CN108795156A - Low resilience flexibility colorful functional lettering pen and preparation method thereof - Google Patents
Low resilience flexibility colorful functional lettering pen and preparation method thereof Download PDFInfo
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- CN108795156A CN108795156A CN201810665363.5A CN201810665363A CN108795156A CN 108795156 A CN108795156 A CN 108795156A CN 201810665363 A CN201810665363 A CN 201810665363A CN 108795156 A CN108795156 A CN 108795156A
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- powder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D13/00—Pencil-leads; Crayon compositions; Chalk compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Low resilience flexibility colorful functional lettering pen and preparation method thereof, is related to the production technical field of plasticity pen.The present invention is first by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain functional color masterbatch, then again high molecular polymer is uniformly mixed to be placed in extrusion molding or injection moulding apparatus with functional color masterbatch and heats, squeezes, stretches, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.The present invention can effectively promote the quality of plasticity pen, color evenly, and it is more fine and smooth smooth to cut rear section.Pen made of the present invention is provided with certain health-care effect, moreover it is possible to be promoted and use the comfortable feel degree of pen, the color of pen more gorgeous at low ambient temperatures, be more prone to find in the dark, while not allowing frangibility more, long-lived pen.
Description
Technical field
The present invention relates to the production technical fields of plasticity pen.
Background technology
Pen be it is a kind of write calligraphy and painting tool, she by pigment be dispersed in solid or（With）In liquid medium, by means of medium
Effect and uniform and delicate be attached on the surface of solid material.But some functional pens on the market, usually have
Some such or such disadvantages.For example, solidity insufficient strength, frangibility（Such as chalk, wax crayon and artistic oil painting stick）；Fluidity
Pen, it is general to be used using dipping in and write the method that interruption carries out（Such as writing brush, pen）, for our routine uses very not
It is convenient, and the inconvenience that ball pen and water-color paintbrush can have pen core leakage and need to be replaced frequently.All there is making for all these pens
Profit complicated, inconvenient to carry and storage be not permanent, is endangered environment, meanwhile, for the children for liking having intimate contact with pen
For, it is more dangerous the problems such as.
A kind of colorful high elastic plasticity pen and production method are disclosed in CN201010622649.9 patent documents, by high score
Sub- polymer, solid powder, pigment and conditioning agent mix together after through extrusion molding formed bar shaped, then through cooling, cutting, obtain modeling
Property pen.Pen obtained by the method only has the simple function write, and its manufacture craft is obtained using single sintering, formation
The case where product meeting existence component is unevenly distributed, in addition, the neck benezene material contained in the conditioning agent of its formula is a kind of right
The ingredient that human body can damage.
Invention content
For the above defect of the existing technology, the present invention proposes that one kind is not easily broken, long-lived functionality book
Write pen.
The present invention is mainly by white or colorless solid powder, pigment, modifying agent, functional powder and high molecular polymer group
At, it is characterised in that：It further include functional powder；
It is described white or colorless solid powder be sulfate, silicate, carbonate containing or with the natural ore powder of silicate, glass
In powder or lignocellulose at least any one；
The pigment is pigment made of natural or organic synthesis the solid color pigments allotment of different colour systems；
The modifying agent is chlorinated paraffin, paraffin, dibutyl sebacate, citric acid fat, polyisobutene succinimide, tristearin
In acid, antioxidant or rosin at least any one；
The functional powder be far infrared nano powder, magnetic powder or noctilucence powder at least any one；
The high molecular polymer is polypropylene, polyurethane, polyolefin, polyethylene, polyester, makrolon, polyvinyl chloride, rubber
In at least any one.
The present invention and the significant difference of existing product are：It further include functional powder in ingredient.Promoted by having for addition
Into with improve blood circulation, enhancing metabolism, the far infrared nano powder for the functions such as improving the immunity of the human body, magnetic meal component,
Pen is provided with certain health-care effect made of making, and can promote the comfortable feel degree for using pen at low ambient temperatures；The present invention adds
After having entered environmentally friendly luminescent powder, the color of pen can be made more gorgeous, while be more prone to find the pen of loss in the dark；And it uses
Flexible material will not only cause human body rigid injury, while not allow frangibility more；Especially for children, these are excellent
Point is especially significant.
In addition, white of the present invention or colorless solid powder, pigment, modifying agent, functional powder and high molecular polymerization
Object accounts for 10~60%, 1~15%, 1~15%, 1~15% and the 25~45% of the quality that always feeds intake respectively.
The middle high molecular material that feeds intake above ensure that the flexibility of this lettering pen, functional powder provide function affect,
White or colorless solid powder can make various powder adsorptions more preferable.
Another object of the present invention is to propose above functional lettering pen production method.
The present invention first by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtains function
Property color masterbatch, then again high molecular polymer is uniformly mixed to be placed in extrusion molding or injection moulding apparatus with functional color masterbatch and adds
Heat, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen；
The white or natural ore powder, glass that colorless solid powder is sulfate, silicate, carbonate containing or silicate-containing
In powder or lignocellulose at least any one；
The pigment is pigment made of natural or organic synthesis the solid color pigments allotment of different colour systems；
The modifying agent is chlorinated paraffin, paraffin, dibutyl sebacate, citric acid fat, polyisobutene succinimide, tristearin
In acid, antioxidant or rosin at least any one；
The functional powder be far infrared nano powder, magnetic powder or noctilucence powder at least any one；
The high molecular polymer is polypropylene, polyurethane, polyolefin, polyethylene, polyester, makrolon, polyvinyl chloride, rubber
In at least any one.
The present invention uses above-mentioned technical proposal, first by white or colorless solid powder, pigment, modifying agent and functional powder
Mixing granulation can effectively promote the quality of plasticity pen, color evenly, it is more fine and smooth smooth to cut rear section.The present invention is also logical
That crosses addition has the far infrared nano functions such as promote and improve blood circulation, enhancing metabolism, improve the immunity of the human body
Powder, magnetic meal component, make manufactured pen be provided with certain health-care effect, can be promoted and the feel of pen is used to relax at low ambient temperatures
Appropriateness；After environmentally friendly luminescent powder, the color of pen can be made more gorgeous, while be more prone to find loss in the dark
Pen；And rigid injury will not only cause human body using flexible material, while not allowing frangibility more；Especially to youngster
For child, these advantages are especially significant, and product can be accomplished compact and flexible, and easy to carry, safety and environmental protection is not easily broken, warp
Pen durable long.
Further, extrusion molding of the present invention or injection molding when heating temperature be 100~210 DEG C.The temperature is logical for high molecular material
Normal heating temperature section, facilitates production.
Specific implementation mode
Part is mass parts in following weighing.
Example one：
Weighing：Polyvinyl chloride（High molecular polymer）45 parts；Kaolin（White or colorless solid powder）Or 10 parts of glass powder；Night
Light is yellow（Functional powder, pigment）8 parts；Paraffin（Modifying agent）15 parts；Diatomite（White or colorless solid powder）20 parts；Far
Infrared nanometer powder（Functional powder）2 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in extrusion moulding apparatus and is heated to again
120 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example two：
Weighing：Polypropylene（High molecular polymer）10 parts；Polyethylene（High molecular polymer）30 parts；Talcum powder（It is white or colourless
Solid powder）15 parts；Noctilucence is red（Functional powder）10 parts；Chlorinated paraffin（Modifying agent）8 parts；Antioxidant（Modifying agent）2 parts；
Calcium carbonate（White or colorless solid powder）23 parts；Magnetic powder（Functional powder）2 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in injection moulding apparatus and is heated to again
To 150 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example three：
Weighing：Polyethylene（High molecular polymer）25 parts；Talcum powder（White or colorless solid powder）30 parts；Pigment blue（Pigment）
10 parts；Citric acid fat（Modifying agent）10 parts；Calcium carbonate（White or colorless solid powder）14 parts；Barium sulfate（It is white or colourless solid
Body powder）9 parts；Magnetic powder（Functional powder）1 part；Far infrared nano powder（Functional powder）1 part.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in extrusion moulding apparatus and is heated to again
180 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example four：
Weighing：Polyester（ABS）30 parts（High molecular polymer）；Polyurethane（High molecular polymer）15 parts；Paratonere（Pigment）8
Part；Calcium stearate（Modifying agent）5 parts；Paraffin（Modifying agent）10 parts；Calcium carbonate（White or colorless solid powder）20 parts；Talcum powder
（White or colorless solid powder）10 parts；Far infrared nano powder（Functional powder）2 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in extrusion moulding apparatus and is heated to again
140 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example five：
Weighing：Makrolon（High molecular polymer）20 parts；Butadiene-styrene rubber（High molecular polymer）25 parts；Pigment white（Pigment）
10 parts；Stearic acid（Modifying agent）10 parts；Rosin（Modifying agent）5 parts；Kaolin（White or colorless solid powder）20 parts；It is wooden
Cellulose powder（White or colorless solid powder）8 parts；Magnetic powder（Functional powder）2 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in injection moulding apparatus and is heated to again
210 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example six：
Weighing：Polyolefin（High molecular polymer）40 parts；Pigment yellow（Pigment）4 parts；Paratonere（Pigment）6 parts；Two fourth of decanedioic acid
Ester（Modifying agent）10 parts；Paraffin（Modifying agent）5 parts；Calcium carbonate（White or colorless solid powder）10 parts；Glass powder（White or nothing
Color solid powder）20 parts；Far infrared nano powder（Functional powder）5 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in injection moulding apparatus and is heated to again
180 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example seven：
Weighing：Polypropylene（High molecular polymer）15 parts；Rubber（High molecular polymer）15 parts；Pigment blue（Pigment）10 parts；It covers
De- soil（White or colorless solid powder）15 parts；Precipitate barium（White or colorless solid powder）20 parts；Lignocellulose（White
Or colorless solid powder）15 parts；Citric acid fat（Modifying agent）5 parts；Magnetic powder（Functional powder）5 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in injection moulding apparatus and is heated to again
175 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Example eight：
Weighing：Polyethylene（High molecular polymer）15 parts；Polyurethane（High molecular polymer）15 parts；Naphthol green（Pigment）10 parts；
Glass powder（White or colorless solid powder）25 parts；Barium sulfate（White or colorless solid powder）25 parts；Polyisobutene succinyl
Imines（Modifying agent）5 parts；Far infrared nano powder（Functional powder）5 parts.
Processing technology：First by white or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, obtain
Functional color masterbatch, then with functional color masterbatch is uniformly mixed high molecular polymer to be placed in injection moulding apparatus and is heated to again
100 DEG C, squeeze, stretch, mould shape, finally after being cooled by water, segmentation to get functional lettering pen.
Claims (5)
1. low resilience flexibility colorful functional lettering pen, mainly by white or colorless solid powder, pigment, modifying agent, functionality
Powder and high molecular polymer composition, it is characterised in that：It further include functional powder；
It is described white or colorless solid powder be sulfate, silicate, carbonate containing or with the natural ore powder of silicate, glass
In powder or lignocellulose at least any one；
The pigment is pigment made of natural or organic synthesis the solid color pigments allotment of different colour systems；
The modifying agent is chlorinated paraffin, paraffin, dibutyl sebacate, citric acid fat, polyisobutene succinimide, tristearin
In acid, antioxidant or rosin at least any one；
The functional powder be far infrared nano powder, magnetic powder or noctilucence powder at least any one；
The high molecular polymer is polypropylene, polyurethane, polyolefin, polyethylene, polyester, makrolon, polyvinyl chloride, rubber
In at least any one.
2. according to the 1 low resilience flexibility colorful functional lettering pen is required, it is characterised in that：The white or colorless solid powder
End, pigment, modifying agent, functional powder and high molecular polymer account for respectively the quality that always feeds intake 10~60%, 1~15%, 1~
15%, 1~15% and 25~45%.
3. the production method of low resilience flexibility colorful functional lettering pen as described in claim 1, it is characterised in that：It first will be white
Or colorless solid powder, pigment, modifying agent and functional powder mixing granulation, functional color masterbatch is obtained, then again high score
Sub- polymer is uniformly mixed to be placed in extrusion molding or injection moulding apparatus with functional color masterbatch and heats, squeezes, stretching, mould shape,
Finally after being cooled by water, segmentation to get functional lettering pen；
It is described white or colorless solid powder be sulfate, silicate, carbonate containing or with the natural ore powder of silicate, glass
In powder or lignocellulose at least any one；
The pigment is pigment made of natural or organic synthesis the solid color pigments allotment of different colour systems；
The modifying agent is chlorinated paraffin, paraffin, dibutyl sebacate, citric acid fat, polyisobutene succinimide, tristearin
In acid, antioxidant or rosin at least any one；
The functional powder be far infrared nano powder, magnetic powder or noctilucence powder at least any one；
The high molecular polymer is polypropylene, polyurethane, polyolefin, polyethylene, polyester, makrolon or polyvinyl chloride, rubber
In glue at least any one.
4. the production method according to the 3 low resilience flexibility colorful functional lettering pens are required, it is characterised in that：It is described white or
Colorless solid powder, pigment, modifying agent, functional powder and high molecular polymer account for 10~60%, the 1 of the quality that always feeds intake respectively
~15%, 1~15%, 1~15% and 25~45%.
5. the production method according to the 3 or 4 low resilience flexibility colorful functional lettering pens are required, it is characterised in that：Extrusion molding or
Heating temperature is 100~210 DEG C when injection molding.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810413711X | 2018-05-03 | ||
| CN201810413711 | 2018-05-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108795156A true CN108795156A (en) | 2018-11-13 |
Family
ID=64070675
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810665363.5A Pending CN108795156A (en) | 2018-05-03 | 2018-06-26 | Low resilience flexibility colorful functional lettering pen and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108795156A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158794A (en) * | 1996-10-14 | 1997-09-10 | 叶程 | Elastic magnetic health pen shaft sleeve and its production and application |
| EP1093494A1 (en) * | 1998-06-17 | 2001-04-25 | Binney & Smith Inc. | Crayons containing ester waxes |
| WO2001079365A1 (en) * | 2000-04-14 | 2001-10-25 | Sicpa Holding S.A. | Solid marking composition as writing means, a writing instrument, an optically variable marking layer and use of a plurality of optically variable pigments |
| CN2506286Y (en) * | 2001-10-22 | 2002-08-21 | 庄国明 | Far infrared multi-function heart rescure pen |
| CN1385319A (en) * | 2001-05-11 | 2002-12-18 | 株式会社文鸟 | Multi-color pen or oil colour wax-pen and production method thereof |
| CN101058663A (en) * | 2007-05-15 | 2007-10-24 | 中南大学 | Far infrared health care macromolecule composite material |
| CN101993636A (en) * | 2009-08-17 | 2011-03-30 | 真彩文具有限公司 | Crayon and manufacturing method thereof |
| CN107523141A (en) * | 2017-08-09 | 2017-12-29 | 无锡南理工科技发展有限公司 | A kind of preparation method of high-elastic environmentally friendly wax crayon |
-
2018
- 2018-06-26 CN CN201810665363.5A patent/CN108795156A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158794A (en) * | 1996-10-14 | 1997-09-10 | 叶程 | Elastic magnetic health pen shaft sleeve and its production and application |
| EP1093494A1 (en) * | 1998-06-17 | 2001-04-25 | Binney & Smith Inc. | Crayons containing ester waxes |
| WO2001079365A1 (en) * | 2000-04-14 | 2001-10-25 | Sicpa Holding S.A. | Solid marking composition as writing means, a writing instrument, an optically variable marking layer and use of a plurality of optically variable pigments |
| CN1385319A (en) * | 2001-05-11 | 2002-12-18 | 株式会社文鸟 | Multi-color pen or oil colour wax-pen and production method thereof |
| CN2506286Y (en) * | 2001-10-22 | 2002-08-21 | 庄国明 | Far infrared multi-function heart rescure pen |
| CN101058663A (en) * | 2007-05-15 | 2007-10-24 | 中南大学 | Far infrared health care macromolecule composite material |
| CN101993636A (en) * | 2009-08-17 | 2011-03-30 | 真彩文具有限公司 | Crayon and manufacturing method thereof |
| CN107523141A (en) * | 2017-08-09 | 2017-12-29 | 无锡南理工科技发展有限公司 | A kind of preparation method of high-elastic environmentally friendly wax crayon |
Non-Patent Citations (1)
| Title |
|---|
| 盖希特: "《塑料添加剂手册》", 31 March 1992, 中国石化出版社 * |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20181113 |