JPH03106995A - Lubricating oil composition for internal combustion engine - Google Patents
Lubricating oil composition for internal combustion engineInfo
- Publication number
- JPH03106995A JPH03106995A JP1243923A JP24392389A JPH03106995A JP H03106995 A JPH03106995 A JP H03106995A JP 1243923 A JP1243923 A JP 1243923A JP 24392389 A JP24392389 A JP 24392389A JP H03106995 A JPH03106995 A JP H03106995A
- Authority
- JP
- Japan
- Prior art keywords
- lubricating oil
- oil
- internal combustion
- weight
- base oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 27
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 238000002485 combustion reaction Methods 0.000 title claims abstract description 10
- KHYKFSXXGRUKRE-UHFFFAOYSA-J molybdenum(4+) tetracarbamodithioate Chemical compound C(N)([S-])=S.[Mo+4].C(N)([S-])=S.C(N)([S-])=S.C(N)([S-])=S KHYKFSXXGRUKRE-UHFFFAOYSA-J 0.000 claims abstract description 12
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000003118 aryl group Chemical group 0.000 claims abstract description 8
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 239000011593 sulfur Substances 0.000 claims abstract description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 8
- 239000003921 oil Substances 0.000 abstract description 21
- 239000000446 fuel Substances 0.000 abstract description 12
- 239000002199 base oil Substances 0.000 abstract 4
- 238000012360 testing method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- -1 alkylnaphthalene Chemical class 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000005078 molybdenum compound Substances 0.000 description 4
- 150000002752 molybdenum compounds Chemical class 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000005461 lubrication Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 229920002367 Polyisobutene Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000010692 aromatic oil Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000010710 diesel engine oil Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000010705 motor oil Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010711 gasoline engine oil Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920013636 polyphenyl ether polymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical class O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M101/00—Lubricating compositions characterised by the base-material being a mineral or fatty oil
- C10M101/02—Petroleum fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/12—Thio-acids; Thiocyanates; Derivatives thereof
- C10M135/14—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond
- C10M135/18—Thio-acids; Thiocyanates; Derivatives thereof having a carbon-to-sulfur double bond thiocarbamic type, e.g. containing the groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/1006—Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
- C10M2203/1025—Aliphatic fractions used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/104—Aromatic fractions
- C10M2203/1045—Aromatic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/106—Naphthenic fractions
- C10M2203/1065—Naphthenic fractions used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/108—Residual fractions, e.g. bright stocks
- C10M2203/1085—Residual fractions, e.g. bright stocks used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
- C10M2219/066—Thiocarbamic type compounds
- C10M2219/068—Thiocarbamate metal salts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/12—Groups 6 or 16
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/251—Alcohol fueled engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
- C10N2040/255—Gasoline engines
- C10N2040/28—Rotary engines
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は内燃機関用ｒ８滑油組成物に関し、さらに詳し
くは、ジチオカルバミン酸モリブデンを水素化分解され
た製油を含む潤滑油製油に配合することにより製造され
る、優れた省燃費性能を有する内燃機関用潤滑油組成物
に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to R8 lubricating oil compositions for internal combustion engines, and more particularly to R8 lubricating oil compositions prepared by incorporating molybdenum dithiocarbamate into lubricating oil refineries, including hydrocracked refineries. The present invention relates to a lubricating oil composition for internal combustion engines having excellent fuel efficiency performance.
従来の技術
石油危機を契機に、省エネルギ一対策が各方面で実施さ
れる中にあって、自動車の燃費改善を図るためのｒｊＪ
滑油の検討が進められている。潤滑油による省燃費対策
としては、ｍ ｌ体ｎ滑下におけるＩ！ｉ！擦損失の低
下を意図した低粘度化、および（２）混合潤滑下および
境界潤滑下における＊ｔ＊損失の低下を意図した摩擦低
減剤の添加、が検討されている。特に近年の優れた省燃
費油では、＊擦低減剤の添加は必須となっており、これ
までに多くの種類の化合物が開発され、成果をあげてい
る。Conventional technology In the wake of the oil crisis, energy-saving measures are being implemented in various fields, and RJJ is being developed to improve the fuel efficiency of automobiles.
Studies on lubricating oil are underway. As a fuel saving measure using lubricating oil, I! i! Lowering the viscosity with the intention of reducing friction loss, and (2) adding a friction reducing agent with the intention of reducing *t* loss under mixed lubrication and boundary lubrication are being considered. Particularly in the recent years of excellent fuel-saving oils, the addition of friction reducing agents has become essential, and many types of compounds have been developed to date and have achieved success.
開発された化合物の中でも特に有効であり、最もよく用
いられているものに、有機モリブデン化合物がある。本
発明者らもこの化合物の使用について長年に渡って検討
しており、その結果、モリブデン化合物の添加による優
れた省燃費効果を確認した。しかしながら、検討の過程
で次に述べるような問題点をも見出した。すなわち、多
くのモリブデン化合物は、劣化を受ける前の新油中では
優れた効果を発揮するが、エンジン運転中の劣化に伴っ
て、省燃費効果が徐々に失われてしまうことである。本
発明者らは、モリブデン化合物のうちジチオカルバミン
酸モリブデンが、この劣化に伴う省燃費性能の低下が起
こりにくいことを見出したが、まだ劣化に伴う省燃費性
能の低下が完全に起こらないとは言えなかった。Among the developed compounds, organic molybdenum compounds are particularly effective and most commonly used. The present inventors have also studied the use of this compound for many years, and as a result, they have confirmed that the addition of a molybdenum compound has an excellent fuel saving effect. However, during the course of the study, the following problems were discovered. That is, many molybdenum compounds exhibit excellent effects in fresh oil before deterioration, but as the oil deteriorates during engine operation, the fuel saving effect is gradually lost. The present inventors have found that, among molybdenum compounds, molybdenum dithiocarbamate is less likely to suffer from a decrease in fuel efficiency performance due to deterioration, but it cannot be said that the decrease in fuel economy performance due to deterioration has not yet completely occurred. There wasn't.
本発明が解決しようとする課題
厳しい使用条件のなかで、艮時間に亘って新油と変わら
ない省燃費性能を維持して行くことが、本当の意味での
燃費節減と考えられる。本発明者らは、ジチオカルバミ
ン酸モリブデンの持つ省燃費性能に着目し、研究を重ね
た結果、水素化分解プロセスにより製造される低芳香族
の製油とジチオカルバミン酸モリブデンとを組み合わせ
ることにより上記目的が達成できることを見出し、本発
明を完成するに至った。Problems to be Solved by the Invention Under severe usage conditions, maintaining fuel efficiency equivalent to that of new oil over a long period of time is considered to be the true fuel saving. The present inventors focused on the fuel-saving performance of molybdenum dithiocarbamate, and as a result of repeated research, the above objective was achieved by combining molybdenum dithiocarbamate with a low-aromatic oil produced by a hydrocracking process. We have discovered that this can be done, and have completed the present invention.
本発明は、水素化分解プロセスにより製造される低芳香
族製油を含むａ滑油製油に、ジチオカルバミン醸モリブ
デン、を必須成分として配合してなる、優れた省燃費性
能を有する内燃機関用潤清油組成物を提供することを目
的とする。The present invention provides a lubricating oil composition for internal combustion engines having excellent fuel efficiency performance, which is formed by blending dithiocarbamin-adjusted molybdenum as an essential component with a lubricant oil containing low aromatic oil produced by a hydrocracking process. The purpose is to provide something.
課題を解決するための手段
すなわち、本発明は、
（Ａ） １００℃における動粘度２〜ＩＱｃＳｔ 、
芳香族含有量３〜１５重最％、硫黄含有量５０ｐｐｍ以
下、窒素含有置５ Ｅｌｌ）１以下の、水素化分解プロ
セスにより製造されるＴｊ１滑油製油を７０重階％以上
含有する潤滑油製油１００重量部に対し、必須或分とし
て（Ｂ） ジチオカルバミン酸モリブデン０，１〜３
．０重量部を配合したことを特徴とする内燃機関用潤滑
油組或物
を提供するものである。Means for solving the problems, that is, the present invention provides: (A) kinematic viscosity at 100°C 2 to IQcSt;
A lubricating oil oil containing 70 weight percent or more of Tj1 lubricant oil produced by a hydrocracking process, having an aromatic content of 3 to 15 weight percent, a sulfur content of 50 ppm or less, and a nitrogen content of 5 weight percent or less. (B) Molybdenum dithiocarbamate 0.1 to 3 as an essential part per 100 parts by weight
．． The present invention provides a lubricating oil composition for an internal combustion engine, characterized in that it contains 0 parts by weight.
以下、本発明の内容をより詳細に説明する。Hereinafter, the content of the present invention will be explained in more detail.
本発明の（Ａ）水素化分解プロセスにより製造される潤
滑油製油の製造方法は任意であり、公知の方法で製造す
ることができる。具体的には例えば、バラフィン系の原
油を減圧蒸留するか、さらに脱アスフアルトした原料油
を水素化分解することにより得られる。この場合の水素
化分解条件としては、通常、温度が３５０〜５００℃、
圧力が６０〜２００Ｎｇ／ｃｄ．ＬＨｓＶが０．１ 〜
２．Ｏｈ−”’１５６。水素化分解触媒としては、モリ
ブデン、クロム、タングステン、バナジウム、白金、ニ
ッケル、銅、鉄、およびコバルトまたはこれらの酸化物
および／または硫化物などが例示される。これらの触媒
はシリカアルミナ、活性アルミナ、ゼオライトなどの担
体に担持されていてもよく、また、単独で用いても２種
以上を併用してもよい。また、水素化分解された潤滑油
製油は、適宜溶剤抽出、溶剤脱ろう、接触脱ろう、水素
化精製などを行ってもよい。The lubricating oil produced by the hydrocracking process (A) of the present invention can be produced by any known method. Specifically, it can be obtained, for example, by distilling paraffin crude oil under reduced pressure, or by hydrocracking a deasphalted feedstock oil. In this case, the hydrogenolysis conditions are usually a temperature of 350 to 500°C;
Pressure is 60-200Ng/cd. LHsV is 0.1~
2. Oh-"'156. Examples of hydrogen cracking catalysts include molybdenum, chromium, tungsten, vanadium, platinum, nickel, copper, iron, and cobalt, or their oxides and/or sulfides. These catalysts may be supported on a carrier such as silica alumina, activated alumina, or zeolite, and may be used alone or in combination of two or more.Furthermore, the hydrocracked lubricating oil may be treated with an appropriate solvent. Extraction, solvent dewaxing, catalytic dewaxing, hydrorefining, etc. may also be performed.
このようにして製造された潤滑油製油は、１００℃にお
ける動粘度が２〜１０ｃＳｔ 、好ましくは３〜７ｃＳ
ｔ、芳香族含有量が３〜１５重量％、好ましくは３〜８
重量％、硫黄含有量５０ｐｐｍ以下、好ましくは２０ｐ
ｐｍ以下、窒素含有鏝が５ ｐｐｍ以下、好ましくは２
ＥＩＥｌ園以下の性状を有するものであることが必要で
ある。１００℃における動粘度が２ ｃｓｔ未満の場合
は、製油として用いたときの油膜形成が十分でなく、さ
らに蒸発損失が大きくなる。また、１０ｃＳｔを超える
場合には、流体潤滑条件下におけるＷｌ擦トルクが増大
し （Ｂ）戒分の効果が発揮されず好ましくない。また
、芳香族含有恐が３重星％未満の場合には （Ｂ）ジチ
オカルバミン酸モリブデンの溶解性が十分でなく、１５
重通％を超える場合には酸化安定性が十分でない。なお
、この場合の芳香族含有吊は、ＡＳＴＨ Ｄ２５４９に
準拠して測定したものである。The lubricating oil produced in this way has a kinematic viscosity at 100°C of 2 to 10 cSt, preferably 3 to 7 cS.
t, aromatic content from 3 to 15% by weight, preferably from 3 to 8
Weight %, sulfur content 50 ppm or less, preferably 20 p
pm or less, the nitrogen-containing trowel is 5 ppm or less, preferably 2
It is necessary that the material has properties equal to or lower than those of EIEL. If the kinematic viscosity at 100° C. is less than 2 cst, oil film formation will not be sufficient when used for oil production, and furthermore, evaporation loss will increase. Moreover, if it exceeds 10 cSt, the Wl friction torque under fluid lubrication conditions will increase, and (B) the effect of precepts will not be exhibited, which is not preferable. In addition, if the aromatic content is less than triple star%, (B) the solubility of molybdenum dithiocarbamate is insufficient, and 15
If the weight ratio exceeds %, the oxidation stability is insufficient. Note that the aromatic content in this case was measured in accordance with ASTH D2549.
さらに、硫黄含有量が５０ｐｐｍを超える場合または窒
素含有社が５ ｐｐｍを超える場合には酸化安定性が十
分でなく、いずれの場合も好ましくない。Furthermore, if the sulfur content exceeds 50 ppm or if the nitrogen content exceeds 5 ppm, the oxidation stability will be insufficient, and either case is not preferred.
またこの水素化分解製油はＶ１が１２０以上であるのが
好ましい。Further, it is preferable that this hydrocracked oil has a V1 of 120 or more.
本発明の（Ａ）Ｂ滑油製油は上記の水素化分解プロセス
により製造される潤滑油製油を７０重量％以上、好まし
くは８０重量％以上含んでいれば、残部は水素化分解プ
ロセスによらない鉱油系潤滑製油およびボリブテン、ポ
リイソブチレン、α−オレフィンオリゴマー、アルキル
ベンゼン、アルキルナフタレン、ジエステル、ボリオー
ルエステル、ボリグリコール、ポリフエニルエーテル、
シリコーン油などの合成油を含んでいてもよい。水素化
分解ブロスによる基抽が製油全体の７０重邑％未渦の場
合には、酸化安定性が十分でなく、好ましくない。If the (A)B lubricating oil of the present invention contains 70% by weight or more, preferably 80% by weight or more of the lubricating oil manufactured by the above-mentioned hydrocracking process, the remainder is not caused by the hydrocracking process. Mineral oil-based lubricating oil and polybutene, polyisobutylene, α-olefin oligomer, alkylbenzene, alkylnaphthalene, diester, polyol ester, polyglycol, polyphenyl ether,
It may also contain synthetic oil such as silicone oil. If 70% of the total oil refinery is extracted using hydrocracking broth, the oxidation stability will be insufficient, which is not preferable.
本発明の（Ｂ）ジチオカルバミン酸モリブデンとは、一
般式
で表される化合物である。式中、Ｒ１およＲ２は同一で
も異なっていてもよく、それぞれ炭素数１〜１Ｂのアル
キル基、シクロアルキル基、アリール基、アルキルアリ
ール基またはアリールアルキル基を示している。また、
ＸおよびＶ Ｇ．ｔＸ 十Ｖ ＝４であるようなＯ〜４
の整数を示している。また、構造の異なるものを２種以
上併用してもよい。この （Ｂ）ジチオカルバミン酸モ
リブデンについては、特開昭５１ − ８０８２５号、
特開昭５２ − １９６２９号、特開昭５２ − １０
６８２４号などに記載されている。(B) Molybdenum dithiocarbamate of the present invention is a compound represented by the general formula. In the formula, R1 and R2 may be the same or different, and each represents an alkyl group, cycloalkyl group, aryl group, alkylaryl group, or arylalkyl group having 1 to 1 B carbon atoms. Also,
X and V G. O~4 such that tX 10V = 4
indicates an integer. In addition, two or more types having different structures may be used in combination. Regarding this molybdenum dithiocarbamate (B), JP-A-51-80825,
JP-A-52-19629, JP-A-52-10
It is described in No. 6824, etc.
この（Ｂ）ジチオカルバミン酸モリブデンの配合量は、
（Ａ）潤滑油製油１００重量部に対し、０．１〜３．０
重量部、好ましくは０．２〜２．０重量部である。The blending amount of this (B) molybdenum dithiocarbamate is:
(A) 0.1 to 3.0 per 100 parts by weight of lubricating oil
Parts by weight, preferably 0.2 to 2.0 parts by weight.
配合母が０．１重量部未満の場合には、配合効果がなく
、３．０重吊部を超える場合には配合論に見合う効果が
なく、それぞれ好ましくない。If the blending base is less than 0.1 part by weight, there will be no blending effect, and if it exceeds 3.0 parts by weight, there will be no effect commensurate with the blending theory, which is not preferable.
本発明の内燃機関用ｒａ滑油組成物には、必要に応じて
、公知の潤滑油用添加剤を配合することができる。この
添加剤としては、ジチオリン酸亜鉛、アルカリ土類金属
スルフォネート、アルカリ土類金属フエネート、アルカ
リ土類金属サリチレート、アルカリ土類金属ホスホネー
トなどの金属系清浄剤、こはく酸イミド、こはく酸エス
テル、ペンジルアミンなどの無灰分散剤、ポリメタクリ
レート、ポリイソブチレン、ボリスチレン、■チレンー
ブロビレン共重合体などの粘度指数向上剤、流動点降下
剤、フェノール系、アミン系、銅系などの酸化防止剤、
ベンゾトリアゾールなどの金属不活性化剤、その他さび
止め剤、消泡剤、ａ！擦調整剤などが例示できる。これ
らは単独でも２種類以上組み合わせて使用してもよい。The RA lubricating oil composition for internal combustion engines of the present invention may contain known lubricating oil additives, if necessary. These additives include metal detergents such as zinc dithiophosphate, alkaline earth metal sulfonates, alkaline earth metal phenates, alkaline earth metal salicylates, alkaline earth metal phosphonates, succinimides, succinic esters, penzylamine, etc. ashless dispersants, viscosity index improvers such as polymethacrylate, polyisobutylene, polystyrene, ethylene-propylene copolymer, pour point depressants, antioxidants such as phenolics, amines, copper, etc.
Metal deactivators such as benzotriazole, other rust inhibitors, antifoaming agents, a! Examples include friction modifiers. These may be used alone or in combination of two or more.
これら添加剤の選定および添加量は任意であり、例えば
エンジン油のＡＰＩサービス分類の品質グレードに応じ
て適宜決定されるが、これら添加剤の合計添加出は、通
常（八）潤滑油製油１００重量部に対し３５重量部以下
、好ましくは２５重吊部以下である。The selection and addition amount of these additives are arbitrary, and are appropriately determined depending on, for example, the quality grade of the API service classification of engine oil, but the total amount of these additives added is usually (8) 35 parts by weight or less, preferably 25 parts by weight or less.
本発明の内燃機関用！１滑油組成物は、例えば、４サイ
クルガソリンエンジン浦、陸用ディーゼルエンジン油、
舶用ディーゼルエンジン油、２サイクルディーピルエン
ジン油などとして用いることができる。For internal combustion engines of the present invention! 1. The lubricating oil composition includes, for example, 4-cycle gasoline engine oil, land diesel engine oil,
It can be used as marine diesel engine oil, 2-stroke deep pill engine oil, etc.
以下、本発明の内容を、実施例および比較例によりさら
に具体的に説明する。Hereinafter, the content of the present invention will be explained in more detail with reference to Examples and Comparative Examples.
実施例１〜２、比較例１〜２
実施例および比較例に用いた内燃機関用潤滑油組成物の
組成を第１表に示した。Examples 1-2, Comparative Examples 1-2 Table 1 shows the compositions of the lubricating oil compositions for internal combustion engines used in the Examples and Comparative Examples.
これらの潤滑油の性能を、以下に示す性能評価試験によ
り評価した。The performance of these lubricating oils was evaluated by the performance evaluation test shown below.
（Ｆａｌｅｘ試験）
試料油の新油および酸化劣化油のＦａｌｅｘ試験を行っ
た。条件は、ｔ５００ｒ．Ｄ．ａ ｘ３０ ｊ！ｂ ，
８０℃とした。なお、酸化劣化油としては、ＪＩＳ
Ｋ ２５１４３．１に規定されるＩＩ２Ｉ滑油酸化安定
度試験に準拠し、試験温度１５０℃、１４４時間の条件
で酸化劣化させた油を用いた。(Falex Test) A Falex test was conducted on new sample oil and oxidized degraded oil. The conditions are t500r. D. a x30 j! b,
The temperature was 80°C. In addition, as oxidized deteriorated oil, JIS
In accordance with the II2I lubricating oil oxidation stability test specified in K 25143.1, oil was used that had been oxidized and deteriorated at a test temperature of 150° C. for 144 hours.
（エンジン試験）
試料油をファイアリング試験により高速市街地走行条件
で５０時間劣化させた後、モーターリング試験により摩
擦損失トルクを評価した。条件は、回転数１５００ｒ．
ｐ．ｓ 、油温８０℃とした。(Engine Test) After the sample oil was deteriorated for 50 hours under high-speed city driving conditions by a firing test, friction loss torque was evaluated by a motoring test. The conditions are rotation speed 1500r.
p. s, the oil temperature was 80°C.
Claims (1)
含有量３〜１５重量％、硫黄含有量５０ｐｐｍ以下、窒
素含有量５ｐｐｍ以下の、水素化分解プロセスにより製
造される潤滑油製油を７０重量％以上含有する潤滑油製
油１００重量部に対し、必須成分として（Ｂ）ジチオカ
ルバミン酸モリブデン０．１〜３．０重量部を配合した
ことを特徴とする内燃機関用潤滑油組成物。(A) 70% by weight of a lubricating oil refinery produced by a hydrocracking process with a kinematic viscosity of 2 to 10 cSt at 100°C, an aromatic content of 3 to 15% by weight, a sulfur content of 50 ppm or less, and a nitrogen content of 5 ppm or less A lubricating oil composition for an internal combustion engine, characterized in that (B) 0.1 to 3.0 parts by weight of molybdenum dithiocarbamate is blended as an essential component to 100 parts by weight of the lubricating oil containing the above.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1243923A JP2602102B2 (en) | 1989-09-20 | 1989-09-20 | Lubricating oil composition for internal combustion engines |
| EP90118026A EP0418860B1 (en) | 1989-09-20 | 1990-09-19 | Lubricating composition for internal combustion engine |
| DE9090118026T DE69001057T2 (en) | 1989-09-20 | 1990-09-19 | LUBRICANT COMPOSITION FOR COMBUSTION ENGINES. |
| US07/937,435 US5281347A (en) | 1989-09-20 | 1992-08-27 | Lubricating composition for internal combustion engine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1243923A JP2602102B2 (en) | 1989-09-20 | 1989-09-20 | Lubricating oil composition for internal combustion engines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03106995A true JPH03106995A (en) | 1991-05-07 |
| JP2602102B2 JP2602102B2 (en) | 1997-04-23 |
Family
ID=17111034
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1243923A Expired - Lifetime JP2602102B2 (en) | 1989-09-20 | 1989-09-20 | Lubricating oil composition for internal combustion engines |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0418860B1 (en) |
| JP (1) | JP2602102B2 (en) |
| DE (1) | DE69001057T2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06306384A (en) * | 1993-04-22 | 1994-11-01 | Kyoseki Seihin Gijutsu Kenkyusho:Kk | Fuel-saving lubricating oil |
| EP0770668A1 (en) | 1995-10-27 | 1997-05-02 | Nippon Oil Co. Ltd. | Lubricating oil composition |
| JP2000256691A (en) * | 1999-03-08 | 2000-09-19 | Nippon Mitsubishi Oil Corp | Lubricating oil composition for internal combustion engine |
| JP2009013355A (en) * | 2007-07-06 | 2009-01-22 | Idemitsu Kosan Co Ltd | Lubricant composition for two cycle engine |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5665684A (en) * | 1993-05-27 | 1997-09-09 | Exxon Research And Engineering Company | Lubricating oil composition |
| JPH06336593A (en) * | 1993-05-27 | 1994-12-06 | Tonen Corp | Lubricant composition |
| JP3510368B2 (en) * | 1995-01-31 | 2004-03-29 | 東燃ゼネラル石油株式会社 | Lubricating oil composition for internal combustion engines |
| US6296757B1 (en) | 1995-10-17 | 2001-10-02 | Exxon Research And Engineering Company | Synthetic diesel fuel and process for its production |
| US5689031A (en) | 1995-10-17 | 1997-11-18 | Exxon Research & Engineering Company | Synthetic diesel fuel and process for its production |
| US5766274A (en) | 1997-02-07 | 1998-06-16 | Exxon Research And Engineering Company | Synthetic jet fuel and process for its production |
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| JPS59122597A (en) * | 1982-11-30 | 1984-07-16 | Honda Motor Co Ltd | Lubricating oil composition |
| JPS62215697A (en) * | 1986-03-17 | 1987-09-22 | Toyota Central Res & Dev Lab Inc | Lubricating oil composition |
| JPS63223094A (en) * | 1987-03-12 | 1988-09-16 | Idemitsu Kosan Co Ltd | Base oil of lubricating oil for internal combustion engine and composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6027711B2 (en) * | 1973-05-19 | 1985-07-01 | 東亜燃料工業株式会社 | Lubricating oil manufacturing method |
| GB1572794A (en) * | 1975-12-16 | 1980-08-06 | Shell Int Research | Baseoil compositions |
| DE3876897T2 (en) * | 1987-03-02 | 1993-06-03 | Idemitsu Kosan Co | LUBRICATING OIL COMPOSITION. |
| US4812246A (en) * | 1987-03-12 | 1989-03-14 | Idemitsu Kosan Co., Ltd. | Base oil for lubricating oil and lubricating oil composition containing said base oil |
| JP2555284B2 (en) * | 1987-05-14 | 1996-11-20 | 出光興産株式会社 | Lubricant composition with improved temperature characteristics |
| JP2608098B2 (en) * | 1988-05-13 | 1997-05-07 | 出光興産株式会社 | Lubricating oil composition |
-
1989
- 1989-09-20 JP JP1243923A patent/JP2602102B2/en not_active Expired - Lifetime
-
1990
- 1990-09-19 EP EP90118026A patent/EP0418860B1/en not_active Expired - Lifetime
- 1990-09-19 DE DE9090118026T patent/DE69001057T2/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59122597A (en) * | 1982-11-30 | 1984-07-16 | Honda Motor Co Ltd | Lubricating oil composition |
| JPS62215697A (en) * | 1986-03-17 | 1987-09-22 | Toyota Central Res & Dev Lab Inc | Lubricating oil composition |
| JPS63223094A (en) * | 1987-03-12 | 1988-09-16 | Idemitsu Kosan Co Ltd | Base oil of lubricating oil for internal combustion engine and composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06306384A (en) * | 1993-04-22 | 1994-11-01 | Kyoseki Seihin Gijutsu Kenkyusho:Kk | Fuel-saving lubricating oil |
| EP0770668A1 (en) | 1995-10-27 | 1997-05-02 | Nippon Oil Co. Ltd. | Lubricating oil composition |
| US5786307A (en) * | 1995-10-27 | 1998-07-28 | Nippon Oil Co., Ltd. | Lubricating oil composition |
| JP2000256691A (en) * | 1999-03-08 | 2000-09-19 | Nippon Mitsubishi Oil Corp | Lubricating oil composition for internal combustion engine |
| JP2009013355A (en) * | 2007-07-06 | 2009-01-22 | Idemitsu Kosan Co Ltd | Lubricant composition for two cycle engine |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69001057T2 (en) | 1993-06-17 |
| JP2602102B2 (en) | 1997-04-23 |
| EP0418860A1 (en) | 1991-03-27 |
| DE69001057D1 (en) | 1993-04-15 |
| EP0418860B1 (en) | 1993-03-10 |
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