JPH03247824A - Deodoriser - Google Patents
DeodoriserInfo
- Publication number
- JPH03247824A JPH03247824A JP4302890A JP4302890A JPH03247824A JP H03247824 A JPH03247824 A JP H03247824A JP 4302890 A JP4302890 A JP 4302890A JP 4302890 A JP4302890 A JP 4302890A JP H03247824 A JPH03247824 A JP H03247824A
- Authority
- JP
- Japan
- Prior art keywords
- water
- adsorption member
- blower
- bad smell
- malodorous components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000001179 sorption measurement Methods 0.000 claims description 55
- 230000001877 deodorizing effect Effects 0.000 claims description 20
- 238000003795 desorption Methods 0.000 claims description 12
- 230000005587 bubbling Effects 0.000 abstract description 8
- 229920006395 saturated elastomer Polymers 0.000 abstract description 8
- 238000004332 deodorization Methods 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 235000019645 odor Nutrition 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000010865 sewage Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000013872 defecation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000017525 heat dissipation Effects 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は硫化水素、アンモニア、各種メルカプタン、ア
ミン類等の悪臭成分を浄化する脱臭装置に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a deodorizing device for purifying malodorous components such as hydrogen sulfide, ammonia, various mercaptans, and amines.
従来の技術
近年クリーン思考を反映して住設機器に脱臭装置が導入
されつつあり、その中で悪臭発生源であるトイレに脱臭
装置を搭載した便器が提案されている。BACKGROUND OF THE INVENTION In recent years, deodorizing devices have been introduced into housing equipment reflecting the trend toward cleanliness, and among these, toilet bowls equipped with deodorizing devices have been proposed in toilets, which are the source of bad odors.
この種の脱臭機能付き便器は、たとえば特開昭63−1
4672号公報によって開示されたものがある。This type of toilet bowl with a deodorizing function is known, for example, from Japanese Patent Application Laid-open No. 63-1
There is one disclosed in Japanese Patent No. 4672.
その構成を第3図に基づいて説明する。同図において1
は脱臭装置であり、便器2の内部後方あるいは側方に開
口する吸入口3と、トイレ内に臨む排出口4を有するダ
クト5の内部にファンモータからなる送風機6及び悪臭
成分を貯留するための活性炭からなる吸着部材7が設け
られている。Its configuration will be explained based on FIG. In the same figure, 1
is a deodorizing device, which includes an air blower 6 consisting of a fan motor inside a duct 5 having an inlet 3 opening to the rear or side of the inside of the toilet bowl 2 and an outlet 4 facing into the toilet, and a blower 6 for storing malodorous components. An adsorption member 7 made of activated carbon is provided.
上記構成において送風116を駆動すると吸入口3から
排出口4にいたる空気流が発生し、排便時の悪臭成分を
含んだ空気は吸入口2から吸入され吸着部材7を通過す
る時に悪臭成分が吸着浄化され排出口4からトイレ内に
排出される。In the above configuration, when the blower 116 is driven, an air flow is generated from the inlet 3 to the outlet 4, and the air containing malodorous components during defecation is sucked in from the inlet 2, and when it passes through the adsorption member 7, the malodorous components are adsorbed. It is purified and discharged into the toilet from the discharge port 4.
発明が解決しようとする課題
このような従来の脱臭装置では吸着部材として活性炭を
用いているため悪臭成分の吸着量は有限である。したが
って飽和吸着量に達すると脱臭効果はなくなるため交換
が必要である。またトイレ内の温度が上昇すると臭気成
分によっては逆に脱着する場合があり、かえって悪臭が
増加し、不快感が増加する。また脱臭効果を長期に渡っ
て継続するためには飽和吸着量を増加させる、つまり吸
着部材の容積を大きくするしかなく装置全体の大型化に
つながる。Problems to be Solved by the Invention Since such conventional deodorizing devices use activated carbon as an adsorption member, the amount of malodorous components adsorbed is limited. Therefore, when the saturated adsorption amount is reached, the deodorizing effect disappears and it is necessary to replace it. Furthermore, when the temperature inside the toilet rises, some odor components may be desorbed, resulting in an increase in odor and discomfort. In addition, in order to maintain the deodorizing effect over a long period of time, the saturated adsorption amount must be increased, that is, the volume of the adsorption member must be increased, which leads to an increase in the size of the entire device.
本発明は上記課題を解決するものであり、吸着部材の交
換を必要とせず、かつ小型の脱臭装置を提供することを
目的としている。The present invention solves the above problems, and aims to provide a small-sized deodorizing device that does not require replacement of the adsorption member.
課題を解決するための手段
上記目的を達成するために本発明は、吸入口と排出口と
送風機を有するダクト内に配設され、悪臭成分を吸着保
持する吸着部材と、前記吸着部材に吸着された悪臭成分
を強制脱着させる脱着部材と、前記吸着部材の下流側に
開口部を有し他端は貯水容器の水内に連設されたバイパ
ス管と、前記バイパス管の流路内に配設されたポンプと
、前記バイパス管を開閉するダンパーを有するとともに
、前記送風機、脱着部材、ポンプ、及びダンパーを制御
する制御回路から構成したものである。Means for Solving the Problems In order to achieve the above objects, the present invention provides an adsorption member that is disposed in a duct having an inlet, an outlet, and a blower, and that adsorbs and holds malodorous components, and an adsorption member that is adsorbed by the adsorption member. a desorption member for forcibly desorbing malodorous components; a bypass pipe having an opening on the downstream side of the adsorption member and the other end of which is connected to water in a water storage container; and a bypass pipe disposed in a flow path of the bypass pipe. The pump includes a damper that opens and closes the bypass pipe, and a control circuit that controls the blower, the detachable member, the pump, and the damper.
作用
本発明の脱着装置は上記構成により、脱臭時には送風機
により悪臭成分を吸引して吸着部材で吸着浄化し、所定
期間脱臭して飽和吸着量に達する前にダンパーを動作さ
せてバイパス管を開口させ、同時に脱着部材及びポンプ
を動作させ、吸着部材に吸着された悪臭成分を脱着させ
、バイパス管を通じて貯水容器の水にバブリングし溶解
するものである。ここで悪臭成分は水に容易に溶解し効
率的に悪臭成分を処理することができ、悪臭成分が溶解
した汚水はたとえば下水として廃棄する。Function The desorption device of the present invention has the above-mentioned configuration. During deodorization, the blower sucks in malodorous components, the adsorption member adsorbs and purifies them, deodorizes for a predetermined period, and before reaching the saturated adsorption amount, operates the damper to open the bypass pipe. At the same time, the desorption member and the pump are operated to desorb the malodorous components adsorbed by the adsorption member and dissolve them by bubbling them into the water in the water storage container through the bypass pipe. Here, the malodorous components are easily dissolved in water and can be efficiently treated, and the wastewater in which the malodorous components are dissolved is disposed of, for example, as sewage.
これにより吸着部材の再生及び悪臭成分の処理が自動的
に行われるため吸着部材の交換なしで長期に渡って脱臭
効果を継続することが可能となる。This automatically regenerates the adsorption member and processes malodorous components, making it possible to maintain the deodorizing effect for a long period of time without replacing the adsorption member.
実施例
以下、本発明の一実施例を添付図面にもとづいて説明す
る。第1図は本発明による脱臭装置の断面図であり、便
器への実施例を示す。Embodiment Hereinafter, one embodiment of the present invention will be described based on the accompanying drawings. FIG. 1 is a cross-sectional view of a deodorizing device according to the present invention, showing an embodiment of the deodorizing device in a toilet bowl.
同図において、8は脱臭装置であり、吸引口9と排出口
10を設けたダクト11の内部には送風機12及び悪臭
成分を物理吸着する活性炭からなる吸着部材13、吸着
部材13にトラップされた悪臭成分を加熱して脱着させ
るヒータからなる脱着部材I4が設けられている。In the figure, 8 is a deodorizing device, and inside a duct 11 provided with a suction port 9 and a discharge port 10, there is a blower 12 and an adsorption member 13 made of activated carbon that physically adsorbs malodorous components. A desorption member I4 consisting of a heater that heats malodorous components to desorb them is provided.
15はバイパス管であり、吸着部材13の下流側に開口
部16を存し、他端は便器である貯水容器17の水中に
開口されており、流路の途中には悪臭を含んだ空気を水
中に排出してバブリングさせるためのポンプ18が設け
られている。Reference numeral 15 denotes a bypass pipe, which has an opening 16 on the downstream side of the adsorption member 13, and the other end is opened into the water of a water storage container 17, which is a toilet bowl. A pump 18 is provided for discharging and bubbling water into the water.
19はバイパス管15の開口部1Gの開閉を行うための
ダンパーである。また20は送風1112、脱着部材1
4、ポンプ18及びダンパー19を制御する制御回路で
あり着座スイッチ21がオンすると送風機12を動作さ
せて脱臭が行われ、内蔵された時限要素(図示せず)に
より吸着部材13の飽和吸着量に達する前の所定の時期
に自動的にダンパー19を動作させて排出口lOを閉じ
るとともにバイパス管15を開口し、同時に脱着部材1
4に通電して吸着部材13を加熱するとともにポンプ1
日を動作させて臭気成分を水中にバブリングさせる。19 is a damper for opening and closing the opening 1G of the bypass pipe 15. In addition, 20 is an air blower 1112, and a detachable member 1.
4. A control circuit that controls the pump 18 and damper 19. When the seat switch 21 is turned on, the blower 12 is operated to perform deodorization, and a built-in timer (not shown) reaches the saturated adsorption amount of the adsorption member 13. The damper 19 is automatically operated at a predetermined time before the discharge port lO is closed, the bypass pipe 15 is opened, and at the same time the desorption member 1 is
4 to heat the adsorption member 13 and the pump 1
Operate the sun to bubble odor components into the water.
以上の構成において、次に動作を説明する。排便時に便
器に着座すると着座スイッチ21がオンして送風機12
が動作し、吸引口9から排出口IOにいたる大風量の空
気の流れが発生し、排便時の悪臭成分は吸入口9から吸
引され吸着部材13に物理吸着される。浄化された空気
は排出口10からトイレ内に放出される。In the above configuration, the operation will be explained next. When you sit on the toilet bowl when defecating, the seat switch 21 is turned on and the blower 12 is turned on.
operates, a large flow of air is generated from the suction port 9 to the discharge port IO, and malodorous components during defecation are sucked through the suction port 9 and physically adsorbed onto the adsorption member 13. The purified air is discharged into the toilet through the outlet 10.
次に吸着部材13の再生について説明する。吸着部材1
3の大きさ(吸着面積)に応じた飽和吸着量にいたらな
いまでの所定時間経過後、#御回路20が動作してダン
パー19が動作し、排出口10を閉しるとともにバイパ
ス管15開口し、同時に脱着部材14に通電して吸着部
材13を加熱する。この時悪臭成分によって比較的低温
で脱着するものと高温にしないと脱着しない成分がある
が約300’C以上に加熱することにより完全に脱着す
ることができる。Next, regeneration of the adsorption member 13 will be explained. Adsorption member 1
After a predetermined period of time has elapsed until the saturated adsorption amount is not reached according to the size (adsorption area) of No. 3, the # control circuit 20 operates, the damper 19 operates, the discharge port 10 is closed, and the bypass pipe 15 is opened. At the same time, electricity is applied to the detachable member 14 to heat the adsorption member 13. At this time, some malodorous components are desorbed at a relatively low temperature and some components are not desorbed unless heated to a high temperature, but they can be completely desorbed by heating to about 300'C or higher.
また吸着部材13として活性炭を用いる場合、約400
℃以上となると燃えてしまうので脱着部材14の温度制
御が必要である。脱着した悪臭成分はポンプ18によっ
て所定時間吸引されバイパス管15を通じて貯水容器(
便器H7の水中にバブリングされる。In addition, when activated carbon is used as the adsorption member 13, approximately 400
If the temperature exceeds .degree. C., it will burn, so it is necessary to control the temperature of the detachable member 14. The desorbed malodorous components are sucked out by the pump 18 for a predetermined period of time, and then passed through the bypass pipe 15 to the water storage container (
Bubbling occurs in the water of toilet bowl H7.
悪臭成分は容易に水に溶解するが、たとえ溶解されずに
再度便器内に放散したとしても吸引口9から再度吸引さ
れバブリングされる。悪臭成分が溶解した汚水はトイレ
使用時に糞便とともに下水に廃棄する。The malodorous components are easily dissolved in water, but even if they are not dissolved and emitted into the toilet bowl again, they will be sucked in again from the suction port 9 and bubbled. Sewage with malodorous components dissolved in it is disposed of into the sewage system along with feces when the toilet is used.
なお上記説明では吸着部材13の飽和吸着量を予測して
自動的に制御回路20によって脱着再生動作を行う例を
述べたが、専用の再生スイッチ(図示せず)を設け、任
意の時期に再生動作を行うようにしてもよい。In the above explanation, an example was described in which the saturated adsorption amount of the adsorption member 13 is predicted and the desorption/regeneration operation is automatically performed by the control circuit 20. You may also perform an action.
以上のように本実施例によれば、脱臭は吸着部材13へ
の物理吸着によって圧力損失を少なくして大風量で行い
、吸着部材13の飽和吸着量になる前に自動的に、もし
くは手動によりダンパー19を動作させて風路切替えを
行い、脱着部材14によって吸着部材13に吸着した悪
臭成分を脱着させるとともに、ポンプ18によりバイパ
ス管15を通じて水中にバブリングさせて溶解させるこ
とにより吸着部材13の再活性を図るものであり、従来
必要であった吸着部材13の交換が不要となり、長期間
に渡って脱臭効果を継続することができる。またこれに
より吸着部材13の飽和吸着量を少なく設定することが
できるため@着部材13の小型化が図れる。As described above, according to this embodiment, deodorization is performed with a large air volume while reducing pressure loss through physical adsorption to the adsorption member 13, and is performed automatically or manually before the adsorption member 13 reaches its saturated adsorption amount. The damper 19 is operated to switch the air path, the desorption member 14 desorbs the malodorous components adsorbed on the adsorption member 13, and the pump 18 causes the adsorption member 13 to be reused by bubbling it into water through the bypass pipe 15 and dissolving it. The deodorizing effect can be maintained for a long period of time since the adsorption member 13 does not need to be replaced, which was necessary in the past. Furthermore, since the saturation adsorption amount of the adsorption member 13 can be set to a small value, the size of the adsorption member 13 can be reduced.
またたとえば酸化触媒体等を設けて分解処理する場合触
媒体を400″C以上に加熱する必要があり、ヒータ及
び断熱部材が必要であるが、本実施例では悪臭成分を水
中にバブリングさせて溶解することにより処理するため
、常温での処理が可能であり、構造の簡素化が図れると
ともに低コスト化が実現できる。For example, when an oxidation catalyst is provided for decomposition treatment, it is necessary to heat the catalyst to 400"C or higher, which requires a heater and a heat insulating member. In this example, the malodorous components are dissolved by bubbling them into the water. Since the process is carried out by doing this, the process can be carried out at room temperature, and the structure can be simplified and costs can be reduced.
第2図は本発明の他の実施例を示すものであり、肌着部
材14aとして陽極22と陰極23を吸着部材13を介
して配設するとともに、吸着部材13にパルスアークを
印加する高圧発生装置24から構成したものである。そ
の他は第1図実施例と同じであり同一番号を付して説明
を省略する。FIG. 2 shows another embodiment of the present invention, in which an anode 22 and a cathode 23 are disposed as an underwear member 14a via an adsorption member 13, and a high-pressure generator is used to apply a pulse arc to the adsorption member 13. It is composed of 24 parts. The other parts are the same as those in the embodiment shown in FIG. 1, so the same reference numerals are given and the explanation will be omitted.
この構成により高圧発生装置24に通電されると陽極2
2、陰極23間に吸着部材13の大きさに応じたパルス
アークが発生し、吸着部材13は全体としての温度は比
較的低温であるが、ミクロ構造的領域内では十数百度の
高温に達し、有機物などの被吸着成分は炭化あるいは熱
分解を受ける。同時に共存する微量の水分が瞬間的に過
熱水蒸気状態となり、炭化された有機物との間に、いわ
ゆる水性ガス反応が起こり部分的にガス化して除去され
ることとなる。このような反応がパルスアークによって
短時間に続発し、連鎖反応的に進行する。With this configuration, when the high voltage generator 24 is energized, the anode 2
2. A pulse arc corresponding to the size of the adsorption member 13 is generated between the cathodes 23, and although the temperature of the adsorption member 13 as a whole is relatively low, it reaches a high temperature of tens of hundreds of degrees within the microstructural region. , organic substances and other adsorbed components undergo carbonization or thermal decomposition. At the same time, a small amount of moisture coexisting with the organic substance instantly turns into a superheated steam state, and a so-called water gas reaction occurs with the carbonized organic matter, resulting in partial gasification and removal. Such a reaction occurs one after another in a short period of time due to the pulsed arc, and progresses like a chain reaction.
ヒータ等により加熱して脱着する場合周囲への熱伝導、
熱放散があり、脱着温度300″Cを得るには比較的長
時間を要するが、パルスアークによれば短時間に脱着が
完了する効果がある。When attaching and detaching by heating with a heater etc., heat conduction to the surroundings,
Due to heat dissipation, it takes a relatively long time to reach a desorption temperature of 300''C, but pulsed arc has the effect of completing desorption in a short time.
発明の効果
以上詳述したように本発明は、吸着部材によって悪臭成
分を吸着するとともに、所定の時期に脱着部材により脱
着し、ポンプによってバイパス管を通じて水中にバブリ
ングして悪臭成分を溶解して処理するものであり以下の
効果を得ることができる。Effects of the Invention As detailed above, the present invention adsorbs malodorous components using an adsorption member, desorbs them at a predetermined time using a desorption member, and dissolves malodorous components by bubbling them into water using a pump through a bypass pipe. The following effects can be obtained.
(1) 吸着部材をくり返し再生して使用できるため
、従来必要であった吸着部材の交換が不要となり、長期
間に渡って高効率の脱臭効果を継続することができる。(1) Since the adsorption member can be repeatedly regenerated and used, there is no need to replace the adsorption member, which was previously necessary, and highly efficient deodorizing effects can be maintained over a long period of time.
またこれにより吸着部材の飽和吸着量を少なく設定する
ことができるため吸着部材及び装置全体の小型化が図れ
る。Furthermore, since the saturation adsorption amount of the adsorption member can be set to a small value, the adsorption member and the entire device can be downsized.
(2)悪臭成分を水中にバブリングさせて溶解すること
により常温での処理が可能であり、たとえば酸化触媒体
等を設けて分解処理する方法に比べて構造の簡素化が図
れるとともに低コスト化が実現できる。(2) It is possible to treat malodorous components at room temperature by bubbling them into water and dissolving them, which simplifies the structure and lowers costs compared to, for example, decomposition treatment using an oxidation catalyst. realizable.
第1図は本発明の一実施例を示す脱臭装置の断面図、第
2図は同地の実施例を示す脱臭装置の断面図、第3図は
従来の脱臭装置の断面図である。
8・・・・・・脱臭装置、9・・・・−・吸引口、10
・・・・・・排出口、11・・・・・・タリト、12・
・・・・・送風機、13・・・・・・吸着部材、14.
14a・・・・・・脱着部材、15・・・・−・バイパ
ス管、16・・・・・・開口部、17・・・・・・貯水
容器、18・・自・・ポンプ、19・・・・・・ダンパ
ー、20・・・・・・制御回路、22・・・・・・陽極
、23・・・・・・陰極、24・・・・・・高圧発生装
置。FIG. 1 is a sectional view of a deodorizing device showing an embodiment of the present invention, FIG. 2 is a sectional view of a deodorizing device showing an embodiment of the same, and FIG. 3 is a sectional view of a conventional deodorizing device. 8... Deodorizing device, 9...-- Suction port, 10
...Exhaust port, 11...Talit, 12.
...Blower, 13...Adsorption member, 14.
14a...Detachable member, 15...Bypass pipe, 16...Opening, 17...Water storage container, 18...Pump, 19... ...Damper, 20 ... Control circuit, 22 ... Anode, 23 ... Cathode, 24 ... High pressure generator.
Claims (2)
ダクト内に配設され悪臭成分を吸着保持する吸着部材と
、前記吸着部材に吸着された悪臭成分を脱着させる脱着
部材と、前記吸着部材の下流側に開口部を有し他端は貯
水容器の水内に連設されたバイパス管と、前記バイパス
管の流路内に配設されたポンプと、前記バイパス管を開
閉するダンパーを有するとともに、前記送風機、脱着部
材、ポンプ、及びダンパーを制御する制御回路から構成
した脱臭装置。(1) A duct having an inlet, an outlet, and a blower, an adsorption member disposed within the duct that adsorbs and holds malodorous components, a desorption member that desorbs the malodorous components adsorbed by the adsorption member, and an adsorption member that adsorbs and holds malodorous components. A bypass pipe having an opening on the downstream side of the member and the other end connected to water in a water storage container, a pump disposed in a flow path of the bypass pipe, and a damper for opening and closing the bypass pipe. and a control circuit for controlling the blower, the detachable member, the pump, and the damper.
着部材にパルスアークを印加する構成とした特許請求の
範囲第1項記載の脱臭装置。(2) The deodorizing device according to claim 1, wherein the desorption member has an anode, a cathode, and a high pressure generator, and is configured to apply a pulse arc to the adsorption member.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4302890A JP2833108B2 (en) | 1990-02-23 | 1990-02-23 | Deodorizing device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4302890A JP2833108B2 (en) | 1990-02-23 | 1990-02-23 | Deodorizing device |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03247824A true JPH03247824A (en) | 1991-11-06 |
JP2833108B2 JP2833108B2 (en) | 1998-12-09 |
Family
ID=12652495
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4302890A Expired - Fee Related JP2833108B2 (en) | 1990-02-23 | 1990-02-23 | Deodorizing device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2833108B2 (en) |
-
1990
- 1990-02-23 JP JP4302890A patent/JP2833108B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2833108B2 (en) | 1998-12-09 |
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LAPS | Cancellation because of no payment of annual fees |