JPH0314675A - Preparation of water-repellent and deep colored web - Google Patents
Preparation of water-repellent and deep colored webInfo
- Publication number
- JPH0314675A JPH0314675A JP14587989A JP14587989A JPH0314675A JP H0314675 A JPH0314675 A JP H0314675A JP 14587989 A JP14587989 A JP 14587989A JP 14587989 A JP14587989 A JP 14587989A JP H0314675 A JPH0314675 A JP H0314675A
- Authority
- JP
- Japan
- Prior art keywords
- fluorine
- water
- containing compound
- repellent
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005871 repellent Substances 0.000 title claims abstract description 22
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 20
- 239000011737 fluorine Substances 0.000 claims abstract description 20
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 15
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 9
- 239000004744 fabric Substances 0.000 claims description 23
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000010409 thin film Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 31
- 238000005108 dry cleaning Methods 0.000 abstract description 10
- 238000011282 treatment Methods 0.000 abstract description 10
- 238000005406 washing Methods 0.000 abstract description 7
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 abstract description 3
- -1 C3F6 Chemical compound 0.000 abstract description 2
- 239000012209 synthetic fiber Substances 0.000 abstract description 2
- 229920002994 synthetic fiber Polymers 0.000 abstract description 2
- 229920006254 polymer film Polymers 0.000 abstract 2
- 238000000034 method Methods 0.000 description 11
- 230000002940 repellent Effects 0.000 description 10
- 239000007789 gas Substances 0.000 description 6
- 239000000835 fiber Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- 239000004721 Polyphenylene oxide Chemical group 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 238000009832 plasma treatment Methods 0.000 description 1
- 229920000570 polyether Chemical group 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 230000003685 thermal hair damage Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、耐久性ある撥水性および深色性を有する布帛
の製造法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing a durable water-repellent and bathochromic fabric.
［従来の技術］
近年、スポーツ衣料分野、ユニホーム衣料分野を中心に
撥水性に対する要求が強まっており、これに伴い、撥水
性のドライクリーニング、洗濯に対する耐久性のレベル
アップが強く望まれている。[Prior Art] In recent years, there has been an increasing demand for water repellency mainly in the fields of sports clothing and uniform clothing, and along with this, there is a strong desire to improve the durability of water repellency against dry cleaning and washing.
現在、布帛の撥水加工は、シリコーンあるいはフッ素系
撥水剤などで布帛を処理することによって行なわれてい
る。Currently, fabrics are made water repellent by treating them with silicone or fluorine-based water repellents.
しかし、シリコーン系撥水剤は、ドライクリーニング用
溶媒であるトリクレン、パークレンなどで容易に膨潤、
溶解し、ドライクリーニングに対する耐久性がほとんど
ない。またシリコーン単独では撥水性のレベルが低く、
近年の高撥水要求に対応できないのが現状で畢る。However, silicone water repellents easily swell with dry cleaning solvents such as trichlene and percrene.
It dissolves and has little resistance to dry cleaning. Also, silicone alone has a low level of water repellency.
The current situation is that it cannot meet the recent demands for high water repellency.
一方、フッ素系撥水剤は初期の撥水性レベルは高いが、
樹脂被膜が硬く、もろいため、洗濯あるいは、着用時の
もみ作用などにより樹脂被膜に亀裂が入り、撥水性が低
下するという欠点を有しており、いずれも最近の高度な
要求に対して満足なものは得られていない。On the other hand, fluorine-based water repellents have a high initial level of water repellency, but
Since the resin coating is hard and brittle, it has the disadvantage that it cracks when washed or rubbed during wear, resulting in a decrease in water repellency. I haven't gotten anything.
また従来のシリコーンあるいはフッ素系樹脂による撥水
加工品は、洗濯、あるいはドライクリーニングなどの工
程を経ると、撥水性に寄与するメチル基、あるいは一Ｃ
Ｆ３基などが樹脂膜内にもぐり込み、撥水性能が大巾に
低下するという重大な欠点を有していた。In addition, when conventional water-repellent products made of silicone or fluorine-based resin undergo processes such as washing or dry cleaning, methyl groups or monocarbon
It had a serious drawback in that F3 groups and the like penetrated into the resin film, resulting in a significant drop in water repellency.
またスポーツ衣料、ブラックフォーマル分野に関しては
、撥水性とともにファッション性の観点から、深色性及
び鮮明性の要求が強く、種々の検討がなされている。In addition, in the field of sports clothing and black formal wear, there are strong demands for deep color and clarity from the viewpoint of water repellency as well as fashion, and various studies are being carried out.
一般に撥水加工剤として使用するシリコーン系およびフ
ッ素系撥水剤は、深色化を同時にもたらすが、先述した
ように、該樹脂の耐久性そのものに問題があるため、撥
水性の低下と深色性の低下が同時に起こるのである。Silicone-based and fluorine-based water repellents, which are generally used as water-repellent finishing agents, simultaneously cause deep coloring, but as mentioned earlier, there are problems with the durability of the resin itself, resulting in a decrease in water repellency and deep coloring. A decline in sexuality occurs at the same time.
一方深色化に関しては、特にポリエステルで数多くの検
討がなされており、コロイダルシリ力などをポリマー中
に添加し、アルカリ減量により微細な凹凸をつくるもの
、またプラズマエッチングにより繊維表面に凹凸を形成
するものなどが提案されているが、これに耐久性のある
撥水加工を施すことは、親水化された繊維表面に、疎水
性の撥水性樹脂を付着させることになるため、樹脂の接
着性は十分でなく、耐久性ある撥水性と深色性を兼備え
たものはない。On the other hand, many studies have been carried out on deepening the color, especially for polyester, such as adding colloidal silica to the polymer and creating fine irregularities by alkali loss, and plasma etching to create irregularities on the fiber surface. However, applying a durable water-repellent finish to this material means adhering a hydrophobic water-repellent resin to the hydrophilized fiber surface, so the adhesiveness of the resin is There is no sufficient, durable water repellent and deep color combination.
［発明が解決しようとする課題］
本発明の目的は、高い撥水性、深色性を有し、かつ、洗
濯あるいはドライクリーニングに対する耐久性の優れた
布帛を製造する方法を提供することにある。[Problems to be Solved by the Invention] An object of the present invention is to provide a method for producing a fabric that has high water repellency, deep color, and excellent durability against washing or dry cleaning.
［課題を解決するための手段コ
本発明は、かかる目的を達成するため次のような構成を
有する。すなわち ′
（１）着色布帛にオルガノポリシロキサン化合物および
／または含フッ素化合物による樹脂処理を行なった後、
含フッ素化合物モノマーの低温プラズマ重合を行ない、
該樹脂加工布帛上に重合薄膜を形成させることを特徴と
する撥水性、深色性布帛の製造法。[Means for Solving the Problems] The present invention has the following configuration to achieve the above objects. (1) After the colored fabric is treated with a resin using an organopolysiloxane compound and/or a fluorine-containing compound,
Performing low-temperature plasma polymerization of fluorine-containing compound monomers,
A method for producing a water-repellent, bathochromic fabric, which comprises forming a polymerized thin film on the resin-treated fabric.
■ 含フッ素化合物モノマーが、Ｃ２Ｆ４、Ｃ２ Ｆ’
）Ｃ３ Ｆ６％ Ｃ３ Ｆ８Ｎ Ｃ４ ＦＢ、Ｃ３ Ｆ
ｅ ＯＸＣ２ Ｈ４ Ｆ２から選ばれた少なくとも１種
である（１）に記載の撥水性、深色性布帛の製造法。■ The fluorine-containing compound monomer is C2F4, C2F'
) C3 F6% C3 F8N C4 FB, C3 F
e The method for producing the water-repellent, bathochromic fabric according to (1), which is at least one selected from OXC2 H4 F2.
以下本発明を詳細に説明する。The present invention will be explained in detail below.
ここで、オルガノポリシロキサン化合物とは、一般に撥
水剤、あるいは柔軟剤として使用されているシリコーン
系撥水剤を適宜選択して使用することができるが、たと
えばジメチルポリシロキサンや、ジメチルポリシロキサ
ン分子末端や側鎖に水酸基、アミノ基、水素、エポキシ
基、ポリエーテル基などを導入することによって変性し
たポリシロキサン化合物などのオイルあるいはエマルジ
ョンなどがあげられる。Here, the organopolysiloxane compound refers to a silicone water repellent that is generally used as a water repellent or a softener, and can be appropriately selected and used. For example, dimethylpolysiloxane or dimethylpolysiloxane molecules Examples include oils or emulsions of polysiloxane compounds modified by introducing hydroxyl groups, amino groups, hydrogen, epoxy groups, polyether groups, etc. into terminals or side chains.
また、含フッ素化合物とは、通常ポリアクリル酸とフッ
素系アルコールから成るポリアクリル酸エステルたとえ
ば、ポリペンタデカフルオロオクチルアクリレート、ポ
リトリフルオロエチルアクリレート、ポリトリフルオロ
エチルアクリレートなど、あるいはテトラフルオロエチ
レンーへキサフルオロプロピレン共重合物などのフッ素
系炭化水素などがあげられる。In addition, fluorine-containing compounds are usually polyacrylic acid esters made of polyacrylic acid and fluorinated alcohol, such as polypentadecafluorooctyl acrylate, polytrifluoroethyl acrylate, polytrifluoroethyl acrylate, or tetrafluoroethylene. Examples include fluorine-based hydrocarbons such as hexafluoropropylene copolymers.
これらの撥水処理剤は、溶剤溶液あるいは、乳化剤等に
よって分散されたエマルジョンの状態で布帛に付与し乾
燥することにより処理され、処理液の付与は、パッド法
、浸漬法、スプレー法など通常用いられる方法が使用で
き、目的に応じて選択することができる。乾燥は、１０
０〜１３０℃で行ない、必要に応じて１６０〜１８０℃
の熱処理を行なう。These water-repellent treatment agents are applied to fabrics in the form of a solvent solution or an emulsion dispersed with an emulsifier, etc., and then dried. Application of the treatment liquid can be performed using commonly used methods such as pad method, dipping method, and spray method. Various methods can be used and can be selected depending on the purpose. Drying is 10
Carry out at 0-130℃, 160-180℃ if necessary
Heat treatment is performed.
これらの撥水剤を布帛に付与した後、含フッ素化合物モ
ノマーを用いて低温プラズマ重合処理することは、本発
明の必須工程である。After applying these water repellents to the fabric, it is an essential step of the present invention to perform a low temperature plasma polymerization treatment using a fluorine-containing compound monomer.
ここで言う低温プラズマ処理とは、高電圧を印加するこ
とによって開始持続する放電によって生成するプラズマ
に被処理物をさらすものであり、かかる放電の形態には
、コロナ放電、火花放電、グロー放電など種々の形態が
あるが、繊維に熱的損傷を与えない放電形態であれば、
特に限定されるものではない。放電均一性に伴う処理効
果の均一性を得るためには、グロー放電がより好ましい
。The low-temperature plasma treatment referred to here refers to exposing the object to be treated to plasma generated by a sustained discharge initiated by applying a high voltage. Forms of such discharge include corona discharge, spark discharge, glow discharge, etc. There are various forms of discharge, but as long as it does not cause thermal damage to the fibers,
It is not particularly limited. Glow discharge is more preferable in order to obtain uniformity of treatment effect due to discharge uniformity.
上記グロー放電とは、低圧力下のガス雰囲気中で、高電
圧を印加した際に開始持続する放電であり、放電電力、
ガス圧力、処理時間などの処理条件は、要求される特性
によって適宜設定される。The above glow discharge is a discharge that starts and continues when a high voltage is applied in a gas atmosphere under low pressure, and the discharge power is
Processing conditions such as gas pressure and processing time are appropriately set depending on the required characteristics.
本発明に使用されるガスは、フッ素を含むモノマーであ
り、該プラズマ雰囲気中でモノマは重合し、樹脂加工布
帛上に重合薄膜を形或する。この結果、耐久性にすぐれ
た撥水性と深色性が得られる。The gas used in the present invention is a fluorine-containing monomer, and the monomer polymerizes in the plasma atmosphere to form a polymerized thin film on the resin-treated fabric. As a result, water repellency and deep color with excellent durability can be obtained.
本発明に使用するガスとしては、重合性を有する含フッ
素化合物であれば特に制約はないが、撥水性、深色性の
両方を兼ねそなえたものとして、Ｃ２ Ｆ４）Ｃ２ Ｆ
’）Ｃ３ Ｆ６・Ｃ ３ Ｆ ８ ｓ Ｃ ｄＦｓ 、
Ｃ３ Ｆ６ ０，Ｃ２ Ｈ４ Ｆ２から選ばれた少なく
とも一種を使用することが好ましい。The gas used in the present invention is not particularly limited as long as it is a polymerizable fluorine-containing compound, but C2 F4) C2 F as a gas that has both water repellency and bathochromic properties
') C3 F6・C 3 F 8 s C dFs,
It is preferable to use at least one selected from C3 F6 0 and C2 H4 F2.
本発明のプラズマ重合は、０．０１〜ｌＱＴｏｒｒ，好
ましくは、０．１〜２Ｔｏｒｒの減圧下で、１秒〜６０
０秒の処理を行なう。またプラズマ重合を行なった後、
１６０〜１９０℃の乾熱で処理しても良い。The plasma polymerization of the present invention is carried out under a reduced pressure of 0.01 to 1Q Torr, preferably 0.1 to 2 Torr, for 1 second to 60
Process for 0 seconds. After plasma polymerization,
You may process by dry heat of 160-190 degreeC.
本発明で言う布帛とは、天然繊維、再生繊維、合成繊維
あるいはこれらの混合された糸錦からなる編織物、不織
布などを意味するものである。The term "fabric" used in the present invention refers to knitted fabrics, non-woven fabrics, etc. made of natural fibers, regenerated fibers, synthetic fibers, or yarn brocades made of a mixture thereof.
以下実施例により本発明を説明するが、本発明はこれら
に限定されるものではない。The present invention will be explained below with reference to Examples, but the present invention is not limited thereto.
なお、実施例、比較例に示す性能値は次の方法で測定し
た。Note that the performance values shown in Examples and Comparative Examples were measured by the following method.
撥水性： Ｊ Ｉ Ｓ−Ｌ１０７９に規定される試験法
（スプレー法）で測定されるものである。Water repellency: Measured by the test method (spray method) specified in JIS-L1079.
また、耐久性は、次の洗濯またはドライクリーニング試
験を２０回繰り返し行なった後に上記の撥水試験を行な
い判定した。Furthermore, durability was determined by repeating the following washing or dry cleaning test 20 times and then performing the water repellency test described above.
外観状態と評価配点との関係は次の通りである。The relationship between the appearance condition and the evaluation score is as follows.
１００点： 表面に付着湿潤のないもの９０点二 表面
にわずかに付着湿潤を示すもの８０点二 表面の水の落
下点が湿潤を示すもの７０点二 表面全体にわたって部
分的湿潤を示すもの
５０点二 表面全体に湿潤を示すもの
０点二 表面が完全に湿潤を示すもの
洗濯は、自動反転うず巻き電気洗濯機（東芝ＶＨ１１５
０型）に４０℃±２℃の０．２％弱アルカリ性合或洗剤
（ＪＩＳ Ｋ３３７に規定される）液を入れ、浴比１
：５０になるように追加布を入れ強条件で１０分間洗濯
し、次いで排水し水洗５分をする工程を１回としてこれ
を２０回繰り返した後、風乾した。100 points: 90 points when there is no adhering moisture on the surface 2 80 points when there is a slight amount of adhering moisture on the surface 2 70 points when the falling point of water on the surface shows moisture 2 50 points when showing partial moisture over the entire surface 2. Items that show moisture on the entire surface. 0 points. 2. Items that show moisture on the entire surface. 2. Items that show moisture on the entire surface.
Pour 0.2% slightly alkaline synthetic detergent (specified in JIS K337) at 40°C ± 2°C into a tank (type 0) and adjust the bath ratio to 1.
:50, and washed under strong conditions for 10 minutes, then drained and washed with water for 5 minutes.This process was repeated 20 times, and then air-dried.
ドライクリーニングは、ドライクリーニングシリンダー
（直径約２２ｃｍ，長さ約３３ｃ＋ｒの円筒でシリンダ
の軸から５０°傾いた軸のまわりを４５〜５ Ｑ ｒｐ
ｍで回転するもの）に常温のパークロルエチレン３．８
１を入れ、これに２３０ｇの試験片を入れ１０分間回転
する工程を１回として、これを５０回繰り返した後、風
乾した。Dry cleaning is carried out using a dry cleaning cylinder (a cylinder with a diameter of approximately 22 cm and a length of approximately 33 cm + r, around an axis inclined at 50 degrees from the axis of the cylinder.
(rotating at m) perchlorethylene at room temperature 3.8
1, 230g of test piece was added thereto, and the process of rotating for 10 minutes was repeated 50 times, and then air-dried.
発色性：デジタル側色色差計算機（スガ試験機■製）で
布帛のＬ値を測定した。Ｌ値は色の視感濃度の指標であ
り、値の小さいもの程、濃色であることを示す。Color development: The L value of the fabric was measured using a digital color difference calculator (manufactured by Suga Test Instruments). The L value is an index of the visual density of a color, and the smaller the value, the darker the color.
洗濯およびドライクリーニングの変色は、撥水性試験を
同様の方法で洗濯した後、Ｌ値を測定した。For discoloration during washing and dry cleaning, the L value was measured after washing in the same manner as in the water repellency test.
［実施例］
実施例１〜１３，比較例１〜６
７５デニール３６フィラメントのポリエステル仮ヨリ加
工糸（東レ■製）を用いたタフタを常法により精練した
後、１８０℃の温度でヒートセットを行なった後、ダイ
アニックス ブラック ＢＧ−ＦＳ （Ｄｉａｎｉｘ
Ｂｌａｃｋ ＢＧ−ＦＳ）１４％ｏｗｆ 、浴比１
対５０で１’３０℃６０分の染色を行なった。引続き還
元洗浄、乾燥し、１７０℃で仕上セットし、幅９２ｃｍ
，目付１３０ｇ／ ｍ ｓ密度タテ／ヨコ １ ５ ０
／１ １ ０本／インチの黒色織物とした。[Example] Examples 1 to 13, Comparative Examples 1 to 6 After scouring taffeta using a 75 denier 36 filament polyester pre-twisted yarn (manufactured by Toray ■) by a conventional method, heat setting was performed at a temperature of 180°C. After doing it, Dianix Black BG-FS (Dianix
Black BG-FS) 14%owf, bath ratio 1
Staining was carried out at 1'30°C for 60 minutes with 50 pairs. Subsequently, reduction cleaning, drying, finishing setting at 170℃, width 92cm
, Fabric weight 130g/m s Density vertical/horizontal 1 5 0
/1 10 black fabrics/inch.
該織物は以下の処理を行ない、撥水性、深色性とその耐
久性を評価した。The fabric was subjected to the following treatments, and its water repellency, deep color, and durability were evaluated.
（樹脂処理）
Ａ．アサヒガードＡＧ−７１０ （フッ素系撥水剤．旭
硝子製） ２０ｇ／Ａ’Ｂ．トーレシリコ
ーンＳＨ−８２４０ （両末端ＯＨ変性シリコーンエマ
ルジョン，トーレシリコーン■製） １５
ｇ／Ａ’樹脂処理は、これらの処理液に織物を浸漬した
後、マングルにて織物の重量に対して８０％の処理液を
付着させ、１３０℃で２分乾燥し、次いで１８０℃で２
分の熱処理を行なった。(Resin treatment) A. Asahi Guard AG-710 (Fluorine water repellent. Manufactured by Asahi Glass) 20g/A'B. Toray Silicone SH-8240 (Both ends OH-modified silicone emulsion, manufactured by Toray Silicone ■) 15
g/A' resin treatment involves immersing the fabric in these treatment solutions, applying 80% of the treatment solution to the weight of the fabric using a mangle, drying at 130°C for 2 minutes, and then drying at 180°C for 2 minutes.
Heat treatment was performed for 10 minutes.
（プラズマ重合）
容量結合型のプラズマ処理装置を用い、１１０ｋＨｘの
高周波を印加しプラズマ重合した。用いた含フッ素モノ
マーは第１表に示した。(Plasma Polymerization) Plasma polymerization was performed using a capacitively coupled plasma processing apparatus by applying a high frequency of 110 kHz. The fluorine-containing monomers used are shown in Table 1.
ガス流量は、７０ｃｃ／分である。The gas flow rate is 70 cc/min.
評価結果は第１表に示した。The evaluation results are shown in Table 1.
本発明によるものは、プラズマ重合による撥水性、発色
性の効果が、樹脂処理を施さないでプラズマ重合したも
の（比較例４，５．６）また、樹脂処理のみ（比較例２
，３）などに比較して高いレベルを示すとともにその耐
久性はすぐれたものであるのが認められる。The products according to the present invention have the effects of water repellency and color development due to plasma polymerization.
, 3), etc., and its durability is recognized to be excellent.
［発明の効果］
本発明によって、耐久性にすぐれた撥水性、深色性を兼
備えた布帛製品が提供できる。[Effects of the Invention] According to the present invention, a fabric product having excellent durability, water repellency, and deep color property can be provided.
Claims (2)
／または含フッ素化合物による樹脂処理を行なった後、
含フッ素化合物モノマーの低温プラズマ重合を行ない、
該樹脂加工布帛上に重合薄膜を形成させることを特徴と
する撥水性、深色性布帛の製造法。(1) After the colored fabric is treated with a resin using an organopolysiloxane compound and/or a fluorine-containing compound,
Performing low-temperature plasma polymerization of fluorine-containing compound monomers,
A method for producing a water-repellent, bathochromic fabric, which comprises forming a polymerized thin film on the resin-treated fabric.
２Ｆ＿６、Ｃ＿３Ｆ＿６、Ｃ＿３Ｆ＿８、Ｃ＿４Ｆ＿８
、Ｃ＿３Ｆ＿６Ｏ、Ｃ＿２Ｈ＿４Ｆ＿２から選ばれた少
なくとも１種である請求項（１）に記載の撥水性、深色
性布帛の製造法。(2) The fluorine-containing compound monomer is C_2F_4, C_
2F_6, C_3F_6, C_3F_8, C_4F_8
, C_3F_6O, and C_2H_4F_2, the method for producing a water-repellent, bathochromic fabric according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14587989A JPH0314675A (en) | 1989-06-08 | 1989-06-08 | Preparation of water-repellent and deep colored web |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP14587989A JPH0314675A (en) | 1989-06-08 | 1989-06-08 | Preparation of water-repellent and deep colored web |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0314675A true JPH0314675A (en) | 1991-01-23 |
Family
ID=15395162
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP14587989A Pending JPH0314675A (en) | 1989-06-08 | 1989-06-08 | Preparation of water-repellent and deep colored web |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0314675A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5971584A (en) * | 1996-08-30 | 1999-10-26 | Kabushiki Kaisha Toshiba | Production control apparatus and a production control method |
| JP2008152171A (en) * | 2006-12-20 | 2008-07-03 | Sekisui House Ltd | Damped pendulum device and device for comparing and experiencing seismic response control system using the same |
| GB2554783A (en) * | 2016-07-15 | 2018-04-11 | Creating Nano Tech Inc | Hydrophobic finishing apparatus of fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5851557A (en) * | 1981-09-24 | 1983-03-26 | Hitachi Ltd | Large scale integrated circuit device |
| JPH0192478A (en) * | 1987-09-29 | 1989-04-11 | Kuraray Co Ltd | Fiber structure and its production |
-
1989
- 1989-06-08 JP JP14587989A patent/JPH0314675A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5851557A (en) * | 1981-09-24 | 1983-03-26 | Hitachi Ltd | Large scale integrated circuit device |
| JPH0192478A (en) * | 1987-09-29 | 1989-04-11 | Kuraray Co Ltd | Fiber structure and its production |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5971584A (en) * | 1996-08-30 | 1999-10-26 | Kabushiki Kaisha Toshiba | Production control apparatus and a production control method |
| JP2008152171A (en) * | 2006-12-20 | 2008-07-03 | Sekisui House Ltd | Damped pendulum device and device for comparing and experiencing seismic response control system using the same |
| GB2554783A (en) * | 2016-07-15 | 2018-04-11 | Creating Nano Tech Inc | Hydrophobic finishing apparatus of fabric |
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