JPH0333242A - Knitted sheet material formed using monofilament of flame- resistant polyester - Google Patents
Knitted sheet material formed using monofilament of flame- resistant polyesterInfo
- Publication number
- JPH0333242A JPH0333242A JP2161159A JP16115990A JPH0333242A JP H0333242 A JPH0333242 A JP H0333242A JP 2161159 A JP2161159 A JP 2161159A JP 16115990 A JP16115990 A JP 16115990A JP H0333242 A JPH0333242 A JP H0333242A
- Authority
- JP
- Japan
- Prior art keywords
- sheet material
- diameter
- monofilament
- textile sheet
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 30
- 229920000728 polyester Polymers 0.000 title claims abstract description 14
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002009 diols Chemical class 0.000 claims abstract description 4
- 239000003063 flame retardant Substances 0.000 claims abstract description 4
- 239000012209 synthetic fiber Substances 0.000 claims abstract description 3
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 3
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract 3
- 125000000217 alkyl group Chemical group 0.000 claims abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract 2
- 125000003118 aryl group Chemical group 0.000 claims abstract 2
- 239000004753 textile Substances 0.000 claims description 16
- 241000446313 Lamella Species 0.000 claims description 7
- 239000000835 fiber Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000002759 woven fabric Substances 0.000 abstract description 2
- 125000000732 arylene group Chemical group 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 239000004952 Polyamide Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/84—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
-
- E—FIXED CONSTRUCTIONS
- E06—DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
- E06B—FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
- E06B9/00—Screening or protective devices for wall or similar openings, with or without operating or securing mechanisms; Closures of similar construction
- E06B9/24—Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blinds
- E06B9/26—Lamellar or like blinds, e.g. venetian blinds
- E06B9/38—Other details
- E06B9/386—Details of lamellae
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、剛化要素を含む耐燃性合成繊維によって形成
された編織布シート材料に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention This invention relates to woven sheet materials formed from flame resistant synthetic fibers containing stiffening elements.
（従来の技術）
ＤＥ−Ｃ−２３４６７８７は、燐含有鎖状要素を組込む
ことによって高耐燃性とされたポリエステル繊維及びフ
ィラメントを開示している。これらの繊維及びフィラメ
ントは、高い耐燃性の結果、とりわけ防水布材料、カー
ペット及びカーテンとして推奨される。PRIOR ART DE-C-2346787 discloses polyester fibers and filaments made highly flame resistant by incorporating phosphorus-containing chain elements. These fibers and filaments are recommended, inter alia, as waterproof fabric materials, carpets and curtains as a result of their high flame resistance.
ある種の用途のためには、該編織布シート材料は剛化す
る必要がある。ＤＥ−Ｕ−７９１５５９３は、２２０〜
２５５°Ｃでの熱処理によって可塑化することによる耐
燃性ポリエステル繊維から形成された剛化シート材料を
開示している。このような熱処理は付加的な工程であり
、シート材料の可塑化によってその編織布特性が損なわ
れる。For certain applications, the textile sheet material needs to be stiffened. DE-U-7915593 is 220~
A stiffened sheet material formed from flame resistant polyester fibers by plasticizing by heat treatment at 255°C is disclosed. Such heat treatment is an additional step and plasticizes the sheet material, thereby impairing its textile properties.
ＤＥ−Ｕ−７１１７０８５は、ポリアミド若しくは高分
子線状ポリエステルのフィラメントが、ストライブ形状
の編織布シート材料内へ横方向に組み入れられることに
より必要な剛性が付与されている、遮光若しくは間仕切
りブラインドのためのラメラを開示している。しかしな
がら、これらのシート材料は耐燃性がほんの少ししかな
い。確かにこれらの材料は、仕上げを施すことによって
耐燃性にすることができる。しかしながら、仕上げを施
すことは資源の増大につながり、従って高価なものとな
る。DE-U-7117085 for blackout or partition blinds in which filaments of polyamide or polymeric linear polyester are incorporated laterally into a textile sheet material in the form of stripes, thereby imparting the necessary stiffness. lamellae are disclosed. However, these sheet materials have only modest flame resistance. Indeed, these materials can be made flame-resistant by applying a finish. However, applying a finish increases resources and is therefore expensive.
本発明の目的は、製造が簡単であり且つ有利な編織布特
性を有する耐燃性で剛性の高い編織布シート材料を提供
することである。It is an object of the present invention to provide a flame resistant, stiff textile sheet material that is simple to manufacture and has advantageous textile properties.
（発明の概要）
上記の目的は、当初に述べたタイプの編織布シート材料
を原料とし、ジカルボン酸及びジオール成分から形成さ
れ且つ難燃剤を組み込んだポリエステルからなるモノフ
ィラメント（２０，３０）から剛化要素を形成すること
により、本発明によって達成される。SUMMARY OF THE INVENTION The above object is based on a textile sheet material of the type initially mentioned, stiffened from monofilaments (20, 30) consisting of polyester formed from dicarboxylic acid and diol components and incorporating flame retardants. This is achieved according to the invention by forming the elements.
耐燃性モノフィラメントを使用するこトニヨって、所望
の剛性度を示すのに、如何なる可塑化若しくは仕上げも
必要としない耐燃性シート材料を作ることが可能となっ
た。該ポリエステルは、製造か簡単であるにもかかわら
ず、実質的に編織布特性を保持する。例えば、たて糸及
びよこ糸に対して異なった応カー歪み関係（例えば、高
弾性率のたて糸と、低い弾性率及び低い収縮率のよこ糸
）を達成することができる。The use of flame resistant monofilaments has made it possible to create flame resistant sheet materials that do not require any plasticization or finishing to exhibit the desired stiffness. The polyester is simple to manufacture yet retains substantially textile properties. For example, different stress-strain relationships for the warp and weft yarns (eg, warp yarns with high modulus and weft yarns with low modulus and shrinkage) can be achieved.
好ましくは、ＤＥ−Ｃ−２３４６７８７に記載されてい
るような原料の改質によって、該ポリエステルを耐燃性
にする。該シート材料は、これらのモノフィラメントの
みからなってもよい。或は、モノフィラメントが該シー
ト材料の一部分のみをなし、残りが耐燃性のマルチフィ
ラメント若しくは制限のないステープル長さの繊維から
なってもよい。Preferably, the polyester is made flame resistant by modification of the raw materials as described in DE-C-2346787. The sheet material may consist only of these monofilaments. Alternatively, monofilaments may form only a portion of the sheet material, with the remainder consisting of flame resistant multifilaments or open-ended staple length fibers.
本発明によって形成されたシート材料の好ましい用途は
、日よけ、遮光ラメラ、ベ不シヤンブラインド、カーテ
ンテープ、スライドドア、ベローズ及び椅子張りである
。該モノフィラメントの直径は、日よけ、べ不シャンブ
ラインド、遮光ラメラ及びカーテンテープの場合は０．
１５〜０．４０■、ベーローズの場合には０．３０−０
．７０ｍｍ。Preferred applications for sheet materials formed according to the invention are sunshades, blackout lamellas, blinds, curtain tapes, sliding doors, bellows and upholstery. The diameter of the monofilament is 0.0 for sunshades, blinds, blackout lamellas, and curtain tapes.
15~0.40■, 0.30-0 in case of bellows
．． 70mm.
スライドドアーの場合には０．３０〜０．８０ｍｍであ
ることが都合がよい。In the case of a sliding door, it is convenient that it is 0.30 to 0.80 mm.
（実施例） 本発明の実施例を図面を参照しつつ説明する。(Example) Embodiments of the present invention will be described with reference to the drawings.
第１図はベローズの断面図であり、第２図は遮光ラメラ
の断面図である。FIG. 1 is a sectional view of the bellows, and FIG. 2 is a sectional view of the light-shielding lamella.
第１図は、列車間において使用される歩み板ベローズを
示す。該ベローズは、中心層目とゴム、ポリ塩化ビニル
（ＰＶＣ）又は他のゴム状プラスチックで作られた２つ
の外側層＋６．ＩＢの間に埋設されたシート成層１０．
１２からなる。FIG. 1 shows a footboard bellows used between trains. The bellows consists of a central layer and two outer layers made of rubber, polyvinyl chloride (PVC) or other rubbery plastics +6. Sheet layer buried between IBs 10.
Consists of 12.
層１０．Ｈを形成するシート材料は、よこ糸が耐燃性ポ
リエステルのフィラメント２０からなり、たて糸が耐ｆ
ｆｉ性ポリエステルのマルチフィラメント２２からなる
、織物である。モノフィラメント２０とマルチフィラメ
ント２２は、両方とも好ましくはＤＥ−Ｃ−２３４６７
８７の教示に従って製造する。Layer 10. The sheet material forming H has a weft yarn made of flame-resistant polyester filament 20, and a warp yarn made of flame-resistant polyester filament 20.
It is a woven fabric made of multifilament 22 of fi-polyester. Monofilament 20 and multifilament 22 are both preferably DE-C-23467
Manufactured according to the teachings of No. 87.
モノフィラメント２０は、丸い好ましくは円形の断面を
有し、その直径は０．３０〜０．７０ｍ＋ｍである。The monofilament 20 has a round, preferably circular cross section and a diameter of 0.30 to 0.70 m+m.
第２図は、遮光ラメラのたて糸方向における断面を示す
。該遮光ラメラは、底部たて糸２４、頂部たて糸２６及
びよこ糸２８．３０を含む織物シート材料からなる。た
て糸２４．２６及びよこ糸２８は、各々、例えば耐燃性
ポリエステル若しくはポリアミドで作られたマルチフィ
ラメントの糸からなる。剛化モノフィラメント３０は、
好ましくはＤＥ−Ｃ−２３４６７８７の教示に従って作
られた耐燃性のポリエステルからなる。FIG. 2 shows a cross section of the light-shielding lamella in the warp direction. The blackout lamella consists of a textile sheet material comprising a bottom warp 24, a top warp 26 and a weft 28.30. The warp yarns 24, 26 and the weft yarns 28 each consist of multifilament yarns made of flame-resistant polyester or polyamide, for example. The stiffened monofilament 30 is
It preferably consists of flame-resistant polyester made according to the teachings of DE-C-2346787.
モノフィラメント３０の直径は０．１５〜０，４０ｍ１
Ｉである。The diameter of the monofilament 30 is 0.15 to 0.40 m1
It is I.
第１図はベローズの断面図であり、第２図は遮光ラメラ
の断面図である。
１０．１２−−−シート材料、 ロー−−中心層、１６
．１８
外側層、
０
七ノフイラメント、
２
マルチフィラメント
２４．２６
たて糸、
Ｈ，３０
よこ糸
代
理
人
弁
理
士
湯
浅
恭
＝１
・１
Ｙ′ｊ
（外４名）FIG. 1 is a sectional view of the bellows, and FIG. 2 is a sectional view of the light-shielding lamella. 10.12---Sheet material, low--center layer, 16
．． 18 Outer layer, 0 Seven filament, 2 Multifilament 24.26 Warp, H, 30 Weft Representative patent attorney Kyo Yuasa = 1 ・1 Y'j (4 others)
Claims (1)
編織布シート材料であって、前記剛化要素が、ジカルボ
ン酸及びジオール成分によって形成され且つ難燃剤が配
合されたポリエステルからなるモノフィラメント（２０
、３０）を含む、編織布シート材料。 ２、前記難燃剤が、一般式 ▲数式、化学式、表等があります▼ （式中、Ｒは飽和開鎖若しくは環状のアルキレン、アリ
ーレン又はアラルキレンであり、Ｒ＿１は炭素原子が１
〜６のアルキル、アリール又はアラルキルである）の構
造単位を含む共重合した鎖状要素の形で、前記ポリエス
テル鎖内に存在する、第１請求項記載の編織布シート材
料。 ３、前記シート材料の繊維のうちのほんの幾つかがモノ
フィラメント（２０、３０）からなる、第１若しくは第
２請求項に記載の編織布シート材料。 ４、前記モノフィラメント（２０、３０）が円形断面を
有し、その直径が０．１５〜０．８０ｍｍである、第１
〜第３請求項のうちのいずれか一の項に記載の編織布シ
ート材料。 ５、前記モノフィラメント（３０）の直径が０．１５〜
０．４０ｍｍである、日よけ、遮光ラメラ及びベネシャ
ンブラインドのための第４請求項記載の編織布シート材
料。 ６、前記モノフィラメントの直径が０．１５〜０．４０
ｍｍである、カーテンテープのための第４請求項記載の
編織布シート材料。 ７、前記モノフィラメント（２０）の直径が０．３０〜
０．７０ｍｍである、ベローズのための第４請求項記載
の編織布シート材料。 ８、前記モノフィラメントの直径が０．３０〜０．８０
ｍｍである、スライドドアのための第４請求項記載の編
織布シート材料。[Scope of Claims] 1. A textile sheet material formed of flame-resistant synthetic fibers containing a stiffening element, the stiffening element being formed of a dicarboxylic acid and diol component and containing a flame retardant. Monofilament made of polyester (20
, 30). 2. The flame retardant has a general formula ▲ mathematical formula, chemical formula, table, etc.
A textile sheet material according to claim 1, wherein the polyester chain is present in the form of copolymerized chain elements comprising structural units of -6 alkyl, aryl or aralkyl. 3. Textile sheet material according to claim 1 or 2, wherein only some of the fibers of said sheet material consist of monofilaments (20, 30). 4. The first monofilament (20, 30) has a circular cross section and a diameter of 0.15 to 0.80 mm.
A textile sheet material according to any one of claims 1 to 3. 5. The monofilament (30) has a diameter of 0.15~
A textile sheet material according to claim 4 for sunshades, blackout lamellas and venetian blinds having a thickness of 0.40 mm. 6. The monofilament has a diameter of 0.15 to 0.40.
5. The textile sheet material according to claim 4 for curtain tape, having a diameter of 1 mm. 7. The monofilament (20) has a diameter of 0.30~
A textile sheet material according to claim 4 for bellows having a diameter of 0.70 mm. 8. The monofilament has a diameter of 0.30 to 0.80.
5. The textile sheet material according to claim 4 for sliding doors, having a diameter of mm.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE8907505U DE8907505U1 (en) | 1989-06-20 | 1989-06-20 | |
| DE8907505.6 | 1989-06-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0333242A true JPH0333242A (en) | 1991-02-13 |
Family
ID=6840276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2161159A Pending JPH0333242A (en) | 1989-06-20 | 1990-06-19 | Knitted sheet material formed using monofilament of flame- resistant polyester |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0403969B1 (en) |
| JP (1) | JPH0333242A (en) |
| CA (1) | CA2019311A1 (en) |
| DE (2) | DE8907505U1 (en) |
| MX (1) | MX173845B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160132553A (en) * | 2015-05-11 | 2016-11-21 | 주식회사 동우 | Method of fabricating synthetic thread using pozzolan and synthetic thread manufactured by the same and gloves comprising the synthetic thread |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4321560A1 (en) * | 1993-06-29 | 1995-01-12 | Danubia Petrochem Deutschland | Polyolefin yarn and fabric |
| DE4344691A1 (en) | 1993-12-27 | 1995-06-29 | Hoechst Ag | High tenacity, flame retardant polyester yarn, process for its manufacture and its use |
| DE29706342U1 (en) * | 1997-04-10 | 1997-07-10 | Certoplast Vorwerk & Sohn Gmbh | Adhesive tape, in particular winding tape for bundling cables in automobiles |
| DE19826120C2 (en) * | 1998-03-20 | 2001-06-07 | Eurea Verpackung | Flame retardant, electrically conductive fabric |
| DE10018484A1 (en) * | 2000-04-14 | 2001-10-18 | Schmitz Werke | Awning fabric and process for its manufacture |
| DE102004043193B4 (en) * | 2004-09-03 | 2006-09-07 | Hübner GmbH | Single or multi-ply, preferably two-ply textile |
| DE102013103901A1 (en) | 2013-04-18 | 2014-10-23 | Contitech Elastomer-Beschichtungen Gmbh | Multilayer article, in particular bellows, containing at least one textile fabric |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1535426B1 (en) * | 1966-07-16 | 1972-05-04 | French & Sons Thomas | Curtain strap |
| DE2346787C3 (en) * | 1973-09-17 | 1980-05-08 | Hoechst Ag, 6000 Frankfurt | Flame retardant linear polyesters, processes for their manufacture and their use |
| DE2940734A1 (en) * | 1979-10-08 | 1981-04-16 | Schlitzer Leinen - Industrie Driessen GmbH & Co KG, 6407 Schlitzen | TEXTILE FABRIC SLATS FOR THE PRODUCTION OF BLINDS OR CURTAINS |
| DE8903746U1 (en) * | 1989-03-25 | 1989-05-11 | Parabeam B.V., Helmond, Nl | |
| US4929497A (en) * | 1989-03-27 | 1990-05-29 | Albany International Corp. | Flame retardant rolling door |
-
1989
- 1989-06-20 DE DE8907505U patent/DE8907505U1/de not_active Expired
-
1990
- 1990-06-15 EP EP90111307A patent/EP0403969B1/en not_active Expired - Lifetime
- 1990-06-15 DE DE59010687T patent/DE59010687D1/en not_active Expired - Fee Related
- 1990-06-19 CA CA002019311A patent/CA2019311A1/en not_active Abandoned
- 1990-06-19 JP JP2161159A patent/JPH0333242A/en active Pending
- 1990-06-20 MX MX021230A patent/MX173845B/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20160132553A (en) * | 2015-05-11 | 2016-11-21 | 주식회사 동우 | Method of fabricating synthetic thread using pozzolan and synthetic thread manufactured by the same and gloves comprising the synthetic thread |
Also Published As
| Publication number | Publication date |
|---|---|
| DE59010687D1 (en) | 1997-04-30 |
| CA2019311A1 (en) | 1990-12-20 |
| EP0403969A2 (en) | 1990-12-27 |
| EP0403969B1 (en) | 1997-03-26 |
| DE8907505U1 (en) | 1989-11-02 |
| EP0403969A3 (en) | 1991-11-13 |
| MX173845B (en) | 1994-04-03 |
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