JPH0314864A - Molding composition for porous material - Google Patents
Molding composition for porous materialInfo
- Publication number
- JPH0314864A JPH0314864A JP14910589A JP14910589A JPH0314864A JP H0314864 A JPH0314864 A JP H0314864A JP 14910589 A JP14910589 A JP 14910589A JP 14910589 A JP14910589 A JP 14910589A JP H0314864 A JPH0314864 A JP H0314864A
- Authority
- JP
- Japan
- Prior art keywords
- polyester resin
- weight
- compsn
- porous material
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011148 porous material Substances 0.000 title claims abstract description 28
- 238000000465 moulding Methods 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 title claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 17
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 7
- 229920005989 resin Polymers 0.000 abstract description 12
- 239000011347 resin Substances 0.000 abstract description 12
- 229920001225 polyester resin Polymers 0.000 abstract description 6
- 239000004645 polyester resin Substances 0.000 abstract description 6
- 239000010456 wollastonite Substances 0.000 abstract description 5
- 229910052882 wollastonite Inorganic materials 0.000 abstract description 5
- 239000003999 initiator Substances 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 abstract description 2
- 239000002657 fibrous material Substances 0.000 abstract description 2
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract description 2
- 239000011152 fibreglass Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000005452 bending Methods 0.000 description 8
- 238000011156 evaluation Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000008187 granular material Substances 0.000 description 7
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- -1 miryoku Substances 0.000 description 3
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009408 flooring Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 239000002649 leather substitute Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- DNJRNBYZLPKSHV-XMHGGMMESA-N (e)-(2,4-dinitrophenoxy)imino-(4-ethoxycarbonylpiperazin-1-yl)-oxidoazanium Chemical compound C1CN(C(=O)OCC)CCN1[N+](\[O-])=N/OC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O DNJRNBYZLPKSHV-XMHGGMMESA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000975357 Salangichthys microdon Species 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000012875 nonionic emulsifier Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Floor Finish (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業七の利用分野］
本発明は建築材料、例えば水に濡れやすい場所に使用さ
れるフロアー材に適する多孔性材料成形用組成物に関す
る。DETAILED DESCRIPTION OF THE INVENTION [Field of Application in Industry 7] The present invention relates to a porous material molding composition suitable for building materials, such as flooring materials used in places that are easily wetted by water.
従来から水に濡れやすい浴室、調理室、便所、玄関、ベ
ランダ、プールサイド、シャワールーム等には多孔性の
フロアー材が使用されている。このような多孔性材料か
らなるフロアー材としては、例えば実公昭５７−１５３
０８号公報記載のものが知られている．この従来の多孔
性材料である透水性レジンコンクリート層は、０．３ｍ
ｍ以上の粒径の砂等の骨材表面を熱硬化性樹脂で被覆し
て骨材の接触部で連結固化することにより、骨材間に連
続する微細孔を形威したものである。この透水性レジン
コンクリート層に形或された透水孔によって、表面から
裏面側へ水を透過させ、水濡れ時の滑りを防止するよう
にしていた．
〔発明が解決しようとする課題］
上記のような従来の多孔性材料は、単に骨材の接触部で
連結固化して骨材間に間隙を形成しているため微細孔の
孔径が大きい。したがって微細孔内に水とともに固体の
夾雑物が入り、目詰まりを起こして透水性が低下すると
共に汚れやすいという問題点を有していた。Traditionally, porous flooring materials have been used in bathrooms, galleys, toilets, entrances, balconies, poolsides, shower rooms, etc. that are prone to getting wet. As a floor material made of such a porous material, for example, Japanese Utility Model Publication No. 57-153
The one described in Publication No. 08 is known. This conventional porous material, water-permeable resin concrete layer, is 0.3 m long.
By coating the surface of aggregate such as sand with a particle size of m or more with a thermosetting resin and connecting and solidifying it at the contact area of the aggregate, continuous fine pores are formed between the aggregates. The water-permeable holes formed in this water-permeable resin concrete layer allow water to permeate from the front side to the back side, preventing slipping when wet. [Problems to be Solved by the Invention] In the conventional porous materials as described above, the diameter of the micropores is large because the aggregates are simply connected and solidified at the contact portions to form gaps between the aggregates. Therefore, solid contaminants enter the micropores together with water, causing clogging, resulting in decreased water permeability and easy staining.
本発明は、かかる従来技術による多孔性材料のよごれ易
いという問題点を解決することを目的としてなされたも
のである．
〔課題を解決するための手段〕
本発明の多孔性材料或形用組威物は、不飽和ポリエステ
ル系樹脂１重量部に水０．０５〜０．８０重量部を分散
させた組或物に対し親水性粉粒体が０．２〜５重量部混
入されていることを特徴としている。The present invention has been made with the aim of solving the problem of the porous materials of the prior art being easily soiled. [Means for Solving the Problems] The porous material or composite material of the present invention is a composite material in which 0.05 to 0.80 parts by weight of water is dispersed in 1 part by weight of an unsaturated polyester resin. On the other hand, it is characterized in that 0.2 to 5 parts by weight of hydrophilic powder or granular material is mixed.
本発明に用いる不飽和ポリエステル系樹脂とは、不飽和
ポリエステル樹脂のみでなく、ビニルエステル樹脂、ア
クリル化ポリエステル樹脂等も含まれ、通常はモノマー
に溶解した常温で液体のものである．そしてラジカル開
始剤により常温または加熱により反応し硬化するか、又
は触媒もしくは感光性或分を含み、紫外線、赤外線等の
照射エネルギーにより硬化するものであってもよい．不
飽和ポリエステル系樹脂１重量部に対して水を０．０５
〜０．８０重量部を混合し乳化させる。乳化の方法には
、単に高速攪拌（乳化器）等によるのみでも乳化は可能
であるが、分散した乳化滴の安定化のためにノニオン系
乳化剤、コロイダルシリ力等の分散安定剤を用いてもよ
い。分散させる水が多いと形威される孔径が大きくなり
汚れやすくなるので上記の程度が望ましい．
親水性粉粒体とは、バルク（堆積状）粉粒体に水を滴下
した場合に、攪拌、振動等の操作がなくても粉粒体空隙
中に水が侵入するものをいう．たとえば、タルク、カオ
リン、ベントナイト、マイ力、ウォラストナイト、水酸
化アルミ粉、アルミナ粉、無処理ガラス粉、セビオライ
ト、硅砂、シラス粉等、充填材に通常用いる無処理の鉱
物粉、吸水性高分子（セルローズ、綿、バルブ）粉等が
挙げられ、ウォラストナイト、ガラス繊維等の繊維状の
ものが望ましい。混入させる粉粒体が上記より多いと脆
くなり、少ないと孔が少なくなりすぎる．
乳化すると共にラジカル開始剤を混入し樹脂組或物中の
樹脂１重量部に対し０。２〜５重量部、好ましくは体積
換算した場合、全体におけるわ｝粒体の割合が２０〜８
０％になるように親水性粉粒体をγ昆入し、この混合物
を注型もしくは加圧により成形し硬化を行い、多孔性材
料を或形する。The unsaturated polyester resin used in the present invention includes not only unsaturated polyester resins but also vinyl ester resins, acrylated polyester resins, etc., and is usually dissolved in a monomer and is liquid at room temperature. It may be cured by reacting with a radical initiator at room temperature or by heating, or it may contain a catalyst or a photosensitive material and be cured by irradiation energy such as ultraviolet rays or infrared rays. 0.05 parts of water per 1 part by weight of unsaturated polyester resin
~0.80 parts by weight are mixed and emulsified. Emulsification can be achieved simply by high-speed stirring (emulsifier), but it is also possible to use a dispersion stabilizer such as a nonionic emulsifier or colloidal silicate to stabilize the dispersed emulsion droplets. good. If there is too much water to be dispersed, the pore size will become larger, making it easier to get dirty, so the above level is desirable. Hydrophilic granular material refers to one in which when water is dropped onto a bulk (deposited) granular material, water enters the pores of the granular material without stirring, vibration, or other operations. For example, untreated mineral powders commonly used as fillers, such as talc, kaolin, bentonite, miryoku, wollastonite, aluminum hydroxide powder, alumina powder, untreated glass powder, seviolite, silica sand, whitebait powder, etc., and high water absorption. Examples include molecular (cellulose, cotton, bulb) powder, etc., and fibrous materials such as wollastonite and glass fiber are preferable. If the amount of powder mixed in is more than the above, it will become brittle, and if it is less, the pores will be too small. When emulsified and mixed with a radical initiator, 0.2 to 5 parts by weight per 1 part by weight of the resin in the resin composition, preferably 20 to 8 parts by weight of the grains in the whole, when converted to volume.
Hydrophilic powder and granules are added to the mixture so that the amount is 0%, and the mixture is molded by casting or pressure and hardened to form a porous material.
不飽和ポリエステル系樹脂１重量部に水０．０５〜０．
８０重量部を分散させた混合物に対し親水性粉粒体が０
．２〜５重量部ｄ人されて成形硬化された多孔性材料は
、水分の分散により発生した孔は比較的微細な５０μ醜
以下であり、孔の内外に親水性粉粒体が分散しているた
め、部分的な連通孔が成形体表面および内部に発生し、
多孔性材料が水と接した場合、多孔性材料内部に水が浸
入する構造となる。0.05 to 0.0% water to 1 part by weight of unsaturated polyester resin.
80 parts by weight of the hydrophilic powder was dispersed in the mixture.
．． In the porous material that has been molded and hardened with 2 to 5 parts by weight, the pores generated by the dispersion of water are relatively fine, less than 50 microns in size, and hydrophilic powder particles are dispersed inside and outside the pores. Therefore, partial communication holes occur on the surface and inside of the molded product,
When the porous material comes into contact with water, the structure is such that water infiltrates into the porous material.
以下実施例を示す。 Examples are shown below.
得られた実施例の組成物より成形された多孔性材料に対
して下記の試験方法及び評価方法により吸水率、曲げ強
度、成形後の収縮率、滑り抵抗の試験を行い評価し、そ
の評価の結果を表−１に示した。The porous material molded from the obtained composition of the example was tested and evaluated for water absorption, bending strength, shrinkage after molding, and slip resistance using the following test method and evaluation method. The results are shown in Table-1.
なお比較のため、比較例及び参考例の成形体についても
同様に試験と評価を行い、表一ｌに併せて示した．
実施員土
不飽和ポリエステルにイソ系、加熱硬化系の樹脂（市販
イソ系高反応タイプ樹脂）を用い、水中安定化したコロ
イダルシリ力（シリカ含有量２０％）を樹脂１重量部に
対して０．６重量部を滴下して高速攪拌器により乳化さ
せ、過酸化ベンゾイル０．０１重量部を加え、チタン酸
カリウム１＠量部を混入し、注型し、加熱硬化（８０゜
Ｃ） Ｌて戊形体を得た．
この成形体は、第１図に示すように微細な孔（１）が均
一に分散すると共に、チタン酸カリウムの粉粒体（２）
の表面にも接触しており、吸水率、曲げ強度、成形後の
収縮率、滑り抵抗等の評価は全てよかった。For comparison, the molded bodies of Comparative Examples and Reference Examples were similarly tested and evaluated, and are also shown in Table 1. Using iso-based, heat-curing resin (commercially available iso-based highly reactive type resin) for unsaturated polyester, colloidal silica stabilized in water (silica content 20%) was added to 0 per 1 part by weight of resin. Add 0.01 part by weight of benzoyl peroxide, mix in 1 part by weight of potassium titanate, cast and heat cure (80°C). Obtained a truncated body. As shown in Fig. 1, this molded body has fine pores (1) uniformly dispersed, and potassium titanate powder (2).
The water absorption rate, bending strength, shrinkage rate after molding, slip resistance, etc. were all evaluated to be good.
夫施旌１
粉粒体にチタン酸カリウム１重量部の代わりに水酸化ア
ルξを３重量部用い、真空注型を用いたほかは実施例ｌ
と同様な！ｌ１戒で、成形体を得た。Example 1 except that 3 parts by weight of aluminum hydroxide ξ was used instead of 1 part by weight of potassium titanate in the powder and granules, and vacuum casting was used.
Similar! A molded body was obtained with 11 precepts.
この成形体の断面図は、第２図に示すように微細な孔（
１）が均一に分散すると共に、水酸化アルミニウムの粉
粒体（３）の表面にも接触しており、評価も全てよかっ
た．
ｚ益斑主
不飽和ポリエステル樹脂にビス系ゲルコート用樹脂（市
販品）を用い、ノニオン系界面活性剤を０．５％７昆大
した水を０．３重量部滴下して高速攪拌器により乳化さ
せ、ナフテン酸コバルト０．００３重１部、メチルエチ
ルケトンバーオキサイド０．０１重量部を加え、ウオラ
ストナイト３．５重量部を混入し、加圧硬化（６０ ’
Ｃ） Ｌて成形体を得た。A cross-sectional view of this molded body shows fine pores (
1) was uniformly dispersed and was also in contact with the surface of the aluminum hydroxide powder (3), and all evaluations were good. Using a bis-based gel coat resin (commercially available) as the main unsaturated polyester resin, 0.3 parts by weight of water containing 0.5% nonionic surfactant was added dropwise and emulsified using a high-speed stirrer. 0.003 parts by weight of cobalt naphthenate, 0.01 parts by weight of methyl ethyl ketone peroxide, 3.5 parts by weight of wollastonite were added, and the mixture was cured under pressure (60'
C) A molded body was obtained.
この成形体の断面図も第１図と同様であり、評価も全て
よかった。The cross-sectional view of this molded article was also the same as that in FIG. 1, and all evaluations were good.
止較開土
実施例１におけるチタン酸カリウムを用いない成形体を
得た。A molded article in which potassium titanate was not used in Example 1 was obtained.
この評価は曲げ強度のみがよかった．
比較班ｉ
実施例ｌにおけるコロイダルシリカ０．６重量部の代わ
りに１重量部用いて成形体を得た。In this evaluation, only the bending strength was good. Comparative Group I A molded article was obtained by using 1 part by weight of colloidal silica instead of 0.6 part by weight in Example 1.
評価は滑り抵抗のみがよかった。Only the slip resistance was evaluated as good.
比較班立
実施例３におけるウォラストナイト３．５重量部の代わ
りに６重量部用いて成形体を得た．この評価は曲げ強度
のみが悪かった。A molded body was obtained by using 6 parts by weight of wollastonite instead of 3.5 parts by weight in Comparative Team Standing Example 3. In this evaluation, only the bending strength was poor.
止較班１
実施例３における、水を０．３重量部の代わりに０．１
重量部加えて戊形体を得た．
この評価は、吸水率と滑り抵抗が悪く、曲げ強度と収縮
率はよかった。Comparison group 1: 0.1 parts by weight of water in place of 0.3 parts by weight in Example 3
The weight part was added to obtain a truncated body. In this evaluation, water absorption and slip resistance were poor, but bending strength and shrinkage were good.
参ｉ斑上 塩ビフロアー材から成形体を得た。On the reference spot A molded article was obtained from a PVC floor material.
この評価は、吸水率と滑り抵抗が悪く、曲げ強度と収縮
率はよかった．
参Ａ朋１
ゲルコート面が形或された成形体を得た．この評価は、
吸水率、曲げ強度が悪く、収縮率、滑り抵抗はよかった
．
なお、吸水性については、ＪＩＳ−Ｋ ７２０９におい
て規定されたＡ法く可溶物がない場合）に準拠して測定
し、（吸水重量一総乾重景）／全表面積で測定し、Ｏ．
ｌｍｇ／ｃｍ”以上のものを○で、それ未満のものを
×で示した。In this evaluation, water absorption and slip resistance were poor, but bending strength and shrinkage were good. Part A 1 A molded article with a gel coated surface was obtained. This evaluation is
Water absorption rate and bending strength were poor, but shrinkage rate and slip resistance were good. In addition, water absorption is measured according to method A specified in JIS-K 7209 (when there is no soluble material), and is measured as (water absorption weight - total dry weight)/total surface area.
1 mg/cm" or more is indicated by ○, and those less than 1 mg/cm" are indicated by ×.
曲げ強度についてはＪ■Ｓ−Ｋ ７２０３により規定さ
れた方法に準拠して測定し、１．５ｋｇ／ａｍ”の以上
のものをＯで、それ未満のものを×で示した。The bending strength was measured in accordance with the method specified by JS-K 7203, and those of 1.5 kg/am" or more were marked O, and those less than that were marked x.
収縮率については、或形直後に長さ１５０問（幅２０！
！ｌＩｍ厚さ５ｍｍ）に切り出し、６０゜Ｃ相対湿度２
０％以下の恒温槽内で３ｈｒ放置し、収縮が長さ方向で
２ｚ未満のものを○で示し、それ以上のものを×で示し
た．
滑り抵抗については、成形体の傾斜面において、ＪＩＳ
Ａ ５７２１の滑り試験におけるフエルトの代わりに
人工皮革片（５０ｍｎ＋ Ｘ ３０ｍｍ ） 、荷重２
ｋｇを用いて、成形体の傾斜を変えて人工皮董片が滑り
出す角度θを測定し、摩擦係数（ｔａｎθ）を計算して
求め、その評価は摩擦係数０．６以上を○で、それ未満
のものを×で示した。Regarding the shrinkage rate, 150 questions in length (20 in width!
! Cut into pieces (5 mm thick) and store at 60°C relative humidity 2.
After being left in a thermostat at 0% or less for 3 hours, those whose shrinkage was less than 2z in the length direction were marked with an ○, and those whose shrinkage was more than 2z were marked with an x. Regarding slip resistance, JIS
A piece of artificial leather (50mm + x 30mm) instead of felt in the sliding test of 5721, load 2
kg, change the inclination of the molded body and measure the angle θ at which the artificial leather piece begins to slide, and calculate the friction coefficient (tan θ). Those are marked with an x.
本発明によれば、成形された多孔性材料の孔は比較的微
細であり、成形体は汚れ難く、吸水性を有するため、水
濡れ時に不滑性を有するフロアー材や結露防止壁材とし
て有効な内装用材料となる。According to the present invention, the pores of the molded porous material are relatively fine, and the molded product is difficult to stain and has water absorption properties, so it is effective as a floor material that is non-slip when wet with water and a wall material that prevents condensation. It is a material for interior decoration.
第１図は本発明の一実施例により成形された多孔性材料
の断面図、第２図は他の実施例により成形された多孔性
材料の断面図である９
１：孔 ２，３：粉粒体
以 上FIG. 1 is a cross-sectional view of a porous material molded according to one embodiment of the present invention, and FIG. 2 is a cross-sectional view of a porous material molded according to another embodiment.9 1: Pores 2, 3: Powder More than granules
Claims (1)
８０重量部を分散させた組成物に対し親水性粉粒体が０
．２〜５重量部混入されていることを特徴とする多孔性
材料成形用組成物。0.05 to 0.0% water to 1 part by weight of unsaturated polyester resin.
The hydrophilic powder was 0 for the composition in which 80 parts by weight was dispersed.
．． A composition for molding a porous material, characterized in that it is mixed in an amount of 2 to 5 parts by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14910589A JPH0314864A (en) | 1989-06-12 | 1989-06-12 | Molding composition for porous material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14910589A JPH0314864A (en) | 1989-06-12 | 1989-06-12 | Molding composition for porous material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0314864A true JPH0314864A (en) | 1991-01-23 |
Family
ID=15467808
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14910589A Pending JPH0314864A (en) | 1989-06-12 | 1989-06-12 | Molding composition for porous material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0314864A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002048225A1 (en) * | 2000-12-15 | 2002-06-20 | Japan U-Pica Company, Ltd. | O/w aqueous thermosetting resin dispersion, frp precision filter medium made with the aqueous dispersion, and process for producing the same |
| EP1405715A1 (en) * | 2002-10-02 | 2004-04-07 | Illinois Tool Works, Inc. | Method of making a sheet of building material |
-
1989
- 1989-06-12 JP JP14910589A patent/JPH0314864A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002048225A1 (en) * | 2000-12-15 | 2002-06-20 | Japan U-Pica Company, Ltd. | O/w aqueous thermosetting resin dispersion, frp precision filter medium made with the aqueous dispersion, and process for producing the same |
| US6756413B2 (en) | 2000-12-15 | 2004-06-29 | Japan U-Pica Company, Ltd. | O/W aqueous thermosetting resin dispersion, FRP precision filter medium made with the aqueous dispersion, and process for producing the same |
| KR100812577B1 (en) * | 2000-12-15 | 2008-03-13 | 니혼 유피카 가부시키가이샤 | O/w aqueous thermosetting resin dispersion, frp precision filter medium made with the aqueous dispersion, and process for producing the same |
| EP1405715A1 (en) * | 2002-10-02 | 2004-04-07 | Illinois Tool Works, Inc. | Method of making a sheet of building material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5228220B2 (en) | Flexible and rollable cementitious membrane and method for producing the same | |
| JP4361602B2 (en) | Aerogel-containing composite material, production method thereof and use thereof | |
| US3317178A (en) | Lining for lightweight fiberglass reinforced polyester resin mold | |
| US3295818A (en) | Lining for lightweight fiberglas reinforced polyester resin mold | |
| JP2001509767A (en) | Use of aerogels for body and / or impact sound attenuation | |
| JPS6025395B2 (en) | Rigid inorganic foam products and their manufacturing method | |
| US6277190B1 (en) | Use of alcohols as additives for plaster and/or mortar | |
| JPH0314864A (en) | Molding composition for porous material | |
| GB2097011A (en) | Stucco composition | |
| JPH07122047B2 (en) | Anti-slip agent | |
| JP2940555B2 (en) | Porous molded body | |
| JPH01322060A (en) | Floor material | |
| JPH03108527A (en) | Manufacture of porous material | |
| JP2763121B2 (en) | Floor material | |
| JPH02178461A (en) | Floor material | |
| JP2940554B2 (en) | Method for producing porous floor material | |
| JPH0313319A (en) | Method of manufacturing porous molding | |
| JP7438803B2 (en) | Face material | |
| JPH0227301B2 (en) | ||
| JPH02228337A (en) | Production of porous flooring | |
| JPH0446074A (en) | Porous material | |
| JPH074265Y2 (en) | Permeable flooring | |
| JPH02228336A (en) | Production of porous flooring | |
| JPH0987053A (en) | Instantaneously demoldable porous concrete molding and its production | |
| JP4109647B2 (en) | Method for producing inorganic molded body |