JPH03208874A - Decorating method for inorganic extrusion molded body - Google Patents
Decorating method for inorganic extrusion molded bodyInfo
- Publication number
- JPH03208874A JPH03208874A JP378790A JP378790A JPH03208874A JP H03208874 A JPH03208874 A JP H03208874A JP 378790 A JP378790 A JP 378790A JP 378790 A JP378790 A JP 378790A JP H03208874 A JPH03208874 A JP H03208874A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- coating
- weight
- cement
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000001125 extrusion Methods 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 title claims description 10
- 238000000576 coating method Methods 0.000 claims abstract description 28
- 239000011248 coating agent Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000004568 cement Substances 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229920006015 heat resistant resin Polymers 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 239000004576 sand Substances 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims abstract description 6
- 238000005520 cutting process Methods 0.000 claims abstract description 5
- 239000000049 pigment Substances 0.000 claims abstract description 5
- 238000000465 moulding Methods 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 17
- 239000002537 cosmetic Substances 0.000 claims description 4
- 239000000839 emulsion Substances 0.000 abstract description 11
- 238000004040 coloring Methods 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 4
- 229920001577 copolymer Polymers 0.000 abstract description 2
- 230000032683 aging Effects 0.000 abstract 1
- 238000006757 chemical reactions by type Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 229920003002 synthetic resin Polymers 0.000 description 6
- 239000000057 synthetic resin Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000007591 painting process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
Landscapes
- Aftertreatments Of Artificial And Natural Stones (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 この発明は無機質押出成形体の化粧方法に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a method for decorating an inorganic extruded body.
従来、瓦として繊維補強セメントよりなるセメント瓦が
非常に広く使用されている。Conventionally, cement tiles made of fiber-reinforced cement have been very widely used as roof tiles.
これらセメント瓦は、基材が吸水性を有すること、及び
地色が灰〜灰黒色で装飾性に乏しいため、防水性付与を
兼ね表面に着色化粧が施されるのが通常である。Since the base material of these cement tiles has water absorption properties and the base color is gray to grayish black, they are poor in decorative properties, so the surface of these cement tiles is usually painted with a colored decoration in order to provide waterproof properties.
これら、セメント瓦の化粧方法としては、セメント配合
物を押出成形後、これを製品寸法に切断し、プレス機へ
供給し、プレス盤で加圧後、表面にセメントスラリー塗
装、次いでエマルジッン系、又は溶剤系樹脂塗料で塗装
し養生硬化させることや、セメント配合物を押出成形後
、プレス、切断したものを一次養生して硬化させた後に
表面にエマルジョン系樹脂塗料、溶剤系樹脂塗料により
下塗、上塗を施し、養生硬化するという方法が行なわれ
ている。These cement tiles are decorated by extruding the cement mixture, cutting it into product dimensions, supplying it to a press, pressurizing it with the press, painting the surface with cement slurry, and then applying emulsion or Painting with solvent-based resin paint and curing and curing, or extrusion molding of cement mixture, pressing, cutting, primary curing and curing, and then undercoating and topcoating with emulsion-based resin paint or solvent-based resin paint. The method used is to cure and harden the material.
しかしながら、前者の化粧方法では、表面のトップコー
ト層が劣化するのは避けられず、１〜３年で劣化剥離し
始めると、下部層のスラリー層が露出してしまうため、
化粧効果が消失してしまう欠点があった。However, with the former cosmetic method, it is unavoidable that the top coat layer on the surface deteriorates and begins to peel off after 1 to 3 years, exposing the slurry layer below.
There was a drawback that the makeup effect disappeared.
又後者の化粧方法では、−次養生後、乾燥した製品表面
に塗装するので基材に対する塗料の密着性が前者の化粧
方法に較べて悪く、瓦として屋根上に葺いた場合、紫外
線、水、熱による劣化があり、３〜５年で塗膜が剥離し
表面が見苦しくなるといった問題があった。In addition, in the latter cosmetic method, the adhesion of the paint to the base material is poorer than that in the former method because it is painted on the dry surface of the product after curing. There was a problem of deterioration due to heat, and the coating film peeled off after 3 to 5 years, making the surface unsightly.
この発明は上記問題点に鑑み、無機質押出成形体の表面
化粧層が、耐候性、耐熱性、耐水性、耐日光堅牢度など
、耐用寿命の改良を目的としてなされたものである。In view of the above-mentioned problems, the present invention was made with the aim of improving the service life of the decorative surface layer of an inorganic extrusion molded product, such as weather resistance, heat resistance, water resistance, and fastness to sunlight.
即ち、この発明の無機質押出成形体の化粧方法はセメン
ト配合物を押出成形、切断、プレス成形を行なった後、
該成形体の表面に、セメント３０〜４０重量部、珪砂３
０〜４０重量部、顔料５〜１０重量部、耐熱性樹脂２０
〜３０重量部、水１０〜２０重量部より成る塗料で一次
塗装を行い強制乾燥後、該一次塗装表面に１００重量部
中着色インク１〜５重量部、耐熱性樹脂塗料８０〜９５
重量部、残部を水とした塗料で二次塗装し、オートクレ
ーブ養生を行うことを特徴とするものである。That is, the method for decorating an inorganic extruded body of the present invention involves extruding, cutting, and press-molding a cement mixture, and then
30 to 40 parts by weight of cement and 3 parts by weight of silica sand are added to the surface of the molded body.
0 to 40 parts by weight, 5 to 10 parts by weight of pigment, 20 parts by weight of heat-resistant resin
A primary coating is applied with a paint consisting of ~30 parts by weight, 10 to 20 parts by weight of water, and after forced drying, 100 parts by weight, 1 to 5 parts by weight of colored ink, and 80 to 95 parts by weight of a heat-resistant resin paint are applied to the surface of the primary coating.
It is characterized by applying a secondary coating with a paint containing part by weight and the balance being water, and curing in an autoclave.
この発明に用いる耐熱性合成樹脂エマルジョン塗料とは
、合成樹脂が架橋型、又は自己架橋型で構成された反応
型エマルジョンをいう。The heat-resistant synthetic resin emulsion paint used in this invention refers to a reactive emulsion composed of a crosslinked or self-crosslinked synthetic resin.
従来用いられている合成樹脂エマルジョンの大多数は非
架橋型のもので、非架橋型のものは水分が蒸発すれば皮
膜を形成するが、本発明で使用する架橋型、自己架橋型
のものは水分が蒸発すれば皮膜を形成し、更に熱を加え
る事に依って架橋反応に依り分子の網状化が行なわれ、
耐熱性、耐水性、高強度の皮膜を形成するものである。The majority of conventionally used synthetic resin emulsions are non-crosslinked, and non-crosslinked types form a film when water evaporates, but the crosslinked and self-crosslinked types used in the present invention When the water evaporates, a film is formed, and when heat is applied, a crosslinking reaction occurs, forming a network of molecules.
It forms a heat-resistant, water-resistant, and high-strength film.
従って、塗装後塗膜の硬化（指触乾燥）が非常に速く下
塗後、上塗工程に至る時間の短縮が図れる。Therefore, the coating film cures (dries to the touch) very quickly after painting, and the time from the undercoating process to the topcoating process can be shortened.
また上記塗料にはセメント及び珪砂が含まれるため、前
記樹脂の硬化に続いてセメント−珪砂の水和反応による
硬化が生じるので、−次塗装として極めて強靭な塗装膜
とすることが出来るのであ更にこの一次塗装表面に反応
性合成樹脂エマルジョン塗料と着色用インクを混合した
塗料で塗装する理由は、インキは着色するが透明感は損
なわない利点を利用したもので、−次塗装に用いた顔料
に依る着色を更に鮮明にするためである。Furthermore, since the above-mentioned paint contains cement and silica sand, subsequent hardening of the resin is followed by hardening due to the hydration reaction of cement and silica sand, making it possible to form an extremely tough coating film for the subsequent coating. The reason why the primary coating surface is painted with a mixture of reactive synthetic resin emulsion paint and coloring ink is to take advantage of the advantage that the ink colors but does not impair transparency, and the pigment used in the secondary coating This is to make the coloring even clearer.
前記耐熱合成樹脂エマルシラン塗料としては、反応型ア
クリル酸、メチルメタアクリレートとスチレンの共重合
体等が用いられる。皮膜は無色透明で耐日光堅牢度のあ
るものがよい。As the heat-resistant synthetic resin emulsion silane paint, reactive acrylic acid, a copolymer of methyl methacrylate and styrene, etc. are used. The film should be colorless and transparent and fast to sunlight.
次に、この発明の実施例について説明する。 Next, embodiments of the invention will be described.
セメント４８、珪砂４２、粘土１０の割合で混合したセ
メント組成物１００重量部に対して、バルブ繊維５重量
部、メチルセルロース１．０重量部を添加し、ドライミ
キサーで均一混合したものに、水２８〜３０重量部添加
しながら二−ダープレンダーで混合し、これを更に混線
機、押出成形機で押出成形し、厚さ１５ｍ５．縦横１５
０ Ｘ２００−閣の試験片を得、プレス成形後、脱型し
て３０〜８０℃相対湿度９５％の条件で４〜１４時間−
次養生し、冷却後−次塗装を行なった。塗装液の配合は
下記の通りである。To 100 parts by weight of a cement composition mixed at a ratio of 48 parts of cement, 42 parts of silica sand, and 10 parts of clay, 5 parts by weight of valve fibers and 1.0 parts by weight of methyl cellulose were added, and the mixture was uniformly mixed with a dry mixer, followed by 28 parts by weight of water. The mixture was mixed in a two-dar blender while adding ~30 parts by weight, and then extruded using a mixing machine and an extrusion molding machine to a thickness of 15 m5. Length and width 15
A test piece of 0×200-kaku was obtained, and after press molding, it was removed from the mold and kept at 30-80°C and 95% relative humidity for 4-14 hours.
After curing and cooling, the next coating was applied. The composition of the coating liquid is as follows.
記 （重量部）
白セメント又は黍ルトランＦ
３０ 〜４０耐熱性アクリル、スチレン
樹脂ヱマルｈン ２０〜３０珪砂
３０〜４０顔料
５〜１０水
１０〜２０塗布量
８００〜１２００Ｊｌ／ｍｌ”−次塗装
したものを１５０℃、３分間乾燥し、樹脂成分を硬化さ
せ次に二次塗装を行った。ｆ！！装液の配合は下記の通
りである。(Parts by weight) White cement or millet Lutran F
30-40 Heat-resistant acrylic, styrene resin 20-30 Silica sand
30-40 pigment
5-10 water
10-20 coating amount
800 to 1200 Jl/ml" - The second coat was dried at 150°C for 3 minutes to harden the resin component, and then the second coat was applied. f!! The formulation of the coating liquid is as follows.
記 （重量部）
耐熱性１クリル、スチレン 樹脂Ｉ７藤ジ１ン０１．Ｖ
、４０χ） ８０〜９５水
５〜２０着色インク
１〜５塗布量
５０〜６０ｇ７ｍ ”二次塗装後、１５０℃、３
分間乾燥し指触乾燥後、８．５ ａｔ■、１０時間オー
トクレーブ養生を行って化粧試験片を得た。Notes (parts by weight) Heat resistant 1 Krylic, Styrene Resin I7 Fujiji 1-01. V
, 40χ) 80-95 water
5-20 colored ink
1-5 coating amount
50-60g7m ”After secondary coating, 150℃, 3
After drying for 1 minute and drying to the touch, the sample was cured in an autoclave at 8.5 at.cm for 10 hours to obtain a cosmetic test piece.
この試験片につき初期密着性、沸騰水浸漬、耐水性、促
進耐候性、及び凍結融解性試験をおこなったところ、表
１の結果となった。When this test piece was subjected to initial adhesion, boiling water immersion, water resistance, accelerated weathering resistance, and freeze-thaw resistance tests, the results shown in Table 1 were obtained.
第１表
試験方法
初期密着試験・・・Ｊ Ｉ Ｓ ５４００に依るセロテ
ープ密着性沸騰水試験 ・・・Ｊ Ｉ Ｓ ５４００温
度９５℃以上、浸漬時間ＩＨｒ以上
耐水性試験 ・・・温度２０℃の流水中に１ケ月浸漬促
進耐候性 ・・・サンシャインウェザ−メータ試験機に
よる。Table 1 Test method Initial adhesion test...Cellotape adhesion according to JIS 5400 Boiling water test...JIS 5400 temperature 95℃ or more, immersion time IHr or more Water resistance test...Flowing water at a temperature of 20℃ Accelerated weather resistance after being immersed in water for 1 month...Based on a Sunshine Weathermeter tester.
凍結融解試験・・・−２０℃、２時間−２０℃２時間を
１〜として２００〜行ったものである。Freeze-thaw test: -20°C, 2 hours -20°C, 2 hours, 200~.
また、表１中比較例は比較例１〜３は耐熱性樹脂の添加
量を本発明以外の添加量としたもので、比較例１は耐熱
性樹脂１．０重量部、同２は１５重量部、同３は５０重
量部としたものである。In addition, Comparative Examples 1 to 3 in Table 1 have a heat-resistant resin added in an amount other than the amount of the present invention, and Comparative Example 1 has a heat-resistant resin of 1.0 parts by weight, and Comparative Example 2 has a heat-resistant resin of 1.0 parts by weight. Parts and 3 are 50 parts by weight.
また比較例４〜５は従来の塗装手段によったものを示し
、比較例４は一次養生した成形体表面に水系エマルシヨ
ンにより一次、二次塗装を行ったものであり、比較例５
は未養生成形板表面に着色スラリーを塗布しさらにその
表面に水系エマルジョンを塗布し、養生硬化させたもの
である。Moreover, Comparative Examples 4 and 5 show those using conventional coating means, and Comparative Example 4 is one in which primary and secondary coatings were applied to the surface of a primarily cured molded product using a water-based emulsion, and Comparative Example 5
A colored slurry was applied to the surface of an uncured molded board, and then a water-based emulsion was further applied to the surface and cured.
表１より明らかなように、本発明によるものは、各試験
方法共に全部合格の結果を得た。As is clear from Table 1, the products according to the present invention passed all test methods.
この発明は、以上説明したように、無機質押出成形体の
表面にセメントモルタル、顔料、耐熱性合成樹脂エマル
シヨンで一次ｆＩ！装を行い乾燥後、更に着色インキを
混入した耐熱性合成樹脂を含む塗料で塗布したものであ
るから、塗装工程中においてはセメント成分の硬化が進
んでいなくても指触乾燥が速く、よりて塗装工程の移送
速度が速くできて生産効率の向上が図れ、また、養生時
に塗料に含まれたセメント−シリカ成分による硬化が生
しるので塗膜全体の強度が非常に強くなり、剥離等が生
じにくく、さらに耐日光堅牢度の良い透明皮膜で被覆さ
れているから、耐候性に優れ、又着色鮮明度も優れた化
粧板を製造することができるなど種々の効果を有する。As explained above, this invention provides a first fI! After coating and drying, it is coated with a paint containing a heat-resistant synthetic resin mixed with colored ink, so it dries quickly to the touch even if the cement component has not yet hardened during the painting process. This increases the transfer speed in the painting process, improving production efficiency, and since the cement-silica component contained in the paint hardens during curing, the overall strength of the paint film becomes extremely strong, reducing peeling and other problems. Since it is coated with a transparent film that is less likely to cause oxidation and has good sunlight fastness, it has various effects such as being able to produce a decorative board with excellent weather resistance and excellent color clarity.
Claims (1)
行なった後、該成形体の表面に、セメント３０〜４０重
量部、珪砂３０〜４０重量部、顔料５〜１０重量部、耐
熱性樹脂２０〜３０重量部、水１０〜２０重量部より成
る塗料で一次塗装を行い強制乾燥後、該一次塗装表面に
１００重量部中着色インク１〜５重量部、耐熱性樹脂塗
料８０〜９５重量部、残部を水とした塗料で二次塗装し
、オートクレーブ養生を行うことを特徴とする無機質押
出成形体の化粧方法。(1) After extrusion molding, cutting, and press molding the cement mixture, 30 to 40 parts by weight of cement, 30 to 40 parts by weight of silica sand, 5 to 10 parts by weight of pigment, and a heat-resistant resin are added to the surface of the molded product. After primary coating with a paint consisting of 20 to 30 parts by weight and 10 to 20 parts by weight of water, and after forced drying, 100 parts by weight, 1 to 5 parts by weight of colored ink, and 80 to 95 parts by weight of heat-resistant resin paint are applied to the surface of the primary coating. A cosmetic method for an inorganic extrusion molded article, which is characterized by applying a secondary coating with a paint with the remainder being water, and curing in an autoclave.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP378790A JPH03208874A (en) | 1990-01-10 | 1990-01-10 | Decorating method for inorganic extrusion molded body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP378790A JPH03208874A (en) | 1990-01-10 | 1990-01-10 | Decorating method for inorganic extrusion molded body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03208874A true JPH03208874A (en) | 1991-09-12 |
Family
ID=11566895
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP378790A Pending JPH03208874A (en) | 1990-01-10 | 1990-01-10 | Decorating method for inorganic extrusion molded body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03208874A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0941977A1 (en) * | 1998-03-09 | 1999-09-15 | Basf Aktiengesellschaft | Process for coating mineral products |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5398325A (en) * | 1977-02-07 | 1978-08-28 | Kubota Ltd | Manufacture of decorated roofing brick |
| JPS5825077A (en) * | 1981-08-07 | 1983-02-15 | Canon Inc | Electronic equipment |
| JPS5914429A (en) * | 1982-07-10 | 1984-01-25 | Sumitomo Electric Ind Ltd | Composite wire for wire-cut electric discharge machining electrode wire and manufacturing method thereof |
-
1990
- 1990-01-10 JP JP378790A patent/JPH03208874A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5398325A (en) * | 1977-02-07 | 1978-08-28 | Kubota Ltd | Manufacture of decorated roofing brick |
| JPS5825077A (en) * | 1981-08-07 | 1983-02-15 | Canon Inc | Electronic equipment |
| JPS5914429A (en) * | 1982-07-10 | 1984-01-25 | Sumitomo Electric Ind Ltd | Composite wire for wire-cut electric discharge machining electrode wire and manufacturing method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0941977A1 (en) * | 1998-03-09 | 1999-09-15 | Basf Aktiengesellschaft | Process for coating mineral products |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107083150B (en) | A kind of UV coating for automobile interiors and its preparation method and application | |
| CN105820720A (en) | UV curing coating for PVC material coating process and preparation method for UV curing material | |
| JP2533950B2 (en) | Aqueous coating composition and method of using the same | |
| JPH03208874A (en) | Decorating method for inorganic extrusion molded body | |
| JPH03208872A (en) | Decorating method for inorganic extrusion molded body | |
| US3949044A (en) | Process for forming decorated sheets of acrylic resin | |
| US3491174A (en) | Method for making integrally colored asbestos-cement products | |
| JPH0776123B2 (en) | Colored aggregate with excellent design and weather resistance | |
| JPS6259677B2 (en) | ||
| JPH04130076A (en) | Decorating method for inorganic building material | |
| US4053664A (en) | Low temperature glazing method | |
| JPS58190884A (en) | Treating agent for inorganic base material | |
| JPH02196077A (en) | Method for facing inorganic building material | |
| CN114806393A (en) | One-coating color-adding high-gloss UV (ultraviolet) curing coating for automotive interior and preparation method thereof | |
| JPH02120286A (en) | Production of thick type slate having coated surface | |
| JPH04128005A (en) | Decorative method of mineral building material | |
| KR0156784B1 (en) | Acryl silicone paint composition | |
| JPS58147447A (en) | Manufacture of colored cement roofing tile | |
| JPS63256582A (en) | Method of dressing ceramic products | |
| JPH0531448A (en) | Coating method of cement product | |
| JPH0371395B2 (en) | ||
| JPS63256583A (en) | Manufacture of colored roof tile | |
| JPH04319405A (en) | Decorating method for cement product | |
| SU1419899A1 (en) | Method of finishing concrete articles | |
| CN118085668A (en) | Preparation method of water-based frosted coating for battery label |