JPH03183744A - Ferrous sintered sliding material - Google Patents

Ferrous sintered sliding material

Info

Publication number
JPH03183744A
JPH03183744A JP32221189A JP32221189A JPH03183744A JP H03183744 A JPH03183744 A JP H03183744A JP 32221189 A JP32221189 A JP 32221189A JP 32221189 A JP32221189 A JP 32221189A JP H03183744 A JPH03183744 A JP H03183744A
Authority
JP
Japan
Prior art keywords
sliding
iron
sliding material
based sintered
abrasive components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP32221189A
Other languages
Japanese (ja)
Other versions
JP2805923B2 (en
Inventor
Kazuhide Inohara
猪原 一英
Takemori Takayama
武盛 高山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Komatsu Ltd
Original Assignee
Komatsu Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Komatsu Ltd filed Critical Komatsu Ltd
Priority to JP1322211A priority Critical patent/JP2805923B2/en
Publication of JPH03183744A publication Critical patent/JPH03183744A/en
Application granted granted Critical
Publication of JP2805923B2 publication Critical patent/JP2805923B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Abstract

PURPOSE:To provide the sliding material with high wear resistance and excellent seizing resistance under high speed sliding by incorporating specified amounts of abrasive components into an Fe-C-Cu-P series material. CONSTITUTION:The compsn. of the ferrous sintered sliding material is formed of, by weight, 0.2 to 2% C, 0.5 to 20% Cu, 0.05 to 2% P, 0.1 to 10% abrasive components and the balance essential Fe. As the abrasive components, at least one kind of metallic oxides among SiO2, Al2O3 and mullite is used. By incorporating the abrasive components, stuck matters onto a mating member are scraped away, by which the seizing resistance of the ferrous sintered material can be improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、高速摺動性に冨む鉄系焼結部材に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to an iron-based sintered member that is rich in high-speed sliding properties.

〔従来の技術〕[Conventional technology]

油潤滑下での高速摺動においては、高い耐摩耗性と優れ
た耐焼付性が要求される。例えば油圧部品の高速摺動部
にはLBA、P31C等の青銅系または高力黄銅系の溶
製部材または焼結部材が使用されている。また負荷が余
り大きくない部位に用いられる摺動材では、Fe−Cu
−3n系の焼結材や、この種の焼結材に塩浴軟窒化処理
または浸硫窒化処理を施したものが用いられている。
High-speed sliding under oil lubrication requires high wear resistance and excellent seizure resistance. For example, bronze-based or high-strength brass-based melted or sintered members such as LBA and P31C are used in high-speed sliding parts of hydraulic parts. In addition, for sliding materials used in areas where the load is not very large, Fe-Cu
-3n-based sintered materials and materials obtained by subjecting this type of sintered material to salt bath nitrocarburizing treatment or sulphonitriding treatment are used.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

前記のような銅系の摺動材は、その摺動特性、特に耐焼
付性に優れているが材料が高価であり、さらに油圧部品
等では鋳込みや接合法等の複雑な工程を用いるため部品
コストが一層高くなる。
The above-mentioned copper-based sliding materials have excellent sliding properties, especially seizure resistance, but they are expensive materials, and in addition, hydraulic parts require complicated processes such as casting and bonding, so parts cannot be manufactured easily. The cost will be even higher.

焼結により得られる摺動材はFe5Fe−C。The sliding material obtained by sintering is Fe5Fe-C.

Fe−Cu、Fe−Cu−C番茶が用いられ、価格的に
有利で、高い耐摩耗性を有しているが、鉄系の相手部材
に移着し易く耐焼付性に劣るという問題点がある。さら
に鉄系焼結材に軟窒化処理または浸硫窒化処理等を施し
ても、その生成硬質皮膜は厚さが3〜15−と薄くて耐
摩耗寿命が短く、処理工程が増える割には利得が少いと
いう問題点もある。
Fe-Cu and Fe-Cu-C bancha are used and are advantageous in price and have high wear resistance, but they have the problem that they tend to transfer to iron-based mating parts and have poor seizure resistance. be. Furthermore, even if iron-based sintered materials are subjected to soft nitriding or sulfonitriding, the resulting hard coating is as thin as 3 to 15-15 mm and has a short wear-resistant life. There is also the problem that there are few.

本発明は、前述した問題点の解消を目的とし、銅系摺動
材より廉価な鉄系摺動材でありながら、鉄系の相手部材
に焼付くことを防止することにより、高い耐摩耗性と優
れた耐焼付性を持たせた鉄系焼結摺動材を提供するもの
である。
The present invention aims to solve the above-mentioned problems, and although it is an iron-based sliding material that is cheaper than copper-based sliding materials, it has high wear resistance by preventing seizing on iron-based mating members. The present invention provides an iron-based sintered sliding material with excellent seizure resistance.

〔課題を解決するための手段] 前述した目的を遠戚するため、本発明は、Cが0.2〜
2wt%、Cuが0.5〜20wt%、Pが0.05〜
2wt%、研摩材成分が001〜10wt%、残部が主
としてFeの組成成分を有する、 ことを特徴とする鉄系焼結摺動材となっている。
[Means for Solving the Problems] In order to achieve the above-mentioned object, the present invention provides a method in which C is 0.2 to 0.2.
2wt%, Cu 0.5~20wt%, P 0.05~
The iron-based sintered sliding material is characterized by having an abrasive component of 0.2 wt%, an abrasive component of 0.001 to 10 wt.%, and the remainder mainly consisting of Fe.

C作 用〕 本発明の鉄系焼結摺動材は、その&Il威成分中に研摩
材成分を有している。
C Effect] The iron-based sintered sliding material of the present invention has an abrasive component in its abrasive component.

一方、通常の鉄系焼結摺動材は負荷の下に使用されてい
るときには鉄系の相手部材に移着し、この移着層の生成
により焼付く。
On the other hand, when a normal iron-based sintered sliding material is used under load, it transfers to an iron-based mating member and seizes due to the formation of this transfer layer.

本発明の鉄系焼結摺動材中の研摩材成分は、前記負荷の
下で使用されたときに鉄系の相手部材へ移着した移着物
を常にこすり取り、焼付きの原因となる移着物を相手部
材面に生成させない。従って、相手部材への焼付きが抑
止され、同時に組成成分中のCuは前記研摩側成分との
濡れ性がよいことからFe相との結合を強固となし、研
摩剤成分の剥落が防止される。
The abrasive component in the iron-based sintered sliding material of the present invention constantly scrapes off the transferred substances that have migrated to the iron-based mating member when used under the above-mentioned load, and the abrasive component that causes seizure. Do not generate kimono on the other member's surface. Therefore, seizure to the mating member is suppressed, and at the same time, since Cu in the composition has good wettability with the abrasive side component, it forms a strong bond with the Fe phase and prevents the abrasive component from peeling off. .

〔発明の効果〕〔Effect of the invention〕

したがって、本発明の鉄系焼結摺動材は、材料費が安価
で比較的低度な製造コストで得られるにも拘らず、高速
摺動下においても高い耐摩耗性と優れた耐焼付性が得ら
れ、生産性の向上が図れる。
Therefore, the iron-based sintered sliding material of the present invention has high wear resistance and excellent seizure resistance even under high-speed sliding, even though the material cost is low and the manufacturing cost is relatively low. can be obtained, and productivity can be improved.

〔実施例〕〔Example〕

次に本発明の具体的な一実施例につき図面を参照しつつ
説明する。
Next, a specific embodiment of the present invention will be described with reference to the drawings.

本発明の鉄系焼結摺動材における高い耐摩耗性と優れた
耐焼付性は、主成分であるFe以外の各組成成分を、そ
れら各組成成分が最も効率よく挙動することができる範
囲に定められることにより得られる。
The high wear resistance and excellent seizure resistance of the iron-based sintered sliding material of the present invention are achieved by controlling the composition components other than Fe, the main component, within the range where each composition component can behave most efficiently. Obtained by being determined.

Cについては、CはFeに固溶し強度を増加するととも
に、FeのCuに対する濡れ性を低下させて含Cu系焼
結体の収縮を抑制し寸法制御を容易にする作用がある。
Regarding C, C dissolves in Fe and increases the strength, and also reduces the wettability of Fe to Cu, suppresses shrinkage of the Cu-containing sintered body, and facilitates dimensional control.

その量が0.2wt%未満ではその効果が得られず、逆
に2wt%を超えると焼付性が低下しそれに伴って強度
が低下するので、Cの含有量は0.2〜2wt%とした
If the amount is less than 0.2 wt%, the effect cannot be obtained, and on the other hand, if it exceeds 2 wt%, the seizability and strength will decrease accordingly, so the content of C was set at 0.2 to 2 wt%. .

Cuについては、CuはCとともにFeに固溶してこれ
を強化し、合金の強度および耐摩耗性を向上させ、さら
に研摩材成分としての金属酸化物との濡れ性がよくこれ
とFe相との結合を強固にし、摺動状態下で前記金属酸
化物等の硬質分散粒子が容易に脱落することを防止する
作用がある。その量が0.5wt%未満では強度および
耐摩耗性が不足し、逆に20−t%を超えると系全体の
素地が軟質化して耐摩耗性が劣化するので、Coの含有
量は0.5〜20wt%とした。
Regarding Cu, Cu is dissolved in Fe together with C to strengthen it and improve the strength and wear resistance of the alloy. Furthermore, it has good wettability with metal oxides as abrasive components, and is compatible with Fe phase. This has the effect of strengthening the bond between the two and preventing the hard dispersed particles such as the metal oxide from falling off easily under sliding conditions. If the amount is less than 0.5 wt%, the strength and wear resistance will be insufficient, and if it exceeds 20-t%, the base of the entire system will become soft and the wear resistance will deteriorate. The content was set at 5 to 20 wt%.

Pについては、Pは焼結を活性化してCおよびCuのF
e相への固溶拡散を促進し、P共晶の析出により焼結体
の高密度化および耐摩耗性の向上に寄与する。その量が
0.05wt%未満ではその効果が得られず、逆に2w
t%を超すと強度を低下させるので、Pの含有量は0.
05〜2wt%とした。
Regarding P, P activates sintering and F of C and Cu.
It promotes solid solution diffusion into the e-phase and contributes to increasing the density and improving the wear resistance of the sintered body through the precipitation of P eutectic. If the amount is less than 0.05wt%, the effect cannot be obtained;
If it exceeds t%, the strength will decrease, so the content of P should be 0.
05 to 2 wt%.

研摩材成分については、例えばSiO2、A 1 * 
Os、ムライトに代表されるようなアルミノケイ酸塩鉱
物またはスピネル等の金属酸化物が用いられる。
Regarding abrasive components, for example, SiO2, A 1 *
Aluminosilicate minerals such as Os, mullite, or metal oxides such as spinel are used.

前記のようにFe、、Fe −C,、Fe −Cu、、
Fe−Cu−C系焼結材は鉄系相手部材に移着し、これ
が原因となって焼付くが、この研摩剤成分を含有させる
ことにより、相手部材への移着物をこすり取り、鉄系焼
結材の耐焼付性を向上させる。金属酸化物の含有量は0
.1wt%未満ではその効果がなく、逆に10−t%を
超すと相手部材を損耗させるからその含有量は0.1〜
10wt%、好ましくは0.5〜1wt%とした。
As mentioned above, Fe, , Fe -C, , Fe -Cu, ,
The Fe-Cu-C based sintered material transfers to the iron-based mating member and causes seizing, but by containing this abrasive component, the transferred material on the mating member is scraped off, and the iron-based mating material is Improves the seizure resistance of sintered materials. Metal oxide content is 0
.. If it is less than 1wt%, it has no effect, and if it exceeds 10-t%, it will damage the mating member, so the content should be 0.1~
The content was 10 wt%, preferably 0.5 to 1 wt%.

以上のように策定した各組成成分にもとづく本発明の鉄
系焼結摺動材として、ブルドーザやパワーショベルの差
動遊星終減速機構に用いられるスラストリングについて
の実施例を示す。このスラストリングlは第1図に示さ
れるように表裏関係に2つの摺動面2および2”を有す
るリング体となっている。
An example of a thrust ring used in a differential planetary final reduction mechanism of a bulldozer or a power shovel will be shown as an iron-based sintered sliding material of the present invention based on each composition formulated as described above. As shown in FIG. 1, this thrust ring 1 is a ring body having two sliding surfaces 2 and 2'' on the front and back sides.

このスラストリング1は、粉末度が100メッシュ(1
49zm)以下の鉄粉、黒鉛、200メツシユ(75−
)以下の電解銅粉、250メツシユ(62n)以下の燐
鉄粉(P〜27wt%、Fe〜残部)および5〜10、
mのハイシリカ(以上いずれも市販品)を、C: 0.
8ivt%    Cu:4wt%P : 0.4wt
%    5i02 : 0.5wt%Fe:残部 とした混合粉に0.5wt%のステアリン酸亜鉛を外掛
けで加えて充分に混合した後、成形圧5T/cm”で圧
粉成形し、第1図に示されるように成形した後、還元雰
囲気が保たれるAX炉で1150°C11時間の焼結を
行って得られたものである。
This thrust ring 1 has a fineness of 100 mesh (1
49zm) or less iron powder, graphite, 200 mesh (75-
) or less electrolytic copper powder, 250 mesh (62n) or less phosphorous iron powder (P ~ 27 wt%, Fe ~ balance) and 5 to 10,
m high silica (all of the above are commercially available products), C: 0.
8ivt% Cu: 4wt%P: 0.4wt
% 5i02: 0.5 wt% Fe: After adding 0.5 wt% zinc stearate to the remaining mixed powder and mixing thoroughly, it was compacted at a molding pressure of 5 T/cm'', as shown in Figure 1. After molding as shown in Figure 1, it was sintered at 1150°C for 11 hours in an AX furnace in which a reducing atmosphere was maintained.

このようなii1′liとされた本発明の鉄系焼結摺動
材は、高耐摩耗性を有するとともに優れた耐焼付性を示
し、その摺動特性を表わすPV値は第2図に示されるよ
うに、高価な溶製材であるリン青銅または高力黄銅に劣
るが、他の在来の鉄系焼結摺動材に比べて優れた特性を
有し、Cu系焼結摺動材と殆んど変らない摺動特性が得
られた。
The iron-based sintered sliding material of the present invention with such ii1'li exhibits high wear resistance and excellent seizure resistance, and the PV value representing its sliding characteristics is shown in Figure 2. Although it is inferior to phosphor bronze or high-strength brass, which are expensive melted materials, it has superior properties compared to other conventional iron-based sintered sliding materials, and is comparable to Cu-based sintered sliding materials. Almost unchanged sliding characteristics were obtained.

前記PV値は、摺動材が相手部材にP(kg/c+a”
)の圧力で圧接されるとともに摺動材と相手部材とが相
互にV (s/S)の速度で摺動関係にある場合に、摺
動材が相手部材に焼付く状態となった時のPとVの相乗
値でこの値が高い程摺動性が優れている。
The above-mentioned PV value means that the sliding material is P(kg/c+a") relative to the mating member.
), and the sliding material and the mating member are in a sliding relationship with each other at a speed of V (s/S), and the sliding material seizes to the mating member. The higher the synergistic value of P and V, the better the sliding properties.

この実施例における摺動材では、相手部材が10m1s
の速度で定速回転している面に、本発明の鉄系焼結摺動
材より切りだしたテストピースを圧接し、その圧力を増
大していって両者が焼付く圧力の時を終点として、PV
値を求めたものである。
In the sliding material in this example, the mating member is 10m1s
A test piece cut from the iron-based sintered sliding material of the present invention is pressed against a surface rotating at a constant speed of , P.V.
The value was calculated.

また、このPV値の測定試験中における本発明摺動材が
相手部材面に擦過痕を生じさせる傾向(いわゆるかじり
性)も検査した。結果は、Cu系焼結材のかじり性と殆
んど変らず相手部材に与える影響も少く、摺動性がよく
優れた耐焼付性を有することが確認された。
Furthermore, during this PV value measurement test, the tendency of the sliding material of the present invention to cause scratch marks on the surface of the mating member (so-called galling property) was also examined. The results showed that the galling property was almost the same as that of the Cu-based sintered material, the effect on the mating member was small, and it was confirmed that the material had good sliding properties and excellent seizure resistance.

さらに、この実施例における鉄系焼結摺動材であるスラ
ストリングを実体差動遊星終減速機構に用いて1000
時間連続運転テストを行った。結果は第1表に示すよう
に優れた耐摩耗性を有することが確認された。
Furthermore, the thrust ring, which is an iron-based sintered sliding material in this embodiment, is used in a real differential planetary final reduction mechanism to
A continuous driving test was conducted. As shown in Table 1, it was confirmed that the material had excellent wear resistance.

第1表 1000時間連続運転テストの結果Table 1 Results of 1000 hours continuous operation test

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例であるスラストリングの斜視
図および 第2図は各材質の摺動材のPV値を示すグラフである。 ( 第2図
FIG. 1 is a perspective view of a thrust ring according to an embodiment of the present invention, and FIG. 2 is a graph showing the PV value of each sliding material. (Figure 2

Claims (1)

【特許請求の範囲】 1 Cが0.2〜2wt%、Cuが0.5〜20wt%
、Pが0.05〜2wt%、研摩材成分が0.1〜10
wt%、残部が主としてFeの組成成分を有する鉄系焼
結摺動材。 2 SiO_2、Al_2O_3、ムライトを含む金属
酸化物の少くとも一種が前記研摩材成分として用いられ
る請求項1に記載の鉄系焼結摺動材。
[Claims] 1 C: 0.2 to 2 wt%, Cu: 0.5 to 20 wt%
, P is 0.05-2wt%, abrasive component is 0.1-10
Iron-based sintered sliding material having a compositional component of wt%, the balance being mainly Fe. 2. The iron-based sintered sliding material according to claim 1, wherein at least one kind of metal oxide including 2 SiO_2, Al_2O_3, and mullite is used as the abrasive component.
JP1322211A 1989-12-11 1989-12-11 Iron-based sintered sliding material Expired - Lifetime JP2805923B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1322211A JP2805923B2 (en) 1989-12-11 1989-12-11 Iron-based sintered sliding material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1322211A JP2805923B2 (en) 1989-12-11 1989-12-11 Iron-based sintered sliding material

Publications (2)

Publication Number Publication Date
JPH03183744A true JPH03183744A (en) 1991-08-09
JP2805923B2 JP2805923B2 (en) 1998-09-30

Family

ID=18141198

Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
JP (1) JP2805923B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7094473B2 (en) 2002-12-27 2006-08-22 Komatsu Ltd. Wear-resistant sintered contact material, wear-resistant sintered composite contact component and method of producing the same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS556490A (en) * 1978-06-29 1980-01-17 Bleistahl Gmbh Material for producing high abrasion resistant products in powder metallurgy
JPS55145151A (en) * 1979-04-26 1980-11-12 Nippon Piston Ring Co Ltd Wear resistant sintered alloy material for internal combustion engine
JPS5770262A (en) * 1980-10-18 1982-04-30 Tsubakimoto Chain Co Wear resistant sintered oilless bearing
JPS58224138A (en) * 1982-06-24 1983-12-26 Teikoku Carbon Kogyo Kk Manufacture of sintered material for collector for traveling in low-speed region
JPS62271913A (en) * 1986-04-11 1987-11-26 Nippon Piston Ring Co Ltd Builtup cam shaft

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS556490A (en) * 1978-06-29 1980-01-17 Bleistahl Gmbh Material for producing high abrasion resistant products in powder metallurgy
JPS55145151A (en) * 1979-04-26 1980-11-12 Nippon Piston Ring Co Ltd Wear resistant sintered alloy material for internal combustion engine
JPS5770262A (en) * 1980-10-18 1982-04-30 Tsubakimoto Chain Co Wear resistant sintered oilless bearing
JPS58224138A (en) * 1982-06-24 1983-12-26 Teikoku Carbon Kogyo Kk Manufacture of sintered material for collector for traveling in low-speed region
JPS62271913A (en) * 1986-04-11 1987-11-26 Nippon Piston Ring Co Ltd Builtup cam shaft

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7094473B2 (en) 2002-12-27 2006-08-22 Komatsu Ltd. Wear-resistant sintered contact material, wear-resistant sintered composite contact component and method of producing the same
US7279228B2 (en) 2002-12-27 2007-10-09 Komatsu Ltd. Wear-resistant sintered contact material, wear-resistant sintered composite contact component and method of producing the same
US7282078B2 (en) 2002-12-27 2007-10-16 Komatsu Ltd. Wear-resistant sintered contact material, wear-resistant sintered composite contact component and method of producing the same
US7473296B2 (en) 2002-12-27 2009-01-06 Komatsu, Ltd. Wear-resistant sintered contact material, wear-resistant sintered composite contact component and method of producing the same

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Publication number Publication date
JP2805923B2 (en) 1998-09-30

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