JPH03132495A - Contamination preventive device for structure in contact with sea water - Google Patents

Contamination preventive device for structure in contact with sea water

Info

Publication number
JPH03132495A
JPH03132495A JP27251189A JP27251189A JPH03132495A JP H03132495 A JPH03132495 A JP H03132495A JP 27251189 A JP27251189 A JP 27251189A JP 27251189 A JP27251189 A JP 27251189A JP H03132495 A JPH03132495 A JP H03132495A
Authority
JP
Japan
Prior art keywords
conductive film
film
current
conductive
contact
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP27251189A
Other languages
Japanese (ja)
Inventor
Masahiro Usami
正博 宇佐美
Akio Nishi
西 昭雄
Kiyomi Tomoshige
友重 清美
Kenji Ueda
健二 植田
Tsutomu Horiguchi
堀口 勉
Hiroshi Yamazaki
弘 山崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHIYOURIYOU ENG KK
Mitsubishi Heavy Industries Ltd
Choryo Engineering Co Ltd
Original Assignee
CHIYOURIYOU ENG KK
Mitsubishi Heavy Industries Ltd
Choryo Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHIYOURIYOU ENG KK, Mitsubishi Heavy Industries Ltd, Choryo Engineering Co Ltd filed Critical CHIYOURIYOU ENG KK
Priority to JP27251189A priority Critical patent/JPH03132495A/en
Publication of JPH03132495A publication Critical patent/JPH03132495A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To provide uniform current density in No.1 electroconductive film in an arrangement in which attachment and growth of marine organism by flowing DC current in the direction of underwater neg. electrode from No.1 conductive film via a No.2 conductive film, by furnishing a plurality of current feed terminals on the No.1 conductive film. CONSTITUTION:An electric insulative coating 03 is applied to the water contact surface side of the external plate 1 of a structure in contact with the sea water, such as a ship, a marine structure or the like constructed from steel plate, and the outside of coating 3 is covered with No.1 electroconductive film 07 consisting of a sheet of a metal or metal oxide having a small specific resistance, a fusion metallization film, evaporation film, or fusion deposit film. The outside of this conductive film 07 is covered with No.2 conductive film 09 with large electric resistance consisting of an unsoluble substance with resistance against oxidation and an organic binder. The contamination preventing effect is exerted by allowing a DC current to flow from a power supply to between the No.1 conductive film 07 and an electric conductive substance, not illustrated, furnished on the surface of the No.2 conductive film 09. A plurality of current feed terminals 2, 3 are furnished on the No.1 conductive film 07, to prevent excessive local rise of the current-feed-terminal current density of the No.1 conductive film 07.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は船舶、海洋構造物等海水に接する構造物の防汚
装置に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an antifouling device for structures in contact with seawater, such as ships and marine structures.

〔従来の技術〕[Conventional technology]

船舶、海洋構造物等海水に接する構造物の防汚手段とし
ては、従来、構造物の接水部分に防汚塗料を塗装する手
段が一般的に採用されている。
BACKGROUND ART Conventionally, as antifouling means for structures that come into contact with seawater, such as ships and offshore structures, a method of applying an antifouling paint to the parts of the structure that come in contact with water has been generally adopted.

しかしながら、このような手段では、次のような欠点が
ある。
However, such means have the following drawbacks.

(1)  防汚塗料の防汚成分溶出速度を調節すること
ができないので、季節、海流、水質変化等に自在に対応
することができない。
(1) Since the elution rate of the antifouling component of the antifouling paint cannot be adjusted, it is not possible to freely respond to changes in seasons, ocean currents, water quality, etc.

(2)  防汚塗料中の毒物含有量に限度があるので、
約2年ごとに塗り替え作業が必要である。
(2) Since there is a limit to the amount of toxic substances contained in antifouling paints,
Repainting is required approximately every two years.

そこで本出願人は、さきに、特願昭61247032号
、特願昭61−248897号をもって、第3図模式図
に示すように、海水01に接する構造物の外板を構成す
る綱板o2に、エポキシ樹脂等の絶縁塗膜03と、カー
ボン粉等を有機質バインダーに混合した導電塗膜04を
塗り重ね、導電塗膜04とそれに対向して海水中に設置
された綱等からなる電気伝導体05との間に、直流電源
06により導電塗膜04を(+)に、電気伝導体05を
(−)にして通電し、導電塗膜04上に 2 C1−=
Cj!24− ’l e  の作用で塩素を発生させる
装置を提案した。
Therefore, the present applicant previously filed Japanese Patent Application No. 61247032 and Japanese Patent Application No. 61-248897 to construct a cable plate o2 constituting the outer panel of a structure in contact with seawater 01, as shown in the schematic diagram in Figure 3. , an electrical conductor consisting of an insulating coating film 03 made of epoxy resin or the like and a conductive coating film 04 made of an organic binder mixed with carbon powder or the like is applied, and the conductive coating film 04 and a rope or the like placed opposite to it in seawater are formed. 05, the conductive coating film 04 is set to (+) and the electric conductor 05 is set to (-) using a DC power supply 06, and electricity is applied to the conductive coating film 04 so that 2 C1-=
Cj! 24- We proposed a device that generates chlorine by the action of 'le.

ところが、このような装置には、次のような不具合があ
ることが判明した。
However, it has been found that such a device has the following defects.

(1)  海水01中に流出する電流密度をある一定値
以上に保持する必要があるが、導電塗膜04の消耗によ
る抵抗上昇のため通電端06a近くに電流密度が集中し
、防汚有効範囲が狭くなる。
(1) It is necessary to maintain the current density flowing into the seawater 01 above a certain value, but due to the increase in resistance due to wear of the conductive coating 04, the current density concentrates near the current-carrying end 06a, and the effective antifouling range becomes narrower.

(2)  導電塗膜04の膜厚のばらつきにより電流密
度が異なり、性能の維持が困難である。
(2) Current density varies due to variations in the thickness of the conductive coating film 04, making it difficult to maintain performance.

(3)  電流密度の均一化には低抵抗の導電塗膜04
が必要であるが、そのためには多量の導電粉を混入する
必要があり製造が困難である。
(3) Low resistance conductive coating 04 for uniform current density
However, for this purpose, it is necessary to mix a large amount of conductive powder, which is difficult to manufacture.

そこで、本出願人は、さきに第4図模式図に示すような
装置を特願昭63−287190号として提案した。
Therefore, the present applicant previously proposed a device as shown in the schematic diagram of FIG. 4 in Japanese Patent Application No. 63-287190.

すなわち、同図において、第3図と同一の符番はそれぞ
れ同図と同一の部材を示し、o7は絶縁塗膜03の外側
を被覆する比抵抗の小さい金属、金属酸化物の薄板、溶
射膜、融着膜又は蒸着膜からなり、通電端08が設けら
れている第1の導電膜で、比抵抗の小さい金属としては
ニノゲル、銅、チタン、アルミニウム1 ニオブ等、金
属酸化物としてはマグネタイト、二酸化マンガン等がそ
れぞれ使用できる。
That is, in the same figure, the same reference numbers as in FIG. 3 indicate the same members as in the same figure, and o7 indicates a metal with low resistivity, a thin plate of metal oxide, or a sprayed film that covers the outside of the insulating coating 03. The first conductive film is made of a fused film or a vapor deposited film and is provided with a current-carrying end 08. Metals with low resistivity include Ninogel, copper, titanium, aluminum 1, niobium, etc., and metal oxides include magnetite, Manganese dioxide, etc. can be used.

09は更に第1の導電膜07の外側を被覆する耐酸化性
不溶性物質と有機バインダーとからなる第2の導電膜で
、耐酸化性不溶性物質としてはグラファイト、カーボン
ブラック、マグネタイト、白金属等が使用でき、有機バ
インダーとしてはエポキシ樹脂、ビニール樹脂、不飽和
ポリエステル樹脂等が使用できる。またこの第2の導電
膜09は第1の導電膜07に比べ電気抵抗が大きくなっ
ている。
09 is a second conductive film made of an oxidation-resistant insoluble substance and an organic binder that coats the outside of the first conductive film 07, and the oxidation-resistant insoluble substance includes graphite, carbon black, magnetite, white metal, etc. Epoxy resins, vinyl resins, unsaturated polyester resins, etc. can be used as organic binders. Further, this second conductive film 09 has a higher electrical resistance than the first conductive film 07.

010は第2の導電膜09と対向して海水01中に設置
された鉄、銅又は炭素等からなる陰極、011は第1の
導電膜07の通電端08と陰極010との間に設置され
、第1の導電膜07から第2の導電膜09を通して陰極
010の方向へ直流を通電する直流電源である。012
は綱板02と陰極010とを接続するリード線である。
010 is a cathode made of iron, copper, carbon, etc. that is placed in seawater 01 facing the second conductive film 09; 011 is a cathode that is placed between the current-carrying end 08 of the first conductive film 07 and the cathode 010; , is a DC power supply that supplies DC current from the first conductive film 07 to the cathode 010 through the second conductive film 09. 012
is a lead wire connecting the rope plate 02 and the cathode 010.

このような装置において、第1の導電膜07から第2の
導電膜09を通して、海水01中の陰極010の方向へ
直流電流を流出させると、第2の導電膜09の表面は濃
い塩素の膜に覆われ、海洋生物がその表面へ付着するこ
とを防止する。
In such a device, when a direct current flows from the first conductive film 07 to the cathode 010 in the seawater 01 through the second conductive film 09, the surface of the second conductive film 09 becomes a thick chlorine film. to prevent marine life from attaching to its surface.

その際の直流電流は、第1の導電膜07に設けられてい
る通電端08から、電気抵抗の小さい第1の導電膜07
のベース電流を通して第2の導電膜09の厚さ方向に供
給されることになり、従って第2の導電膜09が消耗し
ても通電端08近(に電流密度が集中するということは
なく、安定した均一な電流密度分布が長期にわたって維
持でき、ひいては少ない消費電力で高性能な防汚効果を
奏することができる。
At that time, the direct current flows from the current-carrying end 08 provided on the first conductive film 07 to the first conductive film 07 with low electrical resistance.
Therefore, even if the second conductive film 09 is consumed, the current density will not be concentrated near the current-carrying end 08. A stable and uniform current density distribution can be maintained over a long period of time, and high-performance antifouling effects can be achieved with low power consumption.

しかしながら、その後の研究によりこのような装置では
第1の導電膜07のiil電端08が構造物の上端面の
みに付設されたので、通電端08付近の第1の導電膜0
7の電流密度が局部的に高くなるとともに材質が劣化し
て、導電膜が消失しそこから先に電流が流れず防汚作用
が生じな(なることが判明した。
However, subsequent research revealed that in such a device, the IIL conductive end 08 of the first conductive film 07 was attached only to the upper end surface of the structure.
It was found that as the current density of No. 7 locally increased, the material deteriorated, the conductive film disappeared, and the current no longer flowed from there, resulting in no antifouling effect.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

本発明は、このような事情に鑑みて提案されたもので、
第1の導電膜の通電端電流密度が過度に局部的に上昇せ
ず、従って4電膜の耐久性が大きく、かつ電力消費の少
ない経済的な海水に接する構造物の防汚装置を提供する
ことを目的とする。
The present invention was proposed in view of these circumstances, and
To provide an economical antifouling device for a structure in contact with seawater in which the current density of the current-carrying end of a first conductive film does not locally increase excessively, the durability of the four-electrode film is high, and power consumption is low. The purpose is to

〔課題を解決するための手段〕[Means to solve the problem]

そのために本発明は船舶、海洋構造物等海水に接する構
造物の接水面を電気絶縁塗膜を介し被覆し比抵抗の小さ
い金属又は金属酸化物の薄板、ffI射膜、蒸着膜又は
融着膜からなりそれに通電端が設けられている第1の導
電膜と、上記第1の導電膜の外側を′+&覆し耐酸化性
不溶性物質と有機バインダーとからなり上記第1の導電
膜より電気抵抗の大きい第2の導電膜と、上記第2のR
電膜に対向し鉄、銅又は炭素からなり海水中に設置され
た電気伝導体と、上記第1の導電膜と上記電気伝導体と
の間に設置され上記第1の導電膜から上記第2の導電膜
を通して上記電気伝導体方向に直流をiM電する電源装
置とを具えてなる構造物の防汚装置において、上記第1
の導電膜の複数個所に上記通電端を設けることを特徴と
する。
To this end, the present invention covers the water-contact surfaces of structures in contact with seawater, such as ships and offshore structures, with an electrically insulating coating film, which is a thin plate of metal or metal oxide with low specific resistance, an ffI film, a vapor deposited film, or a fused film. a first electrically conductive film comprising a conductive end and a conductive end; a large second conductive film and the second R
an electrical conductor made of iron, copper, or carbon and placed in seawater facing the electrical film; and a power supply device that supplies iM direct current in the direction of the electrical conductor through the conductive film of the structure, wherein the first
The conductive film is characterized in that the conductive ends are provided at a plurality of locations on the conductive film.

〔作用〕[Effect]

通電端が第1の導電膜の上端のみに限定されずその複数
個所に設けられるので、第1の導電膜内での電流密度が
ほぼ均一化されるとともに、電流密度平均値が減少する
Since the current-carrying end is not limited to only the upper end of the first conductive film but is provided at a plurality of locations, the current density within the first conductive film is made substantially uniform, and the average value of the current density is reduced.

〔実施例〕〔Example〕

本発明を船体外板に適用した一実施例を図面について説
明すると、第3〜4図と同一の符番はそれぞれ同図と同
一の部材を示し、まず、第1図斜視図において、1は鋼
板で形成された船体外板、2.3は船体外板lの絶縁塗
膜03上に溶射された第1の導電膜07の上端、中間レ
ベルにそれぞれ設置された通電端、4は通電端2.3と
図示省略の直流電源の陽極とをそれぞれ接続するリード
線である。
An embodiment in which the present invention is applied to a hull shell plate will be described with reference to the drawings. The same reference numerals as in Figs. 3 and 4 indicate the same members as in the same figures. First, in the perspective view of Fig. 1, 1 is A hull outer plate formed of a steel plate, 2.3 is a current-carrying end installed at the upper end and intermediate level of the first conductive film 07 sprayed on the insulating coating 03 of the hull outer board 1, and 4 is a current-carrying end. These are lead wires that connect 2.3 and the anode of a DC power supply (not shown), respectively.

このような装置において、直流電源の陽極からリード線
4を介して通電端2.3にそれぞれ電流を通ずると、通
電端2のみに電流を通じた場合に比べ、第1の導電膜0
7の央部にも通電端3が設置されているので、通電端2
の電流密度が過度に上昇せず、従って第1の導電膜07
内における電流密度がほぼ均一化されるとともに、電力
消費量が減少する。
In such a device, when a current is passed from the anode of the DC power supply to the current carrying ends 2 and 3 via the lead wire 4, the first conductive film 0
Since the current-carrying end 3 is also installed in the center of 7, the current-carrying end 2
Therefore, the current density of the first conductive film 07 does not increase excessively.
The current density within the circuit is approximately equalized, and the power consumption is reduced.

因みに、船体外板1の上端通電端2から下方への距離と
電流密度比との関係を調査したところ、第2図線図に示
す曲線5が得られた。ここで曲線6は通電端2のみによ
る場合を示す。
Incidentally, when the relationship between the distance downward from the upper current-carrying end 2 of the hull outer plate 1 and the current density ratio was investigated, a curve 5 shown in the diagram of FIG. 2 was obtained. Here, curve 6 shows the case where only current-carrying end 2 is used.

これより、従来方式では通電端2付近で防汚に必要な電
流密度(同図鎖線7参照)の4倍程度の高電流密度とな
るが、本発明方式では2倍程度の低電流密度に抑えるこ
とができることが判明した。
From this, in the conventional method, the current density is about four times the current density required for antifouling near the current-carrying end 2 (see chain line 7 in the same figure), but in the method of the present invention, the current density is reduced to a low current density about twice. It turns out that it can be done.

このような装置によれば、下記効果が奏せられる。According to such a device, the following effects can be achieved.

(])  通電端が第1の導電膜の上端のみに限定され
ず央部にも付設されるので、第1の導電膜内での電流密
度がほぼ均一化され、従って第1の導電膜の耐久性が向
上する。
(]) Since the current-carrying end is not limited to the upper end of the first conductive film but is also attached to the center, the current density within the first conductive film is almost uniform, and therefore the current density of the first conductive film is Improves durability.

(2)  通電端が第1の導電膜の上端のみに限定され
ず央部にも付設されるので、第1の導電膜内での電流密
度平均値が下がり、電力消費量が減少し、従って経済性
が向上する。
(2) Since the current-carrying end is not limited to only the upper end of the first conductive film but is also attached to the center, the average current density within the first conductive film is reduced, power consumption is reduced, and therefore Economic efficiency improves.

〔発明の効果〕〔Effect of the invention〕

要するに本発明によれば、船舶、海洋構造物等海水に接
する構造物の接水面を電気絶縁塗膜を介し被覆し比抵抗
の小さい金属又は金属酸化物の薄板、溶射膜、蒸着膜又
は融着膜からなりそれに通電端が設けられている第1の
導電膜と、上記第1の導電膜の外側を被覆し耐酸化性不
溶性物質と有機バインダーとからなり上記第1の導電膜
より電気抵抗の大きい第2の導電膜と、上記第2の導電
膜に対向し鉄、銅又は炭素からなり海水中に設置された
電気伝導体と、上記第1の導電膜と上記電気伝導体との
間に設置され上記第1の導電膜から上記第2の導電膜を
通して上記電気伝導体方向に直流を通電する電源装置と
を具えてなる構造物の防汚装置において、上記第1の導
電膜の複数個所に上記通電端を設けることにより第1の
導電膜の通電端電流密度が過度に局部的に上昇せず、従
って導電膜の耐久性が大きく、かつ電力消費の少ない経
済的な海水に接する構造物の防汚装置を得るから、本発
明は産業上極めて有益なものである。
In short, according to the present invention, the water-contact surfaces of structures in contact with seawater, such as ships and offshore structures, are coated with an electrically insulating coating film, and a thin plate, sprayed film, vapor deposited film, or fusion film of a metal or metal oxide with low specific resistance is coated. A first conductive film is formed of a film and is provided with a conductive end, and the first conductive film is coated with an oxidation-resistant insoluble substance and an organic binder and has a lower electrical resistance than the first conductive film. a large second conductive film; an electric conductor made of iron, copper, or carbon and placed in seawater facing the second conductive film; and between the first conductive film and the electric conductor; An antifouling device for a structure comprising: a power supply device that is installed and supplies direct current from the first conductive film to the second conductive film in the direction of the electrical conductor; By providing the above-mentioned current-carrying end in the first conductive film, the current density at the current-carrying end of the first conductive film does not increase locally excessively, and therefore the durability of the conductive film is high, and an economical structure in contact with seawater with low power consumption is provided. Therefore, the present invention is extremely useful industrially.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明を船体外板に適用したー実施例を示す斜
視図、第2図は第1図装置による電流密度比の分布状態
を示す比較線図である。 第3図、第4図はそれぞれ本出願人がさきに提案した海
水に接する構造物の防汚装置の縦断面を示す模式図であ
る。 1・・・船体外板、2.3・・・通電端、4・・・リー
ド線、5,6・・・曲線、7・・・防汚に必要な電流密
度03・・・絶縁塗膜、07・・・第1の導電膜、09
・・・第2の導電膜、
FIG. 1 is a perspective view showing an embodiment in which the present invention is applied to a ship's outer plate, and FIG. 2 is a comparative diagram showing the state of distribution of current density ratio by the apparatus shown in FIG. 1. FIGS. 3 and 4 are schematic diagrams each showing a longitudinal section of an antifouling device for a structure in contact with seawater, which was previously proposed by the applicant. 1... Hull outer plate, 2.3... Current-carrying end, 4... Lead wire, 5, 6... Curve, 7... Current density required for antifouling 03... Insulating coating film , 07...first conductive film, 09
... second conductive film,

Claims (1)

【特許請求の範囲】[Claims]  船舶、海洋構造物等海水に接する構造物の接水面を電
気絶縁塗膜を介し被覆し比抵抗の小さい金属又は金属酸
化物の薄板、溶射膜、蒸着膜又は融着膜からなりそれに
通電端が設けられている第1の導電膜と、上記第1の導
電膜の外側を被覆し耐酸化性不溶性物質と有機バインダ
ーとからなり上記第1の導電膜より電気抵抗の大きい第
2の導電膜と、上記第2の導電膜に対向し鉄、銅又は炭
素からなり海水中に設置された電気伝導体と、上記第1
の導電膜と上記電気伝導体との間に設置され上記第1の
導電膜から上記第2の導電膜を通して上記電気伝導体方
向に直流を通電する電源装置とを具えてなる構造物の防
汚装置において、上記第1の導電膜の複数個所に上記通
電端を設けることを特徴とする海水に接する構造物の防
汚装置。
The water-contact surfaces of structures in contact with seawater, such as ships and offshore structures, are coated with an electrically insulating coating and are made of a thin plate, sprayed film, vapor deposited film, or fusion film of metal or metal oxide with low specific resistance, and the current-carrying end is a second conductive film that covers the outside of the first conductive film and is made of an oxidation-resistant insoluble substance and an organic binder and has a higher electrical resistance than the first conductive film; , an electrical conductor made of iron, copper, or carbon and placed in seawater facing the second electrically conductive film;
and a power supply device installed between the conductive film and the electric conductor, which supplies direct current from the first conductive film to the second conductive film in the direction of the electric conductor. An antifouling device for a structure in contact with seawater, characterized in that the first electrically conductive film is provided with the current-carrying ends at a plurality of locations.
JP27251189A 1989-10-19 1989-10-19 Contamination preventive device for structure in contact with sea water Pending JPH03132495A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP27251189A JPH03132495A (en) 1989-10-19 1989-10-19 Contamination preventive device for structure in contact with sea water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP27251189A JPH03132495A (en) 1989-10-19 1989-10-19 Contamination preventive device for structure in contact with sea water

Publications (1)

Publication Number Publication Date
JPH03132495A true JPH03132495A (en) 1991-06-05

Family

ID=17514922

Family Applications (1)

Application Number Title Priority Date Filing Date
JP27251189A Pending JPH03132495A (en) 1989-10-19 1989-10-19 Contamination preventive device for structure in contact with sea water

Country Status (1)

Country Link
JP (1) JPH03132495A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54110588A (en) * 1978-01-09 1979-08-30 Lectret Sa Device of preventing attachment of oceanic life to hull
JPS5737091A (en) * 1980-08-14 1982-03-01 Mitsubishi Heavy Ind Ltd Adhesion-proofing process of ship
JPS6487791A (en) * 1987-06-30 1989-03-31 Mitsubishi Heavy Ind Ltd Antifouling device for structure in contact with seawater

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54110588A (en) * 1978-01-09 1979-08-30 Lectret Sa Device of preventing attachment of oceanic life to hull
JPS5737091A (en) * 1980-08-14 1982-03-01 Mitsubishi Heavy Ind Ltd Adhesion-proofing process of ship
JPS6487791A (en) * 1987-06-30 1989-03-31 Mitsubishi Heavy Ind Ltd Antifouling device for structure in contact with seawater

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