JPH0310686B2 - - Google Patents

Info

Publication number
JPH0310686B2
JPH0310686B2 JP5327583A JP5327583A JPH0310686B2 JP H0310686 B2 JPH0310686 B2 JP H0310686B2 JP 5327583 A JP5327583 A JP 5327583A JP 5327583 A JP5327583 A JP 5327583A JP H0310686 B2 JPH0310686 B2 JP H0310686B2
Authority
JP
Japan
Prior art keywords
laser
hardening
hardened
low carbon
pure iron
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP5327583A
Other languages
Japanese (ja)
Other versions
JPS59179776A (en
Inventor
Keiichi Ootsuka
Takashi Kubota
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shinko Electric Co Ltd
Original Assignee
Shinko Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shinko Electric Co Ltd filed Critical Shinko Electric Co Ltd
Priority to JP5327583A priority Critical patent/JPS59179776A/en
Publication of JPS59179776A publication Critical patent/JPS59179776A/en
Publication of JPH0310686B2 publication Critical patent/JPH0310686B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/64Carburising
    • C23C8/66Carburising of ferrous surfaces

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、純鉄又は低炭素鋼の表面に、耐摩耗
性を向上するため、レーザー焼入れにより浸炭焼
入れ表面硬化層を形成するレーザー浸炭焼入れ表
面硬化方法に関するものである。 従来のレーザー焼入れ表面硬化方法は、被加工
材として炭素含有量が多くて焼きが入りやすい
中・高炭素鋼、合金鋼及び鋳鉄などに対し、表面
にレーザー焼入れを施し、高硬度表面硬化層を形
成し、耐摩耗性を向上させて機械部品、装置等の
寿命を向上させていた。 しかし、上記のような従来のレーザー焼入れ表
面硬化方法は、純鉄又は低炭素鋼に対して適用で
きない欠点がある。すなわち、純鉄又は低炭素鋼
は、炭素含有量が少ないために、焼きがほとんど
入らず、レーザー焼入れによる表面硬化を行つて
も硬さの高いマルテンサイト組織が得られないた
め、耐摩耗性の優れた表面硬化層を得ることは極
めて困難である。 本発明は、上記のような欠点を除去することを
目的とするもので、純鉄又は低炭素鋼に対し、耐
摩耗性の極めて優れた高硬度表面硬化層を形成さ
せるレーザー浸炭焼入れ表面硬化方法を提供する
ものである。 以下、本発明によるレーザー浸炭焼入れ表面硬
化方法について説明する。 (1) まず、レーザー反射を防止し、かつ、炭素を
含み浸炭効果を生じさせる物質(例えば、黒色
塗料、黒色印刷インキなどの有機物質やグラフ
アイトカーボン)を純鉄又は低炭素鋼の被加工
材表面に被覆し、黒色皮膜処理を施す。黒色皮
膜を被覆する方法としては、スプレー、浸漬、
はけ塗り等のうち、適宜の方法を選択する。 (2) 次に、レーザーを定位置で照射し、被加工材
を連続移動させる。レーザーの照射条件、及び
被加工材の移動速度・方向は、目的とする表面
硬化層の形状、硬さ、硬化深さによつて適宜選
択する。 このように、レーザー照射を受けた被加工材の
表面温度は高温となるため、黒色皮膜が熱分解し
て発生機の炭素を生成し、炭素が被加工材の内部
に拡散浸透して浸炭が行われる。また、被加工材
の表面近傍は、高温加熱されオーステナイト組織
になる。このようなレーザー照射方法により高温
加熱され照射部は、非照射部への熱伝導によつ
て、連続的に急速冷却されるので、浸炭部はオー
ステナイト組織からマルテンサイト組織に結晶組
織変態し、高硬度の浸炭焼入れ表面硬化層を形成
する。 上記のように、本発明方法によれば、純鉄又は
低炭素鋼の表面に耐摩耗性の優れた表面硬化層を
極めて簡単に形成することができる。この表面硬
化層は、レーザー照射条件と被加工材の移動速
度・方向を適宜選択することにより、任意の形
状、硬さ、硬化深さ、硬化幅とすることができ
る。また、通常の浸炭焼入れや、タフトライド処
理、イオン窒化処理などの方法は、いずれも被加
工材全体の温度を高くしなければならないので、
熱変形が大きく、したがつて後工程として再研摩
の工程が必要となる欠点があるが、本発明方法は
被加工材の局部的な表面加熱であるため、被加工
材の熱変形が極めて少なく、再研摩の工程を必要
としない。さらに、通常の熱処理方法のような水
焼入れや油焼入れ工程を必要としない等の優れた
効果がある。 本発明方法を適用して大きな効果を上げた一例
として、電磁ブレーキ・クラツチの摩擦円板につ
いて説明する。 電磁ブレーキ・クラツチの摩擦円板は、電磁吸
引力を利用するため、磁気特性の良好な純鉄又は
低炭素鋼を使用している。しかし、純鉄又は低炭
素鋼は硬さが低く耐摩耗性に劣るという欠点があ
る。そのため、摩耗量が大きくなつて使用に堪え
なくなり、電磁ブレーキ・クラツチの寿命が短
く、かつ摩耗量が大きいため、電磁吸引力が変動
してトルク特性、動作特性も悪くなるという好ま
しくない現象を引き起こしていた。そこで、電磁
ブレーキの摩擦円板に対し、本発明による浸炭焼
入れ表面硬化方法を実施したところ、電磁ブレー
キの寿命を従来の約3倍に延ばすとともに、良好
なトルク特性、動作特性が得られ、ブレーキの制
動時間も安定するという極めて大きな効果を上げ
ることができた。 次に、本発明方法の一実施例について説明す
る。 試験片として、電磁軟鉄板(素材JIS
SUYPO;寸法100mm×100mm×厚さ5mm;ビツカ
ース硬さHv100)を用い、研摩仕上げし十分脱脂
する。次に、色料としてカーボンブラツク、印刷
膜材としてフエノール樹脂、乾燥剤としてアルコ
ールを主成分とする一般に市販されている黒色印
刷インキをローラ塗布方法により、電磁軟鉄板の
表面に幅約3mm、厚さ約10μm、長さ80mmの範囲
に塗布、乾燥し、黒色皮膜処理を行う。その後、
試験片を700mm/分の移動速度で直線移動させな
がら、レーザー(CO2レーザー、出力1kW)を連
続照射し、浸炭焼入れ表面硬化層を形成する。上
記実験例により得られた試験片の表面硬化部を一
部切断し、断面硬さ分布、硬化深さ、硬化幅等の
金属組織調査を行つたが、高硬度表面硬化層の形
成が認められた。その結果は下記のとおりであ
る。
The present invention relates to a laser carburizing and quenching surface hardening method for forming a carburizing and quenching surface hardening layer on the surface of pure iron or low carbon steel by laser quenching in order to improve wear resistance. The conventional laser quenching surface hardening method applies laser quenching to the surface of workpiece materials such as medium- and high-carbon steels, alloy steels, and cast irons that have a high carbon content and are easily hardened, creating a high-hardness surface hardening layer. It was used to improve wear resistance and extend the lifespan of mechanical parts, equipment, etc. However, the conventional laser quenching surface hardening method as described above has the disadvantage that it cannot be applied to pure iron or low carbon steel. In other words, pure iron or low carbon steel has a low carbon content, so it hardly hardens, and even if the surface is hardened by laser hardening, a martensitic structure with high hardness cannot be obtained, so it has poor wear resistance. It is extremely difficult to obtain an excellent surface hardening layer. The purpose of the present invention is to eliminate the above-mentioned drawbacks, and provides a laser carburizing and quenching surface hardening method for forming a highly hard surface hardened layer with extremely excellent wear resistance on pure iron or low carbon steel. It provides: Hereinafter, the laser carburizing and quenching surface hardening method according to the present invention will be explained. (1) First, a substance that prevents laser reflection and that contains carbon and produces a carburizing effect (e.g., organic substances such as black paint, black printing ink, or graphite carbon) is applied to the workpiece of pure iron or low carbon steel. Coat the surface of the material and apply a black film treatment. Methods for coating the black film include spraying, dipping,
Select an appropriate method such as brush painting. (2) Next, the laser is irradiated at a fixed position and the workpiece is continuously moved. The laser irradiation conditions and the moving speed and direction of the workpiece are appropriately selected depending on the shape, hardness, and hardening depth of the intended hardened surface layer. In this way, the surface temperature of the workpiece that has been irradiated with the laser becomes high, so the black film thermally decomposes and generates carbon, which diffuses into the workpiece and causes carburization. It will be done. Further, the vicinity of the surface of the workpiece is heated to a high temperature and becomes an austenite structure. The irradiated area is heated to a high temperature by this laser irradiation method, and the irradiated area is rapidly cooled continuously by heat conduction to the non-irradiated area, so that the carburized area undergoes a crystal structure transformation from austenite to martensite, resulting in a high-temperature structure. Hard carburized and quenched surface to form a hardened layer. As described above, according to the method of the present invention, a hardened surface layer with excellent wear resistance can be extremely easily formed on the surface of pure iron or low carbon steel. This surface hardening layer can be made into any shape, hardness, hardening depth, and hardening width by appropriately selecting the laser irradiation conditions and the moving speed and direction of the workpiece. In addition, methods such as normal carburizing and quenching, tuftride treatment, and ion nitriding treatment all require the temperature of the entire workpiece to be raised.
Although there is a drawback that thermal deformation is large and therefore a re-polishing process is required as a post-process, the method of the present invention heats the surface of the workpiece locally, so thermal deformation of the workpiece is extremely small. , does not require a re-polishing process. Furthermore, it has excellent effects such as not requiring a water quenching or oil quenching step unlike ordinary heat treatment methods. As an example in which the method of the present invention has been applied to great effect, a friction disk for an electromagnetic brake/clutch will be described. The friction disc of the electromagnetic brake/clutch utilizes electromagnetic attraction, so pure iron or low carbon steel with good magnetic properties is used. However, pure iron or low carbon steel has the disadvantage of low hardness and poor wear resistance. As a result, the amount of wear increases and it becomes unusable, and the life of the electromagnetic brake/clutch is short and the amount of wear is large, causing undesirable phenomena such as fluctuations in electromagnetic attraction force and deterioration of torque characteristics and operating characteristics. was. Therefore, when we applied the carburizing and quenching surface hardening method according to the present invention to the friction discs of electromagnetic brakes, we were able to extend the life of the electromagnetic brakes by about three times compared to conventional ones, and obtain good torque and operating characteristics. We were able to achieve an extremely significant effect by stabilizing the braking time. Next, an embodiment of the method of the present invention will be described. As a test piece, an electromagnetic soft iron plate (material JIS
Using SUYPO; dimensions 100 mm x 100 mm x thickness 5 mm; Bitkers hardness Hv100), polish and thoroughly degrease. Next, a commercially available black printing ink containing carbon black as a coloring agent, phenolic resin as a printing film material, and alcohol as a drying agent is applied to the surface of an electromagnetic soft iron plate by a roller coating method to a width of about 3 mm and a thickness of about 3 mm. Apply to an area of approximately 10 μm in diameter and 80 mm in length, dry, and apply a black film treatment. after that,
While moving the specimen in a straight line at a speed of 700 mm/min, it is continuously irradiated with a laser (CO 2 laser, output 1 kW) to form a carburized and hardened surface layer. A part of the surface-hardened portion of the test piece obtained in the above experimental example was cut to investigate the metallographic structure such as cross-sectional hardness distribution, hardening depth, hardening width, etc., but the formation of a high-hardness hardened surface layer was observed. Ta. The results are as follows.

【表】 また、上記実施例により得られた試験片の表面
硬化部と、未硬化部とを、焼入れ焼戻し後、研摩
仕上げした高速度工具鋼円板(素材SKH2;寸
法、外径30mmφ、板厚2mm、ビツカース硬さ
Hv600)と接触させ、押付荷重2Kg、摩擦速度3
m/秒の条件で摩耗試験を行つた。その結果、第
1図に示すように、表面硬化部Aは未硬化部Bよ
りもはるかに優れた耐摩耗性を示すことが認めら
れた。 以上述べたように、本発明に係るレーザーによ
る純鉄・は低炭素鋼の浸炭焼入れ表面硬化方法
は、耐摩耗性の極めて優れた表面硬化層を純鉄又
は低炭素鋼の表面に容易に形成させることがで
き、これらの材料を使用する機械部品、摺動部
品、装置等の寿命を大幅に延ばす優れた効果があ
る。
[Table] In addition, the surface hardened part and the unhardened part of the test piece obtained in the above example were quenched, tempered, and polished to a high-speed tool steel disc (material SKH2; dimensions, outer diameter 30 mmφ, plate 2mm thick, Bitskers hardness
Hv600), pressing load 2Kg, friction speed 3
A wear test was conducted under conditions of m/sec. As a result, as shown in FIG. 1, it was found that the surface-hardened portion A exhibited far superior wear resistance than the unhardened portion B. As described above, the method of carburizing and hardening the surface of pure iron or low carbon steel using a laser according to the present invention can easily form a hardened surface layer with extremely excellent wear resistance on the surface of pure iron or low carbon steel. This has the excellent effect of significantly extending the life of mechanical parts, sliding parts, equipment, etc. that use these materials.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明方法の一実験例の表面硬化部A
と未硬化部Bとの摩擦距離に対する摩耗体積の関
係を示すグラフである。 A:表面硬化部、B:未硬化部。
Figure 1 shows a surface hardened part A of an experimental example of the method of the present invention.
It is a graph which shows the relationship of abrasion volume with respect to the friction distance of and unhardened part B. A: Surface hardened portion, B: Uncured portion.

Claims (1)

【特許請求の範囲】[Claims] 1 純鉄又は低炭素鋼の表面に炭素を含んだ物質
により黒色皮膜処理を施した後、レーザー焼入れ
加工により浸炭焼入れ表面硬化層を形成すること
を特徴とするレーザーによる純鉄・低炭素鋼の浸
炭焼入れ表面硬化方法。
1 Laser treatment of pure iron and low carbon steel characterized by applying a black film treatment to the surface of pure iron or low carbon steel using a substance containing carbon, and then forming a carburized and hardened surface layer by laser hardening. Carburizing and quenching surface hardening method.
JP5327583A 1983-03-29 1983-03-29 Surface hardening method by carburization hardening of pure iron and low carbon steel by laser Granted JPS59179776A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5327583A JPS59179776A (en) 1983-03-29 1983-03-29 Surface hardening method by carburization hardening of pure iron and low carbon steel by laser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5327583A JPS59179776A (en) 1983-03-29 1983-03-29 Surface hardening method by carburization hardening of pure iron and low carbon steel by laser

Publications (2)

Publication Number Publication Date
JPS59179776A JPS59179776A (en) 1984-10-12
JPH0310686B2 true JPH0310686B2 (en) 1991-02-14

Family

ID=12938182

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5327583A Granted JPS59179776A (en) 1983-03-29 1983-03-29 Surface hardening method by carburization hardening of pure iron and low carbon steel by laser

Country Status (1)

Country Link
JP (1) JPS59179776A (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6296663A (en) * 1985-10-22 1987-05-06 Univ Nagoya Carburizing and hardening method with laser beam
CN100390304C (en) * 2002-11-28 2008-05-28 中国科学院力学研究所 Laser strengthening and toughening method for interface between ground-mass and coating
JP2005319019A (en) * 2004-05-07 2005-11-17 Bridgestone Sports Co Ltd Golf club head
US11186887B2 (en) 2013-12-13 2021-11-30 Tata Steel Limited Multi-track laser surface hardening of low carbon cold rolled closely annealed (CRCA) grades of steels
US10597781B2 (en) 2016-03-02 2020-03-24 Pusan National University Industry-University Cooperation Foundation Method for forming coating film having high heat resistance, high hardness and abrasion resistance, coating film having high heat resistance, high hardness and abrasion resistance, and cutting tool comprising same
CN114150260B (en) * 2022-02-07 2022-04-29 北京煜鼎增材制造研究院有限公司 Laser surface carburizing method for low-carbon steel

Also Published As

Publication number Publication date
JPS59179776A (en) 1984-10-12

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