JPH03156000A - Water-collapsible transfer sheet having three-dimensional pattern - Google Patents
Water-collapsible transfer sheet having three-dimensional patternInfo
- Publication number
- JPH03156000A JPH03156000A JP29693989A JP29693989A JPH03156000A JP H03156000 A JPH03156000 A JP H03156000A JP 29693989 A JP29693989 A JP 29693989A JP 29693989 A JP29693989 A JP 29693989A JP H03156000 A JPH03156000 A JP H03156000A
- Authority
- JP
- Japan
- Prior art keywords
- water
- sheet
- dimensional pattern
- layer
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 18
- 239000000126 substance Substances 0.000 claims abstract description 11
- 238000007740 vapor deposition Methods 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 6
- 239000012790 adhesive layer Substances 0.000 claims description 4
- 239000011241 protective layer Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 18
- 229920005989 resin Polymers 0.000 abstract description 15
- 239000011347 resin Substances 0.000 abstract description 15
- 229920003002 synthetic resin Polymers 0.000 abstract description 13
- 239000000057 synthetic resin Substances 0.000 abstract description 13
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract description 8
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 8
- 238000001816 cooling Methods 0.000 abstract description 6
- 229920001169 thermoplastic Polymers 0.000 abstract description 6
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 6
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 abstract description 2
- 239000001856 Ethyl cellulose Substances 0.000 abstract description 2
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004373 Pullulan Substances 0.000 abstract description 2
- 229920001218 Pullulan Polymers 0.000 abstract description 2
- 229920001525 carrageenan Polymers 0.000 abstract description 2
- 239000001913 cellulose Substances 0.000 abstract description 2
- 229920002678 cellulose Polymers 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract description 2
- 235000010944 ethyl methyl cellulose Nutrition 0.000 abstract description 2
- 150000004676 glycans Chemical class 0.000 abstract description 2
- 229920000609 methyl cellulose Polymers 0.000 abstract description 2
- 239000001923 methylcellulose Substances 0.000 abstract description 2
- 235000010981 methylcellulose Nutrition 0.000 abstract description 2
- 229920003087 methylethyl cellulose Polymers 0.000 abstract description 2
- 229920002432 poly(vinyl methyl ether) polymer Polymers 0.000 abstract description 2
- 229920001282 polysaccharide Polymers 0.000 abstract description 2
- 239000005017 polysaccharide Substances 0.000 abstract description 2
- 235000019423 pullulan Nutrition 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- -1 polypropylene Polymers 0.000 description 6
- 229920001155 polypropylene Polymers 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 238000003475 lamination Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010884 ion-beam technique Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Decoration By Transfer Pictures (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は立体模様を有する水崩壊性転写シートに関し、
更に詳しくは、立体模様を有し高級感に冨み、特に３次
元を有する被写体に好適な水圧転写可能の水崩壊性転写
シートに関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a water-disintegrable transfer sheet having a three-dimensional pattern,
More specifically, the present invention relates to a water-disintegratable transfer sheet that has a three-dimensional pattern, has a luxurious feel, and is particularly suitable for three-dimensional objects, and is capable of hydraulic transfer.
水圧転写とは絵付けや印刷を行なう方法の一種で、従来
、水可溶性フィルムもしくは水膨潤性フィルムに絵や文
字を印刷し、該印刷フィルムの印刷面を上面にして印刷
フィルムを水面に浮かべ、目的とする被写体をその上面
から押し入れることにより、水圧により絵や文字などの
印刷を被写体に転写するものである。Water pressure transfer is a type of painting or printing method. Conventionally, pictures and letters are printed on a water-soluble or water-swellable film, and the printing film is floated on the water surface with the printed side facing up. By pushing the target object from above, water pressure transfers prints such as pictures and letters onto the object.
しかし乍ら、これらの方法では転写した絵などの表面は
、いずれも平坦であるため、いかに美麗な絵柄を転写し
たとしても絵柄表面に立体模様や遠近模様を有し、光沢
度や色調の組み合わせによる立体感を備えたものに比べ
た場合、平凡且つ地味である印象を免れない。However, with these methods, the surface of the transferred picture is flat, so no matter how beautiful the picture is transferred, the surface of the picture will have a three-dimensional pattern or perspective pattern, and the combination of gloss and color tone will be affected. When compared to those with a three-dimensional effect, the impression is unavoidable that they are ordinary and plain.
本発明者らはかかる実情に鑑み、上記問題点を解消する
べく鋭意研究の結果、本発明を完成した。In view of these circumstances, the present inventors completed the present invention as a result of intensive research to solve the above problems.
即ち、本発明はシート状の水溶性物質もしくは水膨潤性
物質からなる水崩壊性シート表面に立体模様を設け、該
立体模様面上に印刷層又は蒸着層又はこれらの両層を設
けてなる水崩壊性転写シートを内容とするものである。That is, the present invention provides a water-disintegrating sheet made of a sheet-like water-soluble or water-swellable substance with a three-dimensional pattern on the surface thereof, and a printed layer, a vapor deposited layer, or both of these layers on the surface of the three-dimensional pattern. It contains a collapsible transfer sheet.
本発明に用いられる水溶性物質又は水膨潤性物質として
は、水中で溶解又は膨潤する物質であれば特に制限はな
く、ポリビニルアルコール、ポリビニルメチルエーテル
、ポリビニルイソブチルエーテル、ポリビニルピロリド
ン、ポリアクリルアミド、ポリアクリル酸ソーダ、ポリ
エチレンオキシド等の合成樹脂、カルボキシメチルセル
ローズ、メチルセルローズ、エチルセルローズ、ヒドロ
キシエチルセルローズ等のセルローズ誘導体、カラギー
ナン、プルラン、でんぷん等のポリサッカライド等が例
示される。The water-soluble or water-swellable substances used in the present invention are not particularly limited as long as they dissolve or swell in water, such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl isobutyl ether, polyvinyl pyrrolidone, polyacrylamide, polyacrylic Examples include synthetic resins such as acid soda and polyethylene oxide, cellulose derivatives such as carboxymethyl cellulose, methyl cellulose, ethyl cellulose, and hydroxyethyl cellulose, and polysaccharides such as carrageenan, pullulan, and starch.
シート状の水溶性物質もしくは水膨潤性物質に立体模様
を付与する方法としては、例えば予め立体模様を付与し
た合成樹脂シート（基材を有していてもよい）の表面に
水溶性物質もしくは水膨潤性物質の水溶液をマイヤバー
等を用いてコーティングを行なった後、乾燥して合成樹
脂シートセコ−ティング層とを剥離する方法が好適に用
いられる。As a method for imparting a three-dimensional pattern to a sheet-shaped water-soluble substance or water-swellable substance, for example, a water-soluble substance or water-swellable substance is applied to the surface of a synthetic resin sheet (which may have a base material) that has been previously imparted with a three-dimensional pattern. A preferred method is to apply a coating with an aqueous solution of a swellable substance using a Meyer bar or the like, then dry it and peel off the synthetic resin sheet secoating layer.
立体模様を付与した合成樹脂シートは特に制限されない
が、押出法によるのが好ましい。The synthetic resin sheet provided with a three-dimensional pattern is not particularly limited, but it is preferably formed by an extrusion method.
先ず第１の方法は、凹凸面を有するシートの凹凸面に熱
可塑性合成樹脂をフィルム状に押出して圧着、冷却した
後、前記シートを剥離分離して前記シートの凹凸を樹脂
フィルム層の表面に転写させる方法である。また、いわ
ゆる押出ラミネート法のサンドインチラミネート方式を
利用し、基材層と上記凹凸面を有するシートの凹凸面と
の間に熱可塑性合成樹脂をフィルム状に押出し、圧着、
冷却後に前記シートを剥離分離してもよい。この場合、
樹脂と凹凸を有するシートとはお互いに離型する組み合
わせでなければならない。この組み合わせは、熱可塑性
合成樹脂として、例えば、ポリエチレン樹脂やポリプロ
ピレン樹脂を使用した場合は、上記シートとしてはポリ
エステル系樹脂やポリ−４−メチルペンテン−１樹脂等
が好適である。また、上記シートは特に制限はなく、樹
脂（発泡体も含む）シート（フィルム）、金属箔、金属
蒸着フィルム、ラミネート紙等が例示され、押出した樹
脂との剥離性を上げるためのシリコン処理などを行って
も差し支えない。また、シートの凹凸は従来のエンボス
加工による凹凸はもちろん、印刷による凹凸も含まれる
。印刷による凹凸はインク（顔料等の他、金属粉、セラ
ミック粉、金属酸化物等印刷に使用できる粉状物、粒状
物）の量及び色を適宜組み合わせ（即ち、これらの粒子
径、形状、分散度等を変化させ）、印刷法によりいろい
ろな段階の光沢度、色調（ｔｏｎｅ ）に組み合わせる
ことにより為される。First, the first method is to extrude a thermoplastic synthetic resin in the form of a film onto the uneven surface of a sheet having an uneven surface, press it, cool it, and then peel and separate the sheet to transfer the unevenness of the sheet to the surface of the resin film layer. This is a method of transferring. In addition, using the so-called sandwich lamination method of extrusion lamination method, a thermoplastic synthetic resin is extruded into a film between the base layer and the uneven surface of the sheet having the uneven surface, and the thermoplastic synthetic resin is pressed and bonded.
After cooling, the sheet may be peeled and separated. in this case,
The resin and the uneven sheet must be in a combination that allows them to be released from each other. In this combination, when polyethylene resin or polypropylene resin is used as the thermoplastic synthetic resin, for example, polyester resin or poly-4-methylpentene-1 resin is suitable for the sheet. In addition, the above-mentioned sheet is not particularly limited, and examples include resin (including foam) sheets (films), metal foil, metal-deposited film, laminated paper, etc., and silicon treatment to improve releasability from extruded resin. There is no harm in doing so. Further, the unevenness of the sheet includes not only unevenness caused by conventional embossing but also unevenness caused by printing. The unevenness caused by printing can be achieved by appropriately combining the amount and color of ink (powdered materials and granular materials that can be used for printing, such as pigments, metal powders, ceramic powders, and metal oxides) (i.e., the particle size, shape, and dispersion of these particles). This is achieved by combining various levels of gloss and tone using printing methods.
この製造方法による特徴は、エンボス加工の凹凸による
マクロ且つダイナミックな凹凸及び／又は印刷法による
ミクロ且つデリケートな凹凸を組合せ乱反射効果を一層
発現させることである。また加工上では、凹凸を有する
シートを取り替えるだけで所望の凹凸に手早く変更出来
るという利点がある。A feature of this manufacturing method is that it combines macroscopic and dynamic unevenness due to embossing and/or microscopic and delicate unevenness due to printing to further enhance the diffused reflection effect. Further, in processing, there is an advantage that the desired unevenness can be quickly changed by simply replacing the sheet having the unevenness.
第２の製造方法は、熱可塑性合成樹脂をフィルム状に押
出し、凹凸を有する冷却ロールを用いて圧着冷却し、前
記冷却ロールの凹凸を前記樹脂フィルム層の表面に転写
させる方法である。この場合には、使用する冷却ロール
の凹凸は所望する多様なものが得られる。The second manufacturing method is a method in which a thermoplastic synthetic resin is extruded into a film, cooled by pressure using a cooling roll having unevenness, and the unevenness of the cooling roll is transferred to the surface of the resin film layer. In this case, the cooling roll used can have various desired unevenness.
次に、上記の如くして得られた立体模様を有する水崩壊
性シート上に印刷層、蒸着層又はこれらの両層を設ける
ことにより立体模様を有した水崩壊性転写シートが得ら
れる。Next, a printing layer, a vapor deposition layer, or both of these layers are provided on the water-disintegrating sheet having a three-dimensional pattern obtained as described above, thereby obtaining a water-disintegrating transfer sheet having a three-dimensional pattern.
印刷方法としては特に制限はなく一般的な印刷方法で可
能であるが、好ましくはグラビア印刷、フレキソ印刷等
が挙げられる。また印刷インキは水に不溶なものであれ
ば任意のものでよい。蒸着を施す方法として真空蒸着法
、スパッタ法、イオンビーム法などが挙げられるが、本
発明においては真空蒸着法が最も好ましい。また用いら
れる物質としては特に制限はないが、好ましくはアルミ
ニウム、金、銀等が挙げられ、通常厚さ３００〜８００
人の範囲で蒸着される。There are no particular restrictions on the printing method, and general printing methods can be used, but gravure printing, flexographic printing, etc. are preferred. Further, any printing ink may be used as long as it is insoluble in water. Vapor deposition methods include vacuum evaporation, sputtering, and ion beam methods, but vacuum evaporation is most preferred in the present invention. The material to be used is not particularly limited, but aluminum, gold, silver, etc. are preferable, and the thickness is usually 300 to 800.
Deposited within human range.
本発明の水崩壊性転写シートにおいて印刷層及び／又は
蒸着層の上にあらかじめ接着層を設けてもよいが、転写
直前においてスプレ一方式等の公知の塗布方法で接着層
を設けてもよい。ここで使用される接着剤とは粘着剤、
粘接着剤を含み、印刷層又は蒸着層と目的とする被写体
とに対し接着性を有するものであれば任意のものでよい
。In the water-disintegrating transfer sheet of the present invention, an adhesive layer may be provided in advance on the printed layer and/or the vapor deposited layer, or the adhesive layer may be provided immediately before transfer by a known coating method such as a one-way spray method. The adhesive used here is adhesive,
Any material may be used as long as it contains an adhesive and has adhesive properties to the printed layer or vapor deposited layer and the intended subject.
尚、本発明における立体模様を有する水崩壊性転写シー
トにおいて、印刷、蒸着等の加工適性を向上させるため
に、立体模様面の裏面に水崩壊性のフィルムや紙等のシ
ート状基材を積層することも可能である。In addition, in the water-disintegrating transfer sheet having a three-dimensional pattern according to the present invention, in order to improve processing suitability for printing, vapor deposition, etc., a sheet-like base material such as a water-disintegrating film or paper is laminated on the back side of the three-dimensional pattern surface. It is also possible to do so.
また目的とする被写体に転写された絵柄等の印刷層立体
模様の表面を保護するために通常、転写した後の該表面
にオーバーコートが施されるが、本発明では立体模様を
有する水崩壊性転写シートの該模様面上に印刷層及び／
蒸着層を施す前にあらかじめ保護層を設けておき、印刷
層及び／又は蒸着層と共に転写させる方法を採用するこ
とができる。Furthermore, in order to protect the surface of the three-dimensional pattern of the printed layer such as a picture transferred to the target object, an overcoat is usually applied to the surface after the transfer, but in the present invention, the water-disintegrating A printing layer and/or a printing layer is formed on the patterned surface of the transfer sheet.
It is possible to adopt a method in which a protective layer is provided in advance before applying the vapor deposited layer, and the protective layer is transferred together with the printed layer and/or the vapor deposited layer.
本発明を実施例を挙げて更に詳細に説明するが、本発明
はこれらのみに制限されるものではない。The present invention will be explained in more detail with reference to Examples, but the present invention is not limited to these examples.
実施例
基材としての純白ロール紙（坪１１２７．９ｇ／ｒｒｒ
）上の押出樹脂と接する面に予めコロナ放電処理（３０
Ｗ ／ ｒｒｒ ／ｌｌ１ｉｎ ） 、Ｔダイ押出ラミ
ネート機（スクリュー径： １１５ｍｍ、 Ｌ／Ｄ ：
２５）を用いて、離型性を有する熱可塑性樹脂として
ポリプロピレン（三井石油化学工業製、［ハイボールＬ
Ａ２２１Ｊ）をＴダイ出口樹脂温度３００°Ｃ、スクリ
ュー回転数１３０ｒｐｍ、加工速度１５０ｍ／ｌｌ１ｉ
ｎ、樹脂厚さ２０ＩＩｍでの条件で押出した。Pure white roll paper (tsubo 1127.9g/rrr) as an example base material
) on the surface in contact with the extruded resin was previously subjected to corona discharge treatment (30
W/rrr/ll1in), T-die extrusion laminating machine (screw diameter: 115mm, L/D:
25), polypropylene (manufactured by Mitsui Petrochemical Industries, [Highball L]) was used as a thermoplastic resin with mold release properties.
A221J) at T-die outlet resin temperature 300°C, screw rotation speed 130 rpm, processing speed 150 m/ll1i
It was extruded under the following conditions: n, resin thickness 20 IIm.
又、一方で所定のパターンを印刷した面が上記樹脂と接
するように配置させたポリエステル印刷シートを、押出
樹脂を中央にはさむように（一般にポリサンドと呼ばれ
る）して、プレスロールにより圧着させ、冷却ロールに
より冷却後、該ラミネート物（印刷シート／ポリプロピ
レン樹脂／基材）を巻取機によって一体として巻取った
。巻き取られたラミネート物のポリプロピレン樹脂面か
ら印刷シートを剥離分離すると、表面に微妙な立体模様
を有するポリプロピレンラミネート紙が得られた。On the other hand, a printed polyester sheet is placed so that the surface printed with a predetermined pattern is in contact with the resin, the extruded resin is sandwiched in the center (generally called polysand), and the sheet is pressed with a press roll and cooled. After cooling with a roll, the laminate (printed sheet/polypropylene resin/substrate) was wound up as one piece with a winder. When the printed sheet was peeled and separated from the polypropylene resin surface of the rolled laminate, a polypropylene laminated paper having a delicate three-dimensional pattern on the surface was obtained.
上記の如くして得られた表面に立体模様を有するポリプ
ロピレンラミネート紙上にポリビニルアルコ−７１／
（Ｐ ＶＡ） １０％水溶液（ＰＶＡ：日本合成化学工
業株式会社製、ＮＨ−１７Ｑ）をマイヤーバーを用いて
固形分量で約４０８／ＩＴｆになるようにコーティング
を行なった。オーブンにて８０ ”ＣＸ ５分間乾燥後
、ポリプロピレンラミネート層とＰＶＡコーティング層
の間で剥離させると立体模様を有する厚さ約３５μｍの
ＰＶＡフィルムが得られた。Polyvinyl alcohol-71/
(PVA) A 10% aqueous solution (PVA: manufactured by Nippon Gosei Kagaku Kogyo Co., Ltd., NH-17Q) was coated using a Mayer bar so that the solid content was about 408/ITf. After drying in an oven at 80''CX for 5 minutes, peeling was performed between the polypropylene laminate layer and the PVA coating layer to obtain a PVA film with a thickness of about 35 μm having a three-dimensional pattern.
次に、該ＰＶＡフィルムの立体模様面上にグラビア印刷
で水不溶性インキを用いて絵柄を印刷し更に該印刷面上
にロールコーティング法によってアクリル系感熱接着剤
をコーティングして立体模様を有する水崩壊性転写シー
トを得た。この水崩壊性転写シートを水槽の水面上に接
着剤層を上面にして浮かべ、被写体としてＡＢＳ樹脂成
形品をその上面から押し入れて水圧により絵柄と立体模
様を同時に転写させた。被写体には立体感を有する絵柄
印刷が転写されており、方向性、光沢差を有し且つ立体
感、遠近感を持つ高級感に冨むものであった。Next, a pattern is printed on the three-dimensional patterned surface of the PVA film using water-insoluble ink by gravure printing, and then an acrylic heat-sensitive adhesive is coated on the printed surface using a roll coating method to form a water-decomposable three-dimensional pattern. A transfer sheet was obtained. This water-disintegratable transfer sheet was floated on the water surface of an aquarium with the adhesive layer on top, and an ABS resin molded article was pushed in from above as a subject, and the picture and three-dimensional pattern were simultaneously transferred by water pressure. A pattern print with a three-dimensional effect was transferred to the subject, and it had a sense of direction and gloss, and was rich in luxury with a three-dimensional effect and a sense of perspective.
比較例
立体模様を有しないＰＶＡフィルムを用いた他は実施例
と同様に操作した。被写体に転写された絵柄９刷は平坦
で方向性、光沢差や立体感、遠近感がなく平凡且つ地味
なものであった。Comparative Example The same procedure as in Example was carried out except that a PVA film without a three-dimensional pattern was used. The nine prints of the image transferred to the subject were flat and had no directionality, difference in gloss, three-dimensional effect, or sense of perspective, and were plain and plain.
軟土の通り、本発明によれば方向性、光沢差並びに立体
感、遠近感を有し、高級感に富む３次元曲面を有する被
写体を提供することができる。According to the present invention, it is possible to provide an object having a three-dimensional curved surface that has directionality, a difference in gloss, a three-dimensional effect, and a sense of perspective, and is rich in luxury.
Claims (1)
る水崩壊性シート表面に立体模様を設け、該立体模様面
上に印刷層又は蒸着層又はこれらの両層を設けてなる水
崩壊性転写シート。 ２、前記印刷層又は蒸着層又はこれらの両層の上に接着
層を設けてなる請求項１記載の水崩壊性転写シート。 ３、立体模様面上に保護層を設けてなる請求項１又は２
記載の水崩壊性転写シート。 ４、立体模様の反対面に水崩壊性のシート状基材を積層
してなる請求項１、２又は３記載の水崩壊性転写シート
。[Claims] 1. A three-dimensional pattern is provided on the surface of a water-disintegratable sheet made of a sheet-like water-soluble or water-swellable substance, and a printed layer, a vapor deposited layer, or both of these layers are provided on the surface of the three-dimensional pattern. A water-disintegrating transfer sheet. 2. The water-disintegratable transfer sheet according to claim 1, further comprising an adhesive layer provided on the printing layer, the vapor deposition layer, or both of these layers. 3. Claim 1 or 2, wherein a protective layer is provided on the three-dimensional pattern surface.
Water-disintegratable transfer sheet as described. 4. The water-disintegratable transfer sheet according to claim 1, 2 or 3, wherein a water-disintegratable sheet-like base material is laminated on the opposite side of the three-dimensional pattern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29693989A JPH03156000A (en) | 1989-11-14 | 1989-11-14 | Water-collapsible transfer sheet having three-dimensional pattern |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29693989A JPH03156000A (en) | 1989-11-14 | 1989-11-14 | Water-collapsible transfer sheet having three-dimensional pattern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03156000A true JPH03156000A (en) | 1991-07-03 |
Family
ID=17840135
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29693989A Pending JPH03156000A (en) | 1989-11-14 | 1989-11-14 | Water-collapsible transfer sheet having three-dimensional pattern |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03156000A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012060256A1 (en) | 2010-11-02 | 2012-05-10 | 船井電機株式会社 | Led lighting device and cable connection detection device |
| US10632777B2 (en) | 2014-12-01 | 2020-04-28 | Taica Corporation | Water pressure transfer method and water pressure transfer film |
-
1989
- 1989-11-14 JP JP29693989A patent/JPH03156000A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012060256A1 (en) | 2010-11-02 | 2012-05-10 | 船井電機株式会社 | Led lighting device and cable connection detection device |
| US10632777B2 (en) | 2014-12-01 | 2020-04-28 | Taica Corporation | Water pressure transfer method and water pressure transfer film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6924026B2 (en) | Foil laminate credit card and method of producing foil laminate credit card with double-sided printing | |
| US4484970A (en) | Method of applying decorative foil to materials | |
| US6874421B2 (en) | Ink jet transfer printing process | |
| US20020178940A1 (en) | Ink jet transfer printing process | |
| JPH03156000A (en) | Water-collapsible transfer sheet having three-dimensional pattern | |
| GB2084931A (en) | Heat transfer printing | |
| JPH04175248A (en) | Production of interlayer for laminated glass having colored band | |
| JPH09295497A (en) | Transfer sheet and transfer method using that | |
| JP2864917B2 (en) | Manufacturing method of packaging material with hologram | |
| JP4202810B2 (en) | Film bonding paper and method for producing the same | |
| JPH0521437Y2 (en) | ||
| JP2908876B2 (en) | Laminated material | |
| JPH0326540A (en) | Base material partially having insulating metal membrane and method for partially applying insulating metal membrane | |
| JP3011442B2 (en) | Injection molding simultaneous transfer method | |
| JPH03106644A (en) | Hot water collapsible sheet having solid pattern | |
| JPS61291199A (en) | Manufacture of transfer sheet | |
| JP3880083B2 (en) | Pseudo-skin film material with a backside coating applied to the back of a polyolefin film | |
| JPH0239839Y2 (en) | ||
| JPH0229332A (en) | Laminated material for transfer and its manufacture | |
| JPH0485100A (en) | Transfer sheet | |
| JPS6220318Y2 (en) | ||
| JP3023930B2 (en) | Transfer foil and method for forming matte or painted surface using the same | |
| JP2524254Y2 (en) | Thermal transfer sheet | |
| JPH04282684A (en) | Adhesive label | |
| JPS5865691A (en) | Method for transferring art printing to other body |