JPH03152193A - Jelly fuel composition - Google Patents
Jelly fuel compositionInfo
- Publication number
- JPH03152193A JPH03152193A JP28995689A JP28995689A JPH03152193A JP H03152193 A JPH03152193 A JP H03152193A JP 28995689 A JP28995689 A JP 28995689A JP 28995689 A JP28995689 A JP 28995689A JP H03152193 A JPH03152193 A JP H03152193A
- Authority
- JP
- Japan
- Prior art keywords
- jelly
- fuel
- parts
- composition
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 30
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 235000015110 jellies Nutrition 0.000 title abstract description 9
- 239000008274 jelly Substances 0.000 title abstract description 9
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004584 polyacrylic acid Substances 0.000 claims abstract description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract description 21
- 238000002485 combustion reaction Methods 0.000 abstract description 6
- 150000001412 amines Chemical class 0.000 abstract description 4
- 159000000000 sodium salts Chemical class 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- -1 alkaline earth metal salts Chemical class 0.000 description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 5
- 239000003349 gelling agent Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FMZUHGYZWYNSOA-VVBFYGJXSA-N (1r)-1-[(4r,4ar,8as)-2,6-diphenyl-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C([C@@H]1OC(O[C@@H]([C@@H]1O1)[C@H](O)CO)C=2C=CC=CC=2)OC1C1=CC=CC=C1 FMZUHGYZWYNSOA-VVBFYGJXSA-N 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229940087101 dibenzylidene sorbitol Drugs 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、ゼリー状を呈した燃料組成物に関し、特に、
昼間においても燃焼の炎を認識できるゼリー状燃料組成
物に関する。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a jelly-like fuel composition, in particular,
This invention relates to a jelly-like fuel composition that allows combustion flames to be recognized even during daytime.
（従来の技術及び解決しようとする課題）従来より、家
庭用又は業務用の燃料の一種として、燃料成分をゲル状
又はゼリー状としたゼリー状燃料が広く知られている。(Prior Art and Problems to be Solved) Jelly-like fuels containing fuel components in the form of gels or jelly have been widely known as a type of fuel for household or commercial use.
このゼリー状燃料は、通常煤の発生の少ないアルコール
、特にメチルアルコールを主成分とし、ゲル化剤である
高級脂肪酸のアルカリ金属又はアルカリ土類金属塩、ジ
ベンジリデンソルビトールあるいはカルボキシビニルポ
リマー、又はカルボキシビニルポリマーと低級アミンと
の混合物等を混合することによって、アルコールをゼリ
ー化し、得られたゼリー状アルコールをポリエチレン袋
又はガス透過性のないポリエチレンーセロファンーボリ
プロビレンよりなる三層の積層フィルムで作成した袋に
少量ずつ入れ、袋のまま着火、使用される。This jelly-like fuel usually contains alcohol that generates little soot, especially methyl alcohol, as a main component, and gelling agents such as alkali metal or alkaline earth metal salts of higher fatty acids, dibenzylidene sorbitol, carboxyvinyl polymer, or carboxyvinyl Alcohol is jelly-formed by mixing a mixture of a polymer and a lower amine, etc., and the resulting jelly-like alcohol is made from a polyethylene bag or a three-layer laminated film made of polyethylene-cellophane-polypropylene that is not gas permeable. A small amount is placed in a sealed bag, and the bag is ignited and used.
しかし、このようなゼリー状燃料の欠点の一つとして、
燃料がメタノールのような低級アルコールを使用してい
るため、燃焼炎が全く無色であり、特に日中又は明るい
部屋で使用する場合には炎が全く見えず、そのため火傷
や火炎をおこす危険性があった。However, one of the drawbacks of such jelly-like fuel is that
Because the fuel is a lower alcohol such as methanol, the combustion flame is completely colorless, and the flame is not visible at all, especially when used during the day or in a bright room, so there is a risk of burns or flames. there were.
この点を改良する目的でゼリー状燃料の燃料成分に少量
のイソプロピルアルコールを添加することがあるが、経
済性及び臭気のためにあまり好ましい方法とはいえない
。In order to improve this point, a small amount of isopropyl alcohol is sometimes added to the fuel component of the jelly-like fuel, but this is not a very preferable method due to economic efficiency and odor.
本発明者は、上記の欠点を解決するために種々検討した
結果、燃料成分中に微量のカルボキシメチルセルロース
ナトリウム又は／及びポリアクリル酸ナトリウムを添加
することによって、その炎は暖かい黄燈色に着色される
ことを見出し、本発明を完成したもので、本発明の目的
はゼリー状燃料において、その燃焼炎が着色したゼリー
状燃料を提供するにある。As a result of various studies to solve the above-mentioned drawbacks, the inventor of the present invention has discovered that by adding a trace amount of sodium carboxymethylcellulose and/or sodium polyacrylate to the fuel component, the flame can be colored a warm yellowish color. The object of the present invention is to provide a jelly-like fuel whose combustion flame is colored.
（課題を解決するための手段）
即ち、本発明は、燃料成分として低級アルコールを含有
したゼリー燃料組成物において、微量のカルボキシメチ
ルセルロースナトリウム及び／又はポリアクリル酸ナト
リウムを添加することを特徴とするゼリー状燃料組成物
である。(Means for Solving the Problems) That is, the present invention provides a jelly fuel composition containing a lower alcohol as a fuel component, characterized in that a trace amount of sodium carboxymethyl cellulose and/or sodium polyacrylate is added. It is a fuel composition.
以下、本発明について詳細に述べる。The present invention will be described in detail below.
本発明で燃料成分として使用する低級アルコールとして
は、経済的理由により通常メタノールを′使用する。As the lower alcohol used as a fuel component in the present invention, methanol is usually used for economical reasons.
又、このアルコールをゲル化するゲル化剤としては高級
脂肪酸のアルカリ金属又はアルカリ土類金属塩、ジベン
ジリデンソルビトール及びカルボキシビニルポリマーと
低級アミンとの混合物等ゲル化剤として通常使用されて
いるものは何れも良いが、特にカルボキシビニルポリマ
ーと低級アミンとの混合物が好適である。In addition, gelling agents that are commonly used for gelling this alcohol include alkali metal or alkaline earth metal salts of higher fatty acids, dibenzylidene sorbitol, and mixtures of carboxyvinyl polymers and lower amines. Any of these may be used, but a mixture of a carboxyvinyl polymer and a lower amine is particularly suitable.
ゲル化剤の添加量としては組成物全量に対して０．０５
〜６部、最も好ましくは０．５〜３部であり、その量を
増加させることによって得られる燃料の硬度を増すこと
ができる。The amount of gelling agent added is 0.05 based on the total amount of the composition.
~6 parts, most preferably 0.5 to 3 parts; increasing the amount can increase the hardness of the resulting fuel.
ただ、カルボキシビニルポリマーの量を増やすことによ
ってゼリー強度も増加するが、燃焼特大が飛び易く、ま
た未燃焼物が残る傾向があるが、このような火の飛び易
さは珪酸化合物を含有させることによって防止すること
ができる（特公昭５８−２０９９６号参照）。However, although the jelly strength increases by increasing the amount of carboxyvinyl polymer, it tends to cause oversized combustible particles to fly and unburnt substances to remain.However, this tendency to easily spread flames can be prevented by adding a silicic acid compound. This can be prevented by (see Japanese Patent Publication No. 58-20996).
次に本願発明のゼリー状燃料の製造方法について説明す
る。Next, a method for producing a jelly-like fuel according to the present invention will be explained.
燃焼成分の低級アルコール、例えばメタノールと水とを
混合し、これをプロペラ式撹拌機を付けた溶解槽中に入
れ、その中にカルボキシメチルセルロースナトリウムを
添加し、撹拌、混合、溶解する。溶解は室温で行なう。A lower alcohol as a combustion component, such as methanol, and water are mixed and placed in a dissolution tank equipped with a propeller type stirrer, and sodium carboxymethyl cellulose is added thereto and stirred, mixed, and dissolved. Dissolution is carried out at room temperature.
得られた粘稠な透明溶液の中に、更にトリエチルアミン
を添加、撹拌を続ける。トリエチルアミンを加えたとき
は急激に粘度が上昇し、チキソトロピー性をもったゼリ
ー状になる。このように得られたゼリー状燃料にカルボ
キシメチルセルロースナトリウム塩及び／又はポリアク
リル酸ナトリウムを加える。Further triethylamine was added to the resulting viscous transparent solution and stirring was continued. When triethylamine is added, the viscosity increases rapidly and the mixture becomes jelly-like with thixotropic properties. Carboxymethylcellulose sodium salt and/or sodium polyacrylate are added to the jelly-like fuel thus obtained.
カルボキシメチルセルロースナトリウム塩及び／又はポ
リアクリル酸ナトリウム塩の添加割合は、全組成物に対
し、０．１部から２．５部、好ましくは０．３部から１
．５部、最も好ましいのは０．６部〜１．５部、最も好
ましくは０．６部〜１．３部である。０．３部より少な
い場合は、炎色の着色が悪く、２．５部より多くなると
溶解性が悪くなる。The addition ratio of carboxymethyl cellulose sodium salt and/or polyacrylic acid sodium salt is 0.1 part to 2.5 parts, preferably 0.3 part to 1 part, based on the total composition.
．． 5 parts, most preferably 0.6 parts to 1.5 parts, most preferably 0.6 parts to 1.3 parts. If it is less than 0.3 parts, the flame coloring will be poor, and if it is more than 2.5 parts, the solubility will be poor.
実施例 以下、実施例をもって本発明を説明する。Example The present invention will be explained below with reference to Examples.
実施例１
メタノール ８０部イソプロピ
ルアルコール １０部カルボキシビニルポリ
マー ２部トリエチルアミン
２部水
４ｗ１３ポリアクリル酸ナトリウム
１部これを、先に述べた製造例と全く同じ方法でゼリー
燃料を製造する。得られたゼリー燃料の燃焼炎は、美し
い黄燈色を呈し、未燃焼物は、極めて少なかった。Example 1 Methanol 80 parts Isopropyl alcohol 10 parts Carboxyvinyl polymer 2 parts Triethylamine
2 parts water
4w13 sodium polyacrylate
One part of this is used to produce jelly fuel in exactly the same manner as in the production example described above. The combustion flame of the obtained jelly fuel exhibited a beautiful yellowish color, and the amount of unburned matter was extremely small.
実施例２
メタノール ９０部カルボキシ
ビニルポリマー ２部トリエチルアミン
２部水
４．７部ポリアクリル酸ナトリウム
０．６部赤色染料 微量これ
を先に示した製造例と全く同じ方法で溶解しゼリー燃料
とする。Example 2 Methanol 90 parts Carboxyvinyl polymer 2 parts Triethylamine
2 parts water
4.7 parts Sodium polyacrylate
0.6 parts red dye A small amount is dissolved to make a jelly fuel in exactly the same manner as in the production example shown above.
得られたゼリー状燃料は赤く着色され、その炎は黄橙色
を呈していた。The resulting jelly-like fuel was colored red, and the flame was yellow-orange.
（発明の効果）
以上述べたように、本発明は、ゼリー状燃料成分中にカ
ルボキシメチルセルローズナトリウム塩又はポリアクリ
ル酸ナトリウム塩を添加することによってその炎は暖か
い黄橙色に着色され、日中でもはっきりと見ることがで
き、且つゼリーの硬さも増加すると共に未燃焼物が殆ど
ない極めて優れたゼリー状燃料が得られる等の効果を奏
する。(Effects of the Invention) As described above, in the present invention, by adding carboxymethyl cellulose sodium salt or polyacrylic acid sodium salt to the jelly-like fuel component, the flame is colored a warm yellow-orange color and is clearly visible even during the day. It can be seen that the hardness of the jelly increases, and an extremely excellent jelly-like fuel with almost no unburned matter can be obtained.
Claims (1)
物において、微量のカルボキシメチルセルロースナトリ
ウム及び／又はポリアクリル酸のナトリウムを添加した
ことを特徴とするゼリー状燃料組成物。1. A jelly-like fuel composition containing a lower alcohol as a fuel component, characterized in that a trace amount of sodium carboxymethyl cellulose and/or sodium polyacrylic acid is added.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1289956A JP3008028B2 (en) | 1989-11-09 | 1989-11-09 | Jelly fuel composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1289956A JP3008028B2 (en) | 1989-11-09 | 1989-11-09 | Jelly fuel composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03152193A true JPH03152193A (en) | 1991-06-28 |
| JP3008028B2 JP3008028B2 (en) | 2000-02-14 |
Family
ID=17749913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1289956A Expired - Lifetime JP3008028B2 (en) | 1989-11-09 | 1989-11-09 | Jelly fuel composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3008028B2 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0418641U (en) * | 1990-05-29 | 1992-02-17 | ||
| DE19956375A1 (en) * | 1999-11-24 | 2001-06-21 | Xcellsis Gmbh | Flame dye additive for methanol to operate a fuel cell system |
| KR20030021861A (en) * | 2001-09-08 | 2003-03-15 | 조정남 | Jelly style unusualness fuel composite that is neted from jelly style unusualness fuel manufacture method |
| WO2006041651A2 (en) * | 2004-10-04 | 2006-04-20 | The Gillette Company | Fuel sources, fuel cells and methods of operating fuel cells |
| KR100738811B1 (en) * | 2006-02-16 | 2007-07-12 | 고재훈 | Fuel gel composition and method of manufacture |
| US8269425B2 (en) | 2007-08-10 | 2012-09-18 | Rohm Co., Ltd. | Driving device |
-
1989
- 1989-11-09 JP JP1289956A patent/JP3008028B2/en not_active Expired - Lifetime
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0418641U (en) * | 1990-05-29 | 1992-02-17 | ||
| DE19956375A1 (en) * | 1999-11-24 | 2001-06-21 | Xcellsis Gmbh | Flame dye additive for methanol to operate a fuel cell system |
| DE19956375C2 (en) * | 1999-11-24 | 2001-10-25 | Xcellsis Gmbh | Flame dye additive for methanol to operate a fuel cell system |
| US6521364B1 (en) | 1999-11-24 | 2003-02-18 | Ballard Power Systems Ag | Flame colorant additive for methanol for the operation of a fuel cell system |
| KR20030021861A (en) * | 2001-09-08 | 2003-03-15 | 조정남 | Jelly style unusualness fuel composite that is neted from jelly style unusualness fuel manufacture method |
| US8003277B2 (en) | 2004-10-04 | 2011-08-23 | The Gillette Company | Fuel source for a fuel cell |
| WO2006041651A3 (en) * | 2004-10-04 | 2007-09-27 | Gillette Co | Fuel sources, fuel cells and methods of operating fuel cells |
| US7470484B2 (en) | 2004-10-04 | 2008-12-30 | The Gillette Company | Fuel sources, fuel cells and methods of operating fuel cells |
| WO2006041651A2 (en) * | 2004-10-04 | 2006-04-20 | The Gillette Company | Fuel sources, fuel cells and methods of operating fuel cells |
| KR100738811B1 (en) * | 2006-02-16 | 2007-07-12 | 고재훈 | Fuel gel composition and method of manufacture |
| US8269425B2 (en) | 2007-08-10 | 2012-09-18 | Rohm Co., Ltd. | Driving device |
| US8558479B2 (en) | 2007-08-10 | 2013-10-15 | Rohm Co., Ltd. | Driving device |
| US8796956B2 (en) | 2007-08-10 | 2014-08-05 | Rohm Co., Ltd. | Driving device |
| US9104215B2 (en) | 2007-08-10 | 2015-08-11 | Rohm Co., Ltd. | Driving device |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3008028B2 (en) | 2000-02-14 |
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