JPH03103500A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- JPH03103500A JPH03103500A JP1240950A JP24095089A JPH03103500A JP H03103500 A JPH03103500 A JP H03103500A JP 1240950 A JP1240950 A JP 1240950A JP 24095089 A JP24095089 A JP 24095089A JP H03103500 A JPH03103500 A JP H03103500A
- Authority
- JP
- Japan
- Prior art keywords
- carboxylic acid
- ether carboxylic
- surfactant
- alkyl ether
- polyoxyethylene alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 17
- 239000003599 detergent Substances 0.000 title abstract description 10
- -1 polyoxyethylene Polymers 0.000 claims abstract description 20
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 5
- 239000011734 sodium Substances 0.000 claims abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 4
- 239000011591 potassium Substances 0.000 claims abstract description 4
- 150000003868 ammonium compounds Chemical class 0.000 claims abstract 3
- 239000004094 surface-active agent Substances 0.000 claims abstract 2
- 238000004140 cleaning Methods 0.000 claims description 13
- 239000002280 amphoteric surfactant Substances 0.000 claims description 11
- 238000005187 foaming Methods 0.000 abstract description 15
- 150000003839 salts Chemical class 0.000 abstract description 8
- 239000002563 ionic surfactant Substances 0.000 abstract 2
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 14
- 230000000694 effects Effects 0.000 description 9
- 229960003237 betaine Drugs 0.000 description 7
- 239000006260 foam Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 description 1
- XPALGXXLALUMLE-UHFFFAOYSA-N 2-(dimethylamino)tetradecanoic acid Chemical compound CCCCCCCCCCCCC(N(C)C)C(O)=O XPALGXXLALUMLE-UHFFFAOYSA-N 0.000 description 1
- 102000001708 Protein Isoforms Human genes 0.000 description 1
- 108010029485 Protein Isoforms Proteins 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 229940117986 sulfobetaine Drugs 0.000 description 1
- 150000005621 tetraalkylammonium salts Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
この発明は洗浄剤組成物に係り、その目的は頭髪、身体
を清潔に保つために全身を刺激も少なく、起潅力、洗浄
力を有し、泡切れ良く、洗浄後の全身のヌルヌル感を与
えず、サッパリしｈｓ触を与える洗浄剤組成物を製造す
ることである．
（従来の技術）
洗浄剤組成物はアニオン性界画活性剤、非イオン性界面
活性剤、及び両性界面活性用のうち一種または二、三ｆ
ｉ１類を混合して得られる、これらの組み合せの多くは
、洗浄力、起泡力等に優れているが、洗浄後身体にヌル
ヌル感を残し、日本人の好むサッパリした感触は得られ
ない．
この目的に一番適したものとしては、古くから石けんが
あり、また近年では、モノアルキルリン酸エステルがこ
の用途に適したものとして市販されている．
しかし、前者は脱脂作用が強＜ｐＨが９〜１０と強アル
カリ性であり、洗浄後皮膚につっぱり感を残す．一方後
者は、石けんと比較して起泡力が弱いという難点がある
．
また最近では、洗浄力及び起泡力を改善する為に両性界
面活性剤を基本とする処方に、アニオン性界面活性剤の
添加、マイルド性を向上させるために、アニオン性界面
活性剤へ両性界面活性剤の併用、洗浄性とリンス効果を
一度に得るために、両性界面活性剤へカチオン性界面活
性剤を加えるといった試みが行われている．また、皮膚
にヌルヌル感を与えない処方として、ラウリルエーテル
硫酸ナトリウムへ石けんを加えるなど種々検討されてい
る．しかし、一つの洗浄剤で、シャンプーリンス効果を
持ち、しかも身体にヌルヌル感を与えないマイルドな洗
浄剤はまだない。日本のバス器具・設備の発達により、
全身に用いることの出来る洗浄剤の要求は大である．本
発明者は、上記事情に鑑み、鋭意研究をかさねた結果、
両性界面活性剤、カチオン性界面活性剤及、びボリオキ
シエチレンアルキルエーテルカルボン酸または、そのア
ルカリ塩を特定の範囲に配合することにより、全身に用
いた時、頭髪は、洗浄され、しかもリンスを用いること
なくしなやかな、くし通りの良い毛髪にし、身体にはヌ
ルヌル感を残さない、サッパリとした感触にする洗浄剤
紐成物を見出し本発明に至った．
（発明の解決課題）
本発明の目的は、全身に用いられる、刺激の少ないもの
であり、毛髪へはリンス効果を与え、身体へはヌルヌル
感を残さない洗浄剤組成物である．
（問題点を解決するための手段及びその作用効果）
毛髪のマイルドな洗浄効果及びリンス効果を持たせるた
めには、両性界面活性剤へカチオン性界面活性剤を加え
ることにより得られ易い．しかし、この場合すすぎが悪
く、毛髪がまつわりついて、ウエット時のくし通りは非
常に悪い．また、身体を洗浄する時、満足な起泡力が得
られないばかりか、ヌルヌル感が残り嫌な仕上がりとな
る．
これをカバーするために、これらの系へ種々のア二オン
性界面活性剤の添加を試みたが、いずれもマイルドな、
ヌルヌル感を残さないものが得られず、ポリオキシアル
キルエーテルカルボン酸の添加のみが欠点を解決する原
料であることを見出した．
（発明の構成）
本発明で用いられる両性界面活性剤は、通常の洗浄剤に
用いられる両性界面活性剤の全てを適応することが出来
る．
具体例を挙げるならば、アミノ酸型の他、４級化された
ベタイン型、スルフォベタイン型、スルフォアミノ酸型
などがあり、さらに詳しくあげるならば、２−ウンデシ
ルーＮ，Ｎ，Ｎ−（ヒドロキシエチル力ルボキシメチル
）−２−イミダゾリンナトリウム、−２−ココイル−２
−イミダゾリニウムヒド口キシドーｌ一カルボキシエチ
ルオキシー２−ナトリウム、２−ヘブタデシルーＮ−カ
ルボキシメチルーＮ−ヒドロキシエチルイミダゾリウム
ベタイン、ラウリルジメチルアミノ酢酸ベタイン、ヤシ
油脂肪酸アミドブロビルベタイン、Ｎ， Ｎ−ジメチ
ルーＮ−アルキルーＮ一カルボキシメチルアンモニウム
ベタイン、Ｎ−ジアルキルアミノアルキレンカルボン酸
、Ｎ，Ｎ−｝リアルキルーＮ−スルファアルキレンアン
モニウムベタイン、などが例示される。Detailed Description of the Invention (Field of Industrial Application) The present invention relates to a detergent composition, the purpose of which is to have stimulant and detergent properties with less irritation to the whole body in order to keep the hair and body clean. It is an object of the present invention to produce a detergent composition which has a good foam removal property, does not give a slimy feeling to the whole body after washing, and gives a refreshing HS touch. (Prior Art) A cleaning composition contains one, two or three of anionic surfactants, nonionic surfactants, and amphoteric surfactants.
Many of these combinations obtained by mixing Type I1 have excellent detergency, foaming power, etc., but leave a slimy feeling on the body after washing, and do not provide the refreshing feel that Japanese people prefer. Soap has long been the most suitable product for this purpose, and in recent years, monoalkyl phosphate esters have been commercially available as suitable for this purpose. However, the former has a strong degreasing effect and is strongly alkaline with a pH of 9 to 10, leaving a feeling of tightness on the skin after washing. On the other hand, the latter has the disadvantage of having weak foaming power compared to soap. Recently, anionic surfactants have been added to formulations based on amphoteric surfactants to improve detergency and foaming power, and amphoteric surfactants have been added to anionic surfactants to improve mildness. Attempts have been made to use active agents in combination, and to add cationic surfactants to amphoteric surfactants in order to obtain both cleaning and rinsing effects at the same time. In addition, various methods are being considered, such as adding soap to sodium lauryl ether sulfate as a formulation that does not leave the skin feeling slippery. However, there is still no mild detergent that has a shampoo-rinsing effect and does not leave the body feeling slimy. With the development of Japanese bath equipment and equipment,
There is a great demand for cleansing agents that can be used on the whole body. In view of the above circumstances, the inventor has conducted extensive research and has found that:
By blending an amphoteric surfactant, a cationic surfactant, and polyoxyethylene alkyl ether carboxylic acid or its alkali salt in a specific range, when used all over the body, the hair is cleansed and does not require rinsing. The present invention was achieved by discovering a detergent string composition that leaves hair supple and easy to comb without using it, and leaves the body with a refreshing feel without leaving a slimy feeling. (Problems to be Solved by the Invention) An object of the present invention is to provide a cleansing composition that can be used on the whole body, is less irritating, has a rinsing effect on the hair, and does not leave a slimy feeling on the body. (Means for solving the problems and their effects) Mild hair cleaning and rinsing effects can be easily obtained by adding a cationic surfactant to the amphoteric surfactant. However, in this case, rinsing is difficult, hair gets stuck, and combing is very difficult when wet. Furthermore, when washing the body, not only is it not possible to obtain satisfactory foaming power, but the product also leaves a slimy feeling and leaves an unpleasant finish. In order to cover this, we tried adding various anionic surfactants to these systems, but all of them were mild,
It was not possible to obtain a product that did not leave a slimy feeling, and it was discovered that the addition of polyoxyalkyl ether carboxylic acid was the only raw material that could solve the problem. (Structure of the Invention) The amphoteric surfactant used in the present invention can be applied to all amphoteric surfactants used in ordinary detergents. Specific examples include, in addition to the amino acid type, quaternized betaine type, sulfobetaine type, and sulfamino acid type. (Ethylcarboxymethyl)-2-imidazoline sodium, -2-cocoyl-2
-Imidazolinium hydroxide l-carboxyethyloxy-2-sodium, 2-hebutadecyl-N-carboxymethyl-N-hydroxyethylimidazolium betaine, lauryldimethylaminoacetic acid betaine, coconut oil fatty acid amidobrobil betaine, N, N- Examples include dimethyl-N-alkyl-N-carboxymethylammonium betaine, N-dialkylaminoalkylenecarboxylic acid, N,N-}realkyl-N-sulfaalkylene ammonium betaine, and the like.
トリアルキルーＮ−スルフォアルキレンアンアンモニ一
ムベタインなどが例示される。Examples include trialkyl-N-sulfoalkylene ammonium betaine.
両性界面活性剤の配合総重量比％は、３〜４０％であり
、３％以下では起泡力、洗浄力が得られず、４０％以上
では、また起泡力、洗浄力弱く、泡切れが悪くなる。The total weight ratio of the amphoteric surfactant is 3 to 40%; if it is less than 3%, no foaming or cleaning power will be obtained, and if it is more than 40%, the foaming or cleaning power will be weak and the foam will break. becomes worse.
カチオン性界面活性剤としては、第１〜３級脂肪アミン
塩、第４級アンモニウム塩で代表されるテトラアルキル
アンモニウム塩、トリアルキルベンジルアンモニウム塩
、アルキルビリジニウム塩、２−アルキルーｌ−アルキ
ルー１−ヒドロキシエチルイミダゾリニウム塩、Ｎ，
Ｎ−ジアルキルモノフォリニウム塩、ポリエチレンボ
リアミン脂肪酸アミド塩、蛋白質の４級化物、セルロー
スの４級化物等が例示される．カチオン性界面活性剤の
配合総重量比％は、０．４〜６％である．０．４％以下
のカチオン性界面活性剤の配合は、リンス効果が得られ
ない．また、カチオン性界面活性剤の６％以上の配合の
場合は、複合生成物を形成し、系を安定化させることが
出来ず、起泡力、洗浄力、リンス効果も得られなくなる
．
次にポリオキシエチレンアルキルエーテルカルボン酸及
びその塩であるが、皮膚一次刺激、起泡力、洗浄力、泡
切れ等アルキル基中の炭素数が、６〜ｌ８の整数を示し
、直鎖型、イソ型、飽和、不飽和のいずれても良い。エ
チレンオキサイドの付加モル数は３〜１５のモル数を示
す構造の酸型または、ナトリウム、カリウム、アミン塩
等のいずれかの構造で使用される。エチレンオキサイド
の付加モル数が３以下の場合は起泡力が得られず、 １
５以上の場合は、可溶化力が強くなり、マイルド性を失
い、結晶点も高くなる．
ポリオキシエチレンアルキルエーテルカルボン酸及びそ
の塩の配合総重量比％は４〜５０である．この理由は、
４％以下では、カチオン性界面活性剤により起泡力、洗
浄力が阻害される。また、５０％以上では、頭髪へのリ
ンス効果が得られず、目的物を得られない．また、系が
増粘して製造困難となる．
（実施例１〜２、比較例１〜４）
表１に示す洗浄剤組成物を調整し、起泡力、洗浄力、泡
切れ、リンス性、身体でのヌルヌル感の有無を評価した
．
［表−ｌ］
表−１から明らかな様に本発明の洗浄剤組成物は全身用
洗浄剤として優れていた。Examples of cationic surfactants include primary to tertiary fatty amine salts, tetraalkylammonium salts represented by quaternary ammonium salts, trialkylbenzylammonium salts, alkylviridinium salts, 2-alkyl-l-alkyl-1 -hydroxyethylimidazolinium salt, N,
Examples include N-dialkylmonopholinium salts, polyethylenebolyamine fatty acid amide salts, quaternized proteins, and quaternized cellulose. The total weight ratio of the cationic surfactant is 0.4 to 6%. If less than 0.4% of cationic surfactant is added, no rinsing effect can be obtained. Furthermore, if the cationic surfactant is blended in an amount of 6% or more, a composite product is formed, the system cannot be stabilized, and foaming power, detergent power, and rinsing effect cannot be obtained. Next, there are polyoxyethylene alkyl ether carboxylic acids and their salts, and the number of carbon atoms in the alkyl group is an integer of 6 to 18, and the linear type, It may be isoform, saturated or unsaturated. The number of moles of ethylene oxide to be added is either an acid type having a structure in which the number of moles added is 3 to 15, or a structure such as a sodium, potassium, or amine salt. If the number of moles of ethylene oxide added is 3 or less, foaming power cannot be obtained, and 1
If it is 5 or more, the solubilizing power becomes strong, the mildness is lost, and the crystalline point becomes high. The total weight ratio of polyoxyethylene alkyl ether carboxylic acid and its salt is 4 to 50%. The reason for this is
If it is less than 4%, the cationic surfactant inhibits foaming power and detergency. Moreover, if it is more than 50%, the hair rinsing effect cannot be obtained and the desired product cannot be obtained. Additionally, the system becomes thicker, making production difficult. (Examples 1 to 2, Comparative Examples 1 to 4) Cleaning compositions shown in Table 1 were prepared and evaluated for foaming power, cleaning power, foam breakage, rinsability, and presence or absence of a slimy feeling on the body. [Table 1] As is clear from Table 1, the cleaning composition of the present invention was excellent as a whole body cleaning agent.
（以下余白）
ボリオキシエチレンアルキルエーテルカルボン酸につい
て詳細に述べる．エチレンオキサイドの付加モル数が、
３以下の場合、水に対する溶解性が低く、起泡力及び洗
浄力に劣り、又、肌に対しては、洗浄後ヌルヌル感をの
こす．一方、付加モル数が１５以上になると浸透力が強
くなり、良好な起泡力を得られない．又、リンス性も得
られない．
さらに、アルキル基は，炭素数６−１８の整数が好まし
く、６以下の場合は、皮膚に対する刺激性が強くなり、
又、使用後にヌルヌル感が残り、マイルド性が目的であ
る本発明に反する．一方、 １８以上の場合は、起泡力
、洗浄力及び泡切れが悪くなり、処方中において相溶性
も悪くなる。(Left below) We will discuss polyoxyethylene alkyl ether carboxylic acid in detail. The number of moles of ethylene oxide added is
If it is less than 3, the solubility in water is low, the foaming power and cleaning power are poor, and the skin feels slimy after washing. On the other hand, if the number of added moles is 15 or more, the penetrating power becomes strong and good foaming power cannot be obtained. Also, rinsing properties cannot be obtained. Furthermore, the alkyl group preferably has an integer of 6 to 18 carbon atoms, and if it is less than 6, it will be more irritating to the skin.
In addition, a slimy feeling remains after use, which is contrary to the present invention, which aims to provide mild properties. On the other hand, if it is 18 or more, the foaming power, detergency, and foam removal will be poor, and the compatibility in the formulation will also be poor.
（実施例３、比較例５〜９）
表２に示す洗浄剤組成物を：ｌｌ！ＩＬ／、起泡力、洗
浄力、泡切れ、リンス性及び身体でのヌルヌル感の有無
を評価した．
［表−２］
表−２から明らかな様に本発明の洗浄剤組成物は全身用
洗浄剤として優れていた．（以下余白〉(Example 3, Comparative Examples 5 to 9) The cleaning composition shown in Table 2: ll! IL/, foaming power, detergency, foam removal, rinsability, and presence or absence of a slimy feeling on the body were evaluated. [Table 2] As is clear from Table 2, the cleaning composition of the present invention was excellent as a whole body cleaning agent. (Margin below)
Claims (1)
般式（ I ）で表わされるポリオキシエチレンアルキル
エーテルカルボン酸またはそのナトリウム、カリウム、
アンモニウム化合物を必須成分として含有し、三種の界
面活性剤の合計重量が８−８０％である洗浄剤組成物。 ２、両性界面活性剤を重量％で３〜４０、カチオン性界
面活性剤を重量％で０．４〜６、及びポリオキシエチレ
ンアルキルエーテルカルボン酸または、そのナトリウム
、カリウム、アンモニウム化合物を重量％で４〜５０％
含有することを特徴とする洗浄剤組成物。 （ I ）Ｃ＿ｎＨ＿ｍ−Ｏ（ＣＨ＿２ＣＨ＿２Ｏ）＿ｘ
ＣＨ＿２ＣＯＯＨ（但し式中のｎは６〜１８の整数、 ｍは１１〜３７の整数、ｘは３〜１５のモル数を表す。[Claims] 1. An amphoteric surfactant, a cationic surfactant, and a polyoxyethylene alkyl ether carboxylic acid represented by the following general formula (I) or its sodium, potassium,
A cleaning composition containing an ammonium compound as an essential component and having a total weight of three surfactants of 8-80%. 2. Amphoteric surfactant in weight% of 3 to 40, cationic surfactant in weight% of 0.4 to 6, and polyoxyethylene alkyl ether carboxylic acid or its sodium, potassium, ammonium compound as weight%. 4-50%
A cleaning composition comprising: (I)C_nH_m-O(CH_2CH_2O)_x
CH_2COOH (where n in the formula is an integer of 6 to 18, m is an integer of 11 to 37, and x represents the number of moles of 3 to 15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1240950A JPH03103500A (en) | 1989-09-18 | 1989-09-18 | Detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1240950A JPH03103500A (en) | 1989-09-18 | 1989-09-18 | Detergent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03103500A true JPH03103500A (en) | 1991-04-30 |
Family
ID=17067066
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1240950A Pending JPH03103500A (en) | 1989-09-18 | 1989-09-18 | Detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03103500A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06122893A (en) * | 1992-10-13 | 1994-05-06 | Toyo Beauty Kk | Detergent composition |
| WO2013031898A1 (en) * | 2011-09-02 | 2013-03-07 | 花王株式会社 | Skin cleanser composition |
| WO2013031899A1 (en) * | 2011-09-02 | 2013-03-07 | 花王株式会社 | Skin cleanser composition |
| JPWO2016093291A1 (en) * | 2014-12-11 | 2017-09-21 | 花王株式会社 | Skin cosmetic and skin care method |
| JP2021521233A (en) * | 2018-04-16 | 2021-08-26 | カオウ・コーポレイション・エセ・ア | Cosmetic composition |
-
1989
- 1989-09-18 JP JP1240950A patent/JPH03103500A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06122893A (en) * | 1992-10-13 | 1994-05-06 | Toyo Beauty Kk | Detergent composition |
| WO2013031898A1 (en) * | 2011-09-02 | 2013-03-07 | 花王株式会社 | Skin cleanser composition |
| WO2013031899A1 (en) * | 2011-09-02 | 2013-03-07 | 花王株式会社 | Skin cleanser composition |
| JP2013053092A (en) * | 2011-09-02 | 2013-03-21 | Kao Corp | Skin cleanser composition |
| JP2013053093A (en) * | 2011-09-02 | 2013-03-21 | Kao Corp | Skin cleanser composition |
| EP2752185A1 (en) * | 2011-09-02 | 2014-07-09 | Kao Corporation | Skin cleanser composition |
| EP2752185A4 (en) * | 2011-09-02 | 2015-03-25 | Kao Corp | Skin cleanser composition |
| EP2752186A4 (en) * | 2011-09-02 | 2015-05-27 | Kao Corp | Skin cleanser composition |
| US9522105B2 (en) | 2011-09-02 | 2016-12-20 | Kao Corporation | Skin cleansing composition |
| JPWO2016093291A1 (en) * | 2014-12-11 | 2017-09-21 | 花王株式会社 | Skin cosmetic and skin care method |
| JP2021521233A (en) * | 2018-04-16 | 2021-08-26 | カオウ・コーポレイション・エセ・ア | Cosmetic composition |
| US11826450B2 (en) | 2018-04-16 | 2023-11-28 | Kao Corporation S.A. | Cosmetic compositions |
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