JPH03146678A - Ornamental body - Google Patents
Ornamental bodyInfo
- Publication number
- JPH03146678A JPH03146678A JP28542789A JP28542789A JPH03146678A JP H03146678 A JPH03146678 A JP H03146678A JP 28542789 A JP28542789 A JP 28542789A JP 28542789 A JP28542789 A JP 28542789A JP H03146678 A JPH03146678 A JP H03146678A
- Authority
- JP
- Japan
- Prior art keywords
- base material
- oxide film
- interference
- film
- oxidized film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 claims abstract description 22
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- 229910052719 titanium Inorganic materials 0.000 claims description 11
- 239000010936 titanium Substances 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 abstract description 12
- 238000007254 oxidation reaction Methods 0.000 abstract description 12
- 238000011282 treatment Methods 0.000 abstract description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 2
- 229910000838 Al alloy Inorganic materials 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000007650 screen-printing Methods 0.000 description 7
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000013527 degreasing agent Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000005238 degreasing Methods 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000011775 sodium fluoride Substances 0.000 description 3
- 235000013024 sodium fluoride Nutrition 0.000 description 3
- 229920001353 Dextrin Polymers 0.000 description 2
- 239000004375 Dextrin Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 235000019425 dextrin Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000694440 Colpidium aqueous Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000002048 anodisation reaction Methods 0.000 description 1
- 238000007743 anodising Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000007261 regionalization Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- -1 titanium-vanadium-aluminum Chemical compound 0.000 description 1
Landscapes
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、チタニウム系基材表面に、密着性の優れた、
所望パターンを形成してなる装飾体に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention provides a titanium base material with excellent adhesion.
The present invention relates to a decorative body formed with a desired pattern.
（従来の技術）
チタニウム系基材は軽量かつ耐食性、機械的強度が高い
ため、種々用途に用いられ、中でも、化粧品容器、筆記
具等といったように比較的小さく、携帯される頻度が高
いものの基材としては、軽量で、経時的劣化、破損とい
った恐れが少ないため、好ましく使用されている。一方
、近年、高級品指向、消費者のニーズの多様化により、
表面に種々装飾を付与した化粧品容器、筆記具等（以下
、単に装飾体とよぶ）が要望されてきているため、上記
チタニウム系基材表面に対して、種々の処理を施す検討
がなされるに至っている。これらの処理を施すことによ
り得られるものとして、単色よりなるもの、複数色より
パターンを形成したものなどがある。複数色よりなるも
のとして、塗装、スクリーン印刷などにより、塗膜、印
刷層を形成したもの、陽極酸化により干渉を有する酸化
皮膜を形成したもの、塗膜又は印刷層と干渉を有する酸
化皮膜を組合せたものがある。(Prior art) Titanium-based substrates are lightweight, have high corrosion resistance, and high mechanical strength, and are therefore used for a variety of purposes. Among them, titanium-based substrates are used as substrates for relatively small and frequently carried items such as cosmetic containers and writing utensils. It is preferably used because it is lightweight and has little risk of deterioration or breakage over time. On the other hand, in recent years, due to the trend toward luxury goods and the diversification of consumer needs,
Since there is a growing demand for cosmetic containers, writing instruments, etc. with various decorations on the surface (hereinafter simply referred to as decorations), various treatments have been considered for the surface of the titanium base material. There is. Products obtained by performing these treatments include those made of a single color and those with patterns formed from multiple colors. Products consisting of multiple colors include those with a coating film or printed layer formed by painting or screen printing, those with an oxide film that has interference formed by anodizing, and those that have a combination of a coating film or a printed layer and an oxide film that has interference. There is something.
（解決しようとする課題）
塗膜、印刷層を形成Ｕ、たちのは、基材との密着性が悪
く、干渉を有する酸化皮膜を形成したものは。(Problems to be Solved) Those that form a coating film or printed layer have poor adhesion to the substrate and form an oxide film that causes interference.
所望パターンが得られ難く、所望パターンを得るため、
塗膜又は印刷層と組合せたものは、塗膜又は印刷層を形
成した後、機械的に剥離せしめ、剥離した部分に陽極酸
化により干渉を有する酸化皮膜を形成するため、陽極酸
化する際、塗膜又は印刷層が剥難してしまうといった問
題が生じていた。It is difficult to obtain the desired pattern, and in order to obtain the desired pattern,
For those combined with a paint film or printed layer, after forming the paint film or print layer, it is mechanically peeled off and an oxide film with interference is formed on the peeled part by anodic oxidation. There has been a problem that the film or printed layer is difficult to peel off.
（課題を解決するための手段）
本発明は、チタニウム系基材表面に、干渉を有する酸化
皮膜及び結晶性酸化皮膜を形成してなることを特徴とす
る装飾体を要旨とする。(Means for Solving the Problems) The gist of the present invention is a decorative body characterized by forming an interfering oxide film and a crystalline oxide film on the surface of a titanium base material.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
チタニウム系基材として、具体的には、チタニウム、又
は、チタニウム−バナジウム−アルミニウムなどのチタ
ニウム合金よりなるもの、或いは、他の基材表面にこれ
らの皮膜を形成してなるものなど挙げられる。Specific examples of the titanium base material include those made of titanium or a titanium alloy such as titanium-vanadium-aluminum, or those made by forming a film of these on the surface of another base material.
前記基材表面には、干渉を有する酸化皮膜及び結晶性酸
化皮膜を形成してなる。干渉を有する酸化皮膜は、基材
を一般に用いている酸化処理溶液に浸漬することにより
得られるもので、処理溶液、条件を適宜選択することに
より、干渉を有する酸化皮膜の色を調整できる。結晶性
酸化皮膜は、基材を炭酸塩及びハロゲン化合物よりなる
水溶液中にて、火花放電させながら、陽極酸化すること
により得られるもので、白〜グレー色、結晶はルチル、
アナターゼ、或いは、これらの混合型があり、処理溶液
、条件を適宜選択することにより、結晶、或いは１色調
整できる。パターン形成は、チタニウム系基材表面に、
１、結晶性酸化皮膜を形成し、所望パターン部分の結晶
性酸化皮膜を除去し、干渉を有する酸化皮膜を形成する
。An oxide film having interference and a crystalline oxide film are formed on the surface of the base material. The oxide film with interference is obtained by immersing the base material in a commonly used oxidation treatment solution, and the color of the oxide film with interference can be adjusted by appropriately selecting the treatment solution and conditions. The crystalline oxide film is obtained by anodic oxidation of the base material in an aqueous solution consisting of carbonate and a halogen compound while subjecting it to spark discharge.It is white to gray in color, and the crystals are rutile,
There is anatase or a mixed type of these, and by appropriately selecting the processing solution and conditions, it is possible to adjust the crystal or one color. Pattern formation is performed on the surface of the titanium base material.
1. Form a crystalline oxide film, remove the crystalline oxide film in a desired pattern portion, and form an oxide film with interference.
２、干渉を有する酸化皮膜を形成し、所望パターン部分
の干渉を有する酸化皮膜を除去し、結晶性酸化皮膜を形
成する。2. Form an oxide film with interference, remove the oxide film with interference from a desired pattern portion, and form a crystalline oxide film.
３、レジストインキを用いて、スクリーン印刷により、
パターン形成して、干渉を有する酸化皮膜を形成し、こ
の後、レジストインキを除去して、結晶性酸化皮膜を形
成する。3. By screen printing using resist ink,
A pattern is formed to form an oxide film with interference, and then the resist ink is removed to form a crystalline oxide film.
４、レジストインキを用いて、スクリーン印刷により、
パターン形成して、干渉を有する酸化皮膜を形成し、こ
の後、レジスにインキを除去して、結晶性酸化皮膜を形
成する。4. By screen printing using resist ink,
Patterning is performed to form an oxide film with interference, and the ink is then removed from the resist to form a crystalline oxide film.
結晶性酸化皮膜は、耐薬品性が高く、基材に対しての密
着性が高いため、結晶性酸化皮膜を形成した後、陽極酸
化しても、皮膜への影響が生じ難いことより、結晶性酸
化皮膜を形成した後、干渉を有する酸化皮膜を形成する
方が好ましい。The crystalline oxide film has high chemical resistance and high adhesion to the base material, so even if the crystalline oxide film is formed and then anodized, the film will not be affected easily. It is preferable to form an oxide film with interference after forming the oxidation film with interference.
（実施例） ス１Ｊす。(Example) S1J.
直径１０．０ｍｍ、厚さ０．３ｍｍ、長さ１００１ｍの
チタニウムよりなるパイプを基材とし、パフ研磨により
研磨処理し、浸漬脱脂剤（Ｅ６６、日本Ｍ ａｎｄ
Ｔ社製）４０ｇ／ｎを含有した５０’Ｃ水溶液にて脱
脂して、３０％塩酸溶液にて中和した後、炭酸ナトリウ
ム２５０ｇ／Ω、フッ化ナトリウム０゜５ ｇ ／ ｎ
を含有した水溶液中で、３Ａ／ｄｍにて表面に火花放電
させながら陽極酸化を１５分行なｔｌ。A titanium pipe with a diameter of 10.0 mm, a thickness of 0.3 mm, and a length of 1001 m was used as the base material, polished by puff polishing, and soaked with an immersion degreaser (E66, Japan M and
After degreasing with a 50'C aqueous solution containing 40 g/n (manufactured by Company T) and neutralizing with a 30% hydrochloric acid solution, sodium carbonate 250 g/Ω and sodium fluoride 0°5 g/n.
Anodic oxidation was carried out for 15 minutes in an aqueous solution containing 3 A/dm with spark discharge on the surface.
白色のルチル型酸化皮膜を５μｍ形成した。乾燥させた
後、ダイヤカット機にセットし１表面を格子状に幅１ｍ
ｍ、深さ０．１ｍカットして、ｒｌｉ化皮膜を除去した
。次に、リン酸１％、デキストリン１％を含有した水溶
液中で、１０ｖにて陽極酸化を５分行ない、結晶性酸化
皮膜を除去した格子状のカット部分にピンク色の干渉を
有する酸化皮膜を形成して、白。A white rutile type oxide film with a thickness of 5 μm was formed. After drying, set it on a diamond cutting machine and cut one surface into a grid pattern with a width of 1m.
The rli coating was removed by cutting the sample to a depth of 0.1 m. Next, anodic oxidation was performed at 10V for 5 minutes in an aqueous solution containing 1% phosphoric acid and 1% dextrin to form an oxide film with pink interference on the lattice-shaped cut portions from which the crystalline oxide film had been removed. Form, white.
ピンクのパターンを形成した装飾体を得た。A decorative body with a pink pattern was obtained.
寒許五ス
実施例１と同様の基材に、平均粒径２００μｍのガラス
ピーズにてブラスト処理を行ない、表面に凹凸形成し、
次に、浸漬脱脂剤（Ｅ６６、日本Ｍａｎｄ Ｔ社製＞
４０ｇ／Ｑ、５０℃水溶液にて脱脂して、３０％塩酸溶
液にて中和した後、炭酸ナトリウム２５０ｇ／Ｒ、フッ
化ナトリウムｌｏｇ／Ｑを含有した水溶液中で、３Ａ／
ｄｍにて表面に火花放電させながら陽極酸化を１５分行
ない、グレーのルチルとアナターゼ混合型酸化皮膜を４
μｍ形成した。The same base material as in Example 1 was blasted with glass beads having an average particle size of 200 μm to form irregularities on the surface.
Next, use an immersion degreaser (E66, manufactured by Mand T Co., Ltd. in Japan).
After degreasing with 40g/Q, 50℃ aqueous solution and neutralizing with 30% hydrochloric acid solution, 3A/Q in an aqueous solution containing 250g/R of sodium carbonate and sodium fluoride log/Q.
Anodic oxidation was performed for 15 minutes with spark discharge on the surface using DM to form a gray rutile and anatase mixed oxide film.
μm was formed.
乾燥させた後、ダイヤカット機にセットし１表面を螺旋
状に＠１．５ｍｍ、深さ０．５＋＋ｏカツトして、酸化
皮膜を除去した０次に、硫１３０％を含有した溶液中で
、３０ｖにて陽極酸化を１０分行ない、結晶性酸化皮膜
を除去した螺旋状のカット部分に淡ブルー色の干渉を有
する酸化皮膜を形成して、グレー淡ブルー色のパターン
を形成した装飾体を得た。After drying, it was set in a diamond cutting machine and one surface was cut in a spiral shape @ 1.5 mm to a depth of 0.5 + o to remove the oxide film. Next, in a solution containing 130% sulfur, Anodic oxidation was performed at 30V for 10 minutes to form an oxide film with pale blue interference on the spiral cut portion from which the crystalline oxide film had been removed, thereby obtaining a decorative body with a gray and pale blue pattern. Ta.
１胤孤立
実施例１と同様の基材にレジストインキ（１６９３５、
■製）を用いて、スクリーン印刷により、５薗おきに１
幅１閣の格子状パターンを形成した。次に、浸漬脱脂剤
（Ｅ６６、日本ＭａｎｄＴ社製）４０ ｇ ／ Ｑを含
有した５０℃水溶液にて脱脂して、１０％塩酸溶液にて
中和した後、リン酸１％、デキストリン１％を含有した
水溶液中で、３０Ｖにて陽極酸化を１ｏ分行ない、乾燥
して、淡ブルー色の干渉を有する酸化皮膜を形成した。1 Seed Isolation Resist ink (16935,
1) every 5 rows by screen printing using
It formed a grid pattern with a width of one square. Next, it was degreased with a 50°C aqueous solution containing 40 g/Q of an immersion degreaser (E66, manufactured by MandT, Japan), neutralized with a 10% hydrochloric acid solution, and then treated with 1% phosphoric acid and 1% dextrin. Anodic oxidation was carried out for 10 minutes at 30 V in the aqueous solution containing the sample and dried to form an oxide film having light blue interference.
次に、レジストインキ（１６９３５，ナツダ■製）を用
いて、スクリーン印刷により、格子と格子の間に、輻１
ｎｗ＊のパタ−ンを形成して、乾燥した。この後、炭酸
ナトリウム２５０ ｇ／Ｒ、フッ化ナトリウム０．５ｇ
／Ｑを含有した水溶液中で、３ Ａ ／ ｄ ｍにて表
面に火花放電させながら陽極酸化を１５分行ない、白色
のルチル型酸化皮膜を５μｍ形成した。乾燥させた後、
トリクレンに基材を浸漬させ、超音波を加えることによ
り、レジストインキを除去し、乾燥して、チタン基材の
有する金属調色、淡ブルー、白色のパターンを形成した
装飾体を得た。Next, using resist ink (16935, manufactured by Natsuda ■), screen printing was performed to create a line between the grids.
A nw* pattern was formed and dried. After this, sodium carbonate 250 g/R, sodium fluoride 0.5 g
Anodic oxidation was performed for 15 minutes in an aqueous solution containing /Q at 3 A/d m while spark discharge was applied to the surface to form a white rutile type oxide film with a thickness of 5 μm. After drying,
The resist ink was removed by immersing the base material in trichlene and applying ultrasonic waves, and the resist ink was dried to obtain a decorative body in which a pattern of metallic toning, light blue, and white of the titanium base material was formed.
友絞髭よ
実施例１と同様の基材をトリクレンにて洗浄して、この
後、アクリル系塗料（白 ユニパール、大橋化学課製）
をスプレーにて塗布して、１６０℃、２０分焼付処理を
行なった。次に、ダイヤカット機にセットし、表面を格
子状に輻１ｍｍ、深さ０．１ｎｎカツトして１次に、リ
ン酸１％、デキストリン１％を含有し、た水溶液中で、
ＩＯＶにて陽極酸化を５分行なった・
ル（君１々
実施例１と同様の基材に、スクリーン印刷用インキ（セ
イコー１０００、セイコーアドバンス潤製）を用いて、
スクリーン印刷により、印刷して、１３０℃、３０分焼
付処理を行なった。次に、浸漬脱脂剤８Ｅ６６、日本Ｍ
ａｎｄＴ社製）４０ｇ／Ｑ、５０℃水溶液にて脱脂して
、１０％塩酸溶液にて中和した後、硫酸１０％を含有し
た水溶液中で、３０Ｖ、１０分陽極酸化処理を行なった
。Dear friend, wash the same base material as in Example 1 with Triclean, and then apply acrylic paint (white Unipearl, manufactured by Ohashi Chemical Division).
was applied by spray and baked at 160° C. for 20 minutes. Next, it was set in a diamond cutting machine, and the surface was cut into a lattice pattern with a diameter of 1 mm and a depth of 0.1 nn.
Anodic oxidation was performed for 5 minutes in IOV (Kimi 1) Using screen printing ink (Seiko 1000, manufactured by Seiko Advance Jun) on the same base material as in Example 1,
It was printed by screen printing and baked at 130° C. for 30 minutes. Next, soaking degreaser 8E66, Japan M
After degreasing with a 50° C. aqueous solution and neutralizing with a 10% hydrochloric acid solution, anodization treatment was performed at 30 V for 10 minutes in an aqueous solution containing 10% sulfuric acid.
（効 果）
実施例１〜３、比較例１，２により得られたサンプルを
、パターン状態について目視判定するとともに、密着性
試験を行なった結果を下表に示す。(Effects) The samples obtained in Examples 1 to 3 and Comparative Examples 1 and 2 were visually judged for pattern condition and subjected to an adhesion test. The results are shown in the table below.
このように、 本発明の装飾体は。in this way, The decorative body of the present invention is:
密着性の優れた。Excellent adhesion.
所望パターンを形成してなるものである。It is formed by forming a desired pattern.
特許出顕人 ぺんてる株式会社patent author Pentel Co., Ltd.
Claims (1)
晶性酸化皮膜を形成してなることを特徴とする装飾体。A decorative body comprising an oxide film having interference and a crystalline oxide film formed on the surface of a titanium base material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28542789A JPH03146678A (en) | 1989-10-31 | 1989-10-31 | Ornamental body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP28542789A JPH03146678A (en) | 1989-10-31 | 1989-10-31 | Ornamental body |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03146678A true JPH03146678A (en) | 1991-06-21 |
Family
ID=17691383
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP28542789A Pending JPH03146678A (en) | 1989-10-31 | 1989-10-31 | Ornamental body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03146678A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007009285A (en) * | 2005-06-30 | 2007-01-18 | Hokkaido Univ | Anodized coating-formed titanium member, method for producing the same, and valve spring for internal combustion engine |
-
1989
- 1989-10-31 JP JP28542789A patent/JPH03146678A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007009285A (en) * | 2005-06-30 | 2007-01-18 | Hokkaido Univ | Anodized coating-formed titanium member, method for producing the same, and valve spring for internal combustion engine |
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