JPH03285970A - Solid painting material - Google Patents
Solid painting materialInfo
- Publication number
- JPH03285970A JPH03285970A JP8649390A JP8649390A JPH03285970A JP H03285970 A JPH03285970 A JP H03285970A JP 8649390 A JP8649390 A JP 8649390A JP 8649390 A JP8649390 A JP 8649390A JP H03285970 A JPH03285970 A JP H03285970A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- solid drawing
- paper
- drawing material
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 41
- 239000007787 solid Substances 0.000 title claims abstract description 38
- 238000010422 painting Methods 0.000 title abstract 3
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 235000013873 oxidized polyethylene wax Nutrition 0.000 claims description 14
- 239000004209 oxidized polyethylene wax Substances 0.000 claims description 13
- 239000001993 wax Substances 0.000 abstract description 12
- 239000012188 paraffin wax Substances 0.000 abstract description 7
- 239000012170 montan wax Substances 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 4
- 235000013871 bee wax Nutrition 0.000 abstract description 3
- 239000012166 beeswax Substances 0.000 abstract description 3
- 239000006229 carbon black Substances 0.000 abstract description 3
- 239000004203 carnauba wax Substances 0.000 abstract description 3
- 235000013869 carnauba wax Nutrition 0.000 abstract description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 abstract description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 abstract description 2
- 229940092738 beeswax Drugs 0.000 abstract 1
- 239000012182 japan wax Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 13
- 239000004615 ingredient Substances 0.000 description 7
- -1 and if necessary Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 235000019809 paraffin wax Nutrition 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000001056 green pigment Substances 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000012169 petroleum derived wax Substances 0.000 description 2
- 235000019381 petroleum wax Nutrition 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- MFYSUUPKMDJYPF-UHFFFAOYSA-N 2-[(4-methyl-2-nitrophenyl)diazenyl]-3-oxo-n-phenylbutanamide Chemical compound C=1C=CC=CC=1NC(=O)C(C(=O)C)N=NC1=CC=C(C)C=C1[N+]([O-])=O MFYSUUPKMDJYPF-UHFFFAOYSA-N 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 235000021588 free fatty acids Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は固形描画材に関し、更に詳細には、紙面が平滑
なアート紙・コート紙などに描画した描画跡の濃度が高
く、シかも、固形描画材自体を持って使用しても手が汚
れない固形描画材に関するものである。Detailed Description of the Invention (Industrial Application Field) The present invention relates to solid drawing materials, and more specifically, the drawing traces drawn on smooth art paper, coated paper, etc. have a high density and may be difficult to use. The present invention relates to a solid drawing material that does not stain hands even when the solid drawing material itself is held and used.
（従来の技術）
従来固形描画材には、顔料と、パラフィンワックス・マ
イクロクリスタリンワックス等の石油系ワックス及び／
又はカルナウバワックス・木ロウ・ミツロウといった植
物系や動物系のワックスと、必要に応じて体質顔料と、
ワセリン・スピンドル油・鉱油等のオイル分とよりなる
所謂クレヨン・パスと呼ばれる軟質固形描画材と、顔料
と、ポリエチレンワックス等の合成ワックス及び／又は
パラフィンワックス・マイクロクリスタリンワックス等
の石油系ワックスと、必要に応じて体質顔料と、ポリエ
チレン等の樹脂やステアリン酸などの滑剤とよりなる所
謂プラスチッククレヨンと呼ばれる硬質固形描画材とが
知られている。(Prior art) Conventional solid drawing materials include pigments, petroleum waxes such as paraffin wax and microcrystalline wax, and/or
Or plant-based or animal-based waxes such as carnauba wax, wood wax, and beeswax, and if necessary, extender pigments.
A soft solid drawing material called a so-called crayon pass consisting of an oil component such as vaseline, spindle oil, mineral oil, etc., a pigment, a synthetic wax such as polyethylene wax, and/or a petroleum wax such as paraffin wax or microcrystalline wax, A hard solid drawing material called a so-called plastic crayon is known, which is made of an extender pigment and a lubricant such as a resin such as polyethylene or stearic acid, if necessary.
（発明が解決しようとする課題）
上記軟質固形描画材は、アート紙・コート紙などの平滑
な紙面でも描画跡の濃度は高いが、紙やプラスチックフ
ィルム等でその表面を覆っておかないと使用時に手指が
汚れるという欠点が有った。(Problem to be solved by the invention) The soft solid drawing material described above has a high density of drawing traces even on smooth paper surfaces such as art paper and coated paper, but it cannot be used unless the surface is covered with paper, plastic film, etc. The downside is that sometimes your hands get dirty.
他方、硬質固形描画材は、裸のままで使用しても手指が
汚れることは無いが、特にアート紙・コート紙のような
平滑な紙面に対して描画跡が薄いという欠点が有った。On the other hand, hard solid drawing materials do not stain hands and fingers even when used naked, but they have the disadvantage that drawing marks are thin, especially on smooth paper surfaces such as art paper and coated paper.
そこで本発明者は、硬質固形描画材タイプであって且つ
平滑な紙面（アート紙・コート紙）への描画跡の濃度が
高い固形描画材を得ることを目的として本発明を完成さ
せた。Therefore, the present inventor completed the present invention with the aim of obtaining a solid drawing material that is a hard solid drawing material type and has a high density of drawing traces on a smooth paper surface (art paper, coated paper).
（課題を解決するための手段）
本発明は、顔料と酸化型ポリエチレンワックスとより少
なくともなる固形描画材を要旨とするものである。(Means for Solving the Problems) The gist of the present invention is a solid drawing material comprising at least a pigment and an oxidized polyethylene wax.
以下本発明の詳細な説明する。The present invention will be explained in detail below.
顔料は、着色剤として使用するものであり従来公知のカ
ーボンブラック、酸化チタン、酸化亜鉛。The pigments used as coloring agents are conventionally known carbon black, titanium oxide, and zinc oxide.
フタロシアニンブルー、フタロシアニングリーン、ワラ
チンブレッド、カーミノ６Ｂ、ハンザイエロー等無機顔
料、有機顔料を問わず使用可能であって単独又は２種以
上混合して用いても良い。その使用量は、顔料の種類に
よって大きく異なるが発色並びに描画性等を考慮すれば
固形描画材全量に対して３〜３０重量％が好ましい。Inorganic pigments and organic pigments such as phthalocyanine blue, phthalocyanine green, waratin bread, carmino 6B, and Hansa yellow can be used, and they may be used alone or in combination of two or more. The amount used varies greatly depending on the type of pigment, but in consideration of color development and drawing properties, it is preferably 3 to 30% by weight based on the total amount of the solid drawing material.
本発明で使用する酸化型ポリエチレンワックスは、固形
描画材を形成すると共に、描画跡の濃度が高く且つ手・
指の汚れが無い固形描画材を得るために用いるものであ
る。具体例としては、ＣＷＯ−３０１、ＣＷＯ−３０７
，ＣＷＯ−３１２゜ＣＷＯ−３４１（以上、スペイン、
ケミカルワックス社製）、ハイワックス４２０２Ｅ−同
４０５２Ｅ、同５２０２Ｅ （以上、三井石油化学工業
■製）サンワックＸＥ−３００、同Ｅ−２５０Ｐ、ビス
コールＴＳ−２０（以上、三洋化成工業■製）ネオワッ
クスＥ−２０（安原ケミカル■製）などが挙げられる。The oxidized polyethylene wax used in the present invention forms a solid drawing material, has a high density of drawing traces, and is easy to handle by hand.
It is used to obtain a solid drawing material that is free from finger stains. Specific examples include CWO-301 and CWO-307.
, CWO-312゜CWO-341 (Spain,
Chemical Wax Co., Ltd.), Hiwax 4202E-4052E, Hiwax 5202E (all manufactured by Mitsui Petrochemical Industries, Ltd.), Sanwac XE-300, Sanwak E-250P, Viscor TS-20 (all manufactured by Sanyo Chemical Industries, Ltd.) Neowax Examples include E-20 (manufactured by Yasuhara Chemical ■).
この酸化型ポリエチレンワックスの酸価（ワックス１ｇ
中に含まれる遊離の脂肪酸を中和するために必要な水酸
化カリウムの量、単位；ＫＯＨｍｇ／ｇ→は１５〜２２
であることが好ましい。これは酸価が大きいと酸化型ポ
リエチレンワックスの硬度（軟化点）が低くなり、それ
に伴って固形描画材の硬度も低くなり強度や成型性が劣
り実用上好ましくない傾向が発生する。Acid value of this oxidized polyethylene wax (1 g of wax
The amount of potassium hydroxide necessary to neutralize the free fatty acids contained in it, unit; KOHmg/g → is 15 to 22
It is preferable that This is because when the acid value is high, the hardness (softening point) of the oxidized polyethylene wax decreases, and the hardness of the solid drawing material decreases accordingly, resulting in poor strength and moldability, which is a tendency that is not desirable in practice.
逆に酸価が小さいと濃度の向上が顕著でないためである
。On the other hand, if the acid value is low, the concentration is not significantly improved.
また使用量は固形描画材全量に対して５〜９０％、更に
好ましくは２０〜５５％が用いられる。The amount used is 5 to 90%, more preferably 20 to 55%, based on the total amount of the solid drawing material.
尚、上記必須成分以外に、必要に応じて直鎖及び側鎖パ
ラフィンワックス、水素添加硬化油、飽和脂肪酸及びそ
の誘導体、カルナウバワックス、ミツロウ、木ロウ、モ
ンタンワックスなど、従来固形描画材に用いられている
天然ワックス、合成ワックスを副成分として使用でき、
その使用量は固形描画材全量に対して１０〜４０％が好
ましい。In addition to the above-mentioned essential ingredients, if necessary, linear and side-chain paraffin waxes, hydrogenated hydrogenated oils, saturated fatty acids and their derivatives, carnauba wax, beeswax, wood wax, montan wax, etc., may be added to conventional solid drawing materials. Natural waxes and synthetic waxes can be used as sub-ingredients.
The amount used is preferably 10 to 40% based on the total amount of the solid drawing material.
また、増量剤若しくは充填剤として従来公知の、戻酸カ
ルシウム、タルク、クレー、シリカ、硫酸バリウム等の
体質顔料を固形描画材全量に対して３〜２５重量％用い
たり、ポリエチレン、ポリプロピレン、ポリ塩化ビニル
等の樹脂を固形描画材全量に対して３〜１５重量％用い
たり、又、界面活性剤を用いたりすることもできる。In addition, conventionally known extenders or fillers such as rehydrated calcium oxide, talc, clay, silica, barium sulfate, and other extender pigments may be used in an amount of 3 to 25% by weight based on the total amount of the solid drawing material, or polyethylene, polypropylene, polychloride, etc. It is also possible to use a resin such as vinyl in an amount of 3 to 15% by weight based on the total amount of the solid drawing material, or to use a surfactant.
本発明の同形描画材は、上記各成分を加熱撹拌混合し、
また必要に応じてニーダ−、ロールミル等の混線機で混
練し、これを溶融状態で型に流し込み、または射出・圧
入もしくは押出しし、冷却固化して得ることができる。The isomorphic drawing material of the present invention is obtained by heating and stirring the above-mentioned components,
Further, if necessary, it can be obtained by kneading with a mixer such as a kneader or a roll mill, pouring the molten state into a mold, or injecting, press-fitting or extruding, and cooling and solidifying.
（作 用）
本発明の固形描画材がアート紙・コート紙などの平滑な
紙面に対して、描画跡の濃度が高くなる理由については
、以下のように推察できる。(Function) The reason why the solid drawing material of the present invention has a higher density of drawing marks on smooth paper surfaces such as art paper and coated paper can be inferred as follows.
本発明に使用するポリエチレンワックスは、酸化によっ
て製造されるものであり、他のエチレン重合型や副生型
などの非酸化型ポリエチレンワックスに比べ、極性が大
きい。更に、可撓性に優れ粘着性も有している。このた
め非酸化型ポリエチレンワックスを用いた固形描画材は
アート紙・コート紙などの表面をコーティングしている
紙に対して濡れ性が良好であり、用いている非酸化型ポ
リエチレンワックスの硬度（軟化点）が非酸化型ポリエ
”チレンワックスと同程度であっても紙面上に厚い塗膜
が形成され易い。従って、アート紙・コート紙などの紙
面でも描画跡濃度が高くなる。The polyethylene wax used in the present invention is produced by oxidation, and has higher polarity than other non-oxidized polyethylene waxes such as ethylene polymerization type and by-product type. Furthermore, it has excellent flexibility and adhesiveness. For this reason, solid drawing materials using non-oxidized polyethylene wax have good wettability with paper that coats the surface of art paper, coated paper, etc., and the hardness (softening) of the non-oxidized polyethylene wax used Even if the amount of wax (point) is the same as that of non-oxidized polyethylene wax, a thick coating film is likely to be formed on the paper surface. Therefore, the density of drawing marks will be high even on paper surfaces such as art paper and coated paper.
（実施例）
以下、本発明を実施例により更に詳細に説明するが、実
施例及び比較例中ｒ部ノとは「重量部Ｊを示す。(Example) Hereinafter, the present invention will be explained in more detail with reference to Examples. In the Examples and Comparative Examples, "part r" means "part by weight J."
失厳豊よ
り−ミツ６Ｂ（赤色顔料） １０部ネオワッ
クスＥ−２０９０部
（酸価；１８）
上記成分をヘンシェルミキサーで加熱溶融して混合した
後冷却しペレット化したものを、成型機にて射出成型し
、赤色固形描画材を得た。From Shigenhoyori - Mitsu 6B (red pigment) 10 parts Neowax E - 2090 parts (acid value: 18) The above ingredients were heated and melted in a Henschel mixer, mixed, cooled and pelletized, and then made into pellets using a molding machine. Injection molding was performed to obtain a red solid drawing material.
災に五Ｉ
カーボンブラック（黒色顔料） ８部ＣＷＯ
−３０７５２部
（酸価；１６）
１３０Ｆ’パラフイン ３０部タルク
１０部上記成分を
実施例１と同様になして黒色固形描画材を得た。Disaster 5 I Carbon black (black pigment) 8 parts CWO
-30752 parts (acid value: 16) 130F' paraffin 30 parts Talc 10 parts A black solid drawing material was obtained using the above ingredients in the same manner as in Example 1.
失１２１ユ
フタロシアニンブルー（青色顔料） １０部ハイワッ
クス４２０２Ｅ ２５部（酸価；１７）
ポリエチレン樹脂 ２０部木口ウ
２５部ステアリン酸亜鉛
１０部クレー
１０部上記成分を実施例１と同様になして青
色固形描画材を得た。Loss 121 Euphthalocyanine Blue (blue pigment) 10 parts Hiwax 4202E 25 parts (acid value: 17) Polyethylene resin 20 parts
25 parts zinc stearate 10 parts clay
A blue solid drawing material was obtained using 10 parts of the above ingredients in the same manner as in Example 1.
夫ｌ舊土
フタロシアニングリーン（緑色顔料） １０部サすワ
ックスＥ２５０−Ｐ ３０部（酸価；２０
）
１５０’Ｆパラフイン ２５部モンタ
ンワックス １８部ステアリン酸
７部タルク
１０部上記成分を実施例１と同様
になして緑色固形描画材を得た。Phthalocyanine green (green pigment) 10 parts Sasuwax E250-P 30 parts (acid value: 20
) 150'F paraffin 25 parts montan wax 18 parts stearic acid
7 parts talc
A green solid drawing material was obtained using 10 parts of the above ingredients in the same manner as in Example 1.
失１旌旦
フタロシアニングリーン（緑色顔料） １０部ハイワッ
クス４０５ＮＰ ３０部（酸価；１）
１５０”Ｆパラフィン ２５部モンタ
ンワックス １８部ステアリン酸
７部タルク
１０部上記成分を実施例１と同様に
なして緑色固形描画材を得た。Phthalocyanine green (green pigment) 10 parts Hiwax 405NP 30 parts (acid value: 1) 150"F paraffin 25 parts Montan wax 18 parts stearic acid
7 parts talc
A green solid drawing material was obtained using 10 parts of the above ingredients in the same manner as in Example 1.
迄笠叢よ
実施例１のネオワックスＥ−２０をネオワックスＣＬ（
非酸化型ポリエチレンワックス、酸価ｉ、安原ケミカル
■製）に変えた以外は実施例１と同様になして赤色固形
描画材を得た。Until then, Neowax E-20 of Example 1 was mixed with Neowax CL (
A red solid drawing material was obtained in the same manner as in Example 1 except that non-oxidized polyethylene wax, acid value i, manufactured by Yasuhara Chemical ■ was used.
炭敗叢裟
実施例２のＣＷ○−３０７をＰＥＷ−に２ （非酸化型
ポリエチレンワックス、酸価；−、チュウセイワックス
ポリマー■製）に変えた以外は実施例２と同様になして
黒色固形描画材を得た。Same as Example 2 except that CW○-307 in Example 2 was changed to PEW-2 (non-oxidized polyethylene wax, acid value: -, manufactured by Chusei Wax Polymer ■). A solid drawing material was obtained.
迄敗五主
実施例３のハイワックス４２０２Ｅをハイワックス４０
０Ｐ （非酸化型ポリエチレンワックス、酸価；−２三
井石油化学工業■製）に変えた以外は実施例３と同様に
なして青色固形描画材を得た。Hiwax 4202E of five main examples 3 to Hiwax 40
A blue solid drawing material was obtained in the same manner as in Example 3, except that 0P (non-oxidized polyethylene wax, acid value: -2 manufactured by Mitsui Petrochemical Industries, Ltd.) was used.
よ敗舅土
実施例４のサンワックス２５０ＰをサンワックスＬＥＬ
−２５０−Ｐ （非酸化型ポリエチレンワックス、酸価
７−１三洋化成工業■製）に変えた以外は実施例４と同
様になして緑色固形描画材を得た。Sunwax 250P of Example 4 is Sunwax LEL
A green solid drawing material was obtained in the same manner as in Example 4, except that -250-P (non-oxidized polyethylene wax, acid value 7-1, manufactured by Sanyo Chemical Industries, Ltd.) was used.
崖笠叢旦
実施例５のハイワックス４５０ＰをサンワックスＬＥＬ
−８００（非酸化型ポリエチレンワックス、酸価；−５
三洋化成工業■製）に変えた以外は実施例５と同様にな
して緑色固形描画材を得た。Sunwax LEL Hiwax 450P of Kaikasa Sodan Example 5
-800 (non-oxidized polyethylene wax, acid value; -5
A green solid drawing material was obtained in the same manner as in Example 5, except that the material was changed to (manufactured by Sanyo Chemical Industries, Ltd.).
（発明の効果）
以上実施例１〜５、比較例１〜５で得た固形描画材につ
いて、アート紙に対する濃度試験を行なった。(Effects of the Invention) The solid drawing materials obtained in Examples 1 to 5 and Comparative Examples 1 to 5 above were subjected to a concentration test on art paper.
結果を表１に示す。The results are shown in Table 1.
表１
濃度試験：
各例で得た固形描画材先端を市販の鉛筆削り器で削り、
筆記角度７５°筆記圧３００ｇでレコード式画線機（精
機工業研究所■製。Table 1 Concentration test: Sharpen the tip of the solid drawing material obtained in each example with a commercially available pencil sharpener.
Record-type drawing machine (manufactured by Seiki Kogyo Kenkyusho ■) with a writing angle of 75° and a writing pressure of 300g.
Ｍｏｄｅｌ Ｐ Ｓ −５）にて、４００ｒｐ鳳の条件
で筆記した。It was written on a Model P S-5) at 400 rpm.
試験用紙：アート紙（三菱製紙■製函アート）濃度測定
：描画跡のＹ値（明度、％）をカラーコンピュータＭｏ
ｄｅｌ Ｓ Ｍ −４（スガ試験機■製）にて、測定し
た。Test paper: Art paper (Mitsubishi Paper ■Box art) Density measurement: Y value (brightness, %) of the drawing trace using color computer Mo
It was measured using del SM-4 (manufactured by Suga Test Instruments).
（Ｙ値が小さい方が濃度が高いことを示す、）尚１手汚
れ性については、実施例、比較例ともほとんど汚れなか
った。(The smaller the Y value is, the higher the concentration is.) Regarding the hand staining property, both the Examples and Comparative Examples showed almost no staining.
以上、詳細に説明したように、本発明に係る固形描画材
は平滑な紙（アート紙・コート紙）に対して、描画跡濃
度が高く、かつ、手指を汚さない優れたものである。As described above in detail, the solid drawing material according to the present invention has a higher density of drawing traces than smooth paper (art paper, coated paper), and is superior in that it does not stain hands and fingers.
Claims (1)
る固形描画材。A solid drawing material consisting of at least a pigment and an oxidized polyethylene wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8649390A JP2870106B2 (en) | 1990-03-31 | 1990-03-31 | Solid drawing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8649390A JP2870106B2 (en) | 1990-03-31 | 1990-03-31 | Solid drawing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03285970A true JPH03285970A (en) | 1991-12-17 |
| JP2870106B2 JP2870106B2 (en) | 1999-03-10 |
Family
ID=13888511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8649390A Expired - Lifetime JP2870106B2 (en) | 1990-03-31 | 1990-03-31 | Solid drawing material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2870106B2 (en) |
-
1990
- 1990-03-31 JP JP8649390A patent/JP2870106B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2870106B2 (en) | 1999-03-10 |
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