JPH0333153A - Thermoplastic resin composition - Google Patents
Thermoplastic resin compositionInfo
- Publication number
- JPH0333153A JPH0333153A JP16679389A JP16679389A JPH0333153A JP H0333153 A JPH0333153 A JP H0333153A JP 16679389 A JP16679389 A JP 16679389A JP 16679389 A JP16679389 A JP 16679389A JP H0333153 A JPH0333153 A JP H0333153A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- compsn
- weight
- resistance
- polyester resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 7
- 239000011342 resin composition Substances 0.000 title claims description 6
- 229920001225 polyester resin Polymers 0.000 claims abstract description 13
- 239000004645 polyester resin Substances 0.000 claims abstract description 13
- 229920005668 polycarbonate resin Polymers 0.000 claims abstract description 12
- 239000004431 polycarbonate resin Substances 0.000 claims abstract description 12
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 5
- 239000000126 substance Substances 0.000 abstract description 7
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- 238000007747 plating Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000004417 polycarbonate Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ULDDEWDFUNBUCM-UHFFFAOYSA-N pentyl prop-2-enoate Chemical compound CCCCCOC(=O)C=C ULDDEWDFUNBUCM-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- MLDVVJZNWASRQL-UHFFFAOYSA-N 4-diethoxyphosphinothioyloxy-n,n,6-trimethylpyrimidin-2-amine Chemical group CCOP(=S)(OCC)OC1=CC(C)=NC(N(C)C)=N1 MLDVVJZNWASRQL-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- AOJOEFVRHOZDFN-UHFFFAOYSA-N benzyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC1=CC=CC=C1 AOJOEFVRHOZDFN-UHFFFAOYSA-N 0.000 description 1
- GCTPMLUUWLLESL-UHFFFAOYSA-N benzyl prop-2-enoate Chemical compound C=CC(=O)OCC1=CC=CC=C1 GCTPMLUUWLLESL-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- KBLWLMPSVYBVDK-UHFFFAOYSA-N cyclohexyl prop-2-enoate Chemical compound C=CC(=O)OC1CCCCC1 KBLWLMPSVYBVDK-UHFFFAOYSA-N 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- LNCPIMCVTKXXOY-UHFFFAOYSA-N hexyl 2-methylprop-2-enoate Chemical compound CCCCCCOC(=O)C(C)=C LNCPIMCVTKXXOY-UHFFFAOYSA-N 0.000 description 1
- LNMQRPPRQDGUDR-UHFFFAOYSA-N hexyl prop-2-enoate Chemical compound CCCCCCOC(=O)C=C LNMQRPPRQDGUDR-UHFFFAOYSA-N 0.000 description 1
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
- FSAJWMJJORKPKS-UHFFFAOYSA-N octadecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C=C FSAJWMJJORKPKS-UHFFFAOYSA-N 0.000 description 1
- NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
- 229940065472 octyl acrylate Drugs 0.000 description 1
- ANISOHQJBAQUQP-UHFFFAOYSA-N octyl prop-2-enoate Chemical compound CCCCCCCCOC(=O)C=C ANISOHQJBAQUQP-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 238000012643 polycondensation polymerization Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、耐衝撃性、耐熱性、耐薬品性、外観特性に優
れる新規な熱可塑性樹脂組成物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a novel thermoplastic resin composition having excellent impact resistance, heat resistance, chemical resistance, and appearance characteristics.
〔従来の技術］
ポリカーボネート樹脂は、耐熱性、耐衝撃性に優れた樹
脂であるが、成形性、めっき性、及び耐薬品性に劣る。[Prior Art] Polycarbonate resin is a resin with excellent heat resistance and impact resistance, but is inferior in moldability, plating property, and chemical resistance.
一方、飽和ポリエステル樹脂は、寸法安定性、耐候性、
耐薬品性には優れるが、耐衝撃性、耐熱性に難点を残し
ている。On the other hand, saturated polyester resin has dimensional stability, weather resistance,
Although it has excellent chemical resistance, it has drawbacks in impact resistance and heat resistance.
そこで、従来より飽和ポリエステル樹脂にポリカーボネ
ート樹脂を加えることによって、耐熱性、耐衝撃性およ
び、耐薬品性、寸法安定性にも優れた樹脂をつくりだそ
うという試みはされているが、単にポリカーボネート樹
脂と飽和ポリエステル樹脂を混合するだけでは、外観特
性が悪く、極端な場合には発泡したり、着色したりし、
また、耐衝撃性にも不十分なものしか得られていない。Therefore, attempts have been made to create resins with excellent heat resistance, impact resistance, chemical resistance, and dimensional stability by adding polycarbonate resins to saturated polyester resins, but polycarbonate resins are simply Merely mixing saturated polyester resin with saturated polyester resin will result in poor appearance characteristics and, in extreme cases, foaming and coloring.
Moreover, only insufficient impact resistance has been obtained.
その目的とするところは、外観特性、耐熱性を満足させ
るとともに耐衝撃性が著しく優れた熱可塑性樹脂組成物
を提供するにある。The purpose is to provide a thermoplastic resin composition that satisfies appearance characteristics and heat resistance, and has extremely excellent impact resistance.
本発明は、ポリカーボネート樹脂１０〜９０重量％と飽
和ポリエステル樹脂９０〜１０重量％からなる組成物１
００重量部に対し、アクリル系共重合体５〜４０重量部
を配合する熱可塑性樹脂組成物に関するものである。The present invention provides a composition 1 consisting of 10 to 90% by weight of a polycarbonate resin and 90 to 10% by weight of a saturated polyester resin.
The present invention relates to a thermoplastic resin composition containing 5 to 40 parts by weight of an acrylic copolymer per 00 parts by weight.
本発明に用いられるポリカーボネート樹脂としては、芳
香族ポリカーボネート、脂肪族ポリカーボネート、脂肪
族−芳香族ポリカーボネート等々を挙げることができる
。Examples of the polycarbonate resin used in the present invention include aromatic polycarbonate, aliphatic polycarbonate, aliphatic-aromatic polycarbonate, and the like.
飽和ポリエステル樹脂ζは、通常ジカルボン酸成分とジ
オチル成分の縮合重合によって製造されたものである。The saturated polyester resin ζ is usually produced by condensation polymerization of a dicarboxylic acid component and a diothyl component.
特に好ましい飽和ポリエステルは、ポリエチレンテレフ
タレート、ポリブチレンテレフタレートおよびその変性
品である。Particularly preferred saturated polyesters are polyethylene terephthalate, polybutylene terephthalate and modified products thereof.
アクリル系樹脂としては、メチルアクリレート、エチル
アクリレート、プロピルアクリレート、ブチルアクリレ
ート、アミルアクリレート、ヘキシルアクリレート、オ
クチルアクリレート、２−エチルへキシルアクリレート
、シクロヘキシルアクリレート、ドデシルアクリレート
、オクタデシルアクリレート、フェニルアクリレート、
ベンジルアクリレート、などのアクリル酸アルキルエス
テル、メチルメタクリレート、エチルメタクリレート、
プロピルメタクリレート、イソブロビルメククリレート
、ブチルメタクリレート、アミルアクリレート、ヘキシ
ルメタクリレート、オクチルメタクリレート、２−エチ
ルへキシルメタクリレート、シクロヘキシルメタクリレ
ート、ドデシルメタクリレート、オクタデシルメタクリ
レート、フェニルメタクリレート、ベンジルメタクリレ
ートなどのメタクリル酸アルキルエステルおよびそれら
の共重合体、およびそれらの変性品をあげることができ
る。Examples of acrylic resins include methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, amyl acrylate, hexyl acrylate, octyl acrylate, 2-ethylhexyl acrylate, cyclohexyl acrylate, dodecyl acrylate, octadecyl acrylate, phenyl acrylate,
Acrylic acid alkyl esters such as benzyl acrylate, methyl methacrylate, ethyl methacrylate,
Methacrylic acid alkyl esters such as propyl methacrylate, isobrobyl meccrylate, butyl methacrylate, amyl acrylate, hexyl methacrylate, octyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, dodecyl methacrylate, octadecyl methacrylate, phenyl methacrylate, benzyl methacrylate, and the like; copolymers and modified products thereof.
また、ポリカーボネート樹脂、飽和ポリエステル樹脂、
およびアクリル系樹脂の混合時、必要により染Ｒ料、安
定剤、可塑剤、帯電防止剤、紫外線吸収剤、滑剤、充填
剤等を添加してもよい。In addition, polycarbonate resin, saturated polyester resin,
When mixing the acrylic resin, dyes, stabilizers, plasticizers, antistatic agents, ultraviolet absorbers, lubricants, fillers, etc. may be added as necessary.
本実施例および比較例に用いられたポリカーボネート樹
脂、飽和ポリエステル樹脂およびアクリル系樹脂は下記
のものである。The polycarbonate resin, saturated polyester resin, and acrylic resin used in the present examples and comparative examples are as follows.
ポリカーボネート樹脂：ＰＣ
奇人化成社製“パンライ） Ｌ−１２２５Ｗ“飽和ポ
リエステル樹ＭＪ： ＰＢＴ
東し社製“東し ＰＢＴ ｌ１００Ｐ”アクリル系樹
脂：ＡＣ
呉羽化学製“ＫＣＡ−３０１”
実施例１〜３
ＰＣＩＯ重量％及びＰＢ７９０量量％からなる組成物１
００重量部にＡＣを５．１５．４０重量部配合した。Polycarbonate resin: PC "Panrai" manufactured by Kijin Kasei Co., Ltd. L-1225W "Saturated polyester resin MJ: PBT "PBT l100P" manufactured by Toshi Co., Ltd. Acrylic resin: AC "KCA-301" manufactured by Kureha Chemical Examples 1 to 3 PCIO Composition 1 consisting of % by weight and PB790% by weight
00 parts by weight was blended with 5.15.40 parts by weight of AC.
実施例４〜６
ＰＣ３０重量％及びＰＢ７７０重量％からなる組成物１
００重量部にＡＣを５．１５．４０重量部配合した。Examples 4-6 Composition 1 consisting of 30% by weight PC and 770% by weight PB
00 parts by weight was blended with 5.15.40 parts by weight of AC.
実施例７〜９
ＰＣ９０重量％及びＰＢＴＩＯ重量％からなる組成物１
００重量部にＡＣを５．１５．４０重量部配合した。Examples 7-9 Composition 1 consisting of 90% by weight PC and % by weight PBTIO
00 parts by weight was blended with 5.15.40 parts by weight of AC.
比較例１ ＰＣＩＯ重量％にＰＢ７９０重量％を配合した。Comparative example 1 790% by weight of PB was blended with % by weight of PCIO.
比較例２ ＰＣ３０重量％にＰＢ７７０重量％を配合した。Comparative example 2 770% by weight of PB was blended with 30% by weight of PC.
比較例３ ＰＣ９０重量％にＰＢＴＩＯ重量％を配合した。Comparative example 3 90% by weight of PC was blended with % by weight of PBTIO.
これらの結果は、第１表に示した。These results are shown in Table 1.
本発明による熱可塑性樹脂組成物は、 耐衝撃性 が著しく優れるとともに、 耐熱性も満足し、外観 特性も改善される。 The thermoplastic resin composition according to the present invention comprises: Impact resistance is significantly superior, and Satisfied with heat resistance and appearance Properties are also improved.
Claims (1)
リエステル樹脂９０〜１０重量％からなる組成物１００
重量部に対し、アクリル系樹脂５〜４０重量部を配合す
ることを特徴とする熱可塑性樹脂組成物。(1) Composition 100 consisting of 10-90% by weight of polycarbonate resin and 90-10% by weight of saturated polyester resin
A thermoplastic resin composition characterized in that 5 to 40 parts by weight of an acrylic resin is blended with respect to parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16679389A JPH0333153A (en) | 1989-06-30 | 1989-06-30 | Thermoplastic resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16679389A JPH0333153A (en) | 1989-06-30 | 1989-06-30 | Thermoplastic resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0333153A true JPH0333153A (en) | 1991-02-13 |
Family
ID=15837778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16679389A Pending JPH0333153A (en) | 1989-06-30 | 1989-06-30 | Thermoplastic resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0333153A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009533520A (en) * | 2006-04-14 | 2009-09-17 | チェイル インダストリーズ インコーポレイテッド | Scratch resistance-flame retardant thermoplastic resin composition |
| WO2015051508A1 (en) * | 2013-10-09 | 2015-04-16 | Sabic Innovative Plastics Ip B.V. | Glass-filled polycarbonate-poly(ethylene terephthalate) composition and associated article |
| US10604650B2 (en) | 2015-01-30 | 2020-03-31 | Sabic Global Technologies B.V. | Foamed polycarbonate articles with improved impact and methods of making and uses thereof |
-
1989
- 1989-06-30 JP JP16679389A patent/JPH0333153A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009533520A (en) * | 2006-04-14 | 2009-09-17 | チェイル インダストリーズ インコーポレイテッド | Scratch resistance-flame retardant thermoplastic resin composition |
| WO2015051508A1 (en) * | 2013-10-09 | 2015-04-16 | Sabic Innovative Plastics Ip B.V. | Glass-filled polycarbonate-poly(ethylene terephthalate) composition and associated article |
| US10604650B2 (en) | 2015-01-30 | 2020-03-31 | Sabic Global Technologies B.V. | Foamed polycarbonate articles with improved impact and methods of making and uses thereof |
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