JPH03202068A - Hardener for hydraulic cast - Google Patents
Hardener for hydraulic castInfo
- Publication number
- JPH03202068A JPH03202068A JP1342100A JP34210089A JPH03202068A JP H03202068 A JPH03202068 A JP H03202068A JP 1342100 A JP1342100 A JP 1342100A JP 34210089 A JP34210089 A JP 34210089A JP H03202068 A JPH03202068 A JP H03202068A
- Authority
- JP
- Japan
- Prior art keywords
- hardener
- water
- foam
- cast
- hydraulic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004848 polyfunctional curative Substances 0.000 title abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 239000006260 foam Substances 0.000 claims abstract description 25
- 239000004088 foaming agent Substances 0.000 claims abstract description 11
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 239000004744 fabric Substances 0.000 claims abstract description 10
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 41
- 239000006261 foam material Substances 0.000 claims description 8
- 238000005266 casting Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 8
- 239000007788 liquid Substances 0.000 abstract description 6
- 230000035515 penetration Effects 0.000 abstract description 2
- 238000004804 winding Methods 0.000 abstract 2
- 230000008034 disappearance Effects 0.000 abstract 1
- 230000003902 lesion Effects 0.000 abstract 1
- -1 fatty acid salts Chemical class 0.000 description 18
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 10
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 229960003237 betaine Drugs 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 201000004624 Dermatitis Diseases 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 206010017076 Fracture Diseases 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 208000010040 Sprains and Strains Diseases 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- 239000004872 foam stabilizing agent Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000000399 orthopedic effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- FWIJLRSOBQIWFM-UHFFFAOYSA-N 2-[1-(2-hydroxyethyl)-2-undecyl-4,5-dihydroimidazol-1-ium-1-yl]acetate Chemical compound CCCCCCCCCCCC1=NCC[N+]1(CCO)CC([O-])=O FWIJLRSOBQIWFM-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- FQPIUCVYAYFKJP-UHFFFAOYSA-N [Na].C(CCCCCCCCCCC)C(N(CCN)CCN)C(=O)O Chemical compound [Na].C(CCCCCCCCCCC)C(N(CCN)CCN)C(=O)O FQPIUCVYAYFKJP-UHFFFAOYSA-N 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229940056585 ammonium laurate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- VJCJAQSLASCYAW-UHFFFAOYSA-N azane;dodecanoic acid Chemical compound [NH4+].CCCCCCCCCCCC([O-])=O VJCJAQSLASCYAW-UHFFFAOYSA-N 0.000 description 1
- PLUHAVSIMCXBEX-UHFFFAOYSA-N azane;dodecyl benzenesulfonate Chemical compound N.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 PLUHAVSIMCXBEX-UHFFFAOYSA-N 0.000 description 1
- LRIHKZMLMWYPFS-UHFFFAOYSA-N azanium;hexadecanoate Chemical compound [NH4+].CCCCCCCCCCCCCCCC([O-])=O LRIHKZMLMWYPFS-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- MQOCIYICOGDBSG-UHFFFAOYSA-M potassium;hexadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCC([O-])=O MQOCIYICOGDBSG-UHFFFAOYSA-M 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、骨折、捻挫、脱臼、矯正等の整形外科的疾患
の固定、支持、保護に用いられるキャストを形成するた
めの水硬性キャスト用硬化剤に間する。[Detailed Description of the Invention] [Industrial Application Field] The present invention is a hydraulic cast for forming casts used for fixing, supporting, and protecting orthopedic diseases such as fractures, sprains, dislocations, and corrections. Add hardener.
骨折、捻挫、脱臼、矯正等の整形外科的疾患は、患部を
中心に上下2関節間を固定、支持、保護することで安静
に保ち治療する。その患部を固定、支持、保護するには
、固定、支持、保護する範囲に綿包装、ストツキネット
(綿性のチューブ包装)、ポリエステル性不織布等の下
巻材を巻き、この下巻材の上から、焼石膏やウレタン樹
脂、アクリル酸塩等の水と反応し硬化する成分を天然繊
維、半合成繊維、合成繊維等からなる目の粗い織物や編
物に塗布してシート状又はロール状にした水硬性キャス
トを巻き付ける方法がとられている。この方法において
は、水硬性キャストは一般に耐水性の包材で密閉した形
で流通し、使用時に開封され、多量の水の中に浸漬して
十分水となじませ患部に適用されるが、そのため適用時
にキャスト材に付着した余分の水が落ちて周辺を濡らし
たり、患部を保護するため巻いた下巻材を濡らして患者
に不快感を与えるという問題点がある。又これらの水硬
性キャスト材は水と接触させる段階より反応が始まり、
2分〜10分の間で硬化するもので、自由に硬化時間を
選択することが困難である。すなわち、一般に水温が高
いと早く硬化し、逆に低いと硬化までの時間が長くなり
過ぎるため、高度な操作が要求され、特に適用領域が小
児の場合のように小さい領域のときはゆっくり巻いても
硬化迄時間が長過ぎるためその間患部を良肢位で保持し
ておく手間が必要であり、又大人の胸部のように広い領
域の場合は手早く巻かないと途中で硬化してしまい、そ
のキャスト材は使用できなくなるという欠点を有してい
る。Orthopedic diseases such as fractures, sprains, dislocations, and corrections are treated by keeping the affected area at rest by fixing, supporting, and protecting the upper and lower joints. To fix, support, and protect the affected area, wrap a lower wrapping material such as cotton wrapping, stocking net (cotton tube wrapping), or polyester nonwoven fabric around the area to be fixed, supported, and protected, and then wrap it over the lower wrapping material. Water is made by coating coarse woven or knitted fabrics made of natural fibers, semi-synthetic fibers, synthetic fibers, etc. with ingredients that harden by reacting with water, such as calcined gypsum, urethane resin, acrylic acid salts, etc., and forming them into sheets or rolls. The method used is to wrap a hard cast around it. In this method, the hydraulic cast is generally distributed in a sealed form in a water-resistant packaging material, which is opened at the time of use, soaked in a large amount of water, thoroughly absorbed, and then applied to the affected area. There is a problem in that during application, excess water adhering to the cast material falls off and wets the surrounding area, or wets the lower wrapping material wrapped to protect the affected area, causing discomfort to the patient. In addition, these hydraulic cast materials begin to react from the stage of contact with water,
It cures within 2 to 10 minutes, making it difficult to freely select the curing time. In other words, in general, if the water temperature is high, it will harden quickly, and if the water temperature is low, it will take too long to harden, so advanced operations are required, especially when the application area is small such as in the case of children. However, since it takes too long for the affected area to harden, it is necessary to take care to hold the affected area in a comfortable position during that time, and if the area is large, such as an adult's chest, it will harden midway if it is not wrapped quickly. The disadvantage is that the material becomes unusable.
これらの点を改善するため、水中に浸漬することなく通
用できるものとして、硬化を促進させる成分を含まない
ウレタンプレポリマーを目の粗い基布に塗布したものと
ウレタンプレポリマーの硬化剤とを組み合わせて使用す
る水硬性キャスト材が本出願人により提案されている(
実開昭63−130031号公報参照)、シかしながら
、このキャスト材においては、ウレタンプレポリマーに
硬化成分が含まれていないため硬化が遅く、愚者や施術
者はその聞良肢位を保つため長時間我慢しなければなら
ず、さらに硬化成分を基布に適用する際余分な硬化剤が
施術者の手や患者の皮膚に接触する可能性が高く、その
結果皮膚炎を起こすおそれがある。一方、硬化剤の種類
を選択すること4により硬化速度を選ぶことができると
いう利点を有するが、硬化速度を調整するために混入す
る触媒は皮膚炎を起こす可能性も高く、かつ硬化が不均
一になるという欠点をも有している。In order to improve these points, we combined a urethane prepolymer that does not contain components that accelerate hardening applied to a coarse base fabric and a urethane prepolymer curing agent as a material that can be used without immersion in water. The applicant has proposed a hydraulic cast material for use in
However, in this cast material, the urethane prepolymer does not contain a curing component, so curing is slow, and the fool and the practitioner can maintain a comfortable position. In addition, when applying the hardening agent to the base fabric, there is a high possibility that excess hardening agent will come into contact with the practitioner's hands or the patient's skin, which may result in dermatitis. . On the other hand, it has the advantage that the curing speed can be selected by selecting the type of curing agent4, but the catalyst that is mixed in to adjust the curing speed has a high possibility of causing dermatitis, and the curing is uneven. It also has the disadvantage of becoming
本発明は、適用される症例による使用領域の大きさに左
右されず、かつ任意の部位から自由に硬化させることが
でき、使用場所を選ばず、周辺を汚すことなく、安全に
且つ経済的に使用できる水硬性キャスト用硬化剤を提供
することを目的としている。The present invention is not affected by the size of the application area depending on the case to which it is applied, and can be cured freely from any part, and can be used anywhere, without polluting the surrounding area, safely and economically. The object of the present invention is to provide a usable curing agent for hydraulic casting.
上記目的を達成するため、本発明の硬化剤においては、
開口を有する繊維性基布に硬化を促進する成分を含む水
活性のウレタンプレポリマーを塗布した水硬性キャスト
のための硬化剤が水を主成分とする泡状物質で構成され
るものである。In order to achieve the above object, in the curing agent of the present invention,
The curing agent for hydraulic casting, in which a water-active urethane prepolymer containing a component that promotes curing is coated on a fibrous base fabric having openings, is composed of a foamy substance mainly composed of water.
上記泡状物質は水の外、起泡剤、泡安全剤を含むことが
できる。In addition to water, the foam material may include a foaming agent and a foam safety agent.
泡状物質の泡の密度は0.01〜0.2g/cm3に選
ぶのが有利である。The foam density of the foam material is advantageously chosen to be between 0.01 and 0.2 g/cm@3.
泡状物質は、水、起泡剤、泡安定剤を高圧ガスボンベ中
に配合して使用し得るようにするのが好ましい。Preferably, the foam material can be used by combining water, a foaming agent, and a foam stabilizer in a high-pressure gas cylinder.
本発明においては、開口を有する繊維性基布に水活性の
ウレタンプレポリマーを塗布した水硬性キャストを患部
に巻いた後、硬化剤を手に取ってキャスト上に塗り付け
るか、又はキャスト上に直接付けた後手で均等に塗り広
げるものであり、それにより泡状の硬化剤は、余分な水
分の滴下を生ずることなくキャスト内に浸透して硬化が
進行する。In the present invention, a hydraulic cast made of a fibrous base fabric with openings coated with a water-active urethane prepolymer is wrapped around the affected area, and then the curing agent is applied to the cast by hand or directly onto the cast. After application, it is spread evenly by hand, allowing the foam-like curing agent to penetrate into the cast and proceed with curing without causing excess moisture to drip.
次に本発明の実施例について説明する。 Next, examples of the present invention will be described.
起泡剤は硬化剤の主成分である水の泡立ち作用を行う物
質で、主に高級脂肪酸塩、高級アルキル硫酸エステル塩
、高級アルキルエーテル硫酸エステル塩、アルキルアリ
ルスルホン酸塩、カルボキシベタイン、イミダゾリニウ
ムベタイン、アミノカルボン酸塩、アルキロールアミド
、アルキルアミンオキサイド等の界面活性剤が使用でき
る。それらの塩は主としてナトリウム塩、カリウム塩、
アミン塩、アンモニウム塩である。Foaming agents are substances that have a foaming effect on water, which is the main component of curing agents, and mainly include higher fatty acid salts, higher alkyl sulfate ester salts, higher alkyl ether sulfate ester salts, alkylaryl sulfonates, carboxybetaine, and imidazolytes. Surfactants such as nium betaine, aminocarboxylic acid salts, alkylolamides, and alkylamine oxides can be used. These salts are mainly sodium salts, potassium salts,
They are amine salts and ammonium salts.
起泡剤の具体例としては、ラウリン酸ナトリウム、ラウ
リン酸カリウム、ラウリン酸アンモニウム、オクチル酸
カリウム、パルミチン酸ナトリウム、パルミチン酸カリ
ウム、パルミチン酸アンモニウム、ラウリル硫酸ナトリ
ウム、ラウリル硫酸トリエタノ−ルアξン、ポリオキシ
エチレンラウリル硫酸ナトリウム、ポリオキシエチレン
ラウリルエーテル硫酸ナトリウム、ポリオキシエチレン
ラウリルエーテル硫酸カリウム、ポリオキシエチレンラ
ウリル硫酸トリエタノールアミン、ドデシルベンゼンス
ルホン酸アンモニウム、ヤシ油脂肪酸アミドプロピルベ
タイン、2−アルキル−N−カルボキシメチル−N−ヒ
ドロキシエチルイミダゾリニウムベタイン、2−ウンデ
シル−N−カルボキシメチル−N−ヒドロキシエチルイ
ミダゾリニウムベタイン、ナトリウムラウリルジ(アミ
ノエチル)グリシン、ヤシ油脂肪酸ジェタノールアミド
、ポリオキシエチレンヤシ油脂肪酸モノエタノールアミ
ド、ラウリン酸ジェタノールアミド、ラウリルジメチル
アミンオキサイド等があげられる。Specific examples of foaming agents include sodium laurate, potassium laurate, ammonium laurate, potassium octylate, sodium palmitate, potassium palmitate, ammonium palmitate, sodium lauryl sulfate, triethanolane lauryl sulfate, and polyester. Sodium oxyethylene lauryl sulfate, sodium polyoxyethylene lauryl ether sulfate, potassium polyoxyethylene lauryl ether sulfate, triethanolamine polyoxyethylene lauryl sulfate, ammonium dodecylbenzenesulfonate, coconut oil fatty acid amidopropyl betaine, 2-alkyl-N- Carboxymethyl-N-hydroxyethylimidazolinium betaine, 2-undecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, sodium lauryl di(aminoethyl)glycine, coconut oil fatty acid jetanolamide, polyoxyethylene coconut Examples include oil fatty acid monoethanolamide, lauric acid jetanolamide, and lauryl dimethylamine oxide.
泡安定剤は硬化剤の主成分である水に生じた泡の安定性
をよくする物質で、アルキロールアミド、ポリオキシエ
チレンジアルキルエーテル、ポリオキシエチレンジアル
キルエステル等の界面活性剤や水溶性高分子が使用でき
る。Foam stabilizers are substances that improve the stability of foam formed in water, which is the main component of hardeners, and include surfactants such as alkylolamides, polyoxyethylene dialkyl ethers, and polyoxyethylene dialkyl esters, and water-soluble polymers. can be used.
泡安定剤の具体例としては、ラウリン酸ジェタノールア
ミド、ヤシ油脂肪酸ジェタノールアミド、ポリオキシエ
チレンヤシ油脂肪酸モノエタノールアミド、ポリオキシ
エチレンジラウリルエーテル、ポリオキシエチレンジス
テアリン酸エステル、ポリビニルアルコール、ポリビニ
ルピロリドン、アルギン酸ナトリウム、カルボキシメチ
ルセルロース、ポリアクリル酸ナトリウムがあげられる
。Specific examples of foam stabilizers include lauric acid jetanolamide, coconut oil fatty acid jetanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, polyoxyethylene dilauryl ether, polyoxyethylene distearate, polyvinyl alcohol, polyvinyl Examples include pyrrolidone, sodium alginate, carboxymethylcellulose, and sodium polyacrylate.
泡状物質の成分として、水、起泡剤、泡安定剤の外、必
要に応じて硬化剤の溶液の低温安定性を付与するための
液安定剤、泡状になった硬化剤の基布への浸透作用を改
善するための浸透剤を添加することができる。この液安
定剤としては、グリセリン、エチレングリコール、ジエ
チレングリコール、プロピレングリコール、エチルセロ
ソルブ等が使用され、浸透剤としては、ジオクチルスル
ホコハク酸ナトリウム、ポリオキシエチレンアルキルエ
ーテル、ポリオキシエチレンアルキルアリルエーテル等
が使用される。In addition to water, a foaming agent, and a foam stabilizer, the foam material includes a liquid stabilizer for imparting low-temperature stability to the hardening agent solution as needed, and a base fabric for the foamed hardening agent. Penetrants can be added to improve the penetration effect. As the liquid stabilizer, glycerin, ethylene glycol, diethylene glycol, propylene glycol, ethyl cellosolve, etc. are used, and as the penetrant, sodium dioctyl sulfosuccinate, polyoxyethylene alkyl ether, polyoxyethylene alkyl allyl ether, etc. are used. Ru.
泡状物質の各成分の配合割合は、起泡剤が10〜50%
、泡安定剤が1〜工0%、水が39〜90%の範囲で含
まれるようにするのが好ましい。The blending ratio of each component of the foam material is 10 to 50% foaming agent.
Preferably, the foam stabilizer is contained in a range of 1 to 0%, and the water is contained in a range of 39 to 90%.
なお、液安定剤は1〜10%、好ましくは2〜5%、浸
透剤は1%以下の範囲で含ませることができる。The liquid stabilizer may be contained in an amount of 1 to 10%, preferably 2 to 5%, and the penetrant may be contained in an amount of 1% or less.
泡状物質の各成分は例えば噴射用ガスと共に高圧ガスボ
ンベに封入し、噴射させることにより泡状にすることが
できるが、気泡密度は0.01〜0゜2g/cd、好ま
しくは0.02〜0.1 g/cdに選ぶのがよい、こ
の気泡密度は、硬化剤を手に取った場合、あるいは水硬
性キャストに直接噴射した場合取り扱いやすい値で、こ
の密度が高過ぎると水に近い状態となり、手に取った場
合溝れて清下し、周辺を汚したり、下巻材を濡らすこと
になり、また密度が低過ぎると量的に使用体積が大きく
なり過ぎ、何回も繰り返し操作をしなければならなくな
るので上記の範囲が好ましい。Each component of the foam material can be made into a foam by, for example, sealing it in a high-pressure gas cylinder together with an injection gas and injecting it, but the bubble density is 0.01 to 0.2 g/cd, preferably 0.02 to It is best to choose 0.1 g/cd. This bubble density is a value that is easy to handle when the curing agent is picked up or sprayed directly onto a hydraulic cast. If this density is too high, it will be in a state close to water. If you pick it up, it will groove and clean, staining the surrounding area and wetting the lower material. Also, if the density is too low, the volume used will be too large, and you will have to repeat the operation many times. Therefore, the above range is preferable.
また本発明の硬化剤は、泡形成後常温で手に取ったとき
又は水硬性キャスト上に付着させたとき少なくとも10
秒以上、好ましくは1分以上泡状を保ち、キャストに塗
り付けてから遅くとも5分以内、好ましくは2分以内に
泡が消失するものが好ましい、この部活性時間は10秒
以内であると水硬性キャストに均等に塗布することが不
可能であり、消泡時間が5分以上であると硬化剤をキャ
ストに塗布し手で擦り込んでもなかなか泡が消失せず、
使用した硬化剤の全量がキャストに接触せず、硬化時間
が遅くなったり、キャストの乾燥が長くなったり、或い
はキャストの目を埋めて通気性を阻害することになるの
で上記の範囲が好ましい。Further, the curing agent of the present invention has a hardening agent of at least 10
It is preferable that the foam stays for at least 1 minute, preferably for at least 1 minute, and that the foam disappears within 5 minutes at the latest, preferably within 2 minutes after being applied to the cast. It is impossible to apply the hardening agent evenly to the hard cast, and if the defoaming time is longer than 5 minutes, the foam will not disappear even if you apply the hardening agent to the cast and rub it in by hand.
The above range is preferable because the entire amount of the curing agent used does not come into contact with the cast, slowing down the curing time, prolonging the drying of the cast, or filling the holes in the cast and impeding air permeability.
本発明の硬化剤の使用方法の一例を説明すると、まず患
部に下巻材を巻き、その上に、適度の開口を有する繊維
性基布に硬化を促進する成分を含む水活性のウレタンプ
レポリマーを塗布した水硬性キャストを巻き付ける。高
圧ガスボンベに封入した本発明の硬化剤を噴出させて泡
状にし、これを手に取って水硬性キャストに塗り付け、
手で均等にキャスト上に塗り広げる。この場合ガスボン
ベから直接キャスト上に硬化剤を噴出させ、それから手
で塗り広げてもよい、硬化剤は泡の状態でキ中スト上に
塗り広げられるからその間に水分が滴下したり下巻材を
濡らすことはなく、泡の消失とともに硬化剤の主成分の
水はキャストの開口を通して浸透し、ウレタンプレポリ
マーは外部より内部に向かって硬化が進行する。その際
施術者は硬化状態を確認しながら患部の微妙な凹凸に対
し水硬性キャストの内側の層がフィツトするよう操作す
ることができる。To explain one example of the method of using the curing agent of the present invention, first, a lower wrapping material is wrapped around the affected area, and on top of that, a water-active urethane prepolymer containing a component that accelerates curing is applied to a fibrous base fabric with moderate openings. Wrap the applied hydraulic cast around it. The curing agent of the present invention sealed in a high-pressure gas cylinder is squirted out to form a foam, which is then picked up and applied to the hydraulic cast.
Spread evenly over the cast using your hands. In this case, you can squirt the hardening agent directly onto the cast from a gas cylinder and then spread it by hand.The hardening agent is spread in the form of a foam over the cast, so there is no chance of moisture dripping or wetting the bottom material during that time. As the bubbles disappear, water, the main component of the curing agent, permeates through the openings in the cast, and the urethane prepolymer hardens from the outside toward the inside. At this time, the practitioner can manipulate the inner layer of the hydraulic cast to fit the delicate unevenness of the affected area while checking the hardening state.
硬化剤を水硬性キャストの全面に一度に塗らず、早く硬
化させたい部分より硬化剤を塗り付け、その部位の固定
、支持、保護を行ってがらその他の部位前ゆっくりと硬
化させることもできる。Instead of applying the hardening agent to the entire surface of the hydraulic cast at once, it is also possible to apply the hardening agent to the areas that you want to harden quickly, and then fix, support, and protect that area while slowly curing the other areas.
本発明の硬化剤成分の例を次に示す。Examples of the curing agent components of the present invention are shown below.
奥上
ラウリン酸カリウム 30! (起泡剤)オクチ
ル酸カリウム 10 (起泡剤)プロピレングリ
コール 5(液安定則)ジオクチルスルホコハク
酸ナトリウム 1 (浸透剤)水
49
上記成分をエーロゾル容器にLPGと共に入れたものを
作製した。その気泡密度は0.045g/d、その泡活
性、消泡時間はそれぞれ1分以上、0.7分であった。Okugami Potassium Laurate 30! (Foaming agent) Potassium octylate 10 (Foaming agent) Propylene glycol 5 (Liquid stability law) Sodium dioctyl sulfosuccinate 1 (Penetrating agent) Water
49 An aerosol container was prepared in which the above components were placed together with LPG. The foam density was 0.045 g/d, and the foam activity and defoaming time were 1 minute or more and 0.7 minutes, respectively.
撚1
プロピレングリコール 2(液安定則)水
83上記成分をエーロゾル容器に
LPGと共に入れたものを作製した。その気泡密度は0
.03g/cii、その泡活性、消泡時間はそれぞれ1
分以上、0.5分であった。Twist 1 Propylene glycol 2 (Liquid stability law) Water
83 An aerosol container was prepared in which the above components were placed together with LPG. The bubble density is 0
.. 03g/cii, its foam activity and defoaming time are each 1
It was more than 0.5 minutes.
亘主
アミドプロピルベタイン 5 (起成刑)ポリオキシエ
チレン
ジステアリン酸エステル 5(泡安定剤)水
70上記成分をエーロゾル容器に
LPGと共に入れたものを作製した。その気泡密度は0
.10g/cm3、その泡活性、消泡時間はそれぞれ1
分以上、1.5分であった。Wataru Amidopropyl Betaine 5 (Kiseikai) Polyoxyethylene Distearate 5 (Foam Stabilizer) Water
70 An aerosol container was prepared in which the above components were placed together with LPG. The bubble density is 0
.. 10g/cm3, its foam activity and defoaming time are each 1
It was more than 1.5 minutes.
本発明によれば、水を主成分とする硬化剤が泡状勧賞で
あるから、従来のように水を容器に入れて用意する必要
がなく、施術場所として特別な室(ギプス室等)を不用
とし、また水のない場所、例えば自動車、航空機等にお
いて救急用として有利に使用することができ、さらに水
のように飛散や滴下することがないから、周辺や衣服を
汚すこともなく、下巻材を濡らして患者に不快感を与え
ることもない。According to the present invention, since the hardening agent whose main component is water is foam-like, there is no need to prepare water in a container as in the past, and a special room (such as a cast room) is required for the treatment area. It is unnecessary and can be advantageously used for emergency purposes in places where there is no water, such as cars and airplanes.Furthermore, since it does not scatter or drip like water, it does not stain the surrounding area or clothes. The material will not get wet and cause discomfort to the patient.
硬化剤に適度の部活性時間、消泡時間を持たせることに
より、その間の保形性を利用して水硬性キャストの所定
箇所に必要最小限の量の硬化剤を目視しながら塗り付は
手でモールデイグ操作することができ、正確かつ経済的
にキャスティングが可能となり、しかも硬化剤と水硬性
キャストとの効果的な接触により満遍なく均一に硬化反
応が進行し、キャストの乾燥も迅速に行われる。By giving the curing agent an appropriate part activation time and defoaming time, it is possible to apply the minimum necessary amount of curing agent to the designated area of the hydraulic cast by hand while visually checking the shape retention properties during that time. The molding operation can be carried out using a molding method, making it possible to cast accurately and economically.Moreover, due to the effective contact between the hardening agent and the hydraulic cast, the curing reaction progresses evenly and uniformly, and the cast dries quickly.
硬化剤は水が主成分で、皮膚炎を起こすような物質を含
んでいないから、安全に使用することができる。The curing agent is mainly water-based and does not contain substances that can cause dermatitis, so it can be used safely.
さらに本発明の硬化剤を使用する場合、水硬性キャスト
そのものは従来のように水を漬けてから巻く必要がない
から、巻く期間中硬化反応は進行せず、患部の大小の領
域に関係なく、患部の形状、状態に最も適した巻き方を
することができ、従来の水に漬けて使用する水硬性キャ
ストでは内部より硬化が始まるのに対し、本発明の硬化
剤を用いると外部より内部に向かって硬化が進むため、
施術者は硬化状態を確認しながら患部の微妙な凹凸に水
硬性キャストの内側をフィツトさせる操作が可能となる
。Furthermore, when using the hardening agent of the present invention, the hydraulic cast itself does not need to be soaked in water and then rolled up as in the past, so the hardening reaction does not proceed during the rolling period, regardless of the size of the affected area. It is possible to wrap the area in a way that is most suitable for the shape and condition of the affected area, and unlike conventional hydraulic casts that are soaked in water and used, hardening starts from the inside, using the hardening agent of the present invention, the hardening agent starts to harden from the outside. As hardening progresses towards
The practitioner can fit the inside of the hydraulic cast to the delicate unevenness of the affected area while checking the hardening state.
Claims (1)
む水活性のウレタンプレポリマーを塗布した水硬性キャ
スト用硬化剤であって、前記硬化剤が水を主成分とする
泡状物質であることを特徴とする水硬性キャスト用硬化
剤。 2)泡状物質が水、起泡剤、泡安定剤からなることを特
徴とする請求項1記載の水硬性キャスト用硬化剤。 3)泡状物質の泡の密度が0.01〜0.2g/cm^
3であることを特徴とする請求項1又は2記載の水硬性
キャスト用硬化剤。 4)水、起泡剤、泡安定剤からなる泡状物質を高圧ガス
ボンベ中に配合したことを特徴とする請求項1〜3の1
つに記載の水硬性キャスト用硬化剤。[Scope of Claims] 1) A curing agent for hydraulic casting in which a water-active urethane prepolymer containing a component that promotes curing is coated on a fibrous base fabric having openings, the curing agent mainly containing water. A curing agent for hydraulic casting characterized by being a foamy substance. 2) The curing agent for hydraulic casting according to claim 1, wherein the foam material comprises water, a foaming agent, and a foam stabilizer. 3) The foam density of the foam material is 0.01 to 0.2 g/cm^
3. The curing agent for hydraulic casting according to claim 1 or 2, characterized in that: 4) Claims 1 to 3, characterized in that a foamy substance consisting of water, a foaming agent, and a foam stabilizer is blended into a high-pressure gas cylinder.
A curing agent for hydraulic casting described in .
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1342100A JPH03202068A (en) | 1989-12-28 | 1989-12-28 | Hardener for hydraulic cast |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1342100A JPH03202068A (en) | 1989-12-28 | 1989-12-28 | Hardener for hydraulic cast |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03202068A true JPH03202068A (en) | 1991-09-03 |
Family
ID=18351159
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1342100A Pending JPH03202068A (en) | 1989-12-28 | 1989-12-28 | Hardener for hydraulic cast |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03202068A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05201511A (en) * | 1992-01-28 | 1993-08-10 | Nippon Kinsen Kikai Kk | Method for forming path for medal and the like |
WO2003028602A1 (en) * | 2001-09-28 | 2003-04-10 | Alcare Co., Ltd. | Water-hardening fixing material and method for using the same |
CN111032818A (en) * | 2017-08-15 | 2020-04-17 | 沙特阿拉伯石油公司 | Thermally stable surfactants for oil-based drilling fluids |
-
1989
- 1989-12-28 JP JP1342100A patent/JPH03202068A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05201511A (en) * | 1992-01-28 | 1993-08-10 | Nippon Kinsen Kikai Kk | Method for forming path for medal and the like |
WO2003028602A1 (en) * | 2001-09-28 | 2003-04-10 | Alcare Co., Ltd. | Water-hardening fixing material and method for using the same |
CN111032818A (en) * | 2017-08-15 | 2020-04-17 | 沙特阿拉伯石油公司 | Thermally stable surfactants for oil-based drilling fluids |
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