JPH03184831A - Manufacture of porous body sheet formed of sintered plastic powder - Google Patents

Manufacture of porous body sheet formed of sintered plastic powder

Info

Publication number
JPH03184831A
JPH03184831A JP32648989A JP32648989A JPH03184831A JP H03184831 A JPH03184831 A JP H03184831A JP 32648989 A JP32648989 A JP 32648989A JP 32648989 A JP32648989 A JP 32648989A JP H03184831 A JPH03184831 A JP H03184831A
Authority
JP
Japan
Prior art keywords
heating
sintering
powder
infrared rays
plastic powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP32648989A
Other languages
Japanese (ja)
Inventor
Masami Kamiya
雅己 神谷
Mitsuo Yokota
横田 光雄
Kenichi Ohori
健一 大堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Priority to JP32648989A priority Critical patent/JPH03184831A/en
Publication of JPH03184831A publication Critical patent/JPH03184831A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To sinter the deep part of powdery plastic and to enhance the line velocity of sintering by irradiating the powdery plastic forming a thin layer with far infrared rays and heating it. CONSTITUTION:Powdery plastic is supplied to a horizontally moved carrier belt 8 by a feeder 7. Powdery plastic receives irradiation of far infrared rays radiated from a horizontally arranged heater 1 in a heating zone 2 and is heated. Then it receives hot wind in a hot air zone 4 and furthermore receives cold wind in a cooling zone 6. Thereby scattering of the powder is not thoroughly caused in a stage of the initial period of sintering. Further sintering is enabled at the line velocity of two times the velocity by a method of either far infrared rays heating or hot wind heating.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、焼結十分なプラスナック粉末焼結多孔質体シ
ート0−)製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing a sintered porous sheet of sintered plastic snack powder.

〔従来り技術〕[Conventional technology]

プラスチック粉末焼結多孔質体には棟々〜拐質、形状0
もOjがあり、そO」用途も色々と開発される趨勢にあ
る。内部り気孔を独立とすることも連通とすることも容
易であるが、断熱胴として0)利用も多く、又%に連通
気孔としてフィルターvc使用する例も多い。
Plastic powder sintered porous body has ridges to grains, shape 0
There is also a tendency for various applications to be developed. Although it is easy to make the internal pores independent or communicated, it is often used as a heat insulating shell, and there are also many examples in which a filter VC is used as a continuous vent.

最近は、多孔質であるがために低@電率であることに看
目して回路用基f2σ」絶縁体層として使用することも
検討されている。特願昭61−204062及び%顛昭
61−2040<54によれば、例えばマイクロストリ
ップアンテナ″′Cは電力を効率良く伝送放射するため
に比誘11L率(εr)、誘電正接(tanδ)が低い
ことを要する。そりため。
Recently, since it is porous and has a low electrical conductivity, its use as an insulating layer for circuit boards is also being considered. According to Japanese patent application No. 61-204062 and %Sho 61-2040<54, for example, a microstrip antenna "'C has a dielectric constant of 11L (εr) and a dielectric loss tangent (tan δ) in order to transmit and radiate power efficiently. Needs to be low.For sledding.

ポリオレフィン糸の低tr 、低tanδり粉末鳩結多
孔質体シートヲ絶縁体層(誘電体)として使用するスト
リップアンテナ用基板が検討されている。
A substrate for a strip antenna using a porous sheet of powder dovetailing with low tr and low tan δ of polyolefin thread as an insulator layer (dielectric) is being considered.

従来、この多孔質体シー1f[遺するKは、先ずプラス
チック粉末を金属ベルト上υ基羽上に散布し、ナイフコ
ータなどによって一定厚みに賦形した後、連続的に熱風
炉中t−通して焼結する方法がある。こσ〕方法は、生
産効率は非常に良いが、熱風利用のため表層部の焼結は
逸むが内部には熱が伝わり難くて焼結が遅い。表層と内
部り焼結が大きく異なるが、こカ問題はシートが厚い程
如者である。又、熱風焼結であるために、焼結σノ初期
段階で粉末が飛散する問題もある。
Conventionally, this porous material sheet 1f [K] was prepared by first scattering plastic powder onto a metal belt, shaping it to a certain thickness using a knife coater, etc., and then continuously passing it through a hot air oven. There is a method of sintering. This method has very good production efficiency, but since it uses hot air, the sintering of the surface layer is missed, but the heat is difficult to transfer to the inside, so sintering is slow. There is a big difference between the surface layer and internal sintering, but the problem becomes more pronounced as the sheet gets thicker. Furthermore, since hot air sintering is used, there is also the problem that powder is scattered during the initial stage of sintering σ.

本発明は、以上り問題点がなく、焼結十分なプラスチッ
ク粉末焼結多孔室体シートり製造方法を提供することを
目的とする。
SUMMARY OF THE INVENTION An object of the present invention is to provide a method for producing a porous chamber sheet made of sintered plastic powder, which is free from the above-mentioned problems and can be sintered satisfactorily.

〔課題を解決するためσ)手段〕[σ) means to solve the problem]

以上σノ目的を達成するために、本発明は薄い層を形成
するプラスチック粉末を遠赤外巌で照射加熱するプラス
チック粉末焼結多孔装体ンートり製造方法である。
In order to achieve the above object, the present invention is a method for producing a porous sintered plastic powder packaging in which plastic powder forming a thin layer is irradiated and heated with far-infrared light.

プラスチックは、近赤外線ヲはとんど吸収しないが、遠
赤外mを照射すると良く吸収して内部から加熱される○
したがって、内部O粉末相互り融着も表面と1m時に進
み強靭な焼結体を形成することができる。遠赤外m〜放
散剤としては、セラミックスが一般的であり、1hos
、5i02−  SiCなど各種類を使用することがで
きる。
Plastics hardly absorb near-infrared rays, but when irradiated with far-infrared rays, they absorb well and are heated from within.
Therefore, the internal O powder can be fused to the surface within 1 m to form a strong sintered body. Ceramics are commonly used as far-infrared m~ diffusing agents, and 1hos
, 5i02-SiC, etc. can be used.

使用する熱源は、電気ヒータ及び過熱蒸気が一般的であ
る。
The heat sources used are generally electric heaters and superheated steam.

プラスチック粉末には熱可そ性柄脂、熱硬化性樹脂σ)
何れも使用することができる0使用できる樹脂を次に例
示すると、ポリエチレン、ポリプロピレン、ポリ−1−
ブテン、ポリ−4メチル−1−ペンテン、エチレン−プ
ロピレン共nte体、 プロピレン−1−ブテン共重合
体、エチレン−酢酸ビニル共重合体、ポリテトラフルオ
ロエチレン。
Plastic powder includes thermoplastic resin and thermosetting resin σ)
Examples of resins that can be used include polyethylene, polypropylene, poly-1-
Butene, poly-4 methyl-1-pentene, ethylene-propylene copolymer, propylene-1-butene copolymer, ethylene-vinyl acetate copolymer, polytetrafluoroethylene.

テトラフルオロエチレン−へキサフルオロエチレン共重
合体、テトラフルオロエテレンーパーフルオロアルコキ
シエテレン共N合体、トリフルオロクロルエチレン、テ
トラフルオロエチレン−エayレン共重合体、ポリスチ
レン、アクリロニトリル−スチレン共重合体、アクリロ
ニトリル−ブタジェン−スチレン共重合体、ポリカーボ
ネート、ポリメチルメタアクリレート、ポリビニルブチ
ラール、ポリビニルホルマールポリイミド、ポリアミド
、ボリアくトイミド、ポリフェニレンサルファイド、ポ
リエーテルサルホン、ポリサルホン、ボリアリレート、
ポリエーテルエーテルケトン、ポリフェニレンオキサイ
ド、ポリエーテルアミド。
Tetrafluoroethylene-hexafluoroethylene copolymer, tetrafluoroethylene-perfluoroalkoxyethene co-N polymer, trifluorochloroethylene, tetrafluoroethylene-hexafluoroethylene copolymer, polystyrene, acrylonitrile-styrene copolymer, Acrylonitrile-butadiene-styrene copolymer, polycarbonate, polymethyl methacrylate, polyvinyl butyral, polyvinyl formal polyimide, polyamide, polyamide, polyphenylene sulfide, polyether sulfone, polysulfone, polyarylate,
Polyetheretherketone, polyphenylene oxide, polyetheramide.

ポリエーテルイミド、ポリイソブチレン、ポリメキシベ
ンジレン、ポリブチレンテレフタレート。
Polyetherimide, polyisobutylene, polymexybenzylene, polybutylene terephthalate.

ポリブタジェン、ポリエステル、ポリ塩化ビニル。Polybutadiene, polyester, polyvinyl chloride.

ポリ塩化ビニリデン、尿素樹脂、メラミン樹脂。Polyvinylidene chloride, urea resin, melamine resin.

ベンゾグアナミン樹脂、フェノール梱脂、エポキシ樹脂
、シリコーン樹脂、ホルマリン樹脂、キシレン樹脂、フ
ラン樹脂、ジアリルフタレート樹脂、ポリイソシアネー
ト樹脂、フェノキシ樹脂等であるO これら樹脂を適宜変性しても良く、又これらσノ混合物
を使用することもできる。樹脂によって架橋剤、硬化剤
を使用する。
These resins such as benzoguanamine resin, phenol buffing fat, epoxy resin, silicone resin, formalin resin, xylene resin, furan resin, diallyl phthalate resin, polyisocyanate resin, and phenoxy resin may be modified as appropriate. Mixtures can also be used. Crosslinking agents and curing agents are used depending on the resin.

これらプラスチック粉末を他力樹脂℃被覆して使用する
方法もある。
There is also a method in which these plastic powders are coated with external resin at °C.

熱硬化性樹脂は、@接粒子間り融層に支障がない程度の
硬化度とする。
The thermosetting resin has a degree of curing that does not interfere with the interparticle melting layer.

熱司そ性樹脂は、隣接粉末粒子間の#層をおこし易く、
本発明には最も通切な樹脂である。
Heat-susceptible resins tend to form #layers between adjacent powder particles,
This is the most suitable resin for the present invention.

回路用基板り絶縁体層に使用する場合は、極性基が少な
く比誘電率及び誘電正接が低いポリオレフィン樹脂が良
く、例えはポリエチレン、ポリプロピレン成るいはそσ
」架橋物、変性物、共電合物などが好ましい。
When used in the insulator layer of circuit boards, polyolefin resins with few polar groups and low dielectric constant and dielectric loss tangent are preferred, such as polyethylene, polypropylene, or σ.
''Crosslinked products, modified products, co-electric compounds, etc. are preferred.

5− 〔作用〕 本発明σJ遠赤外線照豹によると、プラスチック粉末層
の表面層のみたらず、深部までも加熱融着して十分に焼
結する。
5- [Function] According to the σJ far-infrared irradiator of the present invention, not only the surface layer of the plastic powder layer but also the deep part is heat-fused and sintered sufficiently.

又、従来の熱風加熱が加熱初期に粉末を飛散させる欠点
があるが、本発明O方法ではそσ〕様なことなく融着す
る0したがって、本発明り実施例に示すように先ず遠赤
外線照射をし、次いで熱風加熱をすると、深部まで焼結
しかつ焼結Dライン速度を早くすることができる。
In addition, conventional hot air heating has the disadvantage of scattering the powder at the initial stage of heating, but the method of the present invention fuses the powder without such a problem.Therefore, as shown in the embodiments of the present invention, far infrared irradiation is first performed. If this is followed by hot air heating, it is possible to sinter deeply and increase the sintering D-line speed.

〔実施例〕 本発明実施例の装置例を第1図に示す0遠赤外線ヒータ
1食設けた加熱シー72に隣接して、熱風供給ダクト3
を設けた熱風ゾーン4、さらに隣接して冷風ダクト5會
設けた冷却ゾーン6があるO水平に動く搬送ベル)8に
、プラスチック粉末供給装置7でプラスチック粉末が供
給され、加熱シー72で水平に配列したヒータ1から散
剤する遠赤外線0照剖を受けて加熱され、次いで熱j虱
ゾーン4で熱風を受け、さらに冷却ゾーン6で冷風を6
− 受は冷却さnる〇 すなわち、こυ装置は遠赤外線加熱と熱風吹きつけとを
併用する構造である。本実施例O併用桐造で実施する時
、焼結0初期段階における粉末り飛散は全くない。かつ
、併用で運転するときは。
[Embodiment] An example of an apparatus according to an embodiment of the present invention is shown in FIG.
Plastic powder is supplied by a plastic powder supply device 7 to a horizontally moving conveyor belt 8, which has a hot air zone 4 with a hot air zone 4 and a cooling zone 6 with an adjacent cold air duct 5, and is horizontally moved by a heating seam 72. It is heated by receiving far infrared radiation from the arrayed heaters 1, then receives hot air in the heat zone 4, and then receives cold air in the cooling zone 6.
- The receiver is cooled. In other words, this device uses both far-infrared heating and hot air blowing. When this Example O is used in combination with paulownia wood, there is no powder scattering at the initial stage of sintering. And when driving in combination.

同じ見掛は比重とするとして、遠赤外線加熱又は熱風加
熱り何れか単独に比べて2倍σ〕ライン速度で良い。
Assuming the same appearance and specific gravity, the line speed may be twice that of far-infrared heating or hot air heating alone.

(比較試験)第1図の装置によって、遠赤外線加熱ゾー
ン2と冷却ゾーン6を便用する場合と、熱風加熱シー7
4と冷却シー76とを使用する試験を行なって、同じ見
掛は比重σ〕プラスチック粉末焼結体を昨成し、そ0引
裂き強さを測定した0そO結果を表IVC,示す。プラ
スチック粉末には、ポリオレフィンパウダー(ハイゼッ
クスミリオン240M、三井石油化学)を使用し、見掛
は比重り調整はライン速度を変えて行なった0 表 〔発明σつ効果〕 衣・1に示すように、遠赤外t31によると、焼結多孔
質シートσ」見掛は比Mは熱風式と同じであっても、引
裂き強さは熱風加熱に比べて約2倍℃ある○すたわち、
遠赤外樹で照剰すると、熱風加熱より深い層まで加熱し
て粉末粒千金半溶融結合することにμる。
(Comparative test) Using the device shown in Figure 1, there is a case where the far infrared heating zone 2 and a cooling zone 6 are conveniently used, and a case where the hot air heating zone 7 is used conveniently.
4 and a cooling seam 76, a plastic powder sintered body having the same apparent specific gravity σ was formed, and its tear strength was measured. Table IVC shows the results. Polyolefin powder (Hyzex Million 240M, Mitsui Petrochemicals) was used as the plastic powder, and the apparent specific gravity was adjusted by changing the line speed. According to far-infrared t31, even though the apparent ratio M of the sintered porous sheet σ is the same as that of the hot air method, the tear strength is approximately twice that of the hot air method.
Excessive irradiation with far-infrared rays heats the layer deeper than hot air heating, resulting in semi-molten bonding of powder grains.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明σノ実施例である。 1・・・・・・遠赤外線加熱パネル型ヒータ、2・・・
・・・遠赤外線加熱ゾーン、 3・・・・・・熱風供給ダクト、 4・・・・・・熱風加熱ゾーン、 5°°°°°゛冷風ダクト、 6・・・・・・冷却ゾーン、 7・・・・・・粉末供給装置。 8・・・・・・搬送用ベルト。 9−
FIG. 1 shows an embodiment of the present invention. 1...Far-infrared heating panel type heater, 2...
...Far-infrared heating zone, 3...Hot air supply duct, 4...Hot air heating zone, 5°°°°°゛Cold air duct, 6... Cooling zone, 7...Powder supply device. 8... Conveyance belt. 9-

Claims (1)

【特許請求の範囲】[Claims] 1、シート状基材上に薄い層を形成したプラスチック粉
末を遠赤外線で照射加熱することを特徴とするプラスチ
ック粉末焼結多孔質体シートの製造方法。
1. A method for producing a porous sintered plastic powder sheet, which comprises heating the plastic powder formed in a thin layer on a sheet-like base material by irradiating it with far infrared rays.
JP32648989A 1989-12-15 1989-12-15 Manufacture of porous body sheet formed of sintered plastic powder Pending JPH03184831A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP32648989A JPH03184831A (en) 1989-12-15 1989-12-15 Manufacture of porous body sheet formed of sintered plastic powder

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP32648989A JPH03184831A (en) 1989-12-15 1989-12-15 Manufacture of porous body sheet formed of sintered plastic powder

Publications (1)

Publication Number Publication Date
JPH03184831A true JPH03184831A (en) 1991-08-12

Family

ID=18188395

Family Applications (1)

Application Number Title Priority Date Filing Date
JP32648989A Pending JPH03184831A (en) 1989-12-15 1989-12-15 Manufacture of porous body sheet formed of sintered plastic powder

Country Status (1)

Country Link
JP (1) JPH03184831A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2422344A (en) * 2005-01-24 2006-07-26 Univ Montfort Rapid prototyping using infrared sintering

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2422344A (en) * 2005-01-24 2006-07-26 Univ Montfort Rapid prototyping using infrared sintering
GB2422344B (en) * 2005-01-24 2008-08-20 Univ Montfort Rapid prototyping method using infrared sintering

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