JPH0320346A - Vinyl chloride resin composition - Google Patents
Vinyl chloride resin compositionInfo
- Publication number
- JPH0320346A JPH0320346A JP15513189A JP15513189A JPH0320346A JP H0320346 A JPH0320346 A JP H0320346A JP 15513189 A JP15513189 A JP 15513189A JP 15513189 A JP15513189 A JP 15513189A JP H0320346 A JPH0320346 A JP H0320346A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- chloride resin
- resin composition
- pts
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 239000011342 resin composition Substances 0.000 title claims abstract description 11
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 5
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 5
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims abstract description 4
- 229920000359 diblock copolymer Polymers 0.000 claims description 6
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 229920001400 block copolymer Polymers 0.000 abstract description 6
- 239000004014 plasticizer Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000003381 stabilizer Substances 0.000 abstract description 4
- 239000000049 pigment Substances 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 3
- 239000003963 antioxidant agent Substances 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 239000000314 lubricant Substances 0.000 abstract description 2
- 238000000465 moulding Methods 0.000 abstract description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- -1 ethylene, propylene Chemical group 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- ONIKNECPXCLUHT-UHFFFAOYSA-N 2-chlorobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1Cl ONIKNECPXCLUHT-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000805 composite resin Substances 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000002649 leather substitute Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 240000005979 Hordeum vulgare Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- QEZIKGQWAWNWIR-UHFFFAOYSA-N antimony(3+) antimony(5+) oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[Sb+3].[Sb+5] QEZIKGQWAWNWIR-UHFFFAOYSA-N 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011440 grout Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は撓水性の軟質の或形体を戊形しうる塩化ビニル
樹脂組底物に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a vinyl chloride resin bottom that can be shaped into a water-repellent, soft body.
（従米の技術）
軟質の塩化ビニル樹脂フイルム、シート等は包装用，農
業用，インテリア用、合成皮革用等に広く使用されてい
るが、軟質のフイルム、シ剤のマイグレーシーンと表面
の撓水性の低下によシ表面がべたつくようになるという
欠点があクた。(Jumei's technology) Soft vinyl chloride resin films and sheets are widely used for packaging, agriculture, interior design, synthetic leather, etc. The problem was that the surface became sticky due to the decrease in water content.
（発明が解決しようとする課題）
本発明は上記欠点Ｋ鑑み、長期間撹水性がすぐれて釦シ
、表面がべたつくようにたりにくい軟質の底形体を底形
しうる塩化ビニル樹脂組成物を提供することを目的とす
る。(Problems to be Solved by the Invention) In view of the above-mentioned drawback K, the present invention provides a vinyl chloride resin composition that has excellent water agitation properties for a long period of time and can be used to form a soft bottom-shaped body that does not easily become sticky or sticky on the surface. The purpose is to
（ａ題を解決するための手段）
本発明において使用される軟質塩化ビニル樹脂組成物と
は押゛出戒形、射出戊形，キャスティング欧形等の戊形
方法で戊形した際に軟質の収５
形体を得ることのでき一隻ものであって、塩化ビニル系
樹脂と可塑剤からなる。(Means for Solving Problem a) The soft vinyl chloride resin composition used in the present invention has a soft vinyl chloride resin composition that is flexible when shaped by a forming method such as extrusion forming, injection forming, or casting. It is a one-piece product that can obtain a shape of 5. It is made of vinyl chloride resin and a plasticizer.
上記塩化ビニル系樹脂とは、塩化ビニルの単独重合体及
び塩化ピニルモノマーと共重合可能なモノマーとの共重
合体であって、該共重合可能なモノマーとしては、たと
えば酢酸ビニル、エチレン、プロピレン、（メタ）アク
リル酸エステル、マレイン酸エステル、ビニルエーテル
等があげられ、Ｐ．■合体中共重合可能なモノマーは２
０重量％−以下であるのが好ましい。又、塩化ビニル系
樹脂の重合度は８００〜３０００のものが好筐しい。The above-mentioned vinyl chloride resin is a homopolymer of vinyl chloride and a copolymer of a monomer copolymerizable with a pinyl chloride monomer, and examples of the copolymerizable monomer include vinyl acetate, ethylene, propylene, Examples include meth)acrylic esters, maleic esters, vinyl ethers, and P. ■ Monomers that can be copolymerized during coalescence are 2
It is preferably less than 0% by weight. The degree of polymerization of the vinyl chloride resin is preferably 800 to 3,000.
上記可塑剤としては、一般に塩化ビニル系樹脂用の可塑
剤として使用されている任意のものが使用でき、たとえ
ばジオクチル７タレイト、ジブチルフタレイト、トリク
レジルホスフエート、トリエチルホス７エート、アリル
エボキシステアレイト、エボキシ化大豆油等があげられ
、可塑剤は樹脂１００重量部に対し、一般に１０〜１５
０重量部添加される。As the above-mentioned plasticizer, any one generally used as a plasticizer for vinyl chloride resins can be used, such as dioctyl 7-thaleate, dibutyl phthalate, tricresyl phosphate, triethyl phos-7ate, allyl epoxystearate, etc. Examples include leitate, eboxidized soybean oil, etc., and the plasticizer is generally 10 to 15 parts by weight per 100 parts by weight of the resin.
0 parts by weight is added.
父上記樹脂組我物Ｖｃは、安定性，ａｍ性等を付与する
ためにジプチル錫ジラクレートなどの有ＭｊｋｔｊＡ系
、金属石けん系などの安定剤＝７ェノール系、亜リン酸
エステル系などの抗酸化剤：ポリエチレン系ワックス、
酸アミド系化合物、エステル系化合物などの滑剤；二酸
化アンチモン、ハロゲン化リン化合物などの錐燃剤；酸
化チタン、ベンガラｔｔどの顔料：染料：炭酸力ルシク
ム、タルク、カオリン、ガラス繊維、炭酸織維、アラミ
ド繊維，カーボンプラック、金属粉末などの充填剤等を
添加してもよい。The above-mentioned resin composition Vc contains stabilizers such as MjktjA-based such as diptyltin dilacrate, metal soap-based stabilizers, etc., and antioxidants such as 7-phenol-based and phosphite-based to provide stability, amperage, etc. Agent: polyethylene wax,
Lubricants such as acid amide compounds and ester compounds; Pigments such as antimony dioxide and halogenated phosphorus compounds; Pigments such as titanium oxide and red iron tt; Dyes: carbonic acid lucicum, talc, kaolin, glass fiber, carbonated fiber, aramid Fillers such as fibers, carbon plaque, metal powder, etc. may be added.
本発明で使用されるＡ−Ｂ型ブロック共重合体ｔ−ｊＡ
がポリメチルメタクリレート又はボリスチレンで６３）
，ＢＦｉボリ〔パー７ルオロアルキル（メタ）アクリレ
ート〕である。AB type block copolymer t-jA used in the present invention
is polymethyl methacrylate or polystyrene63)
, BFi poly[per7-fluoroalkyl (meth)acrylate].
上記バーフルオロアルキル（メク）アクリレートのパー
フルオロアルキル基は炭素が少たくなるとフッ素原子の
数が少なくなｂｍ水性が低下し、逆に多くなると塩化ビ
ニル系樹脂の特性が低下するので、４〜２０が好１しく
、このような化合物としては、たとえば、
ＣＦ３（ＣＲ）ｙｃＨ２ ＣＨ＠ＯＣＯＣＨ ＝ ＣＨ
！，ＣＦｓ （ ＣＦ＊ ）ａ ＣＨｔ ＯＣＯＣ （
ＣＨ，）＝ ＣＨ！ ＩＣＦｓ（ＣＦ＊）ａ（ＣＨ＊
）＊ＯＣＯＣ（ＣＨｓ）＝ＣＨｚ，？Ｆｓ （ＣＦ！）
ｙ ３０！ Ｎ（ＣｓＨｙ） （ＣＨ＊）ｚ ＯＣＯ
ＣＨ ＝ ＣＨ■ＣＦｓ （ ＣＦｚ） ｔ （ ＣＨ
＊ ） ａ ＯＣＯＣＨ ＝ ＣＨｔ ，ＣＦｓ（ＣＦ
＊）ｙＳ（ｈＮ（ＣＨｓ）（ＣＨＪ＊ＯＣＯＣ（ＣＨＩ
）＝ＣＩ％ ，ＣＦ３（ＣＦ！）ｙＯＣＯＣＲ＝ＣＨ■
等があげられる。When the perfluoroalkyl group of the above-mentioned barfluoroalkyl (mek) acrylate has less carbon, the number of fluorine atoms decreases and the bm aqueous property decreases, and conversely, when the number of carbon atoms increases, the properties of the vinyl chloride resin decrease, so is preferable, and examples of such compounds include, for example, CF3(CR)ycH2 CH@OCOCH = CH
! , CFs (CF*)a CHt OCOC (
CH,) = CH! ICFs(CF*)a(CH*
)*OCOC(CHs)=CHz,? Fs (CF!)
y 30! N(CsHy) (CH*)z OCO
CH = CH■CFs (CFz) t (CH
*) a OCOCH = CHt, CFs(CF
*)yS(hN(CHs)(CHJ*OCOC(CHI
)=CI%, CF3(CF!)yOCOCR=CH■
etc. can be mentioned.
又、Ｂは上記パーフルオロアルキル（メク）アクリレー
トだけの重合体であってもよいが、メチルアクリレート
、メチルメタアクリレート、エチルアクリレート、プチ
ルアクリレート等の（メタ）アクリレートが一部共重合
されてもよいＯ
Ａ−Ｂ型ブロック共重合体の分子ｊｌは５， Ｏ ｛ｌ
Ｏ〜ｉ ｏ ｏ， ｏ ｏ ｏが好ましく、そのうちＢ
グロツク戊分け２０〜７５重量％が好筐しい。Further, B may be a polymer of only the above-mentioned perfluoroalkyl (mech)acrylate, but a part of (meth)acrylate such as methyl acrylate, methyl methacrylate, ethyl acrylate, butyl acrylate may be copolymerized. The molecule jl of the O A-B type block copolymer is 5, O {l
O~i o o, o o o are preferred, among which B
It is preferable to use 20 to 75% by weight of the grout.
Ａ−Ｂ型ブロック共重合体の添加量は少なくなると撓水
性を付与できず、多くなると塩化ビニル系樹脂の有する
性能が低下するようになるので塩化ビニル系樹脂１００
Ｗ量部に対し，α３〜５重量部添加される。If the amount of A-B type block copolymer added is small, water repellency cannot be imparted, and if it is too large, the performance of the vinyl chloride resin will deteriorate.
It is added in an amount of 3 to 5 parts by weight per part of W.
本発明の塩化ビニルＩＭ脂組成物は上述の通シであシ、
この組成物から戊形体を得るには従米公知の任意の方法
が採用されてよく、たとえば押出戊形法、射出戊形法、
キャスティング法等があげられる。The vinyl chloride IM fat composition of the present invention has the above-mentioned composition,
Any known method may be used to obtain a rod from this composition, such as an extrusion molding method, an injection molding method,
Examples include casting methods.
（実施例）
次に本発明の実施例を説明する。尚、以下「部」とある
のは「重量部」を意見する。(Example) Next, an example of the present invention will be described. Note that "parts" hereinafter refer to "parts by weight."
実施例ｌ
塩化ビニル樹脂（重合度１１００） １００部ジプト
キシエチル７タレート ５０部エボキシ大豆油
２部液状亜鉛系安定剤
２部ポリスチレンーボリ（２−パーフ
ルオロオクチルエチルメタクリレート）ブロック共重合
体（重量平均分子量ｓ ｏ， ｏ ｏ ｏ、ポリスチレ
ン収分５０重量％）０．５部
上記組戊よシなる配合物を１５０℃のロールに供給し、
３分間ｌ￥！練した後温度１５０℃、圧力１５Ｇ）ｇ／
一の条件で５分間プレスして厚さＩｍのシートを得た。Example 1 Vinyl chloride resin (degree of polymerization 1100) 100 parts diptoxyethyl 7-talate 50 parts epoxy soybean oil 2 parts liquid zinc stabilizer
2 parts polystyrene-poly(2-perfluorooctylethyl methacrylate) block copolymer (weight average molecular weight s o, o o o, polystyrene yield 50% by weight) 0.5 parts 150 parts of the above composition Feeding into rolls at °C
3 minutes ¥! After kneading, the temperature is 150°C and the pressure is 15G) g/
The sheet was pressed for 5 minutes under the same conditions to obtain a sheet having a thickness of Im.
シートの製造直後、大気中に６０日放置後戊ひ６５℃で
２時Ｉｉｌ熱処理後の接触角を測定して結果を第１表に
示した。Immediately after the sheet was manufactured, it was left in the air for 60 days and then heat treated at 65°C for 2 hours.The contact angle was measured and the results are shown in Table 1.
尚、接触角は純水を用いて液滴法によシ測定した。The contact angle was measured by a droplet method using pure water.
実施例２
Ａ−Ｂ型ブロック共重合体をポリメチルメタクリレート
・ポリ（２−パーフルオロヘキシルエチルメタクリレー
ト）ブロック共重合体（重量平均分子量２ ０， ０
０ ０ 、ポリメチルメタクリレート戚分７５重量５８
）２部に代えた以外Ｆｉ実施例１で行ったと同様にして
シートを得、接触角を測定して結果ｔ−第１表に示した
。Example 2 A-B type block copolymer was mixed with polymethyl methacrylate/poly(2-perfluorohexylethyl methacrylate) block copolymer (weight average molecular weight 20,0
0 0, polymethyl methacrylate relative 75 weight 58
) A sheet was obtained in the same manner as in Example 1 except that 2 parts were used, and the contact angle was measured and the results are shown in Table 1.
比較例Ｉ
Ａ−Ｂ型ブロック共重合体を添県しない以外＃−１実施
例１で行ったと同様にしてシートを得、接触角を測定し
て結果を第１麦に示した。Comparative Example I A sheet was obtained in the same manner as in #-1 Example 1 except that the AB type block copolymer was not added, and the contact angle was measured and the results were shown in the first barley.
比較例２
Ａ−Ｂ型ブロック共重合体冫こ代えてフッ素系界面活性
剤（住友３Ｍ社製、７ロラードＦＣ−４３０）を２部添
加した以外は実施例１で行ったと同橡にしてシートを得
、接触角を測定して結果を第１表に示した。Comparative Example 2 A sheet was prepared in the same manner as in Example 1, except that 2 parts of a fluorine-based surfactant (manufactured by Sumitomo 3M, 7 Lollard FC-430) was added instead of the A-B type block copolymer. The contact angle was measured and the results are shown in Table 1.
第 １ 麦
（発明の効果）
本発明の塩化ビニル樹脂組底物の構戊は上述の通りであ
るから、この塩化ビニル樹脂組収物を使用して成形した
成形は軟質であって攬水性がすぐれてかり、長期間にわ
たって表面がべたつくことがなく、フイルム、シート等
の戊形体として包装用、農業用，インテリア用，合戊皮
革用等広い範囲で好適に使用される。No. 1 (Effects of the Invention) Since the structure of the vinyl chloride resin composite sole of the present invention is as described above, the molding made using this vinyl chloride resin composite sole is soft and water-repellent. It has excellent brightness and does not have a sticky surface over a long period of time, and is suitable for a wide range of uses, including packaging, agriculture, interior design, synthetic leather, etc., as round bodies such as films and sheets.
Claims (1)
合体よりなり、Ａがポリメチルメタクリレート又はポリ
スチレンであり、Ｂがポリ〔パーフルオロアルキル（メ
タ）アクリレート〕であって、Ａ−Ｂ型ブロック共重合
体の添加量が軟質塩化ビニル樹脂組成物に含まれる塩化
ビニル樹脂１００重量部に対し、０．３〜５重量部であ
ることを特徴とする塩化ビニル樹脂組成物。[Claims] 1. Consisting of a soft vinyl chloride resin composition and an A-B type block copolymer, A is polymethyl methacrylate or polystyrene, and B is poly[perfluoroalkyl (meth)acrylate]. , a vinyl chloride resin composition characterized in that the amount of the A-B type block copolymer added is 0.3 to 5 parts by weight based on 100 parts by weight of the vinyl chloride resin contained in the soft vinyl chloride resin composition. .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15513189A JPH0320346A (en) | 1989-06-16 | 1989-06-16 | Vinyl chloride resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15513189A JPH0320346A (en) | 1989-06-16 | 1989-06-16 | Vinyl chloride resin composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0320346A true JPH0320346A (en) | 1991-01-29 |
Family
ID=15599232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15513189A Pending JPH0320346A (en) | 1989-06-16 | 1989-06-16 | Vinyl chloride resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0320346A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0711311A1 (en) * | 1993-07-30 | 1996-05-15 | The University Of North Carolina At Chapel Hill | Heterogeneous polymerisation in carbon dioxide |
| JP2015513579A (en) * | 2012-02-23 | 2015-05-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Fluorinated acrylate block copolymers with low dynamic surface tension |
| JP2021011583A (en) * | 2015-07-01 | 2021-02-04 | 日油株式会社 | Thermosetting resin composition and resin molding thereof |
-
1989
- 1989-06-16 JP JP15513189A patent/JPH0320346A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0711311A1 (en) * | 1993-07-30 | 1996-05-15 | The University Of North Carolina At Chapel Hill | Heterogeneous polymerisation in carbon dioxide |
| EP0711311A4 (en) * | 1993-07-30 | 1999-01-07 | Univ North Carolina | Heterogeneous polymerisation in carbon dioxide |
| JP2015513579A (en) * | 2012-02-23 | 2015-05-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | Fluorinated acrylate block copolymers with low dynamic surface tension |
| JP2021011583A (en) * | 2015-07-01 | 2021-02-04 | 日油株式会社 | Thermosetting resin composition and resin molding thereof |
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