JPH03226911A - Insulated wire - Google Patents
Insulated wireInfo
- Publication number
- JPH03226911A JPH03226911A JP1916490A JP1916490A JPH03226911A JP H03226911 A JPH03226911 A JP H03226911A JP 1916490 A JP1916490 A JP 1916490A JP 1916490 A JP1916490 A JP 1916490A JP H03226911 A JPH03226911 A JP H03226911A
- Authority
- JP
- Japan
- Prior art keywords
- insulating layer
- insulation layer
- outer periphery
- insulation
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 229920000098 polyolefin Polymers 0.000 claims abstract description 10
- 239000004020 conductor Substances 0.000 claims abstract description 9
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- 229920001643 poly(ether ketone) Polymers 0.000 claims abstract description 4
- 229920006380 polyphenylene oxide Polymers 0.000 claims abstract description 4
- -1 polybutylene terephthalate Polymers 0.000 claims description 9
- RYPKRALMXUUNKS-UHFFFAOYSA-N 2-Hexene Natural products CCCC=CC RYPKRALMXUUNKS-UHFFFAOYSA-N 0.000 claims description 3
- 239000004696 Poly ether ether ketone Substances 0.000 claims description 3
- 239000004695 Polyether sulfone Substances 0.000 claims description 3
- 239000004697 Polyetherimide Substances 0.000 claims description 3
- 239000012212 insulator Substances 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920001230 polyarylate Polymers 0.000 claims description 3
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920006393 polyether sulfone Polymers 0.000 claims description 3
- 229920002530 polyetherether ketone Polymers 0.000 claims description 3
- 229920001601 polyetherimide Polymers 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 238000009413 insulation Methods 0.000 abstract description 9
- 238000004132 cross linking Methods 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 3
- 238000005452 bending Methods 0.000 abstract description 2
- 239000011810 insulating material Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 description 5
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229920006351 engineering plastic Polymers 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920001112 grafted polyolefin Polymers 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 230000008733 trauma Effects 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920003189 Nylon 4,6 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920000305 Nylon 6,10 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- WOXXJEVNDJOOLV-UHFFFAOYSA-N ethenyl-tris(2-methoxyethoxy)silane Chemical compound COCCO[Si](OCCOC)(OCCOC)C=C WOXXJEVNDJOOLV-UHFFFAOYSA-N 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Insulated Conductors (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、電気的特性に優れ、耐外傷性、可撓性に富む
絶縁電線に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an insulated wire that has excellent electrical properties, high trauma resistance, and high flexibility.
従来、導体上に架橋ポリオレフィンからなる絶縁層を施
してなる絶縁電線が知られている。また、導体上に機械
的強度が高く、耐外傷性に優れるエンジニアリングプラ
スチック（芳香族ポリマー等）を施してなる絶縁電線も
知られている。さらに、これら２つの従来例を組合せて
なる二重絶縁電線は、当業界では、容易に頚椎できる技
術であり、電線の構成そのものが導体上に絶縁体を施し
、この外周に保護層として、ジャケットを施してなる電
線が汎用のものであり、当業界では多くの例を見ること
ができる。2. Description of the Related Art Insulated wires have been known in which an insulating layer made of crosslinked polyolefin is provided on a conductor. Furthermore, insulated wires are also known in which a conductor is coated with an engineering plastic (such as an aromatic polymer) that has high mechanical strength and excellent trauma resistance. Furthermore, the double insulated wire, which is a combination of these two conventional examples, is a technology that is easily recognized in the industry. Electric wires made with this method are commonly used, and many examples can be found in the industry.
従来の二重絶縁電線では、曲げ時の絶縁破壊特性が未だ
満足ずべきも、のではなかった。そこで、可撓性が良く
、ピンホール等の欠陥確率の低下を図り、かつ電気特性
に優れたものが要望されている。Conventional double-insulated wires still have unsatisfactory dielectric breakdown characteristics when bent. Therefore, there is a need for a material that has good flexibility, reduces the probability of defects such as pinholes, and has excellent electrical characteristics.
本発明は、このような要望を満足する絶縁電線を提供す
ることを目的とする。An object of the present invention is to provide an insulated wire that satisfies such demands.
」二連の目的を達成するため、本発明は、導体の外周に
直接又は他の絶縁物を介して架橋ポリオレフィンポリマ
ーから成る第１絶縁層を施し、この第１絶縁層の外周に
ポリアミドから成る第２絶縁層を施し、この第２絶縁層
の外周にポリフェニレンオキサイド、ポリエーテルケト
ン、ポリエーテルエーテルケトン、ポリカーボネート、
ポリブチレンテレフタレート、ポリエチレンテレフタレ
ート、ポリエーテルイミド、ポリアリレート１、ポリ４
−メチル−１−ペンテン、ポリサルホン、ポリエーテル
ザルホン、フッ素系ポリマーおよびポリアミドからなる
群から選ばれた１種以上のポリマーからなる第３絶縁層
を施したものである。To achieve the dual objectives, the present invention provides a first insulating layer made of a crosslinked polyolefin polymer on the outer periphery of the conductor, either directly or through another insulator, and a first insulating layer made of a polyamide on the outer periphery of the first insulating layer. A second insulating layer is applied, and the outer periphery of the second insulating layer is coated with polyphenylene oxide, polyetherketone, polyetheretherketone, polycarbonate,
Polybutylene terephthalate, polyethylene terephthalate, polyetherimide, polyarylate 1, poly4
A third insulating layer made of one or more polymers selected from the group consisting of -methyl-1-pentene, polysulfone, polyethersulfone, fluorine-based polymers, and polyamides is provided.
本発明では、特殊な三層絶縁構造の組合せにより、曲げ
時の絶縁破壊特性が著しく向上するとともに、可撓性に
富み、電気的特性にも優れていることが判明した。In the present invention, it has been found that the combination of a special three-layer insulation structure significantly improves the dielectric breakdown characteristics during bending, and also provides excellent flexibility and electrical properties.
以下に本発明の好適な実施例を図面に基づいて説明する
。Preferred embodiments of the present invention will be described below based on the drawings.
図面において、すす、ニッケル、銀などのメツキを施し
た銅導体単線１又はより線から成る導体１の外周に架橋
ポリオレフィンから成る第１絶縁層２を施しである。第
１絶縁層２は厚さ０．１〜１ ｍｍ程度に形成した。こ
こでの架橋ポリオレフィンとしては、ポリエチレン、ポ
リプロピレン、ポリ１−ブテン、ポリイソブチレン、ポ
リ４−メチル−１−ペレテンなどのオレフィンモノマー
の単独重合体、エチレン−エチルアクリレート共重合体
（ＥＥＡ）、エチレン−酢酸ビニル共重合体（ＥＶＡ）
、エチレン−プロピレン共重合体（ＥＰＲ）、エチレン
−プロピレン−ジエン共！ 合体（ＥＰＤＭ）、エチレ
ン−ブテン−１共重合体、エチレン−ブテン−１−ジエ
ン共重合体などの共重合体あるいはこれらの２種以上の
ブレンドポリマーなどのポリオレフィンを架橋したもの
が用いられる。ここでの架橋方法としては、ジクミルパ
ーオキサイド、ｔ−プチルクミルパーオキザイドなどの
有機過酸化物を上記ポリオレフィンに適量添加した組成
物を押出被覆し、加熱して架橋する方法、上記ポリオレ
フィンを押出被覆したのち、電子線を照射して架橋する
方法、上記ポリオレフィンにビニルトリメトキシシラン
、ビニ・ルトリエトキシシラン、ビニルトリス（β−メ
トキシエトシ）シラン等のシラン化合物と有機過酸化物
を添加して混練してシラングラフト化ポリオレフィンと
し、このシラングラフト化ポリオレフィンを押出被覆し
たのち、大気中あるいは水中で架橋させる方法などであ
る。電子線照射の場合、二層、三層を施したのち後で一
括して照射架橋を行ってもよい。In the drawing, a first insulating layer 2 made of crosslinked polyolefin is applied around the outer periphery of a conductor 1 made of a single or stranded copper conductor plated with soot, nickel, silver, or the like. The first insulating layer 2 was formed to have a thickness of about 0.1 to 1 mm. Examples of crosslinked polyolefins include homopolymers of olefin monomers such as polyethylene, polypropylene, poly-1-butene, polyisobutylene, and poly-4-methyl-1-peretene, ethylene-ethyl acrylate copolymers (EEA), and ethylene-ethyl acrylate copolymers (EEA). Vinyl acetate copolymer (EVA)
, ethylene-propylene copolymer (EPR), ethylene-propylene-diene! Crosslinked polyolefins such as EPDM, copolymers such as ethylene-butene-1 copolymer, ethylene-butene-1-diene copolymer, or blend polymers of two or more of these are used. The crosslinking method here includes a method in which a composition in which an appropriate amount of an organic peroxide such as dicumyl peroxide or t-butylcumyl peroxide is added to the above polyolefin is extrusion coated, and the above polyolefin is crosslinked by heating. After coating by extrusion, crosslinking is carried out by irradiating with an electron beam, and a silane compound such as vinyltrimethoxysilane, vinylrutriethoxysilane, vinyltris(β-methoxyethoxy)silane and an organic peroxide are added to the polyolefin. This method includes kneading to form a silane-grafted polyolefin, extrusion coating the silane-grafted polyolefin, and then crosslinking in air or water. In the case of electron beam irradiation, irradiation crosslinking may be performed all at once after applying two or three layers.
第１絶縁層２の外周にはポリアミドから成る第２絶縁層
３を施しである。この第２絶縁層３は厚さ０．００１〜
０．５ｎ＋ｍ程度に形成した。使用するポリアミドとし
ては、ナイロン６、ナイロン６６゜ナイロン６１０．ア
イロン６１２．ナイロン１１゜ナイロン１２．ナイロン
４６が好適である。A second insulating layer 3 made of polyamide is applied to the outer periphery of the first insulating layer 2. This second insulating layer 3 has a thickness of 0.001~
It was formed to have a thickness of about 0.5n+m. The polyamides used include nylon 6, nylon 66°, nylon 610. Iron 612. Nylon 11° Nylon 12. Nylon 46 is preferred.
第２絶縁層３の外周には、厚さ０．０５〜１ｍｍ程度の
第３絶縁層４を施した。この第３絶縁層４としては、次
のエンジニアリングプラスチックから成る群から選ばれ
た１種以上のポリマーの使用が好適である。A third insulating layer 4 having a thickness of about 0.05 to 1 mm was applied to the outer periphery of the second insulating layer 3. As the third insulating layer 4, it is preferable to use one or more polymers selected from the group consisting of the following engineering plastics.
（エンジニアリングプラスチック）
ポリフェニレンオキサイド、
ポリエーテルケトン、
ポリエーテルエーテルケトン、
ポリカーボネート、
ポリブチレンテレフタレート、
ポリエチレンテレフタレート、
ポリエーテルイミド、 ポリアリレート、ポリ４−
メチル−１−ペンテン、
ポリサルホン、 ポリエーテルサルホン、フッ素系
ポリマーおよびポリアミド。(Engineering plastics) Polyphenylene oxide, polyetherketone, polyetheretherketone, polycarbonate, polybutylene terephthalate, polyethylene terephthalate, polyetherimide, polyarylate, poly4-
Methyl-1-pentene, polysulfone, polyethersulfone, fluoropolymers and polyamides.
なお、導体１の外周に他の絶縁物を介して第１絶縁層２
を施しても良い。Note that a first insulating layer 2 is formed on the outer periphery of the conductor 1 via another insulator.
may be applied.
次表に本発明の実施例１〜４と比較例１〜６とを示す。The following table shows Examples 1 to 4 of the present invention and Comparative Examples 1 to 6.
以上説明したように、本発明は特殊な三層構造の組合せ
により、絶縁層が三層にもかかわらず全体として薄肉化
でき可撓性に優れるとともに、電気特性にも優れ、ピン
ホール等の欠陥確率を低下できる。As explained above, due to the combination of the special three-layer structure of the present invention, although the insulating layer is three layers, the overall thickness can be made thin and has excellent flexibility, as well as excellent electrical properties and defects such as pinholes. The probability can be lowered.
図面は本発明の好適な実施例を示す断面図である。 １・・・導体、 ２・・・第１絶縁層、 ３・・・第２絶縁層、 ４・・・第３絶縁層。 The drawings are cross-sectional views showing preferred embodiments of the present invention. 1... conductor, 2...first insulating layer, 3... second insulating layer, 4...Third insulating layer.
Claims (1)
橋ポリオレフィンポリマーから成る第１絶縁層（２）を
施し、 この第１絶縁層（２）の外周にポリアミドから成る第２
絶縁層（３）を施し、 この第２絶縁層（３）の外周にポリフェニレンオキサイ
ド、ポリエーテルケトン、ポリエーテルエーテルケトン
、ポリカーボネート、ポリブチレンテレフタレート、ポ
リエチレンテレフタレート、ポリエーテルイミド、ポリ
アリレート、ポリ４−メチル−１−ペンテン、ポリサル
ホン、ポリエーテルサルホン、フッ素系ポリマーおよび
ポリアミドからなる群から選ばれた１種以上のポリマー
からなる第３絶縁層（４）を施したことを特徴とする絶
縁電線。[Claims] 1. A first insulating layer (2) made of a cross-linked polyolefin polymer is applied directly or via another insulator to the outer periphery of the conductor (1), and the first insulating layer (2) is coated on the outer periphery of the first insulating layer (2). A second layer made of polyamide
An insulating layer (3) is applied, and on the outer periphery of this second insulating layer (3) polyphenylene oxide, polyether ketone, polyether ether ketone, polycarbonate, polybutylene terephthalate, polyethylene terephthalate, polyetherimide, polyarylate, poly4- An insulated wire comprising a third insulating layer (4) made of one or more polymers selected from the group consisting of methyl-1-pentene, polysulfone, polyethersulfone, fluorine-based polymers, and polyamides.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1916490A JPH03226911A (en) | 1990-01-31 | 1990-01-31 | Insulated wire |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1916490A JPH03226911A (en) | 1990-01-31 | 1990-01-31 | Insulated wire |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03226911A true JPH03226911A (en) | 1991-10-07 |
Family
ID=11991742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1916490A Pending JPH03226911A (en) | 1990-01-31 | 1990-01-31 | Insulated wire |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03226911A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03110721U (en) * | 1990-05-12 | 1991-11-13 | ||
| JPH0419913A (en) * | 1990-05-14 | 1992-01-23 | Fujikura Ltd | Electric cable |
| JPH04101315U (en) * | 1991-02-20 | 1992-09-01 | 東京特殊電線株式会社 | Multilayer insulated wire for high frequency transformer winding |
| JPH04116310U (en) * | 1991-03-29 | 1992-10-16 | 東京特殊電線株式会社 | Multilayer insulated wire for high frequency transformer winding |
| US6436557B1 (en) * | 1998-05-29 | 2002-08-20 | Sumitomo Electric Industries, Ltd. | Flame retardant resin composition, and insulating electric wire, tube, heat-shrinkable tube, flat cable, and DC high-tension electric wire all made of the composition |
| MY120074A (en) * | 1998-05-29 | 2005-08-30 | Sumitomo Electric Industries | Flame retardant resin composition, and insulating electric wire, tube, heat-shrinkable tube, flat cable and dc high-tension electric wire all made of the composition |
-
1990
- 1990-01-31 JP JP1916490A patent/JPH03226911A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03110721U (en) * | 1990-05-12 | 1991-11-13 | ||
| JPH0419913A (en) * | 1990-05-14 | 1992-01-23 | Fujikura Ltd | Electric cable |
| JPH04101315U (en) * | 1991-02-20 | 1992-09-01 | 東京特殊電線株式会社 | Multilayer insulated wire for high frequency transformer winding |
| JPH04116310U (en) * | 1991-03-29 | 1992-10-16 | 東京特殊電線株式会社 | Multilayer insulated wire for high frequency transformer winding |
| US6436557B1 (en) * | 1998-05-29 | 2002-08-20 | Sumitomo Electric Industries, Ltd. | Flame retardant resin composition, and insulating electric wire, tube, heat-shrinkable tube, flat cable, and DC high-tension electric wire all made of the composition |
| MY120074A (en) * | 1998-05-29 | 2005-08-30 | Sumitomo Electric Industries | Flame retardant resin composition, and insulating electric wire, tube, heat-shrinkable tube, flat cable and dc high-tension electric wire all made of the composition |
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