JPH03294446A - Heat-resistant and wear-resistant aluminum alloy - Google Patents

Heat-resistant and wear-resistant aluminum alloy

Info

Publication number
JPH03294446A
JPH03294446A JP9648790A JP9648790A JPH03294446A JP H03294446 A JPH03294446 A JP H03294446A JP 9648790 A JP9648790 A JP 9648790A JP 9648790 A JP9648790 A JP 9648790A JP H03294446 A JPH03294446 A JP H03294446A
Authority
JP
Japan
Prior art keywords
alloy
resistant
aluminum alloy
wear
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP9648790A
Other languages
Japanese (ja)
Other versions
JPH0621311B2 (en
Inventor
Yoshimasa Okubo
喜正 大久保
Akio Kikuchi
昭雄 菊池
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Light Metal Industries Ltd
Original Assignee
Sumitomo Light Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Light Metal Industries Ltd filed Critical Sumitomo Light Metal Industries Ltd
Priority to JP2096487A priority Critical patent/JPH0621311B2/en
Publication of JPH03294446A publication Critical patent/JPH03294446A/en
Publication of JPH0621311B2 publication Critical patent/JPH0621311B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Landscapes

  • Manufacture Of Alloys Or Alloy Compounds (AREA)

Abstract

PURPOSE:To combinedly provide an Al alloy with heat resistance and wear resistance and to provide it with toughness and sufficient cold forgeability by incorporating a specified amt. of hard grains into an Al alloy matrix contg. each specified amt. of Cu, Mg and Si. CONSTITUTION:The compsn. of an Al alloy is formed of, by weight, 2.0 to 6.0% Cu, 0.3 to 3.0% Mg, 0.2 to 1.2% Si and the balance Al with inevitable impurities. This Al alloy matrix is dispersedly incorporated with 0.5 to 8% of one or more kinds of hard grains with 1 to 8mum average grain size among SiC, Si3N4, Al2O3, TiN, TiC, ZrO2.SiO2 or the like. If required, the Al alloy is incorporated with total 0.4 to 4.0% of one or more kinds among Mn, Fe and Ni and furthermore with total 0.02 to 0.7% of one or two kinds of Zr and Ti. This alloy does not flaw mating members even if used as friction parts.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、すぐれた高力アルミニウム合金の耐摩耗性を
改善し、バルブリフター、バルブスプリングリテーナ−
、オイルポンプギア、スプロケット、その他エンジン部
品に応用し得る耐熱耐摩耗性アルミニウム合金に関する
ものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention improves the wear resistance of an excellent high-strength aluminum alloy, and improves the wear resistance of the excellent high-strength aluminum alloy, and improves the wear resistance of the valve lifter and valve spring retainer.
, a heat-resistant and wear-resistant aluminum alloy that can be applied to oil pump gears, sprockets, and other engine parts.

[従来の技術] 最近、エンジンを従来の鋼材に代えてアルミニウム合金
を用いて作製し1軽量化して省エネルギーを図ることが
行われている。しかし、特にバルブリフター、バルブス
プリングリテーナ−、オイルポンプギア、スプロケット
その他エンジン部品は高温強度、耐摩耗性及び衝撃特性
が必要とされる。
[Prior Art] Recently, engines have been manufactured using aluminum alloys instead of conventional steel materials in order to reduce weight and save energy. However, especially valve lifters, valve spring retainers, oil pump gears, sprockets, and other engine parts require high-temperature strength, wear resistance, and impact properties.

しかし、一般に耐熱用とされるアルミニウム合金には2
219.2618等があるがこれらは耐摩耗性が十分で
ない。又、耐摩耗性とされるアルミニウム合金にはAC
8ASAC9B、 A390等があるが、これらは耐熱
性が乏しい上、靭性、切削性、冷間及び熱間での鍛造性
も十分でない。
However, aluminum alloys that are generally used for heat resistance have 2
219.2618, etc., but these do not have sufficient wear resistance. In addition, AC
There are 8ASAC9B, A390, etc., but these have poor heat resistance, as well as insufficient toughness, machinability, and cold and hot forgeability.

[発明が解決しようとする課題] そこで先に粉末冶金法を利用して耐熱性と耐摩耗性の優
れたAl−高Si系合金を開発しているが(例えば特公
昭83−16459号)、これらの靭性が低いことと冷
間鍛造性の点に問題を有している。
[Problems to be Solved by the Invention] Therefore, an Al-high Si alloy with excellent heat resistance and wear resistance was developed using powder metallurgy (for example, Japanese Patent Publication No. 16459/1983). These have problems in terms of low toughness and cold forgeability.

本発明はかかる点に鑑み、耐熱性と耐摩耗性とを兼ね備
え、しかも靭性と十分な冷間鍛造性をもったアルミニウ
ム合金を提供せんとするものである。
In view of these points, the present invention aims to provide an aluminum alloy that has both heat resistance and wear resistance, as well as toughness and sufficient cold forgeability.

[課題を解決するための手段] 本発明は、Cu :  2.0〜6.0%、Mg:0.
3〜3.0%、Si:0.2〜1.2%を含みあるいは
さらにこれらにM n s F e SN iの中から
1種または2種以上を合計で0.4〜4.0%含み、あ
るいは更にzrlTiのうち1種又は2種を合計で0.
02〜0.7%含み、残部が不可避的不純物を含むAl
からなるアルミニウム合金マトリックスの中に、平均粒
径が1〜8μmであるSiCs S l 3 N 4 
、A 1203 、T iN s T iCsZ ro
2・SiO2の如き硬質粒子の1種又は2種以上を0.
5〜8%分散させてなる耐熱耐摩耗性アルミニウム合金
である。
[Means for Solving the Problems] The present invention provides Cu: 2.0 to 6.0%, Mg: 0.
3 to 3.0%, Si: 0.2 to 1.2%, or further one or more of Mns Fe SN i in a total of 0.4 to 4.0%. or further contains one or two of zrlTi in total of 0.
Al containing 02 to 0.7% and the remainder containing unavoidable impurities
SiCs S13N4 with an average grain size of 1 to 8 μm in an aluminum alloy matrix consisting of
, A 1203 , T iNs T iCsZ ro
2.One or more kinds of hard particles such as SiO2 are mixed with 0.
It is a heat-resistant and wear-resistant aluminum alloy made by dispersing 5 to 8% of aluminum.

上記において合金成分、硬質粒子の限定理由は下記のと
おりである。
The reasons for limiting the alloy components and hard particles in the above are as follows.

Cu:常温及び高温強度を向上する。2.0%未満では
その効果が小さく、6.0%を超えると効果が飽和する
とともに耐食性が低下する。
Cu: Improves strength at room temperature and high temperature. If it is less than 2.0%, the effect will be small, and if it exceeds 6.0%, the effect will be saturated and the corrosion resistance will decrease.

Mg:Cuと共存して時効硬化して常温及び高温強度を
高める。0.8%未満では効果が十分でなく、3.0%
を越えると効果が飽和する。
Mg: Coexists with Cu and ages hardens to increase strength at room temperature and high temperature. If it is less than 0.8%, the effect is not sufficient, and 3.0%
The effect becomes saturated when it exceeds.

Si :Siの添加によりAl−Cu−Mg系析出中間
相(S″)が微細に形成され、時効硬化量が大きくなる
。更に後述のMnが共存していると、Al−Mn−8L
系析出相が生じ、これが転位のピンニング効果を高め、
サブグレイン組織ないし微細な再結晶組織となる。
Si: By adding Si, a fine Al-Cu-Mg precipitated intermediate phase (S'') is formed, increasing the amount of age hardening.Furthermore, when Mn, which will be described later, coexists, Al-Mn-8L
A system precipitated phase is generated, which enhances the pinning effect of dislocations,
It becomes a subgrain structure or a fine recrystallized structure.

0.2%未満ではその効果が小さく、1.2%を越える
と効果が飽和するとともにSi晶出物が生じて延性を低
下させる。
If it is less than 0.2%, the effect will be small, and if it exceeds 1.2%, the effect will be saturated and Si crystallized products will be produced, reducing ductility.

Mn、Fe5Ni:高温強度の向上に役立つ。Mn, Fe5Ni: Helps improve high temperature strength.

合計量が0.4%未満ではその効果が小さく、4.0%
を越えると粗大な晶出物を生じやすく延性を低下させる
If the total amount is less than 0.4%, the effect is small, 4.0%
If it exceeds this amount, coarse crystallized substances tend to form, reducing ductility.

Ti、Zr:凝固時の結晶粒を微細化するとともに、溶
体化処理中に発生する再結晶を抑制し、繊維状組織ある
いは微細な再結晶を有する組織をつくり、強度を向上さ
せる。合計量が0.02%未満ではその効果が小さく、
0.7%を越えると効果が飽和する。
Ti, Zr: Refine crystal grains during solidification, suppress recrystallization that occurs during solution treatment, create a fibrous structure or a structure with fine recrystallization, and improve strength. If the total amount is less than 0.02%, the effect will be small;
If it exceeds 0.7%, the effect will be saturated.

硬質粒子:5iCSSi3N4、Al2O3、TiN、
TiC、ZrO2−SiO2(ジルコン)の如き硬質粒
子を添加することによって耐摩耗性が大幅に向上する。
Hard particles: 5iCSSi3N4, Al2O3, TiN,
Wear resistance is greatly improved by adding hard particles such as TiC, ZrO2-SiO2 (zircon).

平均粒径が1μ−未満では十分な耐摩耗性を得られない
If the average particle size is less than 1 μm, sufficient wear resistance cannot be obtained.

更に粒子の均一分散が困難となり、粒子が偏在する場合
には延性が低下する。平均粒径が8μlを越すと摩擦す
る相手側の材料を傷つける。相手材が鋳鋼材である場合
には、傷も小さく問題となることはあまりないが、相手
材がアルミ合金のような軟質材である場合には、大きな
摩擦傷が生じる。又、添加量が0.5%未満では耐摩耗
性が十分でなく、添加量が8%を越えると延性と切削性
が低下する。
Furthermore, it becomes difficult to uniformly disperse the particles, and when the particles are unevenly distributed, the ductility decreases. If the average particle size exceeds 8 μl, it will damage the material on the other side that is being rubbed. If the mating material is cast steel, the scratches will be small and will not cause much of a problem, but if the mating material is a soft material such as an aluminum alloy, large friction scratches will occur. Furthermore, if the amount added is less than 0.5%, wear resistance will not be sufficient, and if the amount added exceeds 8%, ductility and machinability will decrease.

[実施例〕 表1に示す成分の硬質粒子を含むアルミニウム合金を製
造した。製造方法は次のとおりである。
[Example] An aluminum alloy containing hard particles having the components shown in Table 1 was manufactured. The manufacturing method is as follows.

子を加えポットミルによって混合した。この混合粉末を
外径2.5インチのアルミニウム缶に装入した後、缶内
の空気及び粉末表面に吸着している水分を取除くため4
80℃にて1時間の真空脱ガス処理をして、これを押出
用ビレットとした。これを400℃で直径1811に押
出した(押出比15)。そして、T6処理(480℃X
lh保持→水焼入れ一175℃X6h保持)を施し、引
張試験及びビン・ディスク式摩耗試験を行った。結果を
表1に併記する。ここで摩耗量とは、摩耗試験(120
℃のマシン油の中でビンを供試合金、ディスクをAC2
Aとして、50kgf’/cdの面圧、速度0.5m/
secで摩擦を1時間行う)におけるビンの長さ減量と
ディスクにつく摩擦跡の深さである。
and mixed using a pot mill. After charging this mixed powder into an aluminum can with an outer diameter of 2.5 inches, the air inside the can and moisture adsorbed on the powder surface were removed by
A vacuum degassing treatment was performed at 80° C. for 1 hour, and this was made into a billet for extrusion. This was extruded at 400°C to a diameter of 1811 (extrusion ratio 15). Then, T6 treatment (480℃
The specimens were subjected to a tensile test and a bottle-disk abrasion test. The results are also listed in Table 1. Here, the wear amount refers to the wear test (120
Place the bottle in machine oil at ℃ and place the disk in AC2.
As A, surface pressure of 50 kgf'/cd, speed 0.5 m/
sec for 1 hour) and the depth of the friction mark on the disc.

上記表1から明らかなとおり、本発明合金N011〜1
7は室温及び150℃において十分高い強度と伸びを示
し、更にビンの摩耗量は小さくディスクの摩耗量も小さ
い。それに対し、比較合金No、18〜22は硬質粒子
の寸法あるいは量が適切でないため、伸びが不足してい
るか、又はピンの摩耗量あるいはディスクの摩耗量が大
きく、比較合金N o、28〜2Bはアルミニウム合金
マトリックスの成分が適切でないため、強度又は伸びが
低い。
As is clear from Table 1 above, the invention alloy N011-1
No. 7 shows sufficiently high strength and elongation at room temperature and 150°C, and furthermore, the amount of wear on the bottle and the disk is small. On the other hand, comparative alloys No. 18-22 have insufficient elongation due to the inappropriate size or amount of hard particles, or the amount of pin wear or disk wear is large, and comparative alloy No. 28-2B has low strength or elongation due to inappropriate aluminum alloy matrix components.

又、合金No、2及びNo、11の調質をO材とし、冷
間据込み試験を実施したところ、限界据込み率はそれぞ
れ58%及び52%であった。この値は十分高く、本発
明合金は冷間鍛造が容易であると判断される。
Further, when alloys No. 2 and No. 11 were refined to O material and cold upsetting tests were conducted, the limit upsetting rates were 58% and 52%, respectively. This value is sufficiently high, and it is judged that the alloy of the present invention can be easily cold-forged.

〔発明の効果] 本発明によれば高温強度と耐摩耗性にすぐれたアルミニ
ウム合金を得ることができる。そしてこのものは冷間鍛
造が容易で、本合金を摩擦部品として使用しても相手材
を傷っけない。したがって、本発明合金はバルブリフタ
ー、バルブスプリングリテーナ−をはじめ、エンジン部
品等に適し、従来の鋼製品と置き換え得る材料である。
[Effects of the Invention] According to the present invention, an aluminum alloy having excellent high-temperature strength and wear resistance can be obtained. This alloy is easy to cold forge, and even when this alloy is used as a friction part, it will not damage the mating material. Therefore, the alloy of the present invention is suitable for valve lifters, valve spring retainers, engine parts, etc., and is a material that can replace conventional steel products.

Claims (3)

【特許請求の範囲】[Claims] (1)Cu:2.0〜6.0%(重量%:以下同じ)、
Mg:0.3〜3.0%、Si:0.2〜1.2%を含
み、残部が不可避的不純物を含むAlか らなるアルミニウム合金マトリックスの中 に、平均粒径が1〜8μmであるSiC、 Si_3N_4、Al_2O_3、TiN、TiC、Z
rO_2・SiO_2の如き硬質粒子の1種又は2種以
上を0.5〜8%分散させてなる耐熱耐摩耗性アルミニ
ウム合金。
(1) Cu: 2.0 to 6.0% (weight%: same below),
An aluminum alloy matrix containing Mg: 0.3 to 3.0%, Si: 0.2 to 1.2%, and the balance consisting of Al containing unavoidable impurities has an average grain size of 1 to 8 μm. SiC, Si_3N_4, Al_2O_3, TiN, TiC, Z
A heat-resistant and wear-resistant aluminum alloy comprising 0.5 to 8% of one or more hard particles such as rO_2 and SiO_2 dispersed therein.
(2)Cu:2.0〜6.0%、Mg:0.3〜3.0
%、Si:0.2〜1.2%と更にMn、Fe、Niの
中から1種又は2種以上を合計で0.4〜4.0%を含
み、残部が不可避的不純物を含むAlからなるアルミニ
ウム合金マトリックスの中に、平均粒径が1〜8μmで
あるSiC、Si_3N_4、Al_2O_3、TiN
、TiC、ZrO_2・SiO_2の如き硬質粒子の1
種又は2種以上を0.5〜8%分散させてなる耐熱耐摩
耗性アルミニウム合金。
(2) Cu: 2.0-6.0%, Mg: 0.3-3.0
%, Si: 0.2 to 1.2%, and further contains one or more of Mn, Fe, and Ni in a total of 0.4 to 4.0%, and the remainder is Al containing inevitable impurities. SiC, Si_3N_4, Al_2O_3, TiN with an average grain size of 1 to 8 μm are contained in an aluminum alloy matrix consisting of
, TiC, 1 of hard particles such as ZrO_2・SiO_2
A heat-resistant and wear-resistant aluminum alloy comprising 0.5 to 8% of a species or two or more species dispersed therein.
(3)Cu:2.0〜6.0%、Mg:0.3〜3.0
%、Si:0.2〜1.2%及びMn、Fe、Niの中
から1種又は2種以上を合計で0.4〜4.0%と更に
Zr、Tiのうち1種又は2種を合計で0.02〜0.
7%を含み、残部が不可避的不純物を含むAlからなる
アルミニウム合金マトリックスの中に、平均粒径が1〜
8μmであるSiC、Si_3N_4、Al_2O_3
、TiN、TiC、ZrO_2・SiO_2の如き硬質
粒子の1種又は2種以上を0.5〜8%分散させてなる
耐熱耐摩耗性アルミニウム合金。
(3) Cu: 2.0-6.0%, Mg: 0.3-3.0
%, Si: 0.2 to 1.2% and one or more of Mn, Fe, and Ni in a total of 0.4 to 4.0%, and one or two of Zr and Ti. The total is 0.02~0.
In an aluminum alloy matrix consisting of Al containing 7% and the remainder containing unavoidable impurities, there are
8 μm SiC, Si_3N_4, Al_2O_3
A heat-resistant and wear-resistant aluminum alloy comprising 0.5 to 8% of one or more hard particles such as TiN, TiC, and ZrO_2/SiO_2 dispersed therein.
JP2096487A 1990-04-13 1990-04-13 Heat and wear resistant aluminum alloy Expired - Lifetime JPH0621311B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2096487A JPH0621311B2 (en) 1990-04-13 1990-04-13 Heat and wear resistant aluminum alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2096487A JPH0621311B2 (en) 1990-04-13 1990-04-13 Heat and wear resistant aluminum alloy

Publications (2)

Publication Number Publication Date
JPH03294446A true JPH03294446A (en) 1991-12-25
JPH0621311B2 JPH0621311B2 (en) 1994-03-23

Family

ID=14166429

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2096487A Expired - Lifetime JPH0621311B2 (en) 1990-04-13 1990-04-13 Heat and wear resistant aluminum alloy

Country Status (1)

Country Link
JP (1) JPH0621311B2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06346175A (en) * 1993-06-10 1994-12-20 Sumitomo Light Metal Ind Ltd Bicycle rim material
CN103469037A (en) * 2013-08-28 2013-12-25 中南大学 Aluminum alloy with high heat stability and fatigue resistance and heat treatment technology
CN105506435A (en) * 2015-12-14 2016-04-20 无锡福镁轻合金科技有限公司 Composite material for crankshaft

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60121250A (en) * 1983-12-05 1985-06-28 Mitsubishi Metal Corp Sintered al alloy for friction and sliding members
JPS616243A (en) * 1984-06-19 1986-01-11 Mitsubishi Metal Corp Sliding member of sintered al alloy with superior wear resistance

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60121250A (en) * 1983-12-05 1985-06-28 Mitsubishi Metal Corp Sintered al alloy for friction and sliding members
JPS616243A (en) * 1984-06-19 1986-01-11 Mitsubishi Metal Corp Sliding member of sintered al alloy with superior wear resistance

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06346175A (en) * 1993-06-10 1994-12-20 Sumitomo Light Metal Ind Ltd Bicycle rim material
CN103469037A (en) * 2013-08-28 2013-12-25 中南大学 Aluminum alloy with high heat stability and fatigue resistance and heat treatment technology
CN105506435A (en) * 2015-12-14 2016-04-20 无锡福镁轻合金科技有限公司 Composite material for crankshaft

Also Published As

Publication number Publication date
JPH0621311B2 (en) 1994-03-23

Similar Documents

Publication Publication Date Title
WO2011090451A1 (en) CASTING ALLOY OF THE AIMgSI TYPE
US1947121A (en) Aluminum base alloys
JPH01180938A (en) Wear-resistant aluminum alloy
JPH03294446A (en) Heat-resistant and wear-resistant aluminum alloy
US2357452A (en) Aluminum alloys
JPH04341537A (en) Aluminum alloy having high strength and wear resistance and excellent in cold forgeability
US2908566A (en) Aluminum base alloy
JPH055147A (en) Low thermal expansion aluminum alloy excellent in wear resistance
CN1320713A (en) High-Al Zn-base alloy
JPH04173935A (en) Wear resistant aluminum alloy
JPH09316586A (en) Magnesium alloy with heat resistance and wear resistance
JP3303661B2 (en) Heat resistant high strength aluminum alloy
US2357451A (en) Aluminum alloy
JPS58100654A (en) Aluminum alloy for casting with superior heat resistance
CA2571761C (en) High strength, oxidation and wear resistant titanium-silicon alloy
JPS62127447A (en) Aluminum alloy for casting
JPH1017975A (en) Aluminum alloy for casting
JPH036344A (en) Aluminum alloy having heat resistance and wear resistance
JPH01108339A (en) Aluminum alloy for piston combining heat resistance with high strength
JPS60243241A (en) Aluminum alloy with superior wear resistance
JPH11131180A (en) Wear resistant steel
JPS6227543A (en) Wear-resisting aluminum alloy stock
JPH01238A (en) Wear-resistant Cu alloy with high strength and toughness
JPH07116538B2 (en) Wear resistant Cu alloy with high strength and toughness
KR960005232B1 (en) Cu-al alloy composition