, the metal wires are easily cut and there is a risk of injury to hands, etc., and the fishing nets and ropes are heavy, making them inconvenient to handle. Apart from these, there is also a method of applying paint mixed with metal powder such as copper or tin, but most of the metal powder is buried in the paint and very little contributes to the generation of metal ions, so in practice effect cannot be obtained. There have also been attempts to make fishing nets using synthetic fibers mixed with fine metal particles, but in this case too, most of the particles are buried during maintenance, so the ion generation effect cannot be obtained, and the drawbacks are that they are heavy and that spinning technology is difficult. It had the disadvantage of being bulky and expensive.
（本発明が解決しようとする問題点）
上記したように、従来から紡汚漁網、ロープは
何種類かあるが、防汚効果が持続しないため、１
年間に数回網等を海中から引き上げて、附着した
藻、貝類を除去する手数を必要とする。また、金
属粉を埋め込んだり、練り込んだりしたものは、
金属粉の中で金属イオンを出すものゝ数が極めて
少ないため、いたずらに重くなるだけで実際的効
果が無い。金属細線を用いるものも効果が薄く、
コストが高いという問題点がある。逆に言えば、
製作容易で、効果が持続し、コストが安く、軽く
て取扱いの便利なものが未だ無いという所に問題
がある。(Problems to be Solved by the Present Invention) As mentioned above, there are several types of spun dirty fishing nets and ropes, but since the antifouling effect does not last long,
It is necessary to take the net out of the sea several times a year and remove attached algae and shellfish. In addition, items that have metal powder embedded or kneaded into them,
Since the number of metal powders that emit metal ions is extremely small, it becomes unnecessarily heavy and has no practical effect. Those that use thin metal wires are also less effective,
There is a problem that the cost is high. Conversely,
The problem is that there is still no one that is easy to produce, has long-lasting effects, is low cost, lightweight, and convenient to handle.
なお、もう一つの重大な問題点が最近クローズ
アツプされて来た。それは、漁網やロープの防汚
効果を求めて使用される各種金属、薬剤の中、極
めて毒性の強いものがあるため、保健衛生上見逃
せない事態を生じていることである。例えばトリ
ブチルチンオキサイド等錫化合物や毒性薬剤によ
り、魚類に奇形が急増加しているとの報告で、よ
り安全な物質の使用が求められていることであ
る。 Another serious problem has recently come to the fore. Among the various metals and chemicals used to make fishing nets and ropes antifouling, some are extremely toxic, creating a situation that cannot be overlooked from a health and hygiene perspective. For example, there are reports of a sudden increase in malformations in fish caused by tin compounds and toxic drugs such as tributyltin oxide, and there is a need to use safer substances.
（問題を解決するための手段）
本発明は上述の問題点を解決するため、種々研
究を重ね試行錯誤の後に生れたもので、その基本
的技術に就て述べると、漁網やロープの漁網類の
表面に適宜の塗料、又は接着剤、或はその混合物
等（塗材）５の中に、粒子径が５〜200μｍのセ
ラミツクス又は金属粒子４の該塗材に対し、25〜
400容量％含有させて成る下塗材を塗布し、乾燥
して表面粗さ（Rz）30〜250μｍの皮膜２を形成
し、次いで、この皮膜上に銅又は銅合金を低温溶
射することにより、漁網やロープの表面に銅又は
銅合金の微粒子薄層６′を形成した漁網Ａ又はロ
ープを得るものである。(Means for solving the problem) In order to solve the above-mentioned problems, the present invention was born after various studies and trial and error. Appropriate paint, adhesive, or a mixture thereof (coating material) 5 is coated with ceramic or metal particles 4 having a particle size of 5 to 200 μm on the surface of the coating material.
A fishing net is prepared by applying a primer material containing 400% by volume, drying to form a film 2 with a surface roughness (Rz) of 30 to 250 μm, and then low-temperature spraying copper or copper alloy onto this film. A fishing net A or a rope having a fine particle thin layer 6' of copper or copper alloy formed on the surface of the fishing net A or rope is obtained.
漁網やロープに金属溶射する場合は、漁網であ
れば、たて（又は横）方向に収束して漁網を構成
する脚３及び結節７の隣接するものを互いに寄せ
合はした上で、下塗材の塗布、噴霧並びに金属溶
射を行のう。ロープの場合は、ロープを何本も引
揃え、隙間の無い状態で行のうと効果的である。 When spraying metal on fishing nets or ropes, in the case of fishing nets, the adjacent legs 3 and knots 7 that converge in the vertical (or horizontal) direction to form the fishing net are brought together, and then the base coat material is applied. Coating, spraying and metal spraying. In the case of ropes, it is effective to line up several ropes without any gaps.
前記の下塗材は、普通の塗料のように液状と
し、これを刷毛やスプレーで漁網やロープに塗布
するのである。下塗材自体は、淡水や海水に対し
て強く、漁網やロープに適度の接着力さえあれ
ば、どのようなものでもよく、油性、溶剤性等何
れのタイプのものも利用できる。この性質は下塗
材を構成する樹脂や溶剤によつて決まるから、そ
の選択は大切である。 The above-mentioned primer material is made into a liquid like an ordinary paint, and is applied to fishing nets and ropes with a brush or spray. The undercoating material itself may be of any type as long as it is resistant to freshwater or seawater and has a suitable adhesion to fishing nets or ropes, and can be of any type, such as oil-based or solvent-based. This property is determined by the resin and solvent that make up the primer material, so the selection is important.
漁網やロープに前記した下塗材を塗布すると、
その全体を包み込んで皮膜が形成されるから、剥
落が生じ難い形態となり、平面上に金属を溶射す
る場合の下塗材に比らべ、接着性については、さ
ほど厳格に考えなくてもよい。 When the above-mentioned primer material is applied to fishing nets and ropes,
Since a film is formed covering the entire surface, it is difficult to peel off, and there is no need to consider the adhesion as strictly as compared to an undercoat material when metal is thermally sprayed onto a flat surface.
金属溶射の手段は、いわゆる低温溶射が好まし
く、高温の溶射では漁網やロープが弱化したり燃
える危険がある。低温溶射では溶射した金属微粒
子が対象物に附着する時点でその温度は25℃程度
の低いものであるから、漁網やロープに何らの悪
影響をも与えない。 The preferred method for metal spraying is so-called low-temperature spraying; high-temperature spraying risks weakening fishing nets and ropes or causing them to catch fire. In low-temperature thermal spraying, the temperature of the sprayed metal particles is as low as 25 degrees Celsius when they adhere to the object, so they do not have any adverse effects on fishing nets or ropes.
塗材としては、耐水性を具えた各種塗料、接着
剤、又はその混合物を自由に選択使用できる。例
えば、合成樹脂塗料、接着剤としては、塩化ビニ
ル系、酢酸ビニル系、エポキシ樹脂、フエノール
系樹脂、キシレン系樹脂を主体とするもの、或は
これらの２種以上混合物が利用できるし、これに
着色剤等を混入してもよい。 As the coating material, various water-resistant paints, adhesives, or mixtures thereof can be freely selected and used. For example, as synthetic resin paints and adhesives, those based mainly on vinyl chloride, vinyl acetate, epoxy resin, phenol resin, and xylene resin, or a mixture of two or more of these can be used. A coloring agent or the like may be mixed.
前記下塗剤中に混入する金属粒子としては、銅
又は銅合金の粒子が好適であり、セラミツクスの
材質としては、非金属である石英等の鉱石粉、及
び金属の酸化物、窒化物、炭化物が広く利用でき
る。具体的には酸化アルミニウム、酸化珪素、酸
化鉄、炭化珪素、等である。なお、塗剤の溶媒組
成によつては、合成樹脂粉末を用いることもでき
る。例えばアクリル、スチレン、エポキシ、ポリ
エチレン樹脂等である。粒子の大きさは５〜
200μｍ、好ましくは、20〜120μｍである。そし
て下塗剤が皮膜を形成したときの表面粗さ（Rz）
は50〜150μｍが好ましい。 The metal particles to be mixed in the primer are preferably copper or copper alloy particles, and the ceramic material includes non-metallic ore powder such as quartz, and metal oxides, nitrides, and carbides. Widely available. Specifically, aluminum oxide, silicon oxide, iron oxide, silicon carbide, etc. are used. Note that synthetic resin powder can also be used depending on the solvent composition of the coating material. For example, acrylic, styrene, epoxy, polyethylene resin, etc. Particle size is 5~
200 μm, preferably 20 to 120 μm. and the surface roughness (Rz) when the primer forms a film.
is preferably 50 to 150 μm.
漁網が大きい場合とか、使用目的によつては、
漁網全体に金属溶射するのでなく、部分的に金属
溶射区域を形成することもできる。例えば、広い
漁網に窓の状態で金属溶射区域を適宜の間隔を置
いて設けるとか、紅白の幕状に金属溶射層を有す
る漁網部分と、有しない漁網部分とを交互に連ね
たものとする等である。ロープの場合も所々金属
薄層の無い部分を設けることもできる。 Depending on the size of the fishing net or the purpose of use,
Rather than spraying the entire fishing net with metal, it is also possible to form metal sprayed areas in parts. For example, a wide fishing net may be provided with metal sprayed areas at appropriate intervals in the form of windows, or a red and white curtain-like fishing net may have parts with and without a metal sprayed layer alternately arranged. It is. In the case of a rope, it is also possible to provide portions without a thin metal layer here and there.
下塗材を塗布して形成される皮膜２の厚さは、
用途により自由に選択できるが、実際には樹脂組
成物10〜300ｇ／m2でよい。 The thickness of the film 2 formed by applying the primer material is:
The resin composition can be freely selected depending on the purpose, but in reality, the resin composition may be 10 to 300 g/m 2 .
（作用）
本発明漁網やロープは第１図に示すように、そ
の表面に銅又は銅合金を溶射して成る金属微粒子
の薄層６′を有するのが特徴である。普通、天然
又は合成繊維で作られた漁網やロープに金属溶射
することは不可能であるが、本発明はこれを可能
にしたもので、その理由を第２図、第３図により
説明すると、漁網を構成する糸１の表面に前記し
た塗材５中にセラミツクス粒子４を混入して成る
下塗材を塗布することにより、塗材が乾燥すると
皮膜２が形成される。この皮膜を拡大して見る
と、ランダムに積層する金属粉、又はセラミツク
ス粒子４が塗材５により多くはピラミツド状に接
着されて形成され、塗材と粒子との混合比によ
り、多少その形態は異なるが、ほゞ第３図の状態
で漁網の脚３や結節７の週面に接着形成されてい
るから、この皮膜上に銅又は銅合金を溶射する
と、溶射された銅微粒子６は、金属又はセラミツ
クス粒子４と物理的に強固に結合することにな
る。また、金属やセラミツクス粒子４自体は塗材
５により漁網上に固着しているから、結局溶射金
属粒子６は漁網の上に強固に固着され、金属薄層
６′を形成する。(Function) As shown in FIG. 1, the fishing net or rope of the present invention is characterized by having a thin layer 6' of fine metal particles formed by thermally spraying copper or a copper alloy on its surface. Normally, it is impossible to spray metal onto fishing nets or ropes made of natural or synthetic fibers, but the present invention has made this possible, and the reason for this is explained with reference to Figures 2 and 3. By applying an undercoat material made of the coating material 5 mixed with ceramic particles 4 to the surface of the thread 1 constituting the fishing net, a film 2 is formed when the coating material dries. When this film is enlarged, it is formed by randomly laminating metal powder or ceramic particles 4 adhered to the coating material 5, often in a pyramid shape, and the shape varies depending on the mixing ratio of the coating material and particles. Although it is different, it is adhered to the legs 3 and knots 7 of the fishing net in the state shown in FIG. Alternatively, it will be physically strongly bonded to the ceramic particles 4. Moreover, since the metal or ceramic particles 4 themselves are fixed onto the fishing net by the coating material 5, the sprayed metal particles 6 are eventually firmly fixed onto the fishing net, forming a thin metal layer 6'.
さて、溶射された銅粒子６は、周知の通り非常
に複雑な形状を有し、普通樹枝状と言はれている
が、その表面積は極めて大きいものである。また
第４図に示すように、金属薄層６′の表面６ａは
何ら他物により蔽はれることなく、全面が外界と
接する形状であるから、このような漁網Ａを海中
に入れると、多量の銅イオンが発生し、防汚効果
は絶大なものがある。 Now, as is well known, the thermally sprayed copper particles 6 have a very complicated shape and are usually said to be dendritic, but their surface area is extremely large. Furthermore, as shown in FIG. 4, the surface 6a of the thin metal layer 6' is in such a shape that the entire surface is in contact with the outside world without being blocked by anything else, so when such a fishing net A is put into the sea, a large amount of Copper ions are generated, and the antifouling effect is tremendous.
実験によると、銅又は銅合金の厚さを厚くして
置くことにより、１年〜２年間も藻や貝類の附着
を見ないで、漁網を海中に設置できることが判つ
た。 Experiments have shown that by increasing the thickness of copper or copper alloy, it is possible to set up fishing nets underwater for one to two years without seeing algae or shellfish build up.
実施例
() 合成繊維を用いて成る漁網の全面に、エポ
キシ樹脂100ｇ、キシレン80ｇ、メチルエチル
ケトン60ｇ、ブタノール25ｇを加えて溶解した
後、ポリアミド樹脂10ｇを添加して得たエポキ
シ−ポリアミド樹脂塗材275ｇに、平均粒度
50μｍの炭化珪素221ｇ（微粒子70cm2）を混入
し、充分撹拌して得た下塗材を塗布し、表面粗
さ（Rz）60μｍの皮膜２を形成し、乾燥後、該
皮膜表面に銅を低温溶射し、金属薄層６′（厚
さ40〜50μｍ）を形成した漁網を得た。Example () 275 g of epoxy-polyamide resin coating obtained by adding and dissolving 100 g of epoxy resin, 80 g of xylene, 60 g of methyl ethyl ketone, and 25 g of butanol to the entire surface of a fishing net made of synthetic fibers, and then adding 10 g of polyamide resin. , the average particle size
221 g of 50 μm silicon carbide (fine particles 70 cm 2 ) is mixed in and thoroughly stirred to form an undercoat material, which forms a film 2 with a surface roughness (Rz) of 60 μm. After drying, copper is coated on the surface of the film at a low temperature. A fishing net on which a thin metal layer 6' (thickness: 40 to 50 μm) was formed by thermal spraying was obtained.
() 次に、別の実施例について述べると、天然
繊維を用いた漁網の全面に、アクリルポリオー
ル樹脂170ｇに、イソシアネート樹脂33ｇを添
加して得た溶剤型ウレタン−アクリル樹脂塗材
203ｇと、平均粒子径20μｍの酸化アルミニウ
ム119ｇとを充分撹拌して得た樹脂組成物をシ
ンナーで希釈した下塗材を塗布し、乾燥して表
面粗さ（Rz）40μｍの皮膜２を形成させ、その
上に銅合金を低温溶射することにより、その表
面に銅合金による溶射薄層を有する漁網を得
た。() Next, to describe another example, a solvent-based urethane-acrylic resin coating material obtained by adding 33 g of isocyanate resin to 170 g of acrylic polyol resin was applied to the entire surface of a fishing net using natural fibers.
203g and 119g of aluminum oxide having an average particle size of 20μm are sufficiently stirred, a resin composition obtained by diluting with thinner is applied, and dried to form a film 2 with a surface roughness (Rz) of 40μm. By low-temperature thermal spraying a copper alloy thereon, a fishing net having a thin thermally sprayed layer of copper alloy on its surface was obtained.
() 前記実施例（）に於て得た漁網と普通の
漁網とを一定幅宛交互に継いで所定長の漁網を
得た。() A fishing net of a predetermined length was obtained by alternately splicing the fishing net obtained in Example () above and an ordinary fishing net to a certain width.
() 実施例（）又は（）の加工を漁網の所
定区域のみに施すことにより、漁網の所定位置
に窓状の金属薄層を有する漁網を得た。() By applying the processing in Example () or () only to a predetermined area of a fishing net, a fishing net having a window-like metal thin layer at a predetermined position of the fishing net was obtained.
() ロープを適宜本数引揃えて置き、実施例
（）又は（）の加工を施すことにより、表
面に金属溶射薄層を有するロープを得た。() A suitable number of ropes were arranged and processed in Example () or () to obtain a rope having a thin metal sprayed layer on the surface.
（発明の効果）
本発明の漁網やロープは上述の構造を有し、こ
れを海中に沈めた場合、銅イオンが多量に生じ、
無毒で有効な防汚効果をあらわし、１年〜２年の
長期間、藻や貝類の附着が無いので、清掃等の手
数を要しないから、甚だ便利である。定置網に利
用した場合は、養殖魚の発育が順調で、漁網内の
酸素欠乏などの問題は全く解消される有効なもの
である。(Effect of the invention) The fishing net and rope of the present invention have the above-mentioned structure, and when it is submerged in the sea, a large amount of copper ions are generated,
It exhibits a non-toxic and effective antifouling effect, and is extremely convenient because it does not require any cleaning or other troubles as it does not have adhesion of algae or shellfish for a long period of one to two years. When used in fixed nets, the growth of cultured fish is smooth, and problems such as lack of oxygen in fishing nets are completely eliminated, making it an effective method.
第１図は本発明漁網の一部を示す説明図、第２
図は、漁網を構成する糸の一部切欠き図、第３図
は皮膜の状態を示す拡大図、第４図は溶射した金
属薄層を皮膜を示す拡大説明図。
符号説明、Ａ……本発明漁網、１……漁網やロ
ープの糸、２……皮膜、３……脚、４……セラミ
ツクス粒子、５……塗材、６……金属粒子、６′
……金属薄層、７……結節、６ａ……表面。
Figure 1 is an explanatory diagram showing a part of the fishing net of the present invention, Figure 2 is an explanatory diagram showing a part of the fishing net of the invention.
The figure is a partially cutaway view of the threads constituting the fishing net, FIG. 3 is an enlarged view showing the state of the coating, and FIG. 4 is an enlarged explanatory view showing the coating of a thermally sprayed metal thin layer. Explanation of symbols, A... Fishing net of the present invention, 1... Fishing net or rope thread, 2... Film, 3... Legs, 4... Ceramic particles, 5... Coating material, 6... Metal particles, 6'
...Thin metal layer, 7... Nodule, 6a... Surface.
Claims (1)
料、又は接着剤或は両者の混合より成る塗材中に
粒子径が５〜200μｍのセラミツクス粒子、金属
粒子を25〜400容量％混入して成る下塗材を塗布
し、乾燥後形成される皮膜２上に銅又は銅合金を
低温溶射することにより表面に該金属薄層６′が
形成されたことを特徴とする防汚漁網類。 ２ 漁網の一部区域が金属溶射による金属薄層
６′有する区画とし、且つ該区画を漁網面に必要
数設けたものである特許請求の範囲第１項記載の
防汚漁網類。 ３ 漁網類を収束した状態でその表面に耐水性、
耐海水性の塗料又は接着剤、或は両者の混合より
成る塗材中に粒子径が５〜200μｍのセラミツク
ス粒子を25〜400容量％混入して成る下塗材を塗
布し乾燥後漁網類を表面に形成された皮膜２上に
低温溶射機により、銅又は銅合金を溶射すること
により、金属薄層６′を形成することを特徴とす
る防汚漁網類の製造方法。 ４ 漁網の一部区域に金属薄層６′形成した防汚
区域を漁網面に必要数窓状に形成する特許請求の
範囲第３項記載の防汚漁網類の製造方法。 ５ 表面に金属薄層６′を有する漁網と、金属薄
層を有しない漁網とを交互に連接して漁網を形成
する特許請求の範囲第３項記載の防汚漁網類の製
造方法。[Scope of Claims] 1. Ceramic particles or metal particles with a particle size of 5 to 200 μm are added to the surface of fishing nets in a coating material made of water-resistant, seawater-resistant paint, adhesive, or a mixture of both. The metal thin layer 6' is formed on the surface by applying an undercoating material containing ~400% by volume and then low-temperature spraying copper or a copper alloy onto the film 2 formed after drying. Antifouling fishing nets. 2. The antifouling fishing net according to claim 1, wherein a portion of the fishing net has a thin metal layer 6' formed by metal spraying, and a necessary number of such zones are provided on the surface of the fishing net. 3 Water resistance on the surface of fishing nets
An undercoat consisting of seawater-resistant paint or adhesive, or a mixture of both, mixed with 25 to 400% by volume of ceramic particles with a particle size of 5 to 200 μm is applied, and after drying, fishing nets are coated on the surface. A method for manufacturing antifouling fishing nets, which comprises forming a thin metal layer 6' by thermally spraying copper or a copper alloy onto the film 2 formed on the surface of the net using a low-temperature spraying machine. 4. The method for manufacturing antifouling fishing nets according to claim 3, wherein a necessary number of antifouling areas are formed on the surface of the fishing net in the form of windows by forming a thin metal layer 6' on a partial area of the fishing net. 5. The method for producing antifouling fishing nets according to claim 3, wherein fishing nets are formed by alternately connecting fishing nets having a thin metal layer 6' on their surfaces and fishing nets having no thin metal layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62114974A JPS63279736A (en) | 1987-05-11 | 1987-05-11 | Antifouling fishing nets and production thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62114974A JPS63279736A (en) | 1987-05-11 | 1987-05-11 | Antifouling fishing nets and production thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63279736A JPS63279736A (en) | 1988-11-16 |
| JPH0339647B2 true JPH0339647B2 (en) | 1991-06-14 |
Family
ID=14651234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62114974A Granted JPS63279736A (en) | 1987-05-11 | 1987-05-11 | Antifouling fishing nets and production thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63279736A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4593801B2 (en) * | 2001-01-30 | 2010-12-08 | ハイモ株式会社 | Paper strength enhancement method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007261385A (en) * | 2006-03-28 | 2007-10-11 | Nippon N U S Kk | Substrate structure for anti-fouling of shellfish |
-
1987
- 1987-05-11 JP JP62114974A patent/JPS63279736A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4593801B2 (en) * | 2001-01-30 | 2010-12-08 | ハイモ株式会社 | Paper strength enhancement method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63279736A (en) | 1988-11-16 |
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