JPH03168298A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPH03168298A JPH03168298A JP30879589A JP30879589A JPH03168298A JP H03168298 A JPH03168298 A JP H03168298A JP 30879589 A JP30879589 A JP 30879589A JP 30879589 A JP30879589 A JP 30879589A JP H03168298 A JPH03168298 A JP H03168298A
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- detergent composition
- liquid detergent
- glycoside
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000007788 liquid Substances 0.000 title claims abstract description 23
- 239000003599 detergent Substances 0.000 title claims description 17
- -1 alkyl glucoside Chemical class 0.000 claims abstract description 29
- 150000005215 alkyl ethers Chemical class 0.000 claims abstract description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 4
- 229930182470 glycoside Natural products 0.000 claims description 13
- 238000004140 cleaning Methods 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 150000002338 glycosides Chemical class 0.000 claims description 3
- 238000005187 foaming Methods 0.000 abstract description 11
- 229930182478 glucoside Natural products 0.000 abstract description 4
- 239000002453 shampoo Substances 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract 1
- KJIOQYGWTQBHNH-UHFFFAOYSA-N undecanol Chemical compound CCCCCCCCCCCO KJIOQYGWTQBHNH-UHFFFAOYSA-N 0.000 description 12
- 229940057402 undecyl alcohol Drugs 0.000 description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000008103 glucose Substances 0.000 description 4
- ULDAPNVYSDTSFM-VDWCLKJHSA-N (2r,3s,4s,5r)-2-(hydroxymethyl)-6-undecoxyoxane-3,4,5-triol Chemical compound CCCCCCCCCCCOC1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O ULDAPNVYSDTSFM-VDWCLKJHSA-N 0.000 description 3
- 239000003377 acid catalyst Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000004851 dishwashing Methods 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- JDRSMPFHFNXQRB-CMTNHCDUSA-N Decyl beta-D-threo-hexopyranoside Chemical compound CCCCCCCCCCO[C@@H]1O[C@H](CO)C(O)[C@H](O)C1O JDRSMPFHFNXQRB-CMTNHCDUSA-N 0.000 description 1
- 239000004435 Oxo alcohol Substances 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical group 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940073499 decyl glucoside Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229930182479 fructoside Natural products 0.000 description 1
- 150000008132 fructosides Chemical class 0.000 description 1
- 238000007037 hydroformylation reaction Methods 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、液体洗浄剤組戒物に関する。詳しくは、洗浄
力、起泡力に優れ、かつ、液体安定性の良好なシャンプ
ー、食器用の液体洗浄剤組或物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a liquid detergent composition. Specifically, the present invention relates to shampoos and dishwashing liquid detergent compositions that have excellent detergency, foaming power, and good liquid stability.
従来の洗浄剤組或物は、アルキルベンゼンスルホン酸塩
、高級アルコール硫酸エステル塩などの陰イオン界面活
性剤を活性成分とするものが広汎に使用されている。こ
れらの洗浄剤は、起泡力と洗浄力においては良好である
が、比較的低温における液体安定性が不良で経時的に白
濁や沈澱を生じ、また、手肌に対して刺激性を有する。Conventional detergent compositions containing anionic surfactants such as alkylbenzene sulfonates and higher alcohol sulfates as active ingredients are widely used. Although these detergents have good foaming power and detergent power, they have poor liquid stability at relatively low temperatures, causing cloudiness and precipitation over time, and are irritating to the skin of hands.
そこで近年は、液体安定性およびマイルド性が良好な界
面活性剤が使用される傾向にある。しかしながら、非イ
オン界面活性剤は、起泡力が劣るために、食器用洗浄剤
等には不向きであるとされていた。Therefore, in recent years, there has been a tendency to use surfactants that have good liquid stability and mild properties. However, nonionic surfactants have been considered unsuitable for dishwashing agents and the like because of their poor foaming power.
本発明は、ポリオキシエチレンアルキルエーテルとアル
キルグリコシドとを主或分とする、冷所に長時間保存し
ても自沈を生じず、かつ、洗浄力、起泡力に優れた液体
洗浄剤組成物を提供しようとするものである。The present invention provides a liquid detergent composition that does not cause scuttling even when stored in a cold place for a long time and has excellent detergency and foaming power, which mainly contains polyoxyethylene alkyl ether and alkyl glycoside. This is what we are trying to provide.
即ち、本発明は、アルキルグリコシドおよびポリオキシ
エチレンアルキルエーテルを含有する液体洗浄剤Ｍｉ或
物において、アルキルグリコシドとして、一般式（１）
で示されるグリコシドを用いる液体洗浄剤組成物を提供
するものである。。That is, the present invention provides a liquid detergent Mi containing an alkyl glycoside and a polyoxyethylene alkyl ether, in which the alkyl glycoside is represented by the general formula (1).
The present invention provides a liquid detergent composition using the glycoside shown below. .
Ｒ１０（Ｚ）． （Ｉ）（式中、
Ｒ１は直鎖または分岐の炭素数ｌ１のアルキル基または
アルケニル基であり、Ｚは炭素数５または６の還元糖か
ら誘導される部分であり、ｍは１〜２の数である）
本発明において式（１）で示されるアル牛ルグリコシド
としては、糖の種類によってアルキルグルコシド、アル
ヰルフルクトシド、アルキルマンノシド等が挙げられる
が、原料のアベイラビリティおよびコストの点から、ア
ルヰノレ，グルコシドが好ましい。R10(Z). (I) (wherein,
In the present invention, R1 is a linear or branched alkyl group or alkenyl group having l1 carbon atoms, Z is a moiety derived from a reducing sugar having 5 or 6 carbon atoms, and m is a number from 1 to 2. Alvinole glycosides represented by formula (1) include alkyl glucosides, alwyl fructosides, alkyl mannosides, etc. depending on the type of sugar; preferable.
本発明の組或物に用いられる前記式（Ｉ）で示されるア
ルキルグリコシドの製法は、例えば、アルキルグルコシ
ド場合は、ウンデシルアルコールを酸触媒の存在下でグ
ルコースと反応させるか、または％ＣＩ〜Ｃ６の短鎖ア
ルコールとグルコースとを酸触媒の存在下で反応させて
得た短鎖アルキルグリコシドとウンデシルアルコールと
を酸触媒でアセタール交換することによって得られる。The method for producing the alkyl glycoside represented by formula (I) used in the composition of the present invention includes, for example, in the case of an alkyl glucoside, undecyl alcohol is reacted with glucose in the presence of an acid catalyst, or % CI ~ It is obtained by acetal exchange with undecyl alcohol and a short chain alkyl glycoside obtained by reacting a C6 short chain alcohol with glucose in the presence of an acid catalyst.
ウンデシルアルコールとしては、デセンからヒドロホル
ミル化反応によって得られる才キソ合戊アルコール等が
用いられる。ウンデシルアルコールの直鎮率については
特に制限はないが、通常４０〜９０％程度である。As undecyl alcohol, undecyl alcohol, etc., obtained from decene by a hydroformylation reaction, is used. There is no particular restriction on the direct conversion rate of undecyl alcohol, but it is usually about 40 to 90%.
また、式（１）における糖重合度ｍは１〜２の数である
が、式中糖部分Ｚがグルコースやマンノースの場合には
、洗浄力および起泡力の点で、１〜１．５の範囲が特に
好ましい。Furthermore, the degree of sugar polymerization m in formula (1) is a number of 1 to 2, but when the sugar moiety Z in the formula is glucose or mannose, it is 1 to 1.5 in terms of detergency and foaming power. A range of is particularly preferred.
本発明で用いられるポリオキシエチレンアルキルエーテ
ルとしては、一般式（ｎ）で示されるものが挙げられる
。Examples of the polyoxyethylene alkyl ether used in the present invention include those represented by general formula (n).
Ｒ２０ （ＣＨ．ＣＨ．Ｏ）．Ｈ （ＩＩ）
（式中、Ｒ２は、直鎮または分岐の炭素数８〜２０のア
ルキル基であり、ｎは、５〜２０の数である）
上記のボリ才キシエチレンアルキルエーテルの製法は、
炭素数８〜２０の高級アルコールに、酸触媒またはアル
カリ触媒の存在下、酸化エチレンを付加する。R20 (CH.CH.O). H (II)
(In the formula, R2 is a straight or branched alkyl group having 8 to 20 carbon atoms, and n is a number of 5 to 20.) The method for producing the above polyoxyethylene alkyl ether is as follows:
Ethylene oxide is added to a higher alcohol having 8 to 20 carbon atoms in the presence of an acid catalyst or an alkali catalyst.
高級アルコールとしては、天然アルコール、チーグラー
アルコール、オキソアルコール等が挙げられる。具体的
には、ドバノール２３（商品名、ＣＩ２／ＣＩ３＝４
５／５ ５の混合物、直鎖率７５％、三菱油化＠製）、
ドバノール２５（商品名、Ｃｌ２、Ｃ Ｉ３、Ｃ０、Ｃ
＋ｓの混合物、直鎖率７５％、三菱油化＠製） 、ＤＩ
ＡＤＯＬ−１ ３ （商品名、ＣＩ３、直鎖率約５０％
、三菱化戒■製）、ネオドール２３ （商品名、Ｃ １
２／ Ｃ ＋３＝ ４ ５ ／ ５ ５の混合物、直鎖
率８０％、シェル社製）、ネオドール２５（商品名、Ｃ
Ｉ２、ＣＩ３、ＣＩ４、Ｃ Ｉ５の混合物、直鎮率８
０％、シェル社Ｍ）等が挙げられる。Examples of higher alcohols include natural alcohols, Ziegler alcohols, oxo alcohols, and the like. Specifically, Dovanol 23 (trade name, CI2/CI3=4
5/5 Mixture of 5, straight chain rate 75%, manufactured by Mitsubishi Yuka@),
Dovanol 25 (trade name, Cl2, C I3, C0, C
+s mixture, linear chain rate 75%, manufactured by Mitsubishi Yuka@), DI
ADOL-1 3 (Product name, CI3, linear chain rate approximately 50%
, made by Mitsubishi Kakai ■), Neodoll 23 (product name, C 1
2/C+3=45/55 mixture, linear chain rate 80%, manufactured by Shell Co., Ltd.), Neodol 25 (trade name, C
Mixture of I2, CI3, CI4, CI5, direct compression rate 8
0%, Shell M), etc.
本発明の液体洗浄剤組成物において、アルキルグリコシ
ド（１）とポリオキシエチレンアルキルエーテル（Ｉ［
）との混合比は任意であるが、好ましくは、重量比１０
：１〜ｌ：２であり、とくに８：１〜１：１の範囲にお
いて洗浄力および起泡力が良好である。In the liquid detergent composition of the present invention, alkyl glycoside (1) and polyoxyethylene alkyl ether (I [
) may be mixed at any desired ratio, but preferably at a weight ratio of 10
:1 to 1:2, and the detergency and foaming power are particularly good in the range of 8:1 to 1:1.
また、本発明の液体洗浄剤組戒物において、アルキルグ
リコシド（Ｉ）とポリオヰシエチレンアルキルエーテル
（ＩＩ）と和の濃度は任意であるが、通常、１〜７０重
量％の範囲であり、特に１０〜５０重量％の範囲の場合
、組成物の流動性が良好で、かつ、洗浄力の点からも好
適である。Further, in the liquid detergent composition of the present invention, the concentration of the sum of alkyl glycoside (I) and polyoxyethylene alkyl ether (II) is arbitrary, but is usually in the range of 1 to 70% by weight, In particular, when the amount is in the range of 10 to 50% by weight, the composition has good fluidity and is suitable from the viewpoint of detergency.
本発明の洗浄剤組成物は、任意のアニオン界面活性剤、
カチオン界面活性剤、ノニオン界面活性剤、両性イオン
界面活性剤、ハイドロトロープ、希釈剤、増量剤、蛍光
染料、無機または有機ビルグー等を含むことができる。The cleaning composition of the present invention includes any anionic surfactant,
It can include cationic surfactants, nonionic surfactants, zwitterionic surfactants, hydrotropes, diluents, fillers, fluorescent dyes, inorganic or organic virgoos, and the like.
本発明の洗浄剤組戊物は、皮膚に対してマイルドであり
、かつ、優れた起泡力、洗浄力を有し、さらに低温にお
ける液体安定性が良好である。The cleansing composition of the present invention is mild to the skin, has excellent foaming power and cleansing power, and also has good liquid stability at low temperatures.
次に、実施例によって、本発明を更に具体的に説明する
。Next, the present invention will be explained in more detail with reference to Examples.
〈実施例１〜３〉
ウンデシルアルコール１モルに、グルコースを１．３モ
ル付加させたウンデシルグルコシドと、ドバノール２５
のエチレンオキサイド９モル付加体（Ｄ２５−９ＥＯと
記す）とを、次の割合で含む２０重量％水溶液の液体洗
浄剤組或物を調製し、後述の方法によって、洗浄力、起
泡力および液体安定性を評価した。<Examples 1 to 3> Undecyl glucoside in which 1.3 mol of glucose was added to 1 mol of undecyl alcohol, and Dovanol 25
A 20% by weight aqueous solution liquid detergent composition containing a 9 mole adduct of ethylene oxide (denoted as D25-9EO) in the following proportions was prepared, and the cleaning power, foaming power, and liquid detergent composition were prepared by the method described below. Stability was evaluated.
ウンデシルグルコシド（重合度ｌ．３）：Ｄ２５−９Ｅ
○
＝１７：３ 実施例１
〃 ＝１２：８ 実施例２
／／ ＝ １ ０ ： １ ０ 実施例３〈
比較例１〉
実施例１において、ウンデシルグルコシドの代わりに、
ドデシルグルコシドを用い、下表に示す割合で配合した
以外は、実施例１と同様の方法で調製・評価した。Undecyl glucoside (degree of polymerization 1.3): D25-9E
○ =17:3 Example 1 〃 =12:8 Example 2 // = 1 0 : 1 0 Example 3
Comparative Example 1> In Example 1, instead of undecyl glucoside,
It was prepared and evaluated in the same manner as in Example 1, except that dodecyl glucoside was used and blended in the proportions shown in the table below.
〈比較例２〉
比較例１において、ドデシルグルコシドの代わりに、デ
シルグルコシドを用いて、同様の方法で調製・評価した
。<Comparative Example 2> Comparative Example 1 was prepared and evaluated in the same manner as in Comparative Example 1 except that decyl glucoside was used instead of dodecyl glucoside.
（評価法）
（１）起泡力
洗浄組成物を、蒸留水で２００倍に希釈した水溶液２０
ｍＮと、油成分としてトリオレイン１ｇとを共栓付１０
０ｍｌメスシリンダーに入れ、共栓をして２０回激しく
上下に振蕩する。振蕩後、直ちに共栓を外して水平な場
所にメスシリンダーを静置し、泡の容量を目盛りから読
み取り、これを起泡力とする。(Evaluation method) (1) An aqueous solution 20 diluted with distilled water of a foaming power cleaning composition.
mN and 1 g of triolein as an oil component in a 10 mN bottle with a stopper.
Pour into a 0ml graduated cylinder, cover with a stopper, and shake vigorously up and down 20 times. Immediately after shaking, remove the stopper, place the graduated cylinder on a horizontal surface, read the foam volume from the scale, and use this as the foaming power.
（２）洗浄力
洗浄剤組或物１．５ｇを硬度３゜ＤＨの洗浄液１１に溶
解し、この溶液３００ｍｌを食器洗い用のたらい（直径
約４０ｃｍ）の中に入れる。このたらいの中で、スポン
ジを３０回手で握り泡をたてる。この洗浄液を含ませた
スポンジで、バター０．５ｇを塗布した直径２５ｃｍの
磁製の皿の表面を１０回、裏面を５回こする。この時の
洗浄液は、たらいの中に受け、さらに、バターの付着し
たスポンジをたらいの洗浄液中で１０回手で握り泡をた
てる。これを繰り返し、泡の高さが１ｍｍ以下になるま
で洗浄することのできた皿の枚数を洗浄力とする。(2) Detergent power Dissolve 1.5 g of the detergent composition in cleaning liquid 11 having a hardness of 3° DH, and place 300 ml of this solution in a dishwashing tub (diameter approximately 40 cm). In this tub, squeeze the sponge in your hands 30 times to create foam. Using a sponge soaked in this cleaning solution, rub the surface of a 25 cm diameter porcelain dish coated with 0.5 g of butter 10 times and the back 5 times. The cleaning liquid at this time is collected in a basin, and the butter-adhered sponge is then held in the cleaning liquid in the basin 10 times by hand to create foam. This is repeated, and the number of dishes that can be washed until the height of the bubbles becomes 1 mm or less is defined as the cleaning power.
（３）液体安定性
洗浄剤組成物を５℃に保った冷蔵庫中に静置し、沈澱が
生成するまでの日数によって液体安定性を評価する。(3) Liquid stability The detergent composition is left standing in a refrigerator maintained at 5° C., and the liquid stability is evaluated based on the number of days until a precipitate is formed.
Claims (2)
ルキルエーテルを含有する液体洗浄剤組成物において、
アルキルグリコシドとして、一般式（ I ）で示される
グリコシドを用いる液体洗浄剤組成物。 Ｒ＾１Ｏ（Ｚ）＿ｍ（ I ） （式中、Ｒ＾１は直鎖または分岐の炭素数１１のアルキ
ル基またはアルケニル基であり、Ｚは炭素数５または６
の還元糖から誘導される部分であり、ｍは１〜２の数で
ある）(1) In a liquid cleaning composition containing an alkyl glycoside and a polyoxyethylene alkyl ether,
A liquid detergent composition using a glycoside represented by general formula (I) as an alkyl glycoside. R^1O(Z)_m(I) (wherein, R^1 is a linear or branched alkyl group or alkenyl group having 11 carbon atoms, and Z is a straight-chain or branched alkyl group or alkenyl group having 5 or 6 carbon atoms.
(where m is a number from 1 to 2)
ルエーテルとの重量比が１０：１〜１：２であり、その
含有量が両者の和で１〜７０重量％である特許請求の範
囲第１項記載の液体洗浄剤組成物。(2) The weight ratio of alkyl glycoside and polyoxyethylene alkyl ether is 10:1 to 1:2, and the content thereof is 1 to 70% by weight in total. Liquid cleaning composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30879589A JPH03168298A (en) | 1989-11-28 | 1989-11-28 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30879589A JPH03168298A (en) | 1989-11-28 | 1989-11-28 | Liquid detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03168298A true JPH03168298A (en) | 1991-07-22 |
Family
ID=17985402
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30879589A Pending JPH03168298A (en) | 1989-11-28 | 1989-11-28 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03168298A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07509515A (en) * | 1992-07-30 | 1995-10-19 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Method for producing storable nonionic surfactant |
| US6235703B1 (en) | 1996-04-02 | 2001-05-22 | Lever Brothers, Division Of Conopco, Inc. | Surfactant blends, processes for preparing them and particulate detergent compositions containing them |
-
1989
- 1989-11-28 JP JP30879589A patent/JPH03168298A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07509515A (en) * | 1992-07-30 | 1995-10-19 | ヘンケル・コマンディットゲゼルシャフト・アウフ・アクチェン | Method for producing storable nonionic surfactant |
| US6235703B1 (en) | 1996-04-02 | 2001-05-22 | Lever Brothers, Division Of Conopco, Inc. | Surfactant blends, processes for preparing them and particulate detergent compositions containing them |
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