JPH03159995A - Doping in epitaxial crystal growth process - Google Patents

Abstract

PURPOSE:To obtain a crystal having strictly controlled impurity content by varying the temperature of substrate synchronous to the introduction of a raw material gas and a dopant compound gas. CONSTITUTION:A group III compound gas and a group V compound gas are alternately introduced into the system under respective specific pressure for specific period. A dopant-containing compound gas is introduced synchronous to a part of the period in the exhaustion stage of the group V compound gas, the exhaustion stage of the group III compound gas or the introducing stage of the group III compound gas and, at the same time, the substrate temperature is varied synchronous to the introduction of the doping gas.

Description

DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a doping method in epitaxial crystal growth, and particularly to a doping method in epitaxial crystal growth that has film thickness controllability on the order of a monomolecular layer.

[Conventional technology]

Conventionally, molecular beam epitaxy (hereinafter referred to as MBE) and metal organic vapor phase epitaxial growth (hereinafter referred to as MOCV.D) have been commonly used as thin film crystal growth techniques for semiconductors, for example, and particularly for compound semiconductors. teeth,
These methods have been widely used in the fabrication of semiconductor devices.

The above-mentioned MC)-CVD is widely used because of its simple device structure and excellent mass productivity, but it has not been possible to control the thickness of the grown film on the order of a monomolecular layer. This MO-
In the CVD doping technique, a compound gas of a semiconductor constituent element and a compound gas of a dopant are simultaneously introduced onto a substrate crystal.

In addition, the above-mentioned MBE uses a method of heating the raw material and depositing the vapor of the raw material onto the substrate crystal, and the crystal growth rate can be made very small. is better than. The doping method in MBE is performed by simultaneously depositing the vapor of the dopant element on the substrate crystal together with the vapor of the raw material element. In order to obtain high quality crystals with this MBE,
3 For example, in the case of GaAs, the crystal growth temperature is set to 500 to 600.
It is necessary to set the temperature to a high temperature of °C.
When creating a steep impurity profile such as pn or pnp, redistribution of impurities becomes a problem. Furthermore, since MBE is based on a vapor deposition method, there are problems in that the grown film deviates from the stoichiometric composition and crystal defects such as oval defects occur.

Due to these disadvantages, in recent years molecular layer epitaxy (Molecul
ar layer epitaxy (hereinafter referred to as MLE) is attracting attention.

This MLE is, in the case of crystal growth of ■-V group compounds,
This is a method in which a Group 1 compound gas and a Group V compound gas are alternately introduced onto a substrate crystal to grow the crystal one monolayer at a time.

For example, Junichi Nishizawa et al.'s paper rJ. Nishi
zawa, H. Abe and T. Kurab
ayashi; J. EIectrochem, S
oc. 132 (1985) 1197 ~ 120o"
has been reported.

4. MLE utilizes the adsorption and surface reaction of compound gases, and for example, in the case of Group 1 V crystals, a monomolecular film growth layer is obtained by introducing Group 2 compound gas and Group V compound gas once each. .

In this manner, MLE utilizes monomolecular layer adsorption of a compound gas, so that even if the pressure of the introduced gas changes, growth can always be performed on the order of monomolecular layers within a certain pressure range.

Furthermore, this MLE is effective in crystal growth of GaAs.
Trimethyl gallium (TMG), an alkyl gallium
However, by using triethylgallium (TEG), which is an alkyl gallium, in place of TMG, high-purity GaAsIfi. Long layers can be obtained by growing at lower temperatures.

This can be seen, for example, in the paper by Junichi Nishizawa et al.
zaua. H. Abe, T. Kurabaya
shi and N. Sakurai;J. Vac
．． Sci. Technol. A4 (3), (19
86) reported in 706-710 J.

In addition, the doping method using MLE described above is TEC
, ASI{3 compound gas, and a dopant compound gas are separately and sequentially introduced onto the substrate crystal surface. This makes it possible to obtain high purity crystals with controlled impurities, including highly doped crystals, at low temperatures.

Furthermore, since MLE grows a crystalline film at a low temperature, there is very little redistribution of impurities and a steep impurity profile can be achieved.

For example, Junichi Nishizawa et al.'s paper rJ. Nishi
zawa + H. Abe and T. Kurab
ayashi; J. Blectrochem. S
oc. Vol. 136, No. 2 pp. 478
~484 (1989).

[Problem to be solved by the invention]

By the way, for example, in order to obtain an excellent semiconductor device, it is necessary to obtain a grown film with an even higher impurity density and to realize crystal growth at a lower temperature.

Therefore, it is desired to further improve the doping method in molecular layer evixaxial crystal growth.

In view of the above-mentioned problems, an object of the present invention is to develop an evitaxy method that is based on the basic concept of molecular layer evitaxy and is capable of producing a film grown at a low temperature with a high impurity density on the order of a monomolecular layer with strictly impurity control. An object of the present invention is to provide a doping method in crystal growth.

[Means to solve the problem]

In order to achieve the above object, the doping method for epitaxial growth of the present invention includes doping a gas containing a dopant such as GaAs and Si, Te, S, Ge, Zn, and Cd onto a substrate crystal in a crystal growth chamber maintained in vacuum.
In epitaxial crystal growth, in which a single crystal is grown by sequentially introducing at least one of gases containing a dopant such as It is controlled so that it changes in synchronization with the time.

Furthermore, in an epitaxial growth stage in which a single crystal is grown by sequentially introducing at least one of a gas containing a crystal growth component and a gas containing a dopant onto the substrate crystal in a crystal growth chamber maintained in a vacuum, each gas is is introduced at a predetermined pressure for a predetermined time, the substrate temperature changes in synchronization with the time when at least one of the gases is introduced, and light that is constant or changes in synchronization with the substrate temperature is applied to the substrate crystal. This is achieved by arranging a structure to irradiate the light.

(Function) According to the above precepts, on a substrate crystal heated in vacuum,
When the raw material gas and the dopane 1 compound gas are sequentially introduced, the substrate temperature is modulated in synchronization with each gas introduction to obtain a crystal with strictly impurity control.

When a raw material compound gas is alternately introduced onto a substrate heated in vacuum, a single crystal grows monomolecularly layer by layer through surface adsorption or deposition and surface reaction.

For example, in the crystal growth of GaAs, the raw material for Ga is T.
MG (}limethylgallium), TEG (}ethylgallium), DMGaCI (dimethylgallium chloride), DEGaC] (diethylgallium chloride) and GaCls (gallium trichloride) are used. In addition, As source gas is AsH*
(arsine), TMAs (}limethylarsenic), TEAs
(}ethyl arsenic) and ASCl3 (arsenic trichloride) are used.

Conventionally, crystal growth has been performed while keeping the temperature of the substrate crystal constant.

However, when growing strictly on the order of monomolecular layers, or when introducing a dopant compound gas and incorporating the dopant into the crystal, the optimal temperature value is set for the temperature for growing monomolecular layers and the doping temperature. It was found that it was necessary to modulate the substrate temperature because of the difference in

For example, when using Zn as a dopant, DEZ
n (diethylzinc) is introduced onto the substrate crystal, but at this time it is necessary that the substrate temperature is 350 ° C or less,
When introducing AsH3, from the viewpoint of crystallinity of the grown film, 35
It is desirable that the temperature is 0°C or higher.

In other words, when a dopant causes a surface reaction on the substrate crystal surface and is adsorbed, re-evaporation of the dopant becomes a problem when the temperature exceeds a certain temperature, and when the temperature falls below a certain temperature, the surface reaction does not occur and the raw material elements are not adsorbed onto the substrate crystal surface. arise.

Furthermore, if the growth temperature is selected by considering only the dopant, the growth reaction will be limited.

The above-mentioned content also applies to the case of Si growth, and S
It is also effective for doping when iHzC1x and H2 are used as raw materials and these are alternately introduced onto the substrate crystal.

Furthermore, by irradiating the substrate crystal surface or the gas phase during crystal growth with ultraviolet rays or the like in synchronization with the timing of gas introduction, a single crystal with impurities strictly controlled can be obtained at a lower temperature.

〔Example〕

DESCRIPTION OF THE PREFERRED EMBODIMENTS Preferred embodiments of the present invention will be described in detail below with reference to the accompanying drawings, taking epitaxial crystal growth of semiconductors as an example.

Figure 1 is a time chart regarding the conventional doping method used in molecular layer epitaxy.
This figure shows an example of molecular layer epitaxy of GaAs based on E G AsHs .

That is, in a crystal growth method in which TEG and ASH3 are alternately introduced onto a substrate crystal at a predetermined pressure and for a predetermined period of time, compound gases containing dopants are introduced into the following gases (A) to (D). Select and install one of the modes.

In mode (A), doping gas is introduced in synchronization with the exhaust of ^sH3.

In mode (B), doping gas is introduced in synchronization with the introduction of TEG.

In mode (C), doping gas is introduced in synchronization with TEG exhaust.

In mode (D), doping gas is introduced in synchronization with the introduction of AsH3.

FIGS. 2(a) and 2(b) show time charts of a first embodiment of a doping method in epitaxial growth of a semiconductor crystal.

Figure 2(a) shows GaA by (TEG-8sH3) system.
represents the doping mode in the molecular layer ebitaxis of s. Similar to the example in FIG. 1, TEG and AsH2 are alternately introduced onto the l1 substrate crystal at a predetermined pressure and for a predetermined time, and the compound gas containing the dopant is It is introduced in synchronization with part of the time when G is introduced, TEG is exhausted, and Ashs is introduced, and is represented as the above-mentioned (A), (B)', (C), and (D) modes, respectively.

For example, taking mode (C) as an example, a compound gas containing a dopant is introduced onto the substrate crystal in synchronization with a part of the TEG exhaust, but at this time, as shown in the figure, t, The introduction waiting time, t@, is the introduction time of the compound gas containing the dopant + 1. is the exhaust time of the gas containing the dopant. The timing of gas introduction is determined by selecting the times t7, tB, and tq.

Figure 2 (1+) shows the method of modulating the growth temperature.
This represents a method of varying the substrate temperature by using a decoy period when introducing each of the doping gases in modes (A) to (D) above.

That is, when the doping gas is introduced (on), the substrate temperature is T1, and in other cases (OFF), the substrate temperature is Tztea12. This T1 varies depending on the type of doping gas, and T1
, >72 and TI<72.

For example, in the case of GaAs, Sf is used as a doping gas.
J6+ SiH4, DETe, DESe,
DBS, GeH4+H. S, HzSe+DM
Zn, DEZn, DMCd, etc. are used, but they all have different optimum temperatures T1.

Moreover, the temperature value of T2 varies depending on the raw material gas of the semiconductor.

For example, in molecular layer epitaxy of GaAs, the Ga raw materials are TMG, TEG, DMGaCl, 'DEGaCl
and GaC1. is used, and TMA is used as the raw material for As.
s, TEAs and ASC13 are used.

Figure 3 shows the doping mode shown in Figure 2(a) above in which DESe is introduced onto the substrate crystal in each of the above modes in the molecular layer epitaxial growth method (TEG ASH3), and the crystal is grown monolayer by monolayer. This is the result when doing this.

The growth conditions were a growth temperature of 350°C and the introduction of ^sH3 (D
) is 10 seconds, AsH3 exhaust (A) is 5 seconds, TEG introduction (B); /+<6 seconds, TEG (7) exhaust (C) is 5 seconds.
Seconds.

In all these modes, the introduction latency tl+ta.
t7tlo is 2 seconds, introduction time t2, t5, to,
j++ is 2 seconds. As illustrated above (
The maximum carrier density was obtained in A) mode.

Further, FIG. 4 shows carrier density values using the growth temperature modulation shown in FIG. 2(b) above.

In this case, the substrate temperature (T
2) is 350'C, and the substrate temperature (T,) is changed only when DESe is introduced. In this case, since it was necessary to rapidly change the substrate temperature, an infrared lamp was used to heat the substrate crystal. It is advantageous to heat only the substrate crystal with this infrared lamp because the heat capacity of the controlled portion can be reduced.

As a result, it was found that the lower T was, the more highly doped crystals could be obtained. In this case as well, by introducing TEG and AsH3 once each, GaAs can be grown one monolayer at a time.

Furthermore, FIG. 5 relates to the time tissate method of modulating the growth temperature in the same way as FIG. 2(b), but in this case,
As}+3 when introduced (D) and As 11 3 exhausted (
A), the substrate temperature is modulated during TEG introduction (B) and TBG exhaust (C). This method can be applied to both doped growth and non-doped growth. If the temperature T3 is raised only during the introduction of AsHs (D), the reaction efficiency of AsH3 can be increased and the time for introducing AsH3 can be shortened. Furthermore, if the temperature T is raised after the introduction of TEG [after (B)], the surface migration of the surface-adsorbed particles, which are Ga compounds, will be promoted, and crystals with high integrity can be obtained.

Furthermore, according to this method, the temperature can be raised only in the reaction portions that require high temperatures, and the other portions can be kept as low as possible, so that a low-temperature process can be realized as a whole. Therefore, a highly doped crystal with high perfection can be obtained, and a junction with a steep impurity profile with almost no redistribution of impurities can be created.

The doping method in semiconductor epitaxial growth described above uses Plh (phosphine) instead of ASH3.
Use GaP molecular layer epitaxial precepts 15? It can be used as a doping method in

In addition, TEAI can be used instead of Ga compound gas such as TEG.
(1-liethynoleanoreminium), TIBAI (
triisobutylaluminum). DIBAIH
AI compound gases such as (diisobutyl aluminum hydrogen), TMIn (}trimethylindium), TEIn (}
By using In compound gas such as ethyl indium), AIAs, AIP+ TnAs, InP
It can be used as a doping method in molecular layer epitaxial growth such as. Furthermore, ternary and quaternary mixed crystals 8lx Gal-XAs, Alx Ga+
−P, In)(Ga+−X As, I
n. Ga+-M P , 8 IAs, . P, -,,
GaAsyP. ,, rnAsy P+-y,
^IX Gal-x Asy pl-ITInX
Ga. (2) It can be used as a doping method in molecular layer epitaxial growth of AsyP, -y, etc.

Further, FIG. 6 shows the doping mode of a compound gas containing a dopant in molecular layer epitaxial growth of (SiHzCIzHz)-based Si.

l6? That is, in a crystal growth method in which SiH, +CI■ and 11■ are alternately introduced onto a substrate crystal at a predetermined pressure and for a predetermined time, a compound gas containing a dopant is One of the gas introduction modes (C") is selected and introduced.

(The mode of A゛〉 is SiHzC1. Doping gas is introduced in synchronization with the exhaust of the gas.

In mode (B), doping gas is introduced in synchronization with the introduction of H2.

In the (C°) mode, doping gas is introduced in synchronization with +12 exhaust.

In mode (D'), doping gas is introduced in synchronization with the introduction of SiHzCIz.

FIGS. 7(a) and 7(b) show time charts of a second embodiment of the doping method of the present invention in epitaxial growth of semiconductor crystals.

FIG. 7(a) shows S by the (SiHzCh H2) system.
represents the doping mode in the molecular layer ebitaxy of i. Sill ■ C1 as in the example of FIG. and 112 are respectively applied on the substrate crystal at a predetermined pressure for a predetermined time? The dopant-containing compound gas is introduced alternately, and the compound gas containing the dopant is introduced at the time of evacuation of the SiHzCIz and at the time of introduction of 112. They are introduced in synchronization with part of the time when H2 is exhausted and SiHzC12 is introduced, and the above (A'). (B'). (C
'), (D') mode.

For example, taking the (C゛) mode as an example, a gas containing a dopant is introduced onto the substrate crystal in synchronization with a part of the Ht exhaust time, but the introduction waiting time at this time is t.
27. The introduction time is t2■ and the exhaust time is t29.

In addition, FIG. 7(b) shows a method of modulating the growth temperature in Si molecular layer epitaxy.
This represents a method of changing the substrate temperature in synchronization with the introduction of each doping gas in the ~(D'') mode.

That is, when the doping gas is introduced (ON), the substrate temperature is Tz+, and in other cases (OFF), it is T2■.

This T2I varies depending on the type of doping gas, and T2I varies depending on the type of doping gas.
2. >T, ■ and Tel <72■, which can be used depending on the type of doping gas.

For example, in the case of St, examples of compound gases containing dopant include BzH6, PH3, 8sH. ,, GeHa
etc., but all have different optimum temperatures T21.

Furthermore, FIG. 8 relates to a time chart of a method of modulating the growth temperature similarly to FIG. 7(b), but in this case,
SiH2C]2 (D゛) and SiH. C.I. The temperature of the substrate during growth is modulated at the time of evacuation of (A'), the time of introduction of HZ (B'), and the time of evacuation of H2 (C'). This method can be applied to both doped growth and non-doped growth in Si molecular layer epitaxy. For example, after introducing SiHiC1z (after D"), the temperature Tl?
If the S'i compound is increased, the surface migration of the S'i compound adsorbed on the surface is promoted, and a crystal with high integrity can be obtained.

Moreover, if the temperature T2S is raised during Ha introduction (B'), the reaction efficiency with H2 will increase and the time for introducing H2 can be shortened.

According to this method, the temperature can be raised only in the parts that require a high temperature, and the temperature in other parts can be kept as low as possible, making it possible to realize a low-temperature process as a whole. Therefore, a highly doped crystal with high perfection can be obtained, and a junction with a steep impurity profile with almost no redistribution of impurities can be created.

Also, the doping method of the present invention in epitaxial growth of semiconductor crystals. The third embodiment is shown in FIG.
) and Figures 5, 7(b), and 8, by irradiating the substrate crystal with light of a specific wavelength in synchronization with the modulation of its temperature, the lattice points where impurities enter can be precisely controlled. , it is possible to obtain crystals with higher perfection.

The wavelength of this light can be specified depending on the type of compound containing the dopant, and usually ultraviolet light in the range of 150 to 600 r+m is effective.

FIG. 9 shows an example of a crystal growth apparatus for carrying out the doping method of the present invention in epitaxial growth of semiconductor crystals.

As shown in the figure, the main body of the crystal growth apparatus 1 consists of a closed container 2.

A gate valve 3 is interposed in this airtight container 2, a vacuum evacuation device 4 such as a turbo molecular pump is provided below this gate valve 3, and a crystal growth chamber 5 is provided above. .

A susceptor 6 and a substrate crystal 7 are housed inside the crystal growth chamber 5 .

Further, in the crystal growth chamber 5, facing the substrate crystal 7, there are a raw material gas introduction nozzle 8 and a doping gas introduction nozzle 9.
are provided facing each other.

The raw material gas introduction nozzle 8 and the doping gas introduction nozzle 9 are provided with control valves 8a and 9a, respectively.

These control valves 8a and 9a each have a first
It is connected to a sequencer 11 via an interface 10 .

Further, an infrared lamp house 12 for heating the substrate crystal 7 is provided in the upper part of the crystal growth chamber 5, and an infrared lamp 13 is provided inside the house. This infrared lamp 13 includes an infrared lamp power control device 14.
is provided.

On both sides of the infrared lamp 13 of the infrared lamp house 12, entrance windows 15a and 15b are provided through which light passes. These incident windows 15a to 45b are provided at angles such that the light passing through them has a predetermined incident angle θ with respect to the substrate crystal. The above entrance window 15a
, 15b are provided with light sources 17a, 17b. The entrance windows 15a, 15b and the light sources 17a, 17b
Choppers 18a and 18b for chopping the irradiated light 16a and 16b are interposed between the two.

Further, a substrate temperature measurement window 19 is provided at the upper end of the crystal growth chamber 5, and a temperature measurement pipe-hole meter 20 is provided outside of this substrate temperature measurement window 19.

The choppers 18a, 18b and the infrared lamp power control device W14 are connected to the second interface 2, respectively.
1 to the sequencer 11.

The thermometer 20 is connected to a line connecting the infrared lamp power control device 14 and the second interface 21 .

The sequencer 11 includes an image output 22, a storage device 2
3 and a human power terminal 24.

Raw material gas introduction nozzle 8 and doping gas introduction nozzle 9
The amounts of source gas and doping gas introduced onto the substrate crystal are adjusted by controlling the control valves 8a and 9a, respectively, based on the output of the sequencer 11.

At the same time, the substrate temperature is regulated by converting the output of the sequencer 11 by the second interface 21 and controlling the infrared lamp power control device 14 and the temperature measuring pipe meter 20.

In addition, the outputs of the infrared lamp power control device 14 and the temperature measuring pyrometer 20 are controlled by the choppers 18a and 18b.
, and the irradiation lights 16a and 16b are turned on and off.

With such a device, the present invention can be realized,
The present invention is also a technology suitable for manufacturing active layers necessary for LSIs and ultrahigh-speed ICs.

Although the present invention has been described using an example of semiconductor crystal growth, the present invention is not limited to this, and can of course be applied to various types of single crystals produced by epitaxial growth.

=23 [Effects of the Invention] As described above, the doping method for epitaxial crystal growth of the present invention is such that each of the source gas and the dopant compound gas is alternately introduced in a predetermined order onto a substrate crystal heated in vacuum. By modulating the substrate temperature in synchronization with the gas introduction, impurities can be strictly controlled at low temperatures and crystals doped with high concentrations of impurities can be obtained.

According to this method, a junction with a steep impurity profile can be obtained, and the lattice points where the impurity enters can be strictly controlled, so that a perfect crystal can be obtained.

[Brief explanation of the drawing]

FIG. 1 is a graph showing a time chart regarding the doping gas introduction method in GaAs molecular layer ebitaxis. FIG. 2 is a graph showing a time chart of the first embodiment of the doping method in epitaxial growth of the present invention, and (a) shows the doping mode in molecular layer epitaxy of GaAs by the (TE G ASl+3) system. (b) represents the method of modulating the growth temperature. FIG. 3 is a graph showing the doping method according to the first embodiment of the present invention, which is a graph showing the results when crystal growth is performed by introducing DESe in (TEG AsHs) system molecular layer ebitaxis, and FIG. A graph showing the results when DESe is introduced and temperature modulated in -^ski) system molecular layer epitaxy. Figure 5 is a time chart according to the first embodiment of the present invention in which the substrate temperature is modulated when the source gas is introduced. This is a graph showing. Figure 6 is a graph showing a time chart regarding the doping gas introduction method in Si molecular layer epitaxy;
The figure is a graph showing a time chart of the second embodiment of the doping method in epitaxial growth of the present invention, in which (a) represents the doping mode in molecular layer epitaxy of Si by the (SiHzCIzH2) system;
b) represents a method of modulating the growth temperature in Si molecular layer epitaxy. FIG. 8 is a graph showing a time chart according to a second embodiment of the present invention in which the substrate temperature is modulated when the source gas is introduced. FIG. 9 is a schematic diagram showing a crystal growth apparatus used to carry out the present invention. l...Crystal growth device; 4...Vacuum exhaust device;5.
...Crystal growth chamber; 7. Substrate crystal; 8. Source gas introduction nozzle; 9. Doping gas introduction nozzle;
11... Sequencer; 13... Infrared lamp; 16a, 16b... Irradiation light: 20... Pyrometer for temperature measurement.

Claims (7)

[Claims] (1) On a substrate crystal in a crystal growth chamber kept in vacuum,
In epitaxial crystal growth in which a single crystal is grown by sequentially introducing at least one of a gas containing a crystal growth component and a gas containing a dopant, when each gas is introduced at a predetermined pressure for a predetermined time, the substrate temperature is at least A doping method for epitaxial crystal growth characterized by changing one gas in synchronization with the time when one gas is introduced. (2) The doping method for epitaxial crystal growth according to claim 1, wherein the gas containing the crystal growth component contains elements of group III and group V. (3) The gas containing the element and the dopant is S
2. The doping method for epitaxial crystal growth according to claim 1, wherein the doping method is one of a compound gas of i, Te, S, Ge, Zn, and Cd. (4) The gas containing the crystal growth component contains Si element, and the gas containing the dopant contains B, P, As, etc.
Claim 1, characterized in that the gas is a compound gas of a group III or V element and a group IV element such as Sn or Ge.
Doping method in epitaxial crystal growth described in . (5) The doping method for epitaxial crystal growth according to claim 1, wherein the substrate temperature is changed in synchronization with the time when a gas containing a dopant is introduced. (6) The doping method for epitaxial crystal growth according to claim 1, wherein the substrate temperature is changed in synchronization with the time when a gas containing a crystal growth component is introduced. (7) On the substrate crystal in a crystal growth chamber kept in vacuum,
In epitaxial crystal growth in which a single crystal is grown by sequentially introducing at least one of a gas containing a crystal growth component and a gas containing a dopant, when each gas is introduced at a predetermined pressure for a predetermined time, the substrate temperature is at least Doping in epitaxial crystal growth characterized by changing in synchronization with the time when one of the gases is introduced, and irradiating the substrate crystal with light that is constant or changes in synchronization with the substrate temperature. Method.