JPH01103686A - Fluorinated hydrocarbon mixture - Google Patents
Fluorinated hydrocarbon mixtureInfo
- Publication number
- JPH01103686A JPH01103686A JP62259643A JP25964387A JPH01103686A JP H01103686 A JPH01103686 A JP H01103686A JP 62259643 A JP62259643 A JP 62259643A JP 25964387 A JP25964387 A JP 25964387A JP H01103686 A JPH01103686 A JP H01103686A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- dichloro
- weight
- fluorinated hydrocarbon
- fluorocarbons
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 7
- 229930195733 hydrocarbon Natural products 0.000 title claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 5
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 claims abstract description 8
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 10
- 238000004140 cleaning Methods 0.000 abstract description 6
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 abstract 1
- -1 chlorine radicals Chemical class 0.000 description 5
- 230000004907 flux Effects 0.000 description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- 239000003507 refrigerant Substances 0.000 description 3
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- YMRMDGSNYHCUCL-UHFFFAOYSA-N 1,2-dichloro-1,1,2-trifluoroethane Chemical compound FC(Cl)C(F)(F)Cl YMRMDGSNYHCUCL-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5045—Mixtures of (hydro)chlorofluorocarbons
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G5/00—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
- C23G5/02—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents
- C23G5/028—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons
- C23G5/02809—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing chlorine and fluorine
- C23G5/02825—Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents using organic solvents containing halogenated hydrocarbons containing chlorine and fluorine containing hydrogen
- C23G5/02829—Ethanes
- C23G5/02838—C2HCl2F3
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規なフッ素化炭化水素系混
合物に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a novel fluorinated hydrocarbon mixture that can be used as a fluorocarbon substitute and has excellent properties as a solvent and the like.
［従来の技術］
フッ素化炭化水素系化合物（以下単にフロンという）は
、毒性が少なく不燃で化学的に安定なものが多く、標準
沸点の異なる各種フロンが入手できることから、これら
の特性を生かして溶剤、発泡剤、プロペラントあるいは
冷媒等として種々のフロンが使われている０例えば、溶
剤として１，１．２− ）シクロロ−１，２，２−トリ
フルオロエタン（Ｒ１１３）が、発泡剤としてトリクロ
ロモノフルオロメタン（Ｒ１１）が、プロペラントや冷
媒としてジクロロジフルオロメタン（Ｒ１２）が使われ
ている。[Prior art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are mostly non-toxic, non-flammable, and chemically stable, and various fluorocarbons with different standard boiling points are available, so they can be used to take advantage of these characteristics. Various fluorocarbons are used as solvents, blowing agents, propellants, refrigerants, etc.For example, 1,1,2-)cyclo-1,2,2-trifluoroethane (R113) is used as a blowing agent. Trichloromonofluoromethane (R11) is used as a propellant and dichlorodifluoromethane (R12) as a refrigerant.
［発明の解決しようとする問題点］
化学的に特に安定なＲ１１，Ｒ１２，Ｒ１１３は対流圏
内での寿命が長く、拡散して成層圏に達し、ここで太陽
光線により分解して発生する塩素ラジカルがオゾンと連
鎖反応を起こし、オゾン層を破壊するとのことから、こ
れら従来のフロンの使用を規制する動きがある。このた
め、これらの従来のフロンに替わり、オゾン層を破壊し
にくい代替フロンの探索が活発に行なわれている。[Problems to be solved by the invention] R11, R12, and R113, which are particularly chemically stable, have a long life in the troposphere and diffuse into the stratosphere, where they are decomposed by sunlight and generated chlorine radicals. There is a movement to restrict the use of these conventional fluorocarbons because they are said to cause a chain reaction with ozone and destroy the ozone layer. For this reason, the search for alternative fluorocarbons that are less likely to deplete the ozone layer is being actively conducted in place of these conventional fluorocarbons.
本発明は、従来のフロンが有している優れた特性を満足
しながら代替フロンとして使用できる新規なフロン混合
物を提供することを目的とするものである。An object of the present invention is to provide a novel fluorocarbon mixture that can be used as a fluorocarbon substitute while satisfying the excellent properties of conventional fluorocarbons.
［問題点を解決するための手段］
本発明はジクロロトリフルオロエタン及び１．１−ジク
ロロ−１−フルオロエタンからなるフッ素化炭化水素系
混合物に関するものである。[Means for Solving the Problems] The present invention relates to a fluorinated hydrocarbon mixture consisting of dichlorotrifluoroethane and 1,1-dichloro-1-fluoroethane.
本発明の混合物は不燃又は難燃性であるとともに共沸組
成が存在し、特に洗浄溶剤として従来のＲ１１３よのも
洗浄力が高いため、Ｒ１１３の代替として極めて有用な
ものである。The mixture of the present invention is nonflammable or flame retardant, has an azeotropic composition, and has higher cleaning power than conventional R113 as a cleaning solvent, so it is extremely useful as a substitute for R113.
本発明における １，１−ジクロロ−１−フルオロエタ
ン（Ｒ１’４１ｂ）は可燃性であるが、不燃性のジクロ
ロトリフルオロエタンを混合することにより不燃または
難燃性とすることができる。ジクロロトリフルオロエタ
ンには１．１−ジクロロ−２，２，２−）リフルオロエ
タン（Ｒ１２３）、１，２−ジクロロ−１，２，２−ト
リフルオロエタン（Ｒ１２３ａ）、１．１−ジクロロ−
１，２，２−）リフルオロエタン（Ｒ１２３ｂ）の異性
体が知られているが、物性が互いに類似しているため、
これらを単独で用いてもよく、これらの混合物として用
いてもよい。Although 1,1-dichloro-1-fluoroethane (R1'41b) in the present invention is flammable, it can be made nonflammable or flame retardant by mixing nonflammable dichlorotrifluoroethane. Dichlorotrifluoroethane includes 1,1-dichloro-2,2,2-)rifluoroethane (R123), 1,2-dichloro-1,2,2-trifluoroethane (R123a), 1,1-dichloro −
Isomers of 1,2,2-)lifluoroethane (R123b) are known, but because their physical properties are similar to each other,
These may be used alone or as a mixture thereof.
以下の説明においてはＲ１２３を用いた例を示す。In the following description, an example using R123 will be shown.
リサイクルしても組成の変動が少ないこと、又従来の単
一フロンと同じ使い方ができ、従来技術の大幅な変更を
要しないこと等の利点があることから、本発明の混合物
としてはＲ１２３が５５〜８０重量％及びＲ１４１ｂが
２０〜４５重量％、好ましくはＲ１２３が６０〜７５重
量％及び Ｒ１４１ｂが２５〜４０重量％である共′Ｓ
混合物に近い組成を有する混合物から選定するとよい、
さらに好ましくはＲ１２３の約６７重量％とＲ１４１ｂ
の約３３重量％からなる共沸混合物である。R123 has the advantages of less variation in composition even when recycled, can be used in the same way as conventional single fluorocarbons, and does not require major changes to conventional technology. -80% by weight and 20-45% by weight of R141b, preferably 60-75% by weight of R123 and 25-40% by weight of R141b.
It is best to select from mixtures with a composition similar to that of the mixture.
More preferably about 67% by weight of R123 and R141b
It is an azeotrope consisting of about 33% by weight of
本発明の混合物には、用途に応じてその他の成分をさら
に添加混合することができる。例えば、溶剤としての用
途においては、ペンタン、インペンタン、ヘキサン、イ
ンヘキサン、ヘプタン、イソへブタン等の炭化水素類、
ニトロメタン、ニトロエタン、ニトロエタンくン等のニ
トロアルカン類、ジエチルアミン、トリエチルアミン、
イソプロピルアミン、ブチルアミン、イソブチルアミン
、等のアミン類、メタノール、エタノール、ｎ−プロピ
ルアルコール、ｉ−プロピルアルコール、ｎ−ブタノー
ル、ｉ−ブタノール、等のアルコール類、メチルセロソ
ルブ、テトラヒドロフラン、１，４−ジオキサン等のエ
ーテル類、アセトン、メチルエチルケトン、メチルブチ
ルケトン等のケトン類、酢酸エチル、酢酸プロピル、酢
酸ブチル等のエステル類等から選ばれる１種又は２種以
上を添加混合することができる。Other components may be further added to the mixture of the present invention depending on the intended use. For example, when used as a solvent, hydrocarbons such as pentane, impentane, hexane, inhexane, heptane, isohbutane, etc.
Nitroalkanes such as nitromethane, nitroethane, nitroethane, diethylamine, triethylamine,
Amines such as isopropylamine, butylamine, isobutylamine, alcohols such as methanol, ethanol, n-propyl alcohol, i-propyl alcohol, n-butanol, i-butanol, methyl cellosolve, tetrahydrofuran, 1,4-dioxane One or more selected from ethers such as ethers, ketones such as acetone, methyl ethyl ketone, and methyl butyl ketone, and esters such as ethyl acetate, propyl acetate, butyl acetate, etc. can be added and mixed.
Ｒ１２３及びＲ１４１ｂからなる本発明の混合物は、従
来のフロンと同様、熱媒体、冷媒、プロペラント、発泡
剤等の各種用途に使用でき、特に溶剤として用いた場合
、従来のＲ１１３に比べ溶解力が高いため好適である。The mixture of R123 and R141b of the present invention can be used in various applications such as heat carriers, refrigerants, propellants, and blowing agents, just like conventional fluorocarbons.In particular, when used as a solvent, it has a higher dissolving power than conventional R113. It is suitable because it is expensive.
溶剤の具体的な用途としては、フラックス、グリース、
油、ワックス、インキ等の除去剤、塗料用溶剤、抽出剤
、ガラス、セラミックス、プラスチック、ゴム、金属製
各種物品、特にＩＣ部品、電気機器、精密機械、光学レ
ンズ等の洗浄剤や水切り剤等を挙げることができる。洗
浄方法としては、手拭き、浸漬、スプレー、揺動、超音
波洗浄、蒸気洗浄等を採用すればよい。Specific uses of solvents include flux, grease,
Removers for oil, wax, ink, etc., paint solvents, extractants, cleaning agents and draining agents for glass, ceramics, plastics, rubber, various metal products, especially IC parts, electrical equipment, precision machinery, optical lenses, etc. can be mentioned. As the cleaning method, hand wiping, dipping, spraying, shaking, ultrasonic cleaning, steam cleaning, etc. may be employed.
［実施例コ
実施例１
下記の組成から成る溶剤混合物１０００ｇを蒸留フラス
コに入れ、理論段数２０段の精留塔を用い、大気圧下で
蒸留を行なった。[Example 1] 1000 g of a solvent mixture having the following composition was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
（組 成） （重量％）
Ｒ１２３（沸点２７．１℃）７０
Ｒ１４１ｂ （沸点３２．０℃）３０
その結果２５．０°Ｃに於て留分４００ｇ得た。このも
のをガスクロマトグラフで測定した結果、次の組成であ
った。(Composition) (% by weight) R123 (boiling point 27.1°C) 70 R141b (boiling point 32.0°C) 30 As a result, 400 g of a fraction was obtained at 25.0°C. As a result of measuring this product with a gas chromatograph, it had the following composition.
（組 成） （重量％）
Ｒ１２３Ｂ８．８
Ｒ１４１ｂ ３３．２
実施例２
本発明の混合物（Ｒ１２３／Ｒ１４１ｂ−８７重量％／
３３重量％）を用いてフラックスの洗浄試験を行なった
。(Composition) (% by weight) R123B8.8 R141b 33.2 Example 2 Mixture of the present invention (R123/R141b-87% by weight/
A flux cleaning test was conducted using 33% by weight).
プリント基板全面にフラックスを塗布し、２００℃の電
気炉で２分間焼成後、本発明の前記混合物に１分間浸漬
した。比較例としてＲ１１３についても同様の試験を行
なった。フラックスの除去の度合を第１表に示す。Flux was applied to the entire surface of the printed circuit board, baked in an electric furnace at 200° C. for 2 minutes, and then immersed in the mixture of the present invention for 1 minute. A similar test was also conducted for R113 as a comparative example. Table 1 shows the degree of flux removal.
第 １ 表
０：完全に除去、 Ｏ；微量残存
Δ；少量残存、×；かなり残存
実施例３
実施例２の混合物（Ｒ１２３／Ｒ１４１ｂ−８７重量％
／３３重量％）についてペンスキーマルテンス式測定法
（ＪＩＳ−に２２８５）に従って、測定したところ引火
点がなく不燃であることが確認された。Table 1 0: Completely removed, O: Trace amount remaining Δ; Small amount remaining, ×: Significant amount remaining Example 3 Mixture of Example 2 (R123/R141b-87% by weight
/33% by weight) was measured according to the Pensky-Martens method (JIS-2285), and it was confirmed that it had no flash point and was nonflammable.
［発明の効果］
本発明のフッ素化炭化水素系混合物は、不燃又は難燃性
で従来のフロンが有している優れた特性を満足しながら
代替フロンとして使用できるとともに、共沸点が存在す
るため、リサイクル時に組成変動がない、従来の単一フ
ロンと同じ使い方ができ、従来技術の大幅な変更を要し
ない等の利点がある。又、溶剤としてよく使われている
Ｒ１１３よりもフラックスや油等の溶解除去性に優れる
ためＲ１１３に替わる洗浄溶剤として好適である。[Effects of the Invention] The fluorinated hydrocarbon mixture of the present invention is nonflammable or flame retardant and can be used as a substitute for fluorocarbons while satisfying the excellent properties of conventional fluorocarbons, and has an azeotropic point. It has the advantages of no compositional changes during recycling, can be used in the same way as conventional single fluorocarbons, and does not require major changes to conventional technology. In addition, it is suitable as a cleaning solvent in place of R113 because it has better ability to dissolve and remove flux and oil than R113, which is often used as a solvent.
Claims (1)
−１−フルオロエタンからなるフッ素化炭化水素系混合
物。 ２、ジクロロトリフルオロエタン５５〜８０重量％及び
１，１−ジクロロ−１−フルオロエタン２０〜４５重量
％からなる特許請求の範囲第１項記載の混合物。[Claims] 1. A fluorinated hydrocarbon mixture consisting of dichlorotrifluoroethane and 1,1-dichloro-1-fluoroethane. 2. The mixture according to claim 1, comprising 55 to 80% by weight of dichlorotrifluoroethane and 20 to 45% by weight of 1,1-dichloro-1-fluoroethane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62259643A JPH01103686A (en) | 1987-10-16 | 1987-10-16 | Fluorinated hydrocarbon mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62259643A JPH01103686A (en) | 1987-10-16 | 1987-10-16 | Fluorinated hydrocarbon mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01103686A true JPH01103686A (en) | 1989-04-20 |
Family
ID=17336908
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62259643A Pending JPH01103686A (en) | 1987-10-16 | 1987-10-16 | Fluorinated hydrocarbon mixture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01103686A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4960535A (en) * | 1989-11-13 | 1990-10-02 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane and a mono- or di-chlorinated C2 or C3 alkane |
| US4965011A (en) * | 1989-10-04 | 1990-10-23 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, and nitromethane |
| EP0394992A2 (en) * | 1989-04-27 | 1990-10-31 | Daikin Industries, Limited | Solvent composition |
| WO1990015169A1 (en) * | 1989-06-06 | 1990-12-13 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane and dichlorotrifluoroethane |
| JPH02306927A (en) * | 1989-04-10 | 1990-12-20 | E I Du Pont De Nemours & Co | Azeotropic mixture of 1,1-dichloro-2,2,2- trifluoroethane and 1,1-dichloro-1-fluoro- ethane |
| US4994201A (en) * | 1989-09-25 | 1991-02-19 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, methanol and cyclopentane |
| WO1991005081A1 (en) * | 1989-10-04 | 1991-04-18 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, and nitromethane |
| WO1991007523A1 (en) * | 1989-11-13 | 1991-05-30 | Allied-Signal Inc. | AZEOTROPE-LIKE COMPOSITIONS OF 1,1-DICHLORO-1-FLUOROETHANE, DICHLOROTRIFLUOROETHANE, A MONO- OR DI-CHLORINATED C1, C2 or C3 ALKANE AND OPTIONALLY METHANOL |
| US5145598A (en) * | 1988-12-27 | 1992-09-08 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluorethane, nitromethane and methanol or ethanol |
| US5227087A (en) * | 1989-01-17 | 1993-07-13 | E. I. Du Pont De Nemours And Company | Constant-boiling, azeotrope-like mixtures of dichlorotrifluoroethane, 1,1-dichloro-1-fluoroethane and methanol and/or ethanol |
-
1987
- 1987-10-16 JP JP62259643A patent/JPH01103686A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5145598A (en) * | 1988-12-27 | 1992-09-08 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluorethane, nitromethane and methanol or ethanol |
| US5227087A (en) * | 1989-01-17 | 1993-07-13 | E. I. Du Pont De Nemours And Company | Constant-boiling, azeotrope-like mixtures of dichlorotrifluoroethane, 1,1-dichloro-1-fluoroethane and methanol and/or ethanol |
| JPH02306927A (en) * | 1989-04-10 | 1990-12-20 | E I Du Pont De Nemours & Co | Azeotropic mixture of 1,1-dichloro-2,2,2- trifluoroethane and 1,1-dichloro-1-fluoro- ethane |
| US5194169A (en) * | 1989-04-10 | 1993-03-16 | E. I. Du Pont De Nemours And Company | Azeotrope-like refrigerant mixtures of 1,1-dichloro-2,2,2-trifluoroethane and 1,1-dichloro-1-fluoroethane |
| EP0394992A2 (en) * | 1989-04-27 | 1990-10-31 | Daikin Industries, Limited | Solvent composition |
| EP0394992A3 (en) * | 1989-04-27 | 1991-01-09 | Daikin Industries, Limited | Solvent composition |
| WO1990015169A1 (en) * | 1989-06-06 | 1990-12-13 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane and dichlorotrifluoroethane |
| US4994201A (en) * | 1989-09-25 | 1991-02-19 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, methanol and cyclopentane |
| WO1991004356A1 (en) * | 1989-09-25 | 1991-04-04 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, methanol and cyclopentane |
| WO1991005081A1 (en) * | 1989-10-04 | 1991-04-18 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, and nitromethane |
| US4965011A (en) * | 1989-10-04 | 1990-10-23 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane, and nitromethane |
| WO1991007523A1 (en) * | 1989-11-13 | 1991-05-30 | Allied-Signal Inc. | AZEOTROPE-LIKE COMPOSITIONS OF 1,1-DICHLORO-1-FLUOROETHANE, DICHLOROTRIFLUOROETHANE, A MONO- OR DI-CHLORINATED C1, C2 or C3 ALKANE AND OPTIONALLY METHANOL |
| US4960535A (en) * | 1989-11-13 | 1990-10-02 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, dichlorotrifluoroethane and a mono- or di-chlorinated C2 or C3 alkane |
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