JPH03265636A - Rubber composition - Google Patents
Rubber compositionInfo
- Publication number
- JPH03265636A JPH03265636A JP6262290A JP6262290A JPH03265636A JP H03265636 A JPH03265636 A JP H03265636A JP 6262290 A JP6262290 A JP 6262290A JP 6262290 A JP6262290 A JP 6262290A JP H03265636 A JPH03265636 A JP H03265636A
- Authority
- JP
- Japan
- Prior art keywords
- water
- soluble inorganic
- compound
- rubber composition
- inorganic compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 27
- 239000005060 rubber Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 20
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 13
- 235000002639 sodium chloride Nutrition 0.000 abstract description 9
- 239000011780 sodium chloride Substances 0.000 abstract description 8
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000012047 saturated solution Substances 0.000 abstract description 2
- 238000005299 abrasion Methods 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010344 sodium nitrate Nutrition 0.000 description 1
- 239000004317 sodium nitrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、氷上摩擦性能を向上させたゴム組成物に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a rubber composition with improved friction performance on ice.
凍結した路面、特に氷と水とが混在するような０℃付近
の路面は、滑り易く、歩行や自動車の走行が危険である
。Frozen road surfaces, especially roads at temperatures around 0° C. where ice and water coexist, are slippery and dangerous for walking or driving.
そこで、従来、このような路面での安全な走行を可能と
するために、例えば、タイヤのトレッド部を低温でも軟
質のゴム材料で構成したり、発泡ゴム材料で構成したり
している。しかしながら、この場合、耐摩耗性に劣ると
いう問題がある。Conventionally, in order to enable safe driving on such road surfaces, tire treads have been made of, for example, a rubber material that is soft even at low temperatures, or a foamed rubber material. However, in this case, there is a problem that the wear resistance is poor.
本発明は、このような事情にかんがみなされたものであ
って、耐摩耗性を実質的に損なうことなしに氷上摩擦性
能を向上させたゴム組成物を提供することを目的とする
。The present invention was conceived in view of these circumstances, and an object of the present invention is to provide a rubber composition that has improved friction performance on ice without substantially impairing wear resistance.
本発明のゴム組成物は、水溶性無機化合物を含有してお
り、その粒子同士が実質的に互いに接触していないこと
を特徴とする。The rubber composition of the present invention contains a water-soluble inorganic compound, and is characterized in that its particles are not substantially in contact with each other.
このように本発明では、粒子同士が実質的に互いに接触
していない状態で水溶性無機化合物を含有するため、本
発明のゴム組成物で例えばタイヤのトレッド部を構成し
た場合、凍結した路面の走行時にトレンド表面の水溶性
無機化合物が路面の水に溶は出してトレンド表面に凹凸
が形成されるので、氷上摩擦性能を高めることができる
。また、トレッド部の内部の水溶性無機化合物は溶は出
さないのでトレッド部が発泡状態とはならないから、耐
摩耗性が実質的に損なわれることはない。In this way, in the present invention, since the particles contain a water-soluble inorganic compound in a state in which they are not substantially in contact with each other, when the rubber composition of the present invention is used to form, for example, the tread portion of a tire, it can be used on frozen road surfaces. When driving, the water-soluble inorganic compounds on the trend surface dissolve into the water on the road surface, forming irregularities on the trend surface, which can improve friction performance on ice. Further, since the water-soluble inorganic compound inside the tread portion does not dissolve, the tread portion does not become foamed, so that wear resistance is not substantially impaired.
以下、上記手段につき詳しく説明する。The above means will be explained in detail below.
本発明で用いる水溶性無機化合物は、“０℃の飽和溶液
１００ｇ中に１ｇ以上存在する”という０℃における水
への溶解度を有するものである。この水溶性無機化合物
としては、例えば、塩化カリウム、塩化カルシウム、塩
化鉄、塩化ナトリウム、塩化バリウム、塩化マグネシウ
ムなどの金属塩化物：硝酸カリウム、硝酸ナトリウム等
の硝酸化物：炭酸カリウム、炭酸ナトリウム等の炭酸化
合物；硫酸亜鉛、硫酸銅、硫酸合歓等の硫酸化合物が挙
げられる。これらのうち、塩化ナトリウム、特に塩化ナ
トリウムを主成分とする食塩を用いるのが好ましい。食
塩は、人手し易く、安価だからである。The water-soluble inorganic compound used in the present invention has a solubility in water at 0°C such that 1g or more is present in 100g of a saturated solution at 0°C. These water-soluble inorganic compounds include, for example, metal chlorides such as potassium chloride, calcium chloride, iron chloride, sodium chloride, barium chloride, and magnesium chloride; nitrates such as potassium nitrate and sodium nitrate; and carbonates such as potassium carbonate and sodium carbonate. Compounds: Examples include sulfuric acid compounds such as zinc sulfate, copper sulfate, and sulfuric acid. Among these, it is preferable to use sodium chloride, particularly common salt containing sodium chloride as a main component. This is because table salt is easy to produce and inexpensive.
本発明のゴム組成物は、この水溶性無機化合物を含有す
る。そして、この水溶性無機化合物は、ゴム組成物内に
おいて粒子同士が実質的に互いに接触していない。すな
わち、ゴム組成物内において、水溶性無機化合物の個々
の粒子が実質的に独立に分散した状態となっている。こ
のように分散していない場合には、すなわち、粒子同士
が互いに接触している場合には、そのゴム組成物でタイ
ヤのトレンド部を構成して凍′結した路面を走行すると
トレッド部の内部の水溶性無機化合物まで溶は出してト
レッド表面から内部に至る連通孔が生し、トレッド部が
内部まで発泡状態となり、耐摩耗性が損なわれるからで
ある。The rubber composition of the present invention contains this water-soluble inorganic compound. Particles of this water-soluble inorganic compound are not substantially in contact with each other within the rubber composition. That is, the individual particles of the water-soluble inorganic compound are substantially independently dispersed within the rubber composition. If the particles are not dispersed in this way, that is, if the particles are in contact with each other, the rubber composition will form the trend part of the tire, and when the tire is driven on an icy road surface, the inside of the tread part will be damaged. This is because even the water-soluble inorganic compounds in the tread are leached out, forming communicating pores from the tread surface to the inside, and the tread becomes foamed to the inside, impairing wear resistance.
水溶性無機化合物の個々の粒子を実質的に独立に分散さ
せるには、水溶性無機化合物の粒径および配合量を適宜
勘案して水溶性無機化合物をゴム組成物に配合し、混練
を行えばよい。すなわち、粒径が大きいときには配合量
を少なくし、一方、粒径が小さいときには配合量を多く
するなどすればよい。水溶性無機化合物の平均粒径は、
５〜２０００μ−程度である。In order to substantially independently disperse individual particles of a water-soluble inorganic compound, the water-soluble inorganic compound is blended into a rubber composition, taking into consideration the particle size and blending amount of the water-soluble inorganic compound, and kneaded. good. That is, when the particle size is large, the amount to be blended may be reduced, while when the particle size is small, the amount to be blended may be increased. The average particle size of water-soluble inorganic compounds is
It is about 5 to 2000μ.
また、本発明のゴムＭｉ底物を構成するゴムとしては、
特に限定されるものではなく、例えば、天然ゴム、合成
ポリイソプレンゴム、ポリブタジェンゴム、スチレン−
ブタジェン共重合体ゴムなどのジエン系ゴムである。こ
のゴム組成物は、カーボンブラックなどの配合剤を他に
適宜含有する。In addition, the rubber constituting the rubber Mi sole of the present invention includes:
There are no particular limitations, such as natural rubber, synthetic polyisoprene rubber, polybutadiene rubber, styrene rubber, etc.
Diene rubber such as butadiene copolymer rubber. This rubber composition appropriately contains other compounding agents such as carbon black.
以下に実施例を示す。Examples are shown below.
実施例
第１表に示す配合内容（重量部）でゴム組成物Ａ、Ｂ、
Ｃを作製し、これらのゴム組成物について下記の方法に
て氷上摩擦係数を測定して氷上摩擦性能を評価した。こ
の結果を第１表に示す。Examples Rubber compositions A, B,
C was prepared, and the friction coefficient on ice of these rubber compositions was measured by the method described below to evaluate the friction performance on ice. The results are shown in Table 1.
上 、の゛ ：
試料の加硫は１６０℃×２０分、加圧プレスにより行っ
た。試料は試験前に＃８０の紙ヤスリで表面パフした。Top and bottom: Vulcanization of the sample was performed at 160° C. for 20 minutes using a pressure press. Samples were surface puffed with #80 sandpaper prior to testing.
測定はＡＳＴＨＥ−３０３により行った。路面は、−５
℃に設定した水盤を用いた。得られた氷上摩擦係数につ
いてゴム組成物Ａの場合を１００として指数表示した。Measurements were performed using ASTHE-303. The road surface is -5
A water basin set at ℃ was used. The obtained coefficient of friction on ice was expressed as an index with the case of rubber composition A set as 100.
数値が大きい方が氷上摩擦係数が高いことを表わす。A larger number indicates a higher coefficient of friction on ice.
３０二に
注）
傘１ ： Ｎ−（１，３−ジメチル）゛チル）−Ｎ゛−
フェニルーＰ−フェニレンジアミン。Note on 302) Umbrella 1: N-(1,3-dimethyl)ethyl)-N-
Phenyl-P-phenylenediamine.
＊２：Ｎ−シクロヘキシル−２−ペンジチアゾリルスル
ヘンアミド。*2: N-cyclohexyl-2-pendithiazolylsulfenamide.
日本たばこ産業■製の「キッチンソ
ルト」（商品名）、主成分は塩化ナト
リウム（９９％以上）、平均粒径４００μｍ比重２．１
６１゜
本３ ：
ベルト、
靴底などのゴム材料として好適である。"Kitchen Salt" (product name) manufactured by Japan Tobacco Inc., main ingredient is sodium chloride (99% or more), average particle size 400 μm, specific gravity 2.1
61° book 3: Suitable as a rubber material for belts, shoe soles, etc.
Claims (1)
的に互いに接触していないことを特徴とするゴム組成物
。A rubber composition containing a water-soluble inorganic compound, the particles of which are substantially not in contact with each other.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6262290A JPH03265636A (en) | 1990-03-15 | 1990-03-15 | Rubber composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6262290A JPH03265636A (en) | 1990-03-15 | 1990-03-15 | Rubber composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03265636A true JPH03265636A (en) | 1991-11-26 |
Family
ID=13205604
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6262290A Pending JPH03265636A (en) | 1990-03-15 | 1990-03-15 | Rubber composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03265636A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002211203A (en) * | 2001-01-19 | 2002-07-31 | Sumitomo Rubber Ind Ltd | Studless tire |
| JP2007091853A (en) * | 2005-09-28 | 2007-04-12 | Kinjo Rubber Co Ltd | Swelling material |
| JP2011528735A (en) * | 2008-07-24 | 2011-11-24 | ソシエテ ド テクノロジー ミシュラン | Rubber composition for winter tire tread |
| JP2013514399A (en) * | 2009-12-18 | 2013-04-25 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | Winter tires with improved grip on ice |
| JP2013517356A (en) * | 2010-01-18 | 2013-05-16 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | Rubber composition for snow tire tread |
| WO2022085180A1 (en) * | 2020-10-23 | 2022-04-28 | 株式会社アシックス | Anti-slip member for wearable article or sports article, wearable article, and sports article |
-
1990
- 1990-03-15 JP JP6262290A patent/JPH03265636A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002211203A (en) * | 2001-01-19 | 2002-07-31 | Sumitomo Rubber Ind Ltd | Studless tire |
| JP2007091853A (en) * | 2005-09-28 | 2007-04-12 | Kinjo Rubber Co Ltd | Swelling material |
| JP2011528735A (en) * | 2008-07-24 | 2011-11-24 | ソシエテ ド テクノロジー ミシュラン | Rubber composition for winter tire tread |
| JP2013514399A (en) * | 2009-12-18 | 2013-04-25 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | Winter tires with improved grip on ice |
| JP2013517356A (en) * | 2010-01-18 | 2013-05-16 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | Rubber composition for snow tire tread |
| WO2022085180A1 (en) * | 2020-10-23 | 2022-04-28 | 株式会社アシックス | Anti-slip member for wearable article or sports article, wearable article, and sports article |
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