JPH03173836A - Fluorinated hydrocarbon-based azeotropic and azeotropy-like composition - Google Patents
Fluorinated hydrocarbon-based azeotropic and azeotropy-like compositionInfo
- Publication number
- JPH03173836A JPH03173836A JP1310736A JP31073689A JPH03173836A JP H03173836 A JPH03173836 A JP H03173836A JP 1310736 A JP1310736 A JP 1310736A JP 31073689 A JP31073689 A JP 31073689A JP H03173836 A JPH03173836 A JP H03173836A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- composition
- difluoroethane
- nitromethane
- trichloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 57
- 150000002430 hydrocarbons Chemical class 0.000 title description 4
- 229930195733 hydrocarbon Natural products 0.000 title description 3
- 239000004215 Carbon black (E152) Substances 0.000 title description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 36
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims abstract description 36
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims abstract description 35
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims abstract description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 27
- FQAMAOOEZDRHHB-UHFFFAOYSA-N 1,2,2-trichloro-1,1-difluoroethane Chemical compound FC(F)(Cl)C(Cl)Cl FQAMAOOEZDRHHB-UHFFFAOYSA-N 0.000 claims abstract description 24
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 claims abstract description 13
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 2
- 238000004064 recycling Methods 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 description 10
- -1 CFCs R11 Chemical class 0.000 description 7
- 238000004140 cleaning Methods 0.000 description 7
- 230000004907 flux Effects 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- 239000010721 machine oil Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 2
- INEMUVRCEAELBK-UHFFFAOYSA-N 1,1,1,2-tetrafluoropropane Chemical compound CC(F)C(F)(F)F INEMUVRCEAELBK-UHFFFAOYSA-N 0.000 description 1
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 1
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 description 1
- OXHNLMTVIGZXSG-UHFFFAOYSA-N 1-Methylpyrrole Chemical compound CN1C=CC=C1 OXHNLMTVIGZXSG-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- QWQNFXDYOCUEER-UHFFFAOYSA-N 2,3-ditert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1C(C)(C)C QWQNFXDYOCUEER-UHFFFAOYSA-N 0.000 description 1
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- CEBKHWWANWSNTI-UHFFFAOYSA-N 2-methylbut-3-yn-2-ol Chemical compound CC(C)(O)C#C CEBKHWWANWSNTI-UHFFFAOYSA-N 0.000 description 1
- JHUUPUMBZGWODW-UHFFFAOYSA-N 3,6-dihydro-1,2-dioxine Chemical compound C1OOCC=C1 JHUUPUMBZGWODW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- RIWRFSMVIUAEBX-UHFFFAOYSA-N n-methyl-1-phenylmethanamine Chemical compound CNCC1=CC=CC=C1 RIWRFSMVIUAEBX-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- XTTGYFREQJCEML-UHFFFAOYSA-N tributyl phosphite Chemical compound CCCCOP(OCCCC)OCCCC XTTGYFREQJCEML-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
- C07C19/10—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine
- C07C19/12—Acyclic saturated compounds containing halogen atoms containing fluorine and chlorine having two carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Manufacturing Of Printed Wiring (AREA)
- Cleaning Or Drying Semiconductors (AREA)
- Extraction Or Liquid Replacement (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規な弗素化炭化水素系共沸
および共沸様組成物に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a novel fluorinated hydrocarbon azeotropic and azeotrope-like composition that can be used as a CFC substitute and has excellent properties as a solvent. be.
［従来の技術］
弗素化炭化水素系化合物（以下単にフロンという）は、
毒性が少なく化学的に安定なものが多く、標準沸点の異
なる各種フロンが入手できることから、これらの特性を
活かして溶剤、発泡剤、プロペラントあるいは冷媒とし
て１．１．２−トリクロロ−１，２，２−トリフロロエ
タン（Ｒ１１３）が、発泡剤としてトリクロロモノフロ
ロメタン（Ｒ１１）が、プロペラントや冷媒としてジク
ロロジフロロメタン（Ｒ１２）が使われている。[Prior art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are
Many of them are less toxic and chemically stable, and various types of chlorofluorocarbons with different standard boiling points are available.Using these properties, 1.1.2-trichloro-1,2-trichloro-1,2 can be used as a solvent, blowing agent, propellant or refrigerant. , 2-trifluoroethane (R113), trichloromonofluoromethane (R11) as a blowing agent, and dichlorodifluoromethane (R12) as a propellant or refrigerant.
［発明が解決しようとする課題］
化学的に特に安定なフロンＲ１１，Ｒ１２，Ｒ１１３等
の完全ハロゲン化炭化水素は成層圏に達した際に太陽光
線により分解発生する塩素ラジカルがオゾンと連鎖反応
を起こし、オゾン層を破壊するとの事から、これら特定
フロンの生産量規制が実施されることとなった。このた
め、これらの従来のフロンに代わり、オゾン層を破壊し
にくい代替物質の探索が活発に行なわれている。[Problems to be solved by the invention] When fully halogenated hydrocarbons such as CFCs R11, R12, and R113, which are particularly chemically stable, reach the stratosphere, chlorine radicals decomposed by sunlight cause a chain reaction with ozone. Since these substances are believed to destroy the ozone layer, regulations have been implemented on the production of these specific fluorocarbons. Therefore, in place of these conventional fluorocarbons, there is active search for alternative substances that are less likely to deplete the ozone layer.
本発明は、従来のフロンの使用量を低減し、かつ該物質
が有している優れた特性を満足しながら代替物質として
使用できる新規なフロン組成物を提供することを目的と
するものである。An object of the present invention is to provide a new fluorocarbon composition that can be used as a substitute material while reducing the amount of conventional fluorocarbons used and satisfying the excellent properties of the material. .
［課題を解決するための手段］
本発明は、メタノール、エタノール、１−プロパノール
、２−プロパノール、Ｔｅｒ−ブタノールのいずれか一
種および１’、１．２−）−ジクロロ−２，２−ジフロ
ロエタン、ニトロメタンとからなる共沸および共沸様組
成物に関するものである。[Means for Solving the Problems] The present invention provides any one of methanol, ethanol, 1-propanol, 2-propanol, and Ter-butanol, and 1', 1,2-)-dichloro-2,2-difluoroethane, azeotrope and azeotrope-like compositions consisting of nitromethane.
本発明の組成物は、共沸組成が存在する上、洗浄溶剤と
しては従来のＲ１１３単体より洗浄力が高いため、８１
１３代替として極めて有用なものである。また、近年地
下水汚染やオゾン層破壊等環境破壊の点より使用規制の
唱われている１、１゜１−トリクロロエタン代替として
もきわめて有用である。更に、リサイクルしても組成変
動が少ないこと、また従来の単一フロン同様の使用方法
が可能であり従来技術の大幅な変更を要しない等の利点
を有している。The composition of the present invention has an azeotropic composition and, as a cleaning solvent, has higher cleaning power than conventional R113 alone.
It is extremely useful as a substitute for No. 13. It is also extremely useful as a substitute for 1,1°1-trichloroethane, whose use has been regulated in recent years due to environmental damage such as groundwater contamination and ozone layer destruction. Furthermore, it has the advantage that there is little change in composition even after recycling, and that it can be used in the same manner as conventional single fluorocarbons, and does not require major changes in conventional technology.
本発明における組成物の１．１．２− ）−リクロロー
２．２−ジフロロエタン、メタノールおよびニトロメタ
ンの混合比は１，１．２−トリクロロ−２，２−ジフロ
ロエタン６０〜９９．９重量％、メタノール０．１〜４
０重量％およびニトロメタン０．１〜５．０重量％が好
ましい。また、実用時における組成変化等による組成物
の性状変化を防止するためには、１，１．２−トリクロ
ロ−２，２−ジフロロエタン７７．８〜９９．８重量％
、メタノール０．１〜２２．０重量％およびニトロメタ
ン０．１−１．９重量％の本発明共沸様組成が好ましく
、更に好ましくは１．１．２−）−リクロロー２．２−
ジフロロエタン８３．４重量％、メタノール１６．２重
量％およびニトロメタン０．４重量％である本発明の共
沸組成である。The mixing ratio of 1.1.2-)-lichloro-2,2-difluoroethane, methanol and nitromethane in the composition of the present invention is 60 to 99.9% by weight of 1,1.2-trichloro-2,2-difluoroethane, methanol 0.1-4
0% by weight and 0.1-5.0% by weight of nitromethane are preferred. In addition, in order to prevent changes in the properties of the composition due to changes in composition during practical use, 77.8 to 99.8% by weight of 1,1,2-trichloro-2,2-difluoroethane should be added.
, methanol 0.1-22.0% by weight and nitromethane 0.1-1.9% by weight azeotrope-like compositions of the present invention are preferred, more preferably 1.1.2-)-lichloro2.2-
The azeotropic composition of the present invention is 83.4% by weight difluoroethane, 16.2% by weight methanol and 0.4% by weight nitromethane.
本発明における組成物の１．１．２−トリクロロ−２，
２−ジフロロエタン、エタノールおよびニトロメタンの
混合比は１，１．２−トリクロロ−２，２−ジフロロエ
タン６０〜９９．９重量％、エタノール０．１〜４０重
量％およびニトロメタン０．１〜５．０重量％が好まし
い。また、実用時における組成変化等による組成物の性
状変化を防止するためには、１，１．２−トリクロロ−
２．２−ジフロロエタン８２．８〜９９．８重量％、エ
タノール０．１〜！７．０重１％およびニトロメタン０
．１〜１．９重量％の本発明共沸様組成が好ましく、更
に好ましくは１．１．２−トリクロロ−２，２−ジフロ
ロエタン８８８５重量％、エタノール１１．０重量％お
よびニトロメタン０．５重量％である本発明の共沸組成
である。1.1.2-trichloro-2 of the composition according to the invention,
The mixing ratio of 2-difluoroethane, ethanol and nitromethane is 60-99.9% by weight of 1,1.2-trichloro-2,2-difluoroethane, 0.1-40% by weight of ethanol and 0.1-5.0% by weight of nitromethane. % is preferred. In addition, in order to prevent changes in the properties of the composition due to changes in composition during practical use, 1,1,2-trichloro-
2.2-difluoroethane 82.8~99.8% by weight, ethanol 0.1~! 7.0wt 1% and nitromethane 0
．． An azeotrope-like composition of the present invention of 1 to 1.9% by weight is preferred, more preferably 8885% by weight of 1.1.2-trichloro-2,2-difluoroethane, 11.0% by weight of ethanol and 0.5% by weight of nitromethane. This is the azeotropic composition of the present invention.
本発明における組成物の１．１．２− ）リクロロー２
．２−ジフロロエタン、１−プロパノールおよびニトロ
メタンの混合比は１，１．２−トリクロロ−２，２−ジ
フロロエタン６０〜９９．９重量％、１−プロパノール
０．１〜４０重量％およびニトロメタン０．１〜５．０
重量％が好ましい。また、実用時における組成変化等に
よる組成物の性状変化を防止するためには、１，１．２
−トリクロロ−２，２−ジフロロエタン８７．８〜９９
．８重量％、１−プロパノール０．１〜１２．０重量％
およびニトロメタン０．１〜１．９重量％の本発明共沸
様組成が好ましく、更に好ましくは１，１．２−トリク
ロロ−２，２−ジフロロエタン９７．０重量％、１−プ
ロパノール２．０重量％およびニトロメタン１．０重量
％である本発明の共沸組成である。1.1.2-) of the composition according to the present invention
．． The mixing ratio of 2-difluoroethane, 1-propanol, and nitromethane is 60 to 99.9% by weight of 1,1.2-trichloro-2,2-difluoroethane, 0.1 to 40% by weight of 1-propanol, and 0.1 to 0.1 to nitromethane. 5.0
Weight percent is preferred. In addition, in order to prevent changes in the properties of the composition due to changes in composition during practical use, 1, 1.2
-Trichloro-2,2-difluoroethane 87.8-99
．． 8% by weight, 1-propanol 0.1-12.0% by weight
and nitromethane 0.1 to 1.9% by weight, the azeotrope-like composition of the present invention is preferred, more preferably 97.0% by weight 1,1.2-trichloro-2,2-difluoroethane, 2.0% by weight 1-propanol. % and 1.0% by weight of nitromethane.
本発明における組成物の１．１．２−トリクロロ−２，
２−ジフロロエタン、２−プロパノールおよびニトロメ
タンの混合比は１，１．２−トリクロロ−２，２−ジフ
ロロエタン６０〜９９．９重量％、２−プロパノール０
．１〜４０重量％およびニトロメタン０．１〜５．０重
量％が好ましい。また、実用時における組成変化等によ
る組成物の性状変化を防止するためには、１，１．２−
）−リクロロー２．２−ジフロロエタン８２．８〜９９
．８重量％、２−プロパノール０．１〜１７．０重量％
およびニトロメタン０．１〜１．９重量％の本発明共沸
様組成が好ましく、更に好ましくは１，１．２−トリク
ロロ−２，２−ジフロロエタン９０．０重量％、２−プ
ロパノール９．１重量％およびニトロメタン０．９重量
％である本発明の共沸組成である。1.1.2-trichloro-2 of the composition according to the invention,
The mixing ratio of 2-difluoroethane, 2-propanol and nitromethane is 60 to 99.9% by weight of 1,1.2-trichloro-2,2-difluoroethane and 0% of 2-propanol.
．． 1 to 40% by weight and 0.1 to 5.0% by weight of nitromethane are preferred. In addition, in order to prevent changes in the properties of the composition due to changes in composition during practical use, 1,1.2-
)-lichloro2,2-difluoroethane 82.8-99
．． 8% by weight, 2-propanol 0.1-17.0% by weight
and nitromethane 0.1 to 1.9% by weight, an azeotrope-like composition of the present invention is preferred, more preferably 1,1,2-trichloro-2,2-difluoroethane 90.0% by weight, 2-propanol 9.1% by weight % and nitromethane 0.9% by weight.
本発明における組成物の１．１．２−トリクロロ−２，
２−ジフロロエタン、Ｔｅｒ−ブタノールおよびニトロ
メタンの混合比は１，１．２−トリクロロ−２，２−ジ
フロロエタン６０〜９９．９重量％、Ｔｅｒ−ブタノー
ル０．１〜４０重量％およびニトロメタン０．１〜５．
０重量％が好ましい。また、実用時における組成変化等
による組成物の性状変化を防止するためには、１，１．
２−トリクロロ−２，２−ジフロロエタン８７．８〜９
９．８重量％、Ｔｅｒ−ブタノール０．１〜１２．０重
量％およびニトロメタン０．１〜１．９重量％の本発明
共沸様組成が好ましく、更に好ましくは１，１．２−ト
リクロロ−２，２−ジフロロエタン９７．０重量％、Ｔ
ｅｒ−ブタノール２．０重量％およびニトロメタン１．
０重量％である本発明の共沸組成である。1.1.2-trichloro-2 of the composition according to the invention,
The mixing ratio of 2-difluoroethane, Ter-butanol and nitromethane is 60-99.9% by weight of 1,1.2-trichloro-2,2-difluoroethane, 0.1-40% by weight of Ter-butanol and 0.1-99.9% by weight of nitromethane. 5.
0% by weight is preferred. In addition, in order to prevent changes in the properties of the composition due to changes in composition during practical use, 1.1.
2-Trichloro-2,2-difluoroethane 87.8-9
The azeotrope-like composition of the invention of 9.8% by weight, 0.1-12.0% by weight of Ter-butanol and 0.1-1.9% by weight of nitromethane is preferred, more preferably 1,1,2-trichloro- 2,2-difluoroethane 97.0% by weight, T
er-butanol 2.0% by weight and nitromethane 1.
The azeotropic composition of the present invention is 0% by weight.
本共沸組成物の共沸組成比は、混合する１゜１．２−ト
リクロロ−２，２−ジフロロエタン等の純度や測定誤差
等の影響により±１．０重量％程度変動しつるものであ
る。The azeotropic composition ratio of this azeotropic composition fluctuates by about ±1.0% by weight due to the purity of the 1゜1.2-trichloro-2,2-difluoroethane, etc. to be mixed, measurement errors, etc. .
本発明の組成物には、用途に応じてその他の成分を更に
添加混合することができる。例えば、溶剤としての用途
においては、ペンタン。Other components may be further added to the composition of the present invention depending on the intended use. For example, pentane in its application as a solvent.
イソペンタン、ヘキサン、イソヘキサン、ネオヘキサン
、ヘプタン、イソへブタン、２．３−ジメチルブタン、
シクロペンタン等の炭化水素類、ニトロエタン、ニトロ
プロパン等のニトロアルカン類、フェノール、２．６−
ジーｔ−ブチル−ｐ−クレゾール等のフェノール類、ジ
エチルアミン、トリエチルアミン、イソプロピルアミン
、ジイソプロピラミン、ジアリルアミン、Ｎ−メチルベ
ンジルアミン、ブチルアミン、イソブチルアミン等のア
ミン類、メタノール、エタノール、ｎ−プロピルアルコ
ール、ｉ−プロピルアルコール。Isopentane, hexane, isohexane, neohexane, heptane, isohebutane, 2,3-dimethylbutane,
Hydrocarbons such as cyclopentane, nitroalkanes such as nitroethane and nitropropane, phenol, 2.6-
Phenols such as di-t-butyl-p-cresol, amines such as diethylamine, triethylamine, isopropylamine, diisopropylamine, diallylamine, N-methylbenzylamine, butylamine, isobutylamine, methanol, ethanol, n-propyl alcohol, i-Propyl alcohol.
ｎ−ブチルアルコール、ｉ−ブチルアルコール、 Ｓ−
ブチルアルコール、ｔ−ブチルアルコール、３−メチル
−１−ブチン−３−オール等のアルコール類、メチルセ
ロソルブ、エチルセロソルブ、ブチルセロソルブ、１．
４−ジオキサン、ブチルグリシジルエーテル、１．２−
メトキシエタン等のエーテル類、β−アミレン、β−イ
ソアミレン等のアミレ゛ン類、トリフェニルホスファイ
ト、トリブチルホスファイト等のホスファイト類、１．
２−プチレンオキサイド、エピクロルヒドリン等のエポ
キサイド類、テトラヒドロフラン、Ｎ−メチルビロール
等のフラン類、アセトン、メチルエチルケトン、メチル
ブチルケトン等のケトン類、酢酸エチル、酢酸プロピル
、酢酸ブチル等のエステル類、１，２．３−ベンゾトリ
アゾール等のトリアゾール類、ジクロロメタン、！、１
．１トリクロロエタン、トリクロルエチレン、テトラク
ロルエチレン、 ｔｒａｎｓ−１，２−ジクロロエチレ
ン、ｃｉｓ−１，２−ジクロロエチレン等のハロゲン化
炭化水素類、その他、１，１．２−）−ジクロロ−１，
２，２−トリフロロエタン、１，１，２．２−テトラク
ロロ−１，２−ジクロロメタン、１．１−ジクロロ−２
，２，３，３，３−テトラフロロプロパン、１．３−ジ
クロロ−１，２，２，３，３−ペンタフロロプロパン等
の本発明以外のフロン類等から選ばれる１種または２種
以上を適宜添加することができる。n-butyl alcohol, i-butyl alcohol, S-
Alcohols such as butyl alcohol, t-butyl alcohol, 3-methyl-1-butyn-3-ol, methyl cellosolve, ethyl cellosolve, butyl cellosolve, 1.
4-dioxane, butyl glycidyl ether, 1.2-
Ethers such as methoxyethane, amylenes such as β-amylene and β-isoamylene, phosphites such as triphenyl phosphite and tributyl phosphite, 1.
Epoxides such as 2-butylene oxide and epichlorohydrin, furans such as tetrahydrofuran and N-methylpyrrole, ketones such as acetone, methyl ethyl ketone and methyl butyl ketone, esters such as ethyl acetate, propyl acetate and butyl acetate, 1,2 Triazoles such as 3-benzotriazole, dichloromethane,! ,1
．． Halogenated hydrocarbons such as 1-trichloroethane, trichlorethylene, tetrachlorethylene, trans-1,2-dichloroethylene, cis-1,2-dichloroethylene, others, 1,1.2-)-dichloro-1,
2,2-trifluoroethane, 1,1,2,2-tetrachloro-1,2-dichloromethane, 1,1-dichloro-2
, 2,3,3,3-tetrafluoropropane, 1,3-dichloro-1,2,2,3,3-pentafluoropropane, etc. One or more types selected from fluorocarbons other than the present invention, etc. can be added as appropriate.
本発明の共沸組成物は、従来のフロンと同様、熱媒体や
発泡剤等の各種用途に使用でき、特に溶剤として用いた
場合、従来のＲ１１３に比べ溶解力が高いため代替物質
として好適である。The azeotropic composition of the present invention can be used for various purposes such as a heat medium and a blowing agent, just like conventional fluorocarbons. Especially when used as a solvent, it has a higher dissolving power than conventional R113, so it is suitable as a substitute material. be.
溶剤の具体的な用途としては、フラックス、グリース、
油、ワックス、インキ等の除去剤、塗料用溶剤、抽出剤
、ガラス、セラミックス、プラスチック、ゴム、金属製
各種部品、特にＩＣ部品、電気機器、精密機械、光学レ
ンズ等の洗浄剤や水切り剤等をあげることができる。洗
浄方法としては手拭き、浸漬、スプレー、揺動、超音波
洗浄、蒸気洗浄等を採用すればよい。Specific uses of solvents include flux, grease,
Removal agents for oil, wax, ink, etc., paint solvents, extractants, cleaning agents and draining agents for glass, ceramics, plastics, rubber, various metal parts, especially IC parts, electrical equipment, precision machinery, optical lenses, etc. can be given. As a cleaning method, hand wiping, dipping, spraying, shaking, ultrasonic cleaning, steam cleaning, etc. may be used.
［実施例］ 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例中のＲ１２２の記載は１，１．２−）ジクロロ−
２，２−トリフロロエタンを、ＮＭはニトロメタンを示
す。The description of R122 in the examples is 1,1.2-)dichloro-
2,2-trifluoroethane and NM represent nitromethane.
実施例１
第１表に示した各組成からなる混合物１０００ｇを各々
蒸留フラスコに入れ、理論段数２０段の精留塔を用い、
大気圧下で蒸留を行ない各々２００ｇの留分を得た。こ
の時の留出温度および留分のガスクロマトグラフ測定結
果を第２表に示す。Example 1 1000 g of a mixture consisting of each composition shown in Table 1 was placed in a distillation flask, and a rectification column with 20 theoretical plates was used.
Distillation was carried out under atmospheric pressure to obtain 200 g of each fraction. Table 2 shows the distillation temperature and gas chromatograph measurement results of the fraction at this time.
第１表
第２表
実施例２
本発明の組成物を用いてフラックスの洗浄試験を行なっ
た。プリント基板全面にフラックスを塗布し、２００℃
の電気炉で２分間焼成後、本発明の前記組成物に５分間
浸漬した。比較例としてＲ１１３についても同様の試験
を実施した。Table 1 Table 2 Example 2 A flux cleaning test was conducted using the composition of the present invention. Apply flux to the entire surface of the printed circuit board and heat to 200℃
After baking in an electric furnace for 2 minutes, the sample was immersed in the composition of the present invention for 5 minutes. A similar test was conducted for R113 as a comparative example.
フラックスの除去の度合を第３表に示す。Table 3 shows the degree of flux removal.
第３表 ０； 良好に除去できる、 Ｏ： はぼ良好 △ ； 微量残存、 ×；かなり残量 実施例３・ 本発明の組成物を用いて機械油の洗浄試験を行なった。Table 3 0; can be removed well, O: Good condition △ ; trace amount remaining, ×; Considerable amount remaining Example 3・ A machine oil cleaning test was conducted using the composition of the present invention.
５ＵＳ３０４製テストピース（２５ｍｍＸ ３０ｍｍＸ
２ｍｍ厚）を機械油（ＣＱ−３０，日本石油製）中に
浸漬した後、本発明の前期組成物に５分間浸漬洗浄した
。比較例としてＲ１１３についても同様の試験を実施し
た。機械油の除去の度合を第４表に示す。5US304 test piece (25mmX 30mmX
2 mm thick) was immersed in machine oil (CQ-30, manufactured by Nippon Oil) and then immersed in the composition of the present invention for 5 minutes for cleaning. A similar test was conducted for R113 as a comparative example. Table 4 shows the degree of machine oil removal.
第４表
０；良好に除去できる、 Ｏ；はぼ良好△；微量残存、
×；かなり残量［発明の効果］
本発明の共沸および共沸様組成物は、従来のＲ１１３，
１，１，１−トリクロロエタンが有している優れた特性
を満足しながら代替物質として使用できるとともに、リ
サイクルしても組成変動が小さいため、従来のＲ１１３
，１，１，ｉトリクロロエタン単一物と同等の使い方が
でき、従来技術の大幅な変更を要しない等の利点がある
。また、溶剤としてもフラックス、機械油等の除去性能
に優れるためＲ１１３、１、 １、 ｌ−トリクロロエ
タンに替わるフラックス除去溶剤、脱脂洗浄溶剤として
最適である。Table 4 0: Can be removed well, O: Good △: Trace amount remains,
×: Significant residual amount [Effect of the invention] The azeotrope and azeotrope-like composition of the present invention are similar to conventional R113,
It can be used as a substitute substance while satisfying the excellent properties of 1,1,1-trichloroethane, and the composition change is small even when recycled, so it can be used as a substitute for conventional R113.
, 1, 1, i It has the advantage that it can be used in the same way as trichloroethane alone and does not require major changes to the conventional technology. Furthermore, as a solvent, it has excellent performance in removing flux, machine oil, etc., so it is most suitable as a flux removal solvent and a degreasing cleaning solvent in place of R113, 1, 1, 1-trichloroethane.
Claims (1)
プロパノール、Ｔｅｒ−ブタノールのいずれか一種およ
び１，１，２−トリクロロ−２，２−ジフルオロエタン
、ニトロメタンとからなる共沸および共沸様組成物。 ２、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン７７．８〜９９．８重量％、メタノール０．１〜２２
．０重量％およびニトロメタン０．１〜１．９重量％か
らなる請求項１に記載の共沸様組成物。 ３、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン８３．４重量％、メタノール１６．２重量％およびニ
トロメタン０．４重量％からなる請求項１に記載の共沸
組成物。 ４、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン８２．８〜９９．８重量％、エタノール０．１〜１７
．０重量％およびニトロメタン０．１〜１．９重量％か
らなる請求項１に記載の共沸様組成物。 ５、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン８８．５重量％、エタノール１１．０重量％およびニ
トロメタン０．５重量％からなる請求項１に記載の共沸
組成物。 ６、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン８７．８〜９９．８重量％、１−プロパノール０．１
〜１２重量％およびニトロメタン０．１〜１．９重量％
からなる請求項１に記載の共沸様組成物。 ７、１，１，２−トリクロロ−２．２−ジフルオロエタ
ン９７．０重量％、１−プロパノール２．０重量％およ
びニトロメタン１．０重量％からなる請求項１に記載の
共沸組成物。 ８、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン８２．８〜９９．８重量％、２−プロパノール０．１
〜１７．０重量％およびニトロメタン０．１〜１．９重
量％からなる請求項１に記載の共沸様組成 物。 ９、１，１，２−トリクロロ−２，２−ジフルオロエタ
ン９０．０重量％、２−プロパノール９．１重量％およ
びニトロメタン０．９重量％からなる請求項１に記載の
共沸組成物。 １０、１，１，２−トリクロロ−２，２−ジフルオロエ
タン８７．８〜９９．８重量％、Ｔｅｒ−ブタノール０
．１〜１２．０重量％およびニトロメタン０．１〜１．
９重量％からなる請求項１に記載の共沸様組成 物。 １１、１，１，２−トリクロロ−２，２−ジフルオロエ
タン９７．０重量％、Ｔｅｒ−ブタノール２．０重量％
およびニトロメタン１．０重量％からなる請求項１に記
載の共沸組成物。[Claims] 1, methanol, ethanol, 1-propanol, 2-
Azeotropic and azeotrope-like compositions comprising any one of propanol and ter-butanol and 1,1,2-trichloro-2,2-difluoroethane and nitromethane. 2,1,1,2-trichloro-2,2-difluoroethane 77.8-99.8% by weight, methanol 0.1-22%
．． 2. The azeotrope-like composition of claim 1, comprising 0% by weight and 0.1-1.9% by weight of nitromethane. The azeotropic composition according to claim 1, consisting of 83.4% by weight of 3,1,1,2-trichloro-2,2-difluoroethane, 16.2% by weight of methanol and 0.4% by weight of nitromethane. 4,1,1,2-trichloro-2,2-difluoroethane 82.8-99.8% by weight, ethanol 0.1-17
．． 2. The azeotrope-like composition of claim 1, comprising 0% by weight and 0.1-1.9% by weight of nitromethane. The azeotropic composition according to claim 1, consisting of 88.5% by weight of 5,1,1,2-trichloro-2,2-difluoroethane, 11.0% by weight of ethanol and 0.5% by weight of nitromethane. 6,1,1,2-trichloro-2,2-difluoroethane 87.8-99.8% by weight, 1-propanol 0.1
~12% by weight and 0.1-1.9% nitromethane
The azeotrope-like composition of claim 1 consisting of. The azeotropic composition according to claim 1, consisting of 97.0% by weight of 7,1,1,2-trichloro-2,2-difluoroethane, 2.0% by weight of 1-propanol and 1.0% by weight of nitromethane. 8,1,1,2-trichloro-2,2-difluoroethane 82.8-99.8% by weight, 2-propanol 0.1
2. The azeotrope-like composition of claim 1 consisting of ~17.0% by weight and 0.1-1.9% nitromethane. The azeotropic composition according to claim 1, consisting of 90.0% by weight of 9,1,1,2-trichloro-2,2-difluoroethane, 9.1% by weight of 2-propanol and 0.9% by weight of nitromethane. 10, 1,1,2-trichloro-2,2-difluoroethane 87.8-99.8% by weight, Ter-butanol 0
．． 1-12.0% by weight and 0.1-1.0% nitromethane.
The azeotrope-like composition of claim 1 comprising 9% by weight. 11,1,1,2-trichloro-2,2-difluoroethane 97.0% by weight, Ter-butanol 2.0% by weight
and 1.0% by weight of nitromethane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1310736A JPH03173836A (en) | 1989-12-01 | 1989-12-01 | Fluorinated hydrocarbon-based azeotropic and azeotropy-like composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1310736A JPH03173836A (en) | 1989-12-01 | 1989-12-01 | Fluorinated hydrocarbon-based azeotropic and azeotropy-like composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03173836A true JPH03173836A (en) | 1991-07-29 |
Family
ID=18008870
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1310736A Pending JPH03173836A (en) | 1989-12-01 | 1989-12-01 | Fluorinated hydrocarbon-based azeotropic and azeotropy-like composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03173836A (en) |
-
1989
- 1989-12-01 JP JP1310736A patent/JPH03173836A/en active Pending
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