JPH0324286A - Method and device for continuously annealing and pickling band stainless steel - Google Patents

Method and device for continuously annealing and pickling band stainless steel

Info

Publication number
JPH0324286A
JPH0324286A JP15704289A JP15704289A JPH0324286A JP H0324286 A JPH0324286 A JP H0324286A JP 15704289 A JP15704289 A JP 15704289A JP 15704289 A JP15704289 A JP 15704289A JP H0324286 A JPH0324286 A JP H0324286A
Authority
JP
Japan
Prior art keywords
scale
stainless steel
pickling
roll
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP15704289A
Other languages
Japanese (ja)
Inventor
Takashi Shiokawa
隆 塩川
Hiroshi Yaginuma
寛 柳沼
Junichi Yamamoto
準一 山本
Akira Kishida
朗 岸田
Kokichi Sonoyama
園山 光吉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP15704289A priority Critical patent/JPH0324286A/en
Publication of JPH0324286A publication Critical patent/JPH0324286A/en
Pending legal-status Critical Current

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  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

PURPOSE:To prevent the damage of a band stainless steel by the scale depositing on a bridle roll at the time of removing the scale on the surface of the annealed steel by pickling by cooling the steel from a specified temp. before pickling and then removing the scale having a high oxidation degree. CONSTITUTION:A band stainless steel 1 continuously annealed in an annealing furnace 2 is cooled to >= about 100 deg.C in a cooling tank 4, then introduced into a water cooling tank 5 and quenched. A scale having a low oxidation degree is formed on the surface of the steel with high adhesive strength, and a scale having a high oxidation degree and easy to release is deposited thereon. Accordingly, the upper-layer scale quenched in the tank 5 is released and removed by a cleaning brush 7 and a wringer roll 8. Consequently, an oxide scale is not deposited on the succeeding roll 9, and the steel is not damaged by the deposition of the oxide scale. The steel is then sent to a pickling tank 10 to dissolve and remove the highly adhesive remaining scale, and a band stainless steel free of damage and having a lustrous surface is produced.

Description

【発明の詳細な説明】 く産業上の利用分野〉 本発明は生産能率を低下することなく、ステンレス鋼帯
の製品品質を向上させ、かっ歩留りを改善できるステン
レス鋼帯のa続焼鈍酸洗方l去およびその装置に関する
[Detailed description of the invention] Industrial application field> The present invention provides a method for a-continuous annealing and pickling of stainless steel strips that can improve the product quality of stainless steel strips and improve the yield without reducing production efficiency. 1 and its apparatus.

く従来の技術〉 一般にステンレス製品は、その表面性状として高光沢で
かつキズの無いことが要求される。
BACKGROUND ART Stainless steel products are generally required to have high gloss and scratch-free surface properties.

第2図にステンレス製品を製造するのに従来用いられて
いる焼鈍酸洗ラインの一概略図を示す。
FIG. 2 shows a schematic diagram of an annealing and pickling line conventionally used to manufacture stainless steel products.

すなわちステンレスm帯1は、支持ロール3で保持され
、焼鈍炉2、冷却設備4そして酸洗槽10へと運ばれる
That is, the stainless steel m-band 1 is held by support rolls 3 and transported to an annealing furnace 2, a cooling facility 4, and a pickling tank 10.

従来の方法においても、ターンロールをなくした。 横
型炉を用いたり、支持ロール3の材質も疵のはいりにく
い非鉄製軟質ロールを使用したり等、工夫がなされてい
る. さらに近年、連続焼鈍酸洗ライン (continuous Annealing and
 Pickling Line)の高生産性が要求され
るようになり、炉長が次第に長くなり、それにつれて酸
洗槽10も長くなってきている。 そのため焼鈍炉2と
、この次工程である酸洗槽10の間にプライドルロール
9を設置することが多くなってきている。
Even in the conventional method, turn rolls were eliminated. Efforts have been made such as using a horizontal furnace and using a non-ferrous soft roll that is less prone to scratches as the material for the support roll 3. Furthermore, in recent years, continuous annealing and pickling lines have been developed.
As high productivity of the pickling line (pickling line) is required, the length of the furnace is gradually becoming longer, and the length of the pickling tank 10 is also becoming longer. For this reason, a priddle roll 9 is increasingly installed between the annealing furnace 2 and the pickling tank 10, which is the next step.

これは長大な焼鈍炉と酸洗槽に対して各々に最通な張力
を銅帯に付加することで、安定した通板を達成するため
である。
This is to achieve stable threading by applying sufficient tension to the copper strip in each of the long annealing furnace and pickling tank.

第3図にこの例の概略図を示す。FIG. 3 shows a schematic diagram of this example.

く発明が解決しようとする問題点〉 このプライドルロール9を設置した場合、焼鈍炉2にて
ステンレス鋼帯1の表面に生成したスケールがプライド
ルロール表面に付着し、このためにステンレス鋼”II
FIに疵を発生させることがわかった。
[Problems to be Solved by the Invention] When this Prydle roll 9 is installed, the scale generated on the surface of the stainless steel strip 1 in the annealing furnace 2 adheres to the surface of the Prydle roll, and as a result, the stainless steel "II"
It was found that it caused flaws in FI.

このスケールについて調査したところ、ステンレス鋼帯
と良く密着した酸化度の低い(CrxOyでクロム酸化
物を表わした場合、Y/Xがおよそ4以下)スケールと
、その外側にある酸化が進んだ(酸化度が4をこえてい
る)ボーラスで、かつ剥離しやすいスケールとから成り
立っていることが判明した。 更にプライドルロール9
に付着しているスケール成分を調べたところ、酸化度の
高いスケールであることがわかり、上記のボーラスで剥
離しやすいスケール部がプライドルロール9に付着し、
疵の原因となっていることがわかった。
When we investigated this scale, we found that there was a scale with a low degree of oxidation (Y/X is about 4 or less when chromium oxide is represented by CrxOy) that adhered well to the stainless steel strip, and a scale that was oxidized on the outside (Y/X is approximately 4 or less). It was found that the scale consists of a bolus (with a degree of over 4) and a scale that is easily peeled off. More pride roll 9
When the scale component adhering to the roll was examined, it was found that it was highly oxidized scale, and the scale part that was easily peeled off by the bolus was attached to the pridle roll 9.
It was found that this was the cause of the crack.

〈課題を解決するための手段〉 そこで、プライドルロール以前でスケールを除去する必
要があり、この目的を達成するためにブラシ研摩を施し
たが、 ■銅帯の冷却を十分に行なわないと研摩ブラシが溶けて
銅帯に焼付き、それがプライドルロールに付着して逆効
果となる。
<Means for solving the problem> Therefore, it was necessary to remove the scale before the priddle roll, and brush polishing was performed to achieve this purpose, but ■ If the copper strip is not cooled sufficiently, the polishing brush melts and burns onto the copper strip, which then adheres to the pridle roll and has the opposite effect.

■銅帯と密着したスケール層まで除去するため効率が悪
く、無駄が多いことがわかった。
■It was found that the efficiency was low and there was a lot of waste because it removed even the scale layer that was in close contact with the copper strip.

そこでプライドルロールには付着しないステンレス鋼帯
と良く密着した酸化度の低いスケール層は残し、疵の原
因となる剥離しやすい酸化度の高い一番外側のスケール
層だけ除去する方法を調査したところ、水洗槽中に高温
のスケール付き鋼帯を入れることにより、その時に発生
する蒸気により、外側の剥離しやすいスケール分だけ除
去でき、プライドルロールに付着するスケールが減少す
ることがわかった。
Therefore, we investigated a method of removing only the outermost scale layer with a high oxidation degree, which easily peels off and causes scratches, while leaving the low-oxidation scale layer that adheres well to the stainless steel strip, which does not adhere to the Prydle roll. It has been found that by placing a high-temperature scaled steel strip in a water washing tank, the steam generated at that time can remove only the scale on the outside that is easy to peel off, reducing the amount of scale that adheres to the priddle roll.

そこで、本発明によれば、焼鈍炉、冷却設備、プライド
ルロールおよび酸洗槽を有する酸洗ラインにおいて、ス
テンレス鋼帯を洗浄するに際し、 前記冷却設備で100℃以上に冷却したステンレス鋼板
を、前記冷却設備とプライドルロールとの間において水
洗することを特徴とするステンレス鋼帯の連続焼鈍酸洗
方7去が提供される。
Therefore, according to the present invention, when cleaning a stainless steel strip in a pickling line having an annealing furnace, a cooling equipment, a priddle roll, and a pickling tank, the stainless steel plate cooled to 100° C. or higher in the cooling equipment is A method for continuous annealing and pickling of stainless steel strip is provided, which is characterized by water rinsing between a cooling facility and a priddle roll.

また、本発明によれば、焼鈍炉、冷却設備、プライドル
ロールおよび酸洗槽を有する酸洗ラインにおいて、 前記冷却設備とプライドルロールとの間に水洗槽を設け
てなることを特徴とするステンレス鋼帯の連続焼鈍酸洗
装置が提供される。
Further, according to the present invention, in a pickling line having an annealing furnace, a cooling equipment, a pridle roll, and a pickling tank, a stainless steel is characterized in that a washing tank is provided between the cooling equipment and the pridle roll. An apparatus for continuous annealing and pickling of strips is provided.

さらに前記水洗槽内に洗浄用ブラシを設けるのがよい。Furthermore, it is preferable to provide a cleaning brush in the washing tank.

以下、本発明について詳細に説明する。The present invention will be explained in detail below.

本発明の連続焼鈍酸洗装置の概略図を第1図に示す。A schematic diagram of the continuous annealing and pickling apparatus of the present invention is shown in FIG.

装置の構成は、第2図および第3図に示したと同様に、
ステンレス鋼帯1は、焼鈍炉2で所定の熱処理を施した
後、支持ロール3を伝って、冷却設備4で急冷される。
The configuration of the device is similar to that shown in FIGS. 2 and 3.
After the stainless steel strip 1 is subjected to a predetermined heat treatment in an annealing furnace 2, it passes through a support roll 3 and is rapidly cooled in a cooling facility 4.

 冷却されたステンレスtjAilは、本発明の構成要
件である水洗槽5中に浸漬ロール6によって浸漬させ、
蒸気発生を伴なった水洗を行なう。
The cooled stainless steel tjAil is immersed by a dipping roll 6 into a washing tank 5, which is a component of the present invention, and
Wash with water accompanied by steam generation.

これにより、前述の酸化度の高い!lIllしやすいス
ケールを容易に除去することができる。
This results in the aforementioned high degree of oxidation! It is possible to easily remove scales that are susceptible to lIll.

ステンレス!t1は、水洗4!5の出側に洗浄ブラシ7
を付け、ブラシ研摩を施すと酸化度の高い外側のスケー
ル層が除去され、さらに効果が高まる。
stainless! t1 is the cleaning brush 7 on the outlet side of the water wash 4!5.
If you apply and brush polish, the highly oxidized outer scale layer will be removed, further increasing the effectiveness.

これにより、プライドルロール表面へのスケール付着は
激減する。
As a result, scale adhesion to the surface of the Prydle roll is drastically reduced.

このステンレス鋼帯1は、このあと酸洗槽10に入り、
脱スケールを完了する。
This stainless steel strip 1 then enters a pickling tank 10,
Complete descaling.

本発明において、ステンレス鋼帯を水洗槽に入れる際、
銅帯の温度は100℃以上が好ましい。  100℃未
満でもスケール除去は可能ではあるが、蒸気発生はほと
んどないため、その除去効果は劣る。
In the present invention, when placing the stainless steel strip in the washing tank,
The temperature of the copper strip is preferably 100°C or higher. Although scale removal is possible at temperatures below 100° C., the removal effect is poor because almost no steam is generated.

また、水洗槽出側の洗浄ブラシは一般的なものを用いる
ことができ、例えばナイロン製、ボリブロピレン製等が
例示される。
Further, the cleaning brush on the outlet side of the washing tank may be a common one, such as one made of nylon or polypropylene.

また、用いる水洗槽は、一般的に用いられるものでよく
、クエンチタイプ、スプレータイプのいずれでもよい。
Further, the water washing tank used may be a commonly used one, and may be either a quench type or a spray type.

く実施例〉 次に本発明を実施例に基づいて具体的に説明するが、本
発明はこれらに限定されるものではない。
EXAMPLES Next, the present invention will be specifically explained based on Examples, but the present invention is not limited thereto.

(実施例1) 本発明の実施例に用いた連続焼鈍酸洗装置の構成を、第
1図を用いて説明する。
(Example 1) The configuration of a continuous annealing and pickling apparatus used in an example of the present invention will be explained using FIG. 1.

ステンレス鋼帯(SUS304、1.0mm厚)を、炉
長45mの焼鈍炉2で焼鈍し、アスベスト製の支持ロー
ル3で冷却設備4に送った。 この冷却設m4は長さ1
5mを有し、ステンレス鋼帯は、グラファイト製支持ロ
ール3bで本発明の構成要件である水張りした全長5m
のクエンチタンクからなる水洗槽5に移され、ここで板
温130℃のステンレス!gllF2を冷却、水洗した
。 この時用いる浸漬ロール6はゴム製である. この
あと、ナイロン製の洗浄ブラシ7で洗浄し、リンガーロ
ール8でワイビングされた。
A stainless steel strip (SUS304, 1.0 mm thick) was annealed in an annealing furnace 2 with a furnace length of 45 m, and sent to a cooling facility 4 using an asbestos support roll 3. This cooling installation m4 has a length of 1
The stainless steel strip has a total length of 5 m filled with water, which is a component of the present invention, with a graphite support roll 3b.
The stainless steel plate is transferred to the washing tank 5, which consists of a quench tank, where the plate temperature is 130℃! gllF2 was cooled and washed with water. The dipping roll 6 used at this time is made of rubber. Thereafter, it was cleaned with a nylon cleaning brush 7 and wiped with a ringer roll 8.

その後さらに、3本駆動のプライドルロール9を通り、
ライン張力を焼鈍炉0 .  4 kg/mm’、酸洗
槽1 .  2 kg/mm2にコントロールしている
After that, it passes through three driven priddle rolls 9,
Line tension in annealing furnace 0. 4 kg/mm', pickling tank 1. It is controlled at 2 kg/mm2.

なお、プライドルロール9表面の材質はネオプレン、ロ
ール径は1200mmφを用′いた。
The surface material of the Priddle roll 9 was neoprene, and the roll diameter was 1200 mmφ.

以上に示した設備を用い、水洗槽5の入側でステンレス
鋼帯の温度を変えた場合のプライドルロールの汚れ具合
を調べ、その結果を第4図に示す。 また、洗浄ブラシ
を用いた場合と用いなかった場合のプライドルロールの
汚れ具合のちがいも同図に示す. 第4図でプライドルロール汚れは白い紙をロール表面に
一定時間かつ一定圧力で押し付けたときの汚れ具合につ
いて色の濃淡を限界見本との比較で表わし、従来法の結
果を1.0として相対的に表現したものである。
Using the equipment described above, the degree of contamination of the priddle roll was investigated when the temperature of the stainless steel strip was varied on the inlet side of the washing tank 5, and the results are shown in FIG. The figure also shows the difference in the degree of dirt on the Prydle roll when a cleaning brush was used and when it was not used. In Figure 4, Prydle roll stains are expressed by comparing the color shading with a limit sample when white paper is pressed against the roll surface for a certain period of time and with a certain pressure, and the result of the conventional method is set as 1.0. It is expressed in

また、これらのプライドルロールでの疵発生率について
も最終製品での歩留りによって従来のものと比較し、第
5図に示す。
Furthermore, the flaw occurrence rate of these pre-dol rolls was compared with the conventional one based on the yield of the final product, and is shown in FIG.

く発明の効果〉 本発明により、プライドルロールへのスケール付着がな
くなり、ここでの疵発生が激減した。
Effects of the Invention> According to the present invention, scale adhesion to the Prydle roll is eliminated, and the occurrence of defects therein is drastically reduced.

さらに、プライドルロール清掃のためのライン休止が不
必要となりライン稼動率が大幅に向上した。
Furthermore, there is no need to stop the line for cleaning the priddle rolls, significantly improving line operation rates.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明のステンレス鋼帯の連続焼鈍酸洗装置
の一例を示す概略図である。 第2図は、従来のステンレス鋼帯の連続焼鈍酸洗装置の
一例を示す概略図である。 第3図は、従来のその他のステンレスmiの連続焼鈍酸
洗装置の一例を示す概略図である. 第4図は、本発明の実施例において、本発明法と従来法
とを用いて焼鈍酸洗した際のプライドルロールの汚れを
比較したグラフである。 第5図は、本発明の実施例において、本発明法と従来法
とを用いて、焼鈍酸洗した際のプライドルロールの疵発
生率を比較したグラフである. 8・・・リンガーロール、 9・・・プライドルロール、 10・・・酸洗槽、 3b・・・支持ロール 符号の説明 1・・・ステンレス鋼帯、 2・・・焼鈍炉、 3・・・支持ロール、 4・・・冷却設備、 5・・・水洗槽、 6・・・浸漬ロール、 7・・・洗浄ブラシ、 FIG,1 FIG.4 FIG.2 3 FIG.3
FIG. 1 is a schematic diagram showing an example of a continuous annealing and pickling apparatus for stainless steel strip according to the present invention. FIG. 2 is a schematic diagram showing an example of a conventional continuous annealing and pickling apparatus for stainless steel strips. FIG. 3 is a schematic diagram showing an example of another conventional continuous annealing and pickling apparatus for stainless steel. FIG. 4 is a graph comparing the stains on the pridle rolls when annealing and pickling were performed using the method of the present invention and the conventional method in Examples of the present invention. FIG. 5 is a graph comparing the flaw occurrence rate of pridle rolls when annealing and pickling were performed using the method of the present invention and the conventional method in an example of the present invention. 8... Ringer roll, 9... Prydle roll, 10... Pickling tank, 3b... Support roll code explanation 1... Stainless steel strip, 2... Annealing furnace, 3... Support roll, 4... Cooling equipment, 5... Washing tank, 6... Soaking roll, 7... Washing brush, FIG. 1 FIG. 4 FIG. 2 3 FIG. 3

Claims (3)

【特許請求の範囲】[Claims] (1)焼鈍炉、冷却設備、プライドルロールおよび酸洗
槽を有する酸洗ラインにおいて、ステンレス鋼帯を洗浄
するに際し、 前記冷却設備で100℃以上に冷却したステンレス鋼板
を、前記冷却設備とブライドルロールとの間において水
洗することを特徴とするステンレス鋼帯の連続焼鈍酸洗
方法。
(1) When cleaning stainless steel strips in a pickling line that has an annealing furnace, cooling equipment, bridle rolls, and a pickling tank, the stainless steel sheet that has been cooled to 100°C or higher in the cooling equipment is transferred to the cooling equipment and the bridle roll. A method for continuous annealing and pickling of stainless steel strips, characterized by washing with water between.
(2)焼鈍炉、冷却設備、ブライドルロールおよび酸洗
槽を有する酸洗ラインにおいて、 前記冷却設備とブライドルロールとの間に水洗槽を設け
てなることを特徴とするステンレス鋼帯の連続焼鈍酸洗
装置。
(2) A pickling line having an annealing furnace, a cooling facility, a bridle roll, and a pickling tank, characterized in that a water washing tank is provided between the cooling facility and the bridle roll. Washing equipment.
(3)前記水洗槽内に洗浄用ブラシを設ける請求項2に
記載のステンレス鋼帯の連続焼鈍酸洗装置。
(3) The continuous annealing and pickling apparatus for stainless steel strips according to claim 2, wherein a cleaning brush is provided in the washing tank.
JP15704289A 1989-06-20 1989-06-20 Method and device for continuously annealing and pickling band stainless steel Pending JPH0324286A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP15704289A JPH0324286A (en) 1989-06-20 1989-06-20 Method and device for continuously annealing and pickling band stainless steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP15704289A JPH0324286A (en) 1989-06-20 1989-06-20 Method and device for continuously annealing and pickling band stainless steel

Publications (1)

Publication Number Publication Date
JPH0324286A true JPH0324286A (en) 1991-02-01

Family

ID=15640924

Family Applications (1)

Application Number Title Priority Date Filing Date
JP15704289A Pending JPH0324286A (en) 1989-06-20 1989-06-20 Method and device for continuously annealing and pickling band stainless steel

Country Status (1)

Country Link
JP (1) JPH0324286A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04311531A (en) * 1991-04-09 1992-11-04 Mitsubishi Heavy Ind Ltd Annealing and pickling equipment for stainless steel sheet
KR20020054413A (en) * 2000-12-28 2002-07-08 이구택 Compact Pickling Process With Deoxygenated Furnace and Cooling Roll

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04311531A (en) * 1991-04-09 1992-11-04 Mitsubishi Heavy Ind Ltd Annealing and pickling equipment for stainless steel sheet
KR20020054413A (en) * 2000-12-28 2002-07-08 이구택 Compact Pickling Process With Deoxygenated Furnace and Cooling Roll

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