JPH03257178A - Method for etching decorative member - Google Patents
Method for etching decorative memberInfo
- Publication number
- JPH03257178A JPH03257178A JP5403690A JP5403690A JPH03257178A JP H03257178 A JPH03257178 A JP H03257178A JP 5403690 A JP5403690 A JP 5403690A JP 5403690 A JP5403690 A JP 5403690A JP H03257178 A JPH03257178 A JP H03257178A
- Authority
- JP
- Japan
- Prior art keywords
- gold
- plating layer
- etching
- resist
- decorative member
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005530 etching Methods 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims description 21
- 238000007747 plating Methods 0.000 claims abstract description 72
- 239000010931 gold Substances 0.000 claims abstract description 60
- 229910052737 gold Inorganic materials 0.000 claims abstract description 59
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 57
- 238000009713 electroplating Methods 0.000 claims abstract description 13
- 238000007639 printing Methods 0.000 claims abstract description 11
- 229910001020 Au alloy Inorganic materials 0.000 claims abstract description 4
- 239000003353 gold alloy Substances 0.000 claims abstract description 4
- 239000010935 stainless steel Substances 0.000 claims description 13
- 229910001220 stainless steel Inorganic materials 0.000 claims description 13
- 230000000873 masking effect Effects 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 5
- 229910017398 Au—Ni Inorganic materials 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 229910017392 Au—Co Inorganic materials 0.000 claims description 2
- 229910002668 Pd-Cu Inorganic materials 0.000 claims description 2
- 229910015363 Au—Sn Inorganic materials 0.000 claims 1
- 238000007654 immersion Methods 0.000 abstract description 8
- 229910045601 alloy Inorganic materials 0.000 abstract description 4
- 239000000956 alloy Substances 0.000 abstract description 4
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 206010011732 Cyst Diseases 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000001259 photo etching Methods 0.000 description 1
- 238000011176 pooling Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明はステンレス材を用いた装飾部材表面に凹状また
は凸状の文字および模様を形成する装飾部材の蝕刻方法
に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method of etching a decorative member made of stainless steel to form concave or convex characters and patterns on the surface of the decorative member.
［発明の概要１
本発明はステンレス材を用いた装飾部材表面に、凹状ま
たは凸状の文字および模様を形成する方法において、該
部材表面に予め電気メッキ法により金ストライクメッキ
層を被覆し、次いで有機系メッキ用レジストを用い凹状
となる文字および模様のパターンを印刷した後、電気メ
ッキ法により金メッキ層を被覆し、その後に該有機系メ
ッキ用レジストを有機溶剤にて溶解除去し、次に金メッ
キ剥離液中に浸漬し金ストライクメッキ層を剥離除去す
ることにより文字および模様のパターンに素地表面を露
出させ金メッキ層によるエツチング用マスキング層を形
成した後、エツチング液により蝕刻を行いしかる後金メ
ッキ剥離液中に浸漬し該金メッキ層を剥離除去すること
により装飾部材表面に所望の書体図パターンを凹状また
は凸状に形成し、装飾的価値の高い装飾部材を品質的に
安定で且つ安価に提供するところにある。[Summary of the Invention 1 The present invention provides a method for forming concave or convex characters and patterns on the surface of a decorative member made of stainless steel, in which the surface of the member is coated with a gold strike plating layer in advance by electroplating, and then After printing a concave character and pattern pattern using an organic plating resist, a gold plating layer is coated using an electroplating method, and then the organic plating resist is dissolved and removed using an organic solvent, and then gold plating is performed. The gold strike plating layer is peeled off and removed by immersion in a stripping solution to expose the surface of the substrate in the pattern of letters and patterns, and a masking layer for etching is formed using the gold plating layer.After etching with the etching solution, the gold plating stripping solution is applied. To form a desired typeface pattern in a concave or convex shape on the surface of a decorative member by immersing it in the gold-plated layer and peeling off the gold plating layer, thereby providing a decorative member with high decorative value in a stable quality and at a low cost. It is in.
［従来の技術］
従来のステンレス材を用いた装飾部材表面に、凹状また
は凸状の文字または模様を形成する方法には、
■部材表面にフォトレジ法により所望の書体図パターン
をマスキングした後にエツチングを行い、次にマスキン
グを剥離除去するフォトエツチング法。[Prior art] Conventional methods for forming concave or convex characters or patterns on the surface of a decorative member made of stainless steel include etching after masking a desired typeface pattern on the surface of the member using a photoresist method. This is followed by a photo-etching method in which the masking is peeled off and removed.
■部材表面に有機系のメッキ用レジストをタコ印刷・ス
クリーン印刷等により所望の書体図パターンに印刷マス
キングした後に電気メッキ法により銀、金、金合金メッ
キ層の内の一種を被覆形成し、次に印刷マスキングを剥
離除去し、次いでエツチングを行った後にメッキ層を剥
離除去する方法。■After printing and masking an organic plating resist in the desired typeface pattern by tacho printing, screen printing, etc. on the surface of the component, one type of silver, gold, or gold alloy plating layer is formed by electroplating, and then A method in which the printed masking is peeled off and then the plating layer is peeled off after etching.
が知られている。It has been known.
［発明が解決しようとする課題〕
しかし、おおむね複雑な形状、多種多様な表面仕上げを
有する装飾部材の選択的所定部分にのみ蝕刻を行うため
には選択的所定部分以外の表面全体をマスキングする必
要があるが、従来の方法では次の欠点がある。[Problems to be Solved by the Invention] However, in order to etch only selectively predetermined portions of a decorative member that has a generally complex shape and a wide variety of surface finishes, it is necessary to mask the entire surface other than the selectively predetermined portions. However, the conventional method has the following drawbacks.
■の方法では、予め表面全体にフォトレジ法（・をコー
ティングする際、複雑形状であるために液たまり防止が
不可能であり膜厚のバラツキが発生してしまうため、露
光時の位置合せ用治具へのセットが困難である。又、レ
ジスト膜はピンホールが発生しやすく、ピンホール部は
エツチングされてしまい、装飾価値が低下してしまうた
め、ピンホール修正が必要であるが、肉眼では発見しに
くいために顕微鏡等により拡大して検査、修正しなくて
はならず長時間を要し、作業効率が悪く、コストが高い
等の問題がある。In method (2), when coating the entire surface with photoresist () in advance, it is impossible to prevent liquid from pooling due to the complex shape, resulting in variations in film thickness. It is difficult to set it on the jig.Also, the resist film is prone to pinholes, and the pinholes are etched away, reducing the decorative value. Since it is difficult to detect, inspection and correction must be performed under magnification using a microscope, which takes a long time, resulting in poor work efficiency and high costs.
■の方法では、ステンレス上への電気メッキを行う際、
素地との密着性確保のためにメッキ前洗浄に於て強力な
活性化が必要であり、予め印刷されたレジストが該メッ
キ前洗浄により部分的に剥離してしまう、又、印刷時に
付着した汚れ・印刷後の１／シスト焼成時の発生ガス付
着による汚れによるメッキ層の密着不良が発生してしま
う等により所定部分以外の部分がエツチングされてしま
う等の問題がある０本発明はこのような問題点を解決す
るもので、その目的とするところは、ステンレス材を用
いた装飾部材表面に所望の書体図パターンを凹、状また
は凸状に形成し装飾的価値の高い装飾部材を品質的に安
定で且つ安価に提供することにある。In method ①, when electroplating on stainless steel,
Strong activation is required during pre-plating cleaning to ensure adhesion to the substrate, and the pre-printed resist may partially peel off during the pre-plating cleaning, and stains that may have adhered during printing.・After printing 1/There are problems such as poor adhesion of the plating layer due to stains caused by gas adhesion during cyst firing, resulting in etching of areas other than the designated areas. The purpose of this product is to form a desired typeface pattern in a concave, convex or concave shape on the surface of a decorative component made of stainless steel, thereby improving the quality of the decorative component with high decorative value. The aim is to provide stable and inexpensive products.
「課題を解決するための手段〕
本発明の装飾部材の蝕刻方法は、ステンレス材を用いた
装飾部材表面に、凹状または凸状の文字および模様を形
成する方法において、該部材表面に予め電気メッキ法に
より金ストライクメッキ層を被覆し、次いで有機系メッ
キ用レジストを用い凹状となる文字および模様のパター
ンを印刷した後、電気メッキ法により金メッキ層を被覆
し、その後に該有機系メッキ用レジストを有機溶剤にて
溶解除去し、次に金メッキ剥離液中に浸漬し金ストライ
クメッキ層を剥離除去することにより文字および模様の
パターンに素地表面を露出させ金メッキ層によるエツチ
ング用マスキング層を形成した後、エツチング液により
蝕刻を行いしかる後金メッキ剥離液中に浸漬し該金メッ
キ層を剥離除去することにを特徴とする。Means for Solving the Problems The method of etching a decorative member of the present invention is a method for forming concave or convex characters and patterns on the surface of a decorative member made of stainless steel, in which the surface of the member is pre-electroplated. A gold strike plating layer is coated by a method, and then a concave character and pattern pattern is printed using an organic plating resist, a gold plating layer is coated by an electroplating method, and then the organic plating resist is applied. After dissolving and removing it with an organic solvent and then immersing it in a gold plating remover to peel off and remove the gold strike plating layer, the base surface is exposed in the pattern of letters and patterns, and a masking layer for etching is formed using the gold plating layer. The method is characterized in that after etching with an etching solution, the gold plating layer is removed by immersion in a gold plating stripping solution.
また前記金ストライクメッキ層が２４にで、厚みが０．
ｌＬＬｍ以内であり、前記金メッキ層１４〜２４にのＡ
ｕ−Ａｇ、Ａｕ−Ｎｉ、Ａｕ−Ｃｏ、Ａｕ−５ｎ、Ａｕ
−Ｐｄ−Ｃｕ、Ａｕの金合金または純金メッキ層の内の
一種であり、庫みが０．５〜５μｍであることを特徴と
する。Further, the gold strike plating layer has a thickness of 24 mm and a thickness of 0.
within lLLm, and the A of the gold plating layers 14 to 24 is
u-Ag, Au-Ni, Au-Co, Au-5n, Au
It is a type of gold alloy of -Pd-Cu, Au or a pure gold plating layer, and is characterized by a depth of 0.5 to 5 μm.
［作 用］
本発明の上記方法によれば、ステンレス材を用いた装飾
部材表面全体に予め電気メッキ法により金ストライクメ
ッキ層を被覆することにより、般的に行われているステ
ンレス表面活性化のメッキ前洗浄が容易に可能であり、
素地との密着性が確保できる。又、メッキ被膜厚みは０
．ＩＬ１ｍ以内であるため、印刷時の位置合せ用治具へ
のセットには何ら影響しない、従って印刷は選択的所定
部分に所望の書体図パターンの転写が可能である。印刷
後の金メッキ層被覆に於けるメッキ前洗浄は予め金スト
ライクメッキ層が形成されているためステンレス用の強
力な活性化は不要であり、−量的な脱脂、中和洗浄のみ
で密着性確保が可能であるため、レジストの剥離は発生
しない０次に、レジスト溶解除去後の金ストライクメッ
キ層の剥離除去においては、上層の金メッキ層も剥離す
る恐れもあるが、金ストライクメッキ層は０．１μｍ以
内であるため短時間で剥離でき、しかも、上層の金メッ
キ層が０．５〜５μｍであるため上層の金メッキ層への
影響はない、上記方法により蝕刻用のマスキングは素地
との密着性が確保され、且つ書体図パターンを正確に転
写した金メッキ層により形成され、蝕刻が容易に可能で
ある。以下本発明について実施例に基づいて説明する。[Function] According to the above method of the present invention, the entire surface of a decorative member made of stainless steel is coated with a gold strike plating layer by electroplating in advance, thereby eliminating the commonly performed stainless steel surface activation. Easy to clean before plating,
Adhesion to the substrate can be ensured. Also, the plating film thickness is 0.
．． Since the IL is within 1 m, it does not affect the setting on the alignment jig during printing, and therefore, it is possible to selectively transfer a desired typeface pattern to a predetermined portion during printing. The pre-plating cleaning for covering the gold plating layer after printing does not require strong activation for stainless steel as the gold strike plating layer has been formed in advance, and adhesion is ensured only by quantitative degreasing and neutralization cleaning. Therefore, no peeling of the resist occurs.In peeling and removing the gold strike plating layer after dissolving and removing the resist, there is a risk that the upper gold plating layer may also peel off, but the gold strike plating layer does not peel off. Since the thickness is within 1 μm, it can be peeled off in a short time, and since the upper gold plating layer has a thickness of 0.5 to 5 μm, there is no effect on the upper gold plating layer. By using the above method, the masking for etching has good adhesion to the substrate. It is formed by a gold plated layer that is secured and accurately transfers the typeface pattern, and can be easily etched. The present invention will be described below based on examples.
〔実 施 例１
第１図の（ａ）〜（ｇ）は本発明の蝕刻仕上を行う場合
の５ｔＪＳ３０４を素材とした時計用外装部品の基本製
造工程を段階的に示した該部品の一部分を示す断面図で
ある。まず第１図（ａ）に示す様に５ＵＳ３０４素材１
よりなる時計用外装部品表面全体に電気メッキ法により
金ストライクメッキ層２を０，０５ＬＬｍ形成させた６
次に予め準備された所望の書体図パターンを用いて作成
したガラスＪＩＩＩ版を用い（ｂ）に示す様に有機系レ
ジスト３をタコ印刷により部品表面に印刷し焼成の後に
、（Ｃ）に示す様にアルカリ脱脂、酸中和の前処理洗浄
を行い、次いで電気メッキ法により、２３にのＡｕ−Ｎ
ｉ合金メッキ層４を２μｍ形成した。その後（ｄ）に示
す様に有機溶剤中に浸漬して有機系レジスト３を剥離除
去し、次いで（ｅ）に示す様に、金剥離液中に１０秒間
浸漬して表面に露出した金ストライクメッキ層２を剥離
除去し蝕刻しようとする部分のステンレス素地を露出さ
せた後、４２％塩化第二鉄溶液中に浸漬し、６０秒間部
品を揺動してステンレス素地露出部を蝕刻し水洗を行っ
た後の状態を（ｅ）に示した。更に、金剥離液中に浸漬
して蝕刻用マスキングに用いた２３にのＡｕ−Ｎｉ合金
メッキ層４および金ストライクメッキ層２を剥離除去し
くｇ）に示す様に５ＵＳ３０４から成る時計用外装部品
の表面に凹状または凸状の文字および模様を形成した。[Example 1] Figure 1 (a) to (g) shows a part of the part showing step by step the basic manufacturing process of an exterior part for a watch made of 5t JS304 when the etching finish of the present invention is applied. FIG. First, as shown in Figure 1(a), 5US304 material 1
A gold strike plating layer 2 of 0.05 LLm was formed on the entire surface of a watch exterior part by electroplating.
Next, using a glass JIII plate prepared using a desired typeface pattern prepared in advance, an organic resist 3 is printed on the surface of the part by tacho printing as shown in (b), and after baking, as shown in (C). After performing pre-treatment cleaning such as alkaline degreasing and acid neutralization as described above, Au-N was applied to 23 by electroplating.
The i-alloy plating layer 4 was formed to have a thickness of 2 μm. Thereafter, as shown in (d), the organic resist 3 is peeled off by immersion in an organic solvent, and then, as shown in (e), the gold strike plating exposed on the surface is immersed in a gold stripping solution for 10 seconds. After peeling off and removing layer 2 to expose the stainless steel base in the area to be etched, the part was immersed in a 42% ferric chloride solution, rocked for 60 seconds to etch the exposed stainless steel base, and washed with water. The state after this is shown in (e). Furthermore, the Au-Ni alloy plating layer 4 and the gold strike plating layer 2 used for etching masking were peeled off and removed by immersion in a gold stripping solution, as shown in g). Concave or convex characters and patterns are formed on the surface.
上記方法により作成した時計用外装部品は、上載的に高
級感を有するものであった０品質試験は人工汗耐食試験
（４０℃×湿度９０％Ｘ４８Ｈ）、人工海水耐食試験（
４０℃×濃度９０％×４８Ｈ）を行い上記試験結果は全
て時計用外装部品としての品質を十分満足するものであ
った。The exterior parts for watches produced by the above method had a luxurious feel.The quality tests were artificial sweat corrosion resistance test (40℃ x 90% humidity x 48H), artificial seawater corrosion resistance test (
40° C. x 90% concentration x 48 hours), and the above test results all fully satisfied the quality as an exterior part for a watch.
また、本発明の適用にあたっては、メガネフレーム、ラ
イター、ネクタイビン、装身具等の装飾部品への適用も
可能である。Furthermore, the present invention can also be applied to decorative parts such as eyeglass frames, lighters, tie bins, and accessories.
［発明の効果１
以上述べた如く本発明によれば、ステンレス材を用いた
装飾部材表面に予め電気メッキ法により金ストライクメ
ッキ層を形成した後に所望の書体図パターンを有機系メ
ッキ用レジストを用いて印刷し、次いで電気メッキ法に
より金メッキ層を被覆し、その後に該有機系メッキ用レ
ジストを有機溶剤にて溶解除去し１次に金メッキ剥離液
中に浸漬し金ストライクメッキ層を剥離除去することに
より文字および模様のパターンに素地表面を露出させ金
メッキ層によるエツチング用マスキング層を形成した後
、エツチング液により蝕刻を行いしかる後金メッキ剥離
液中に浸漬し該金メッキ層を剥離除去することにより、
従来のフォトレジ法における治具セット困難、ピンホー
ル修正、又はメッキ被膜によるマスキングにおけるレジ
スト剥離等のＣａを克服し、選択的所定部分に所望の書
体図パターンを凹状または凸状に形成し、装飾的価値の
高い装飾部材を品質的に安定で且つ、安価に提供するこ
とが回前となった。[Effects of the Invention 1] As described above, according to the present invention, a gold strike plating layer is formed in advance on the surface of a decorative member made of stainless steel by electroplating, and then a desired typeface pattern is formed using an organic plating resist. Next, a gold plating layer is coated by electroplating, and then the organic plating resist is dissolved and removed with an organic solvent, and first, the gold strike plating layer is peeled off and removed by immersion in a gold plating stripping solution. After exposing the surface of the substrate to the letter and pattern patterns and forming a masking layer for etching with a gold plating layer, etching with an etching solution, and then immersing in a gold plating remover to peel off and remove the gold plating layer.
Overcoming problems such as difficulty in setting a jig in the conventional photoresist method, pinhole correction, or resist peeling during masking with a plating film, it is possible to form a desired typeface pattern in a concave or convex shape in a selective predetermined area and create a decoration. It has become necessary to provide decorative members of high value with stable quality and at low cost.
第１図（ａ）〜（ｇ）は本発明の蝕刻仕上を行う場合の
５ＵＳ３０４を素材とした時計用外装部品の基本製造工
程を段階的に示した該部品の一部分を示す断面図である
。
１ ・ ・ ・ ５ＵＳ３０４
２・・・金ストライクメッキ層
３・・・有機系レジスト
４・・・Ａｕ−Ｎｉ合金メッキ層
以
上FIGS. 1(a) to 1(g) are cross-sectional views showing a part of a watch exterior part, step by step, showing the basic manufacturing process of a watch exterior part made of 5US304 when the etching finish of the present invention is applied. 1 ・ ・ ・ 5US304 2...Gold strike plating layer 3...Organic resist 4...Au-Ni alloy plating layer or higher
Claims (2)
は凸状の文字および模様を形成する方法において、該部
材表面に予め電気メッキ法により金ストライクメッキ層
を被覆し、次いで有機系メッキ用レジストを用い凹状と
なる文字および模様のパターンを印刷した後、電気メッ
キ法により金メッキ層を被覆し、その後に該有機系メッ
キ用レジストを有機溶剤にて溶解除去し、次に金メッキ
剥離液中に浸漬し金ストライクメッキ層を剥離除去する
ことにより文字および模様のパターンに素地表面を露出
させ金メッキ層によるエッチング用マスキング層を形成
した後、エッチング液により蝕刻を行い、しかる後金メ
ッキ剥離液中に浸漬し該金メッキ層を剥離除去すること
を特徴とする装飾部材の蝕刻方法。(1) In a method for forming concave or convex characters and patterns on the surface of a decorative member made of stainless steel, the surface of the member is coated with a gold strike plating layer in advance by electroplating, and then an organic plating resist is applied. After printing a pattern of concave characters and patterns using a gold plate, a gold plating layer is coated by electroplating, and then the organic plating resist is dissolved and removed with an organic solvent, and then it is immersed in a gold plating remover. After peeling off and removing the gold strike plating layer, the base surface is exposed to the letter and pattern patterns, and a masking layer for etching is formed using the gold plating layer. After that, etching is performed with an etching solution, and then immersed in a gold plating stripping solution. A method of etching a decorative member, which comprises peeling off and removing the gold plating layer.
．１μｍ以内であり、前記金メッキ層が１４〜２４Ｋの
Ａｕ−Ａｇ、Ａｕ−Ｎｉ、Ａｕ−Ｃｏ、Ａｕ−Ｓｎ、Ａ
ｕ−Ｐｄ−Ｃｕ、Ａｕの金合金または純金メッキ層の内
の一種であり、厚みが０．５〜５μｍであることを特徴
とする請求項１記載の装飾部材の蝕刻方法。(2) The gold strike plating layer is 24K and has a thickness of 0.
．． Au-Ag, Au-Ni, Au-Co, Au-Sn, A with a thickness of 1 μm or less, and the gold plating layer is 14 to 24K.
2. The method of etching a decorative member according to claim 1, wherein the layer is one of a gold alloy of u-Pd-Cu or Au or a pure gold plating layer, and has a thickness of 0.5 to 5 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5403690A JPH03257178A (en) | 1990-03-06 | 1990-03-06 | Method for etching decorative member |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5403690A JPH03257178A (en) | 1990-03-06 | 1990-03-06 | Method for etching decorative member |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03257178A true JPH03257178A (en) | 1991-11-15 |
Family
ID=12959365
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5403690A Pending JPH03257178A (en) | 1990-03-06 | 1990-03-06 | Method for etching decorative member |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03257178A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011032557A (en) * | 2009-08-04 | 2011-02-17 | Dainippon Printing Co Ltd | Method of forming gold plating pattern on stainless substrate |
| JP2013139639A (en) * | 2011-02-09 | 2013-07-18 | Dainippon Printing Co Ltd | Stainless substrate with gold-plated layer |
| JP2013216981A (en) * | 2013-07-31 | 2013-10-24 | Dainippon Printing Co Ltd | Stainless steel substrate |
| JP2014001409A (en) * | 2012-06-15 | 2014-01-09 | Dainippon Printing Co Ltd | Method for forming polymer compound layer and gold plating pattern on stainless substrate |
| JP2017082339A (en) * | 2016-12-28 | 2017-05-18 | 大日本印刷株式会社 | Stainless substrate |
-
1990
- 1990-03-06 JP JP5403690A patent/JPH03257178A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011032557A (en) * | 2009-08-04 | 2011-02-17 | Dainippon Printing Co Ltd | Method of forming gold plating pattern on stainless substrate |
| JP2013139639A (en) * | 2011-02-09 | 2013-07-18 | Dainippon Printing Co Ltd | Stainless substrate with gold-plated layer |
| JP2014001409A (en) * | 2012-06-15 | 2014-01-09 | Dainippon Printing Co Ltd | Method for forming polymer compound layer and gold plating pattern on stainless substrate |
| JP2013216981A (en) * | 2013-07-31 | 2013-10-24 | Dainippon Printing Co Ltd | Stainless steel substrate |
| JP2017082339A (en) * | 2016-12-28 | 2017-05-18 | 大日本印刷株式会社 | Stainless substrate |
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